Thulium(III) bromide

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Thulium(III) bromide
Names
IUPAC name
Tribromothulium
Identifiers
3D model (JSmol)
ECHA InfoCard 100.034.934 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 238-444-4
PubChem CID
  • InChI=1S/3BrH.Tm/h3*1H;/q;;;+3/p-3
    Key: HQSWGSFQSCMHFQ-UHFFFAOYSA-K
  • [Tm+3].[Br-].[Br-].[Br-]
Properties
TmBr3
Molar mass 408.65 [1]
AppearanceWhite crystalline solid
Melting point 952 °C (1,746 °F; 1,225 K) [1]
Boiling point 1,440 °C (2,620 °F; 1,710 K) [1]
Soluble [2]
Hazards
GHS labelling:
GHS-pictogram-exclam.svg
Warning
H315, H319, H335 [3]
P261, P305+P351+P338 [3] P264, P271, P280, P302+P352, P304+P340, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501 [4]
NFPA 704 (fire diamond)
2
0
0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Thulium(III) bromide is a crystalline compound of one thulium atom and three bromine atoms. [5] The salt is a white powder at room temperature. [1] It is hygroscopic. [6]

Usage

Thulium(III) bromide is used as a reagent for the complexation of lanthanide bromides with aluminium bromide, and as a reactant for preparing alkali metal thulium bromides. [2] It is also used to create discharge lamps that are free of mercury. [7]

Related Research Articles

Atomic absorption spectroscopy Type of spectroanalytical procedure

Atomic absorption spectroscopy (AAS) and atomic emission spectroscopy (AES) is a spectroanalytical procedure for the quantitative determination of chemical elements using the absorption of optical radiation (light) by free atoms in the gaseous state. Atomic absorption spectroscopy is based on absorption of light by free metallic ions.

Bromine Chemical element, symbol Br and atomic number 35

Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest halogen and is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig and Antoine Jérôme Balard, its name was derived from the Ancient Greek βρῶμος, referring to its sharp and pungent smell.

Halogen Group of chemical elements

The halogens are a group in the periodic table consisting of five or six chemically related elements: fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and astatine (At). The artificially created element 117, tennessine (Ts), may also be a halogen. In the modern IUPAC nomenclature, this group is known as group 17.

Holmium Chemical element, symbol Ho and atomic number 67

Holmium is a chemical element with the symbol Ho and atomic number 67. It is a rare-earth element and the eleventh member of the lanthanide series. It is a relatively soft, silvery, fairly corrosion-resistant and malleable metal. Like a lot of other lanthanides, holmium is too reactive to be found in native form, as pure holmium slowly forms a yellowish oxide coating when exposed to air. When isolated, holmium is relatively stable in dry air at room temperature. However, it reacts with water and corrodes readily, and also burns in air when heated.

Thulium Chemical element, symbol Tm and atomic number 69

Thulium is a chemical element with the symbol Tm and atomic number 69. It is the thirteenth and third-last element in the lanthanide series. Like the other lanthanides, the most common oxidation state is +3, seen in its oxide, halides and other compounds; however, the +2 oxidation state can also be stable. In aqueous solution, like compounds of other late lanthanides, soluble thulium compounds form coordination complexes with nine water molecules.

Thallium Chemical element, symbol Tl and atomic number 81

Thallium is a chemical element with the symbol Tl and atomic number 81. It is a gray post-transition metal that is not found free in nature. When isolated, thallium resembles tin, but discolors when exposed to air. Chemists William Crookes and Claude-Auguste Lamy discovered thallium independently in 1861, in residues of sulfuric acid production. Both used the newly developed method of flame spectroscopy, in which thallium produces a notable green spectral line. Thallium, from Greek θαλλός, thallós, meaning "green shoot" or "twig", was named by Crookes. It was isolated by both Lamy and Crookes in 1862; Lamy by electrolysis, and Crookes by precipitation and melting of the resultant powder. Crookes exhibited it as a powder precipitated by zinc at the international exhibition, which opened on 1 May that year.

In chemistry, a halide is a binary chemical compound, of which one part is a halogen atom and the other part is an element or radical that is less electronegative than the halogen, to make a fluoride, chloride, bromide, iodide, astatide, or theoretically tennesside compound. The alkali metals combine directly with halogens under appropriate conditions forming halides of the general formula, MX. Many salts are halides; the hal- syllable in halide and halite reflects this correlation. All Group 1 metals form halides that are white solids at room temperature.

Mercury(I) bromide or mercurous bromide is the chemical compound composed of mercury and bromine with the formula Hg2Br2. It changes color from white to yellow when heated and fluoresces a salmon color when exposed to ultraviolet light. It has applications in acousto-optical devices.

Praseodymium(III) bromide is a crystalline compound of one praseodymium atom and three bromine atoms.

Neodymium(III) bromide Chemical compound

Neodymium(III) bromide is an inorganic salt of bromine and neodymium the formula NdBr3. The anhydrous compound is an off-white to pale green solid at room temperature, with an orthorhombic PuBr3-type crystal structure. The material is hydroscopic and forms a hexahydrate in water (NdBr3· 6H2O), similar to the related neodymium(III) chloride.

Samarium(III) bromide is a crystalline compound of one samarium and three bromine atoms with the chemical formula of SmBr3. Samarium(III) bromide is a dark brown powder at room temperature. The compound has a crystal structure isotypic to that of plutonium(III) bromide.

Europium(II) bromide Chemical compound

Europium(II) bromide is a crystalline compound of one europium atom and two bromine atoms. Europium(II) bromide is a white powder at room temperature, and odorless. Europium dibromide is hygroscopic.

Europium(III) bromide is a crystalline compound, a salt, made of one europium and three bromine atoms. Europium tribromide is a grey powder at room temperature. It is odorless. Europium tribromide is hygroscopic.

Gadolinium(III) bromide is a crystalline compound of gadolinium atoms and three bromine atoms. This salt is hygroscopic.

Holmium(III) bromide is a crystalline compound made of one holmium atom and three bromine atoms. Holmium bromide is a yellow powder at room temperature. Holmium bromide is hygroscopic. Holmium bromide is odorless.

Lutetium(III) bromide is a crystalline compound made of one lutetium atom and three bromine atoms. It takes the form of a white powder at room temperature. It is hygroscopic. It is odorless.

Cerium(III) iodide (CeI3) is the compound formed by cerium(III) cations and iodide anions.

Thulium(III) nitrate Chemical compound

Thulium(III) nitrate is an inorganic compound, a salt of thulium and nitric acid with the chemical formula Tm(NO3)3. The compound forms dark-green crystals, readily soluble in water, also forms crystalline hydrates.

Thulium(III) iodide Chemical compound

Thulium(III) iodide is an iodide of thulium, with the chemical formula of TmI3. Thulium(III) iodide is used as a component of metal halide lamps.

Holmium(III) iodide Chemical compound

Holmium(III) iodide is an iodide of holmium, with the chemical formula of HoI3. It is used as a component of metal halide lamps.

References

  1. 1 2 3 4 Elements, American. "Thulium Bromide". American Elements. Retrieved 21 December 2016.
  2. 1 2 "14456-51-0 - Thulium(III) bromide, ultra dry, 99.99% (REO) - 47196 - Alfa Aesar". www.alfa.com. Retrieved 21 December 2016.
  3. 1 2 "Thulium(III) bromide anhydrous, powder, 99.99% | Sigma-Aldrich". www.sigmaaldrich.com. Retrieved 21 December 2016.
  4. "Thulium bromide | Br3Tm - PubChem". pubchem.ncbi.nlm.nih.gov. Retrieved 21 December 2016.
  5. Phillips, Sidney L.; Perry, Dale L. (1995). Handbook of inorganic compounds. Boca Raton: CRC Press. p. 415. ISBN   9780849386718.
  6. "THULIUM BROMIDE | 14456-51-0". www.chemicalbook.com. Retrieved 21 December 2016.
  7. Kashiwagi, Takahito; Ishida, Masazumi; Matsuda, Mikio; Uemura, Kozo (2007). "Mercury-free high-pressure discharge lamp and luminaire using the same" . Retrieved 21 December 2016.