Identifiers | |
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3D model (JSmol) | |
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Properties | |
Ca2O4Ru | |
Molar mass | 245.22 g·mol−1 |
Related compounds | |
Other cations | Distrontium ruthenate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Dicalcium ruthenate, with the chemical formula Ca2RuO4, is a stochiometric oxide compound that hosts a multi-orbital (band) Mott insulating ground state. For this reason, Ca2RuO4 serves as an important "meeting-point" between conceptual developments [1] [2] of strongly correlated multi-band physics and advanced experimental spectroscopies. [3] [4] Its electronic structure and also orbital magnetism are therefore subjects of experimental and theoretical scrutiny.
Around 350 K, Ca2RuO4 undergoes a metal insulator transition which involves a crystal structure transition leading to a strong c-axis compression. Negative thermal expansion has also been reported in conjunction with this c-axis compression. [5] The metal insulator transition is sensitive to electrical current. [6] [7] Below 80 K, an anti-ferromagnetic ordering emerges.
Ca1.8Sr0.2RuO4 has been proposed as a candidate system for orbital selective Mott physics. [8] The bilayer compound Ca3Ru2O7 is metallic, but display a sequence of electronic transitions below 60 K. Finally, Sr2RuO4 hosts an unconventional superconducting state. [9]
A Rydberg atom is an excited atom with one or more electrons that have a very high principal quantum number, n. The higher the value of n, the farther the electron is from the nucleus, on average. Rydberg atoms have a number of peculiar properties including an exaggerated response to electric and magnetic fields, long decay periods and electron wavefunctions that approximate, under some conditions, classical orbits of electrons about the nuclei. The core electrons shield the outer electron from the electric field of the nucleus such that, from a distance, the electric potential looks identical to that experienced by the electron in a hydrogen atom.
Mott insulators are a class of materials that are expected to conduct electricity according to conventional band theories, but turn out to be insulators. These insulators fail to be correctly described by band theories of solids due to their strong electron–electron interactions, which are not considered in conventional band theory. A Mott transition is a transition from a metal to an insulator, driven by the strong interactions between electrons. One of the simplest models that can capture Mott transition is the Hubbard model.
A quantum critical point is a point in the phase diagram of a material where a continuous phase transition takes place at absolute zero. A quantum critical point is typically achieved by a continuous suppression of a nonzero temperature phase transition to zero temperature by the application of a pressure, field, or through doping. Conventional phase transitions occur at nonzero temperature when the growth of random thermal fluctuations leads to a change in the physical state of a system. Condensed matter physics research over the past few decades has revealed a new class of phase transitions called quantum phase transitions which take place at absolute zero. In the absence of the thermal fluctuations which trigger conventional phase transitions, quantum phase transitions are driven by the zero point quantum fluctuations associated with Heisenberg's uncertainty principle.
A topological insulator is a material whose interior behaves as an electrical insulator while its surface behaves as an electrical conductor, meaning that electrons can only move along the surface of the material.
Resonant inelastic X-ray scattering (RIXS) is an advanced X-ray spectroscopy technique.
Piers Coleman is a British-born theoretical physicist, working in the field of theoretical condensed matter physics. Coleman is professor of physics at Rutgers University in New Jersey and at Royal Holloway, University of London.
Distrontium ruthenate, also known as strontium ruthenate, is an oxide of strontium and ruthenium with the chemical formula Sr2RuO4. It was the first reported perovskite superconductor that did not contain copper. Strontium ruthenate is structurally very similar to the high-temperature cuprate superconductors, and in particular, is almost identical to the lanthanum doped superconductor (La, Sr)2CuO4. However, the transition temperature for the superconducting phase transition is 0.93 K (about 1.5 K for the best sample), which is much lower than the corresponding value for cuprates.
In condensed matter physics, a time crystal is a quantum system of particles whose lowest-energy state is one in which the particles are in repetitive motion. The system cannot lose energy to the environment and come to rest because it is already in its quantum ground state. Time crystals were first proposed theoretically by Frank Wilczek in 2012 as a time-based analogue to common crystals – whereas the atoms in crystals are arranged periodically in space, the atoms in a time crystal are arranged periodically in both space and time. Several different groups have demonstrated matter with stable periodic evolution in systems that are periodically driven. In terms of practical use, time crystals may one day be used as quantum computer memory.
A hidden state of matter is a state of matter which cannot be reached under ergodic conditions, and is therefore distinct from known thermodynamic phases of the material. Examples exist in condensed matter systems, and are typically reached by the non-ergodic conditions created through laser photo excitation. Short-lived hidden states of matter have also been reported in crystals using lasers. Recently a persistent hidden state was discovered in a crystal of Tantalum(IV) sulfide (TaS2), where the state is stable at low temperatures. A hidden state of matter is not to be confused with hidden order, which exists in equilibrium, but is not immediately apparent or easily observed.
Dimitri Roditchev is a French physicist of Russian-Ukrainian origin, specializing in electronic properties of nano-materials, superconductors, electron transport, and quantum tunneling phenomena. He is a professor at ESPCI ParisTech and a research director at CNRS.
In physics, Dirac cones are features that occur in some electronic band structures that describe unusual electron transport properties of materials like graphene and topological insulators. In these materials, at energies near the Fermi level, the valence band and conduction band take the shape of the upper and lower halves of a conical surface, meeting at what are called Dirac points.
In condensed matter physics, the quantum dimer magnet state is one in which quantum spins in a magnetic structure entangle to form a singlet state. These entangled spins act as bosons and their excited states (triplons) can undergo Bose-Einstein condensation (BEC). The quantum dimer system was originally proposed by Matsubara and Matsuda as a mapping of the lattice Bose gas to the quantum antiferromagnet. Quantum dimer magnets are often confused as valence bond solids; however, a valence bond solid requires the breaking of translational symmetry and the dimerizing of spins. In contrast, quantum dimer magnets exist in crystal structures where the translational symmetry is inherently broken. There are two types of quantum dimer models: the XXZ model and the weakly-coupled dimer model. The main difference is the regime in which BEC can occur. For the XXZ model, the BEC occurs upon cooling without a magnetic field and manifests itself as a symmetric dome in the field versus temperature phase diagram centered about H = 0. The weakly-coupled dimer model does not magnetically order in zero magnetic field, but instead orders upon the closing of the spin gap, where the BEC regime begins and is a dome centered at non-zero field.
Many-body localization (MBL) is a dynamical phenomenon occurring in isolated many-body quantum systems. It is characterized by the system failing to reach thermal equilibrium, and retaining a memory of its initial condition in local observables for infinite times.
John F. Mitchell is an American chemist and researcher. He is the deputy director of the materials science division at the U.S. Department of Energy's (DOE) Argonne National Laboratory and leads Argonne's Emerging Materials Group.
An electron-on-helium qubit is a quantum bit for which the orthonormal basis states |0⟩ and |1⟩ are defined by quantized motional states or alternatively the spin states of an electron trapped above the surface of liquid helium. The electron-on-helium qubit was proposed as the basic element for building quantum computers with electrons on helium by Platzman and Dykman in 1999.
Bogdan Andrei Bernevig is a Romanian Quantum Condensed Matter Professor of Physics at Princeton University and the recipient of the John Simon Guggenheim Fellowship in 2017.
Gang Cao is an American condensed matter physicist, academic, author, and researcher. He is a professor of physics at the University of Colorado Boulder. and Director of Center for Experiments on Quantum Materials.
Alexander Avraamovitch Golubov is a doctor of physical and mathematical sciences, associate professor at the University of Twente (Netherlands). He specializes in condensed matter physics with the focus on theory of electronic transport in superconducting devices. He made key contributions to theory of Josephson effect in novel superconducting materials and hybrid structures, and to theory of multiband superconductivity.
Shuyun Zhou is a Chinese physicist and a tenured professor of physics at Tsinghua University. She is the distinguished Professor of the 2017 "Cheung Kong Scholars" of the Ministry of Education of the People's Republic of China, and won the 13th "China Young Women Scientists Award".
Fractional Chern insulators (FCIs) are lattice generalizations of the fractional quantum Hall effect that have been studied theoretically since 1993 and have been studied more intensely since early 2010. They were first predicted to exist in topological flat bands carrying Chern numbers. They can appear in topologically non-trivial band structures even in the absence of the large magnetic fields needed for the fractional quantum Hall effect. In principle, they can also occur in partially filled bands with trivial band structures if the inter-electron interaction is unusual. They promise physical realizations at lower magnetic fields, higher temperatures, and with shorter characteristic length scales compared to their continuum counterparts. FCIs were initially studied by adding electron-electron interactions to a fractionally filled Chern insulator, in one-body models where the Chern band is quasi-flat, at zero magnetic field. The FCIs exhibit a fractional quantized Hall conductance.