Ytterbium(III) phosphide

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Ytterbium(III) phosphide
Names
Other names
Phosphanylidyneytterbium
Identifiers
3D model (JSmol)
EC Number
  • 234-865-2
  • InChI=1S/P.Yb
    Key: SYXPIBUUJXGISU-UHFFFAOYSA-N
  • P#[Yb]
Properties
PYb
Molar mass 204.01
AppearanceBlack crystals
Density 6.94 g/cm3
Insoluble
Structure
Cubic
Related compounds
Other anions
Ytterbium nitride
Ytterbium arsenide
Ytterbium antimonide
Other cations
Thulium phosphide
Lutetium phosphide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Ytterbium(III) phosphide is an inorganic compound of ytterbium and phosphorus with the chemical formula YbP. [1] This is one of the phosphides of ytterbium. [2] [3]

Contents

Synthesis

Ytterbium and phosphine reacts in liquid ammonia to form Yb(PH2)2·5NH3, which can be decomposed to obtain ytterbium(III) phosphide: [4]

Yb(PH2)2•5NH3 → Yb(PH2)2 + 5NH3
2Yb(PH2)2 → YbP + 2PH3 + H2

Physical properties

Ytterbium(III) phosphide decomposes at or above 550 °C:

12 YbP → 4 Yb3P2 + P4

It is soluble in hydrochloric acid, nitric acid, and aqua regia.

The compound forms black crystals of a cubic system, space group Fm3m. [5]

Uses

The ytterbium(III) phosphide compound is a semiconductor used in high power, high frequency applications and in laser and other photo diodes. [1]

Related Research Articles

<span class="mw-page-title-main">Ammonia</span> Chemical compound

Ammonia is an inorganic chemical compound of nitrogen and hydrogen with the formula NH3. A stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous waste, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to fertilisers. Around 70% of ammonia produced industrially is used to make fertilisers in various forms and composition, such as urea and diammonium phosphate. Ammonia in pure form is also applied directly into the soil.

Urea, also called carbamide, is an organic compound with chemical formula CO(NH2)2. This amide has two amino groups joined by a carbonyl functional group. It is thus the simplest amide of carbamic acid.

<span class="mw-page-title-main">Ytterbium</span> Chemical element, symbol Yb and atomic number 70

Ytterbium is a chemical element; it has symbol Yb and atomic number 70. It is a metal, the fourteenth and penultimate element in the lanthanide series, which is the basis of the relative stability of its +2 oxidation state. Like the other lanthanides, its most common oxidation state is +3, as in its oxide, halides, and other compounds. In aqueous solution, like compounds of other late lanthanides, soluble ytterbium compounds form complexes with nine water molecules. Because of its closed-shell electron configuration, its density, melting point and boiling point are much lower than those of most other lanthanides.

<span class="mw-page-title-main">Phosphine</span> Chemical compound hydrogen phosphide

Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula PH3, classed as a pnictogen hydride. Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane (P2H4). With traces of P2H4 present, PH3 is spontaneously flammable in air (pyrophoric), burning with a luminous flame. Phosphine is a highly toxic respiratory poison, and is immediately dangerous to life or health at 50 ppm. Phosphine has a trigonal pyramidal structure.

<span class="mw-page-title-main">Indium phosphide</span> Chemical compound

Indium phosphide (InP) is a binary semiconductor composed of indium and phosphorus. It has a face-centered cubic ("zincblende") crystal structure, identical to that of GaAs and most of the III-V semiconductors.

<span class="mw-page-title-main">Ytterbium(III) oxide</span> Chemical compound

Ytterbium(III) oxide is the chemical compound with the formula Yb2O3. It is one of the more commonly encountered compounds of ytterbium. It occurs naturally in trace amounts in the mineral gadolinite. It was first isolated from this in 1878 by Jean Charles Galissard de Marignac.

<span class="mw-page-title-main">Lutetium(III) oxide</span> Chemical compound

Lutetium(III) oxide, a white solid, is a cubic compound of lutetium sometimes used in the preparation of specialty glasses. It is also called lutecia. It is a lanthanide oxide, also known as a rare earth.

<span class="mw-page-title-main">Yttrium phosphide</span> Chemical compound

Yttrium phosphide is an inorganic compound of yttrium and phosphorus with the chemical formula YP. The compound may be also classified as yttrium(III) phosphide.

<span class="mw-page-title-main">Ytterbium(III) nitrate</span> Chemical compound

Ytterbium(III) nitrate is an inorganic compound, a salt of ytterbium and nitric acid with the chemical formula Yb(NO3)3. The compound forms colorless crystals, dissolves in water, and also forms crystalline hydrates.

Lutetium phosphide is an inorganic compound of lutetium and phosphorus with the chemical formula LuP. The compound forms dark crystals, does not dissolve in water.

Neodymium phosphide is an inorganic compound of neodymium and phosphorus with the chemical formula NdP.

Europium phosphide is an inorganic compound of europium and phosphorus with the chemical formula EuP. Other phosphides are also known.

Samarium(III) phosphide is an inorganic compound of samarium and phosphorus with the chemical formula SmP.

Thulium phosphide is an inorganic compound of thulium and phosphorus with the chemical formula TmP.

Holmium phosphide is a binary inorganic compound of holmium and phosphorus with the chemical formula HoP. The compound forms dark crystals and does not dissolve in water.

Dysprosium phosphide is an inorganic compound of dysprosium and phosphorus with the chemical formula DyP.

<span class="mw-page-title-main">Europium compounds</span> Compounds with at least one europium atom

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

Erbium compounds are compounds containing the element erbium (Er). These compounds are usually dominated by erbium in the +3 oxidation state, although the +2, +1 and 0 oxidation states have also been reported.

Ytterbium compounds are chemical compounds that contain the element ytterbium (Yb). The chemical behavior of ytterbium is similar to that of the rest of the lanthanides. Most ytterbium compounds are found in the +3 oxidation state, and its salts in this oxidation state are nearly colorless. Like europium, samarium, and thulium, the trihalides of ytterbium can be reduced to the dihalides by hydrogen, zinc dust, or by the addition of metallic ytterbium. The +2 oxidation state occurs only in solid compounds and reacts in some ways similarly to the alkaline earth metal compounds; for example, ytterbium(II) oxide (YbO) shows the same structure as calcium oxide (CaO).

Ytterbium(II) sulfide is a binary inorganic compound of ytterbium and sulfur with the chemical formula YbS.

References

  1. 1 2 "Ytterbium Phosphide". American Elements . Retrieved 21 December 2021.
  2. Shur, Michael S.; Levinshtein, Michael E. (8 December 1995). Best Of Soviet Semiconductor Physics And Technology (1989-1990). World Scientific. p. 384. ISBN   978-981-4502-62-7 . Retrieved 21 December 2021.
  3. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. U.S. Government Printing Office. 1979. p. 90. Retrieved 21 December 2021.
  4. Pytlewski, L. L.; Howell, J. K. (1 January 1967). "Preparation of Europium and ytterbium phosphides in liquid ammonia". Chemical Communications (24): 1280. doi:10.1039/C19670001280 . Retrieved 21 December 2021.
  5. "mp-2390: YbP (cubic, Fm-3m, 225)". materialsproject.org . Retrieved 21 December 2021.