Ytterbium(III) iodide

Last updated
Ytterbium(III) iodide
Kristallstruktur Bismut(III)-iodid.png
Names
Other names
Ytterbium triiodide
Ytterbium iodide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.053 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 237-474-5
PubChem CID
  • InChI=1S/3HI.Yb/h3*1H;/q;;;+3/p-3
    Key: LSSJSIMBIIVSTN-UHFFFAOYSA-K
  • [I-].[I-].[I-].[Yb+3]
Properties
YbI3
Appearanceyellow crystals [1]
Melting point 700 °C (1,292 °F; 973 K) decomposes [1]
soluble [1]
Hazards
GHS labelling: [2]
GHS-pictogram-exclam.svg
Warning
H315, H319, H335
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Ytterbium(III) iodide is one of ytterbium's iodides, with the chemical formula of YbI3.

Contents

Preparation

Ytterbium(III) iodide can be prepared by reacting metallic ytterbium with iodine at 500°C with a 30 atm pressure: [3]

2 Yb + 3 I2 → 2 YbI3

Ytterbium(III) oxide, ytterbium(III) hydroxide or ytterbium(III) carbonate can react with hydroiodic acid to obtain ytterbium(III) iodide in aqueous solution:

Yb2O3 + 6 HI → 2 YbI3 + 3 H2O
Yb(OH)3 + 3 HI → YbI3 + 3 H2O
Yb2(CO3)3 + 6 HI → 2 YbI3 + 3 H2O + 3 CO2

The ytterbium(III) iodide hydrate crystallized from the solution can be heated with ammonium iodide to obtain the anhydrous form. [4]

Reactions

Ytterbium(III) iodide decomposes to ytterbium(II) iodide upon heating: [5]

2 YbI3 → 2 YbI2 + I2

Related Research Articles

<span class="mw-page-title-main">Ytterbium</span> Chemical element, symbol Yb and atomic number 70

Ytterbium is a chemical element; it has symbol Yb and atomic number 70. It is a metal, the fourteenth and penultimate element in the lanthanide series, which is the basis of the relative stability of its +2 oxidation state. Like the other lanthanides, its most common oxidation state is +3, as in its oxide, halides, and other compounds. In aqueous solution, like compounds of other late lanthanides, soluble ytterbium compounds form complexes with nine water molecules. Because of its closed-shell electron configuration, its density, melting point and boiling point are much lower than those of most other lanthanides.

<span class="mw-page-title-main">Samarium(II) iodide</span> Chemical compound

Samarium(II) iodide is an inorganic compound with the formula SmI2. When employed as a solution for organic synthesis, it is known as Kagan's reagent. SmI2 is a green solid and solutions are green as well. It is a strong one-electron reducing agent that is used in organic synthesis.

<span class="mw-page-title-main">Hydrogen iodide</span> Chemical compound

Hydrogen iodide (HI) is a diatomic molecule and hydrogen halide. Aqueous solutions of HI are known as hydroiodic acid or hydriodic acid, a strong acid. Hydrogen iodide and hydroiodic acid are, however, different in that the former is a gas under standard conditions, whereas the other is an aqueous solution of the gas. They are interconvertible. HI is used in organic and inorganic synthesis as one of the primary sources of iodine and as a reducing agent.

Iodometry, known as iodometric titration, is a method of volumetric chemical analysis, a redox titration where the appearance or disappearance of elementary iodine indicates the end point.

Terbium(III) iodide (TbI3) is an inorganic chemical compound.

<span class="mw-page-title-main">Tellurium tetraiodide</span> Chemical compound

Tellurium tetraiodide (TeI4) is an inorganic chemical compound. It has a tetrameric structure which is different from the tetrameric solid forms of TeCl4 and TeBr4. In TeI4 the Te atoms are octahedrally coordinated and edges of the octahedra are shared.

<span class="mw-page-title-main">Germanium(II) iodide</span> Chemical compound

Germanium(II) iodide is an iodide of germanium, with the chemical formula of GeI2.

Iron(III) iodide is an inorganic compound with the chemical formula FeI3. It is a thermodynamically unstable compound that is difficult to prepare. Nevertheless, iron(III) iodide has been synthesised in small quantities in the absence of air and water.

<span class="mw-page-title-main">Praseodymium(III) iodide</span> Chemical compound

Praseodymium(III) iodide is an inorganic salt, consisting of the rare-earth metal praseodymium and iodine, with the chemical formula PrI3. It forms green crystals. It is soluble in water.

<span class="mw-page-title-main">Europium compounds</span> Compounds with at least one europium atom

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

<span class="mw-page-title-main">Lanthanum(III) iodide</span> Chemical compound

Lanthanum(III) iodide is an inorganic compound containing lanthanum and iodine with the chemical formula LaI
3
.

Europium(III) iodide is an inorganic compound containing europium and iodine with the chemical formula EuI3.

<span class="mw-page-title-main">Lutetium(III) iodide</span> Chemical compound

Lutetium(III) iodide or lutetium iodide is an inorganic compound consisting of iodine and lutetium, with the chemical formula of LuI3.

<span class="mw-page-title-main">Gadolinium(III) iodide</span> Chemical compound

Gadolinium(III) iodide is an iodide of gadolinium, with the chemical formula of GdI3. It is a yellow, highly hygroscopic solid with a bismuth(III) iodide-type crystal structure. In air, it quickly absorbs moisture and forms hydrates. The corresponding oxide iodide is also readily formed at elevated temperature.

<span class="mw-page-title-main">Thulium(III) iodide</span> Chemical compound

Thulium(III) iodide is an iodide of thulium, with the chemical formula of TmI3. Thulium(III) iodide is used as a component of metal halide lamps.

<span class="mw-page-title-main">Holmium(III) iodide</span> Chemical compound

Holmium(III) iodide is an iodide of holmium, with the chemical formula of HoI3. It is used as a component of metal halide lamps.

Ytterbium compounds are chemical compounds that contain the element ytterbium (Yb). The chemical behavior of ytterbium is similar to that of the rest of the lanthanides. Most ytterbium compounds are found in the +3 oxidation state, and its salts in this oxidation state are nearly colorless. Like europium, samarium, and thulium, the trihalides of ytterbium can be reduced to the dihalides by hydrogen, zinc dust, or by the addition of metallic ytterbium. The +2 oxidation state occurs only in solid compounds and reacts in some ways similarly to the alkaline earth metal compounds; for example, ytterbium(II) oxide (YbO) shows the same structure as calcium oxide (CaO).

Lutetium compounds are compounds formed by the lanthanide metal lutetium (Lu). In these compounds, lutetium generally exhibits the +3 oxidation state, such as LuCl3, Lu2O3 and Lu2(SO4)3. Aqueous solutions of most lutetium salts are colorless and form white crystalline solids upon drying, with the common exception of the iodide. The soluble salts, such as nitrate, sulfate and acetate form hydrates upon crystallization. The oxide, hydroxide, fluoride, carbonate, phosphate and oxalate are insoluble in water.

<span class="mw-page-title-main">Ytterbium(II) iodide</span> Chemical compound

Ytterbium(II) iodide is an iodide of ytterbium, with the chemical formula of YbI2. It is a yellow solid.

<span class="mw-page-title-main">Thulium(II) iodide</span> Chemical compound

Thulium diiodide is an inorganic compound with the chemical formula TmI2.

References

  1. 1 2 3 Lide, David R., ed. (2009). CRC Handbook of Chemistry and Physics (90th ed.). Boca Raton, Florida: CRC Press. pp. 4–99. ISBN   978-1-4200-9084-0.
  2. "Ytterbium iodide (YbI3)". pubchem.ncbi.nlm.nih.gov.
  3. Asprey, L. B.; Keenan, T. K.; Kruse, F. H. Preparation and crystal data for lanthanide and actinide triiodides. Inorg. Chem., 1964. 3 (8): 1137-1240
  4. 无机化学丛书 第七卷 钪 稀土元素. 科学出版社. pp 211
  5. G. Jantsch, N. Skalla, H. Jawurek (1931-11-10). "Zur Kenntnis der Halogenide der seltenen Erden. V. Über die Halogenide des Ytterbiums". Zeitschrift für anorganische und allgemeine Chemie. 201 (1): 207–220. doi:10.1002/zaac.19312010119 . Retrieved 2022-09-15.{{cite journal}}: CS1 maint: multiple names: authors list (link)