Magnesium bromide

Last updated
Magnesium bromide [1]
Magnesium-bromide-xtal-layer-3D-bs-17.png
Magnesium-bromide-xtal-3D-bs-17.png
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.246 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
UNII
  • InChI=1S/2BrH.Mg/h2*1H;/q;;+2/p-2 Yes check.svgY
    Key: OTCKOJUMXQWKQG-UHFFFAOYSA-L Yes check.svgY
  • InChI=1/2BrH.Mg/h2*1H;/q;;+2/p-2
    Key: OTCKOJUMXQWKQG-NUQVWONBAY
  • [Mg+2].[Br-].[Br-]
Properties
  • MgBr2 (anhydrous)
  • MgBr2·6H2O (hexahydrate)
Molar mass 184.113 g/mol (anhydrous)
292.204 g/mol (hexahydrate)
Appearancewhite hygroscopic hexagonal crystals (anhydrous)
colorless monoclinic crystals (hexahydrate)
Density 3.72 g/cm3 (anhydrous)
2.07 g/cm3 (hexahydrate)
Melting point 711 °C (1,312 °F; 984 K) 172.4 °C, decomposes (hexahydrate)
Boiling point 1,250 °C (2,280 °F; 1,520 K)
102 g/(100 mL) (anhydrous)
316 g/(100 mL) (0 °C, hexahydrate)
Solubility ethanol: 6.9 g/(100 mL)
methanol: 21.8 g/(100 mL)
−72.0·10−6 cm3/mol
Structure
Rhombohedral, hP3
P-3m1, No. 164
octahedral
Thermochemistry
70 J/(mol·K)
Std molar
entropy
(S298)
117.2 J/(mol·K)
−524.3 kJ/mol
Hazards
NFPA 704 (fire diamond)
NFPA 704.svgHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
0
0
Safety data sheet (SDS) External SDS
Related compounds
Other anions
Other cations
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
X mark.svgN  verify  (what is  Yes check.svgYX mark.svgN ?)

Magnesium bromide are inorganic compounds with the chemical formula MgBr2(H2O)x, where x can range from 0 to 9. They are all white deliquescent solids. Some magnesium bromides have been found naturally as rare minerals such as: bischofite and carnallite. [2] [3]

Contents

Synthesis

Magnesium bromide can be synthesized by treating magnesium oxide (and related basic salts) with hydrobromic acid. [3] It can also be made by reacting magnesium carbonate and hydrobromic acids, and collecting the solid left after evaporation. [2]

As suggested by its easy conversion to various hydrates, anhydrous MgBr2 is a Lewis acid. In the coordination polymer with the formula MgBr2(dioxane)2, Mg2+ adopts an octahedral geometry. [4]

Uses and reactions

Magnesium bromide is used as a Lewis acid catalyst in some organic synthesis, e.g., in aldol reaction. [5]

Magnesium bromide also has been used as a tranquilizer [2] and as an anticonvulsant for treatment of nervous disorders. [6]

Magnesium bromide modifies the catalytic properties of palladium on charcoal. [7]

Magnesium bromide hexahydrate has properties as a flame retardant. [8]

Treatment of magnesium bromide with chlorine gives magnesium chloride. This reaction is employed in the production of magnesium chloride from brines. [9]

Structure

Two hydrates are known, the hexahydrate and the nonahydrate. Several reports claim a decahydrate, but X-ray crystallography confirmed that it is a nonahydrate. The hydrates feature [Mg(H2O)6]2+ ions. [10]

Related Research Articles

<span class="mw-page-title-main">Magnesium chloride</span> Inorganic salt: MgCl2 and its hydrates

Magnesium chloride is an inorganic compound with the formula MgCl2. It forms hydrates MgCl2·nH2O, where n can range from 1 to 12. These salts are colorless or white solids that are highly soluble in water. These compounds and their solutions, both of which occur in nature, have a variety of practical uses. Anhydrous magnesium chloride is the principal precursor to magnesium metal, which is produced on a large scale. Hydrated magnesium chloride is the form most readily available.

<span class="mw-page-title-main">Zinc chloride</span> Chemical compound

Zinc chloride is an inorganic chemical compound with the formula ZnCl2·nH2O, with n ranging from 0 to 4.5, forming hydrates. Zinc chloride, anhydrous and its hydrates, are colorless or white crystalline solids, and are highly soluble in water. Five hydrates of zinc chloride are known, as well as four forms of anhydrous zinc chloride. All forms of zinc chloride are deliquescent. Zinc chloride finds wide application in textile processing, metallurgical fluxes, and chemical synthesis. In a major monograph, zinc chlorides have been described as "one of the important compounds of zinc."

<span class="mw-page-title-main">Hydrogen bromide</span> Chemical compound

Hydrogen bromide is the inorganic compound with the formula HBr. It is a hydrogen halide consisting of hydrogen and bromine. A colorless gas, it dissolves in water, forming hydrobromic acid, which is saturated at 68.85% HBr by weight at room temperature. Aqueous solutions that are 47.6% HBr by mass form a constant-boiling azeotrope mixture that boils at 124.3 °C (255.7 °F). Boiling less concentrated solutions releases H2O until the constant-boiling mixture composition is reached.

In chemistry, water(s) of crystallization or water(s) of hydration are water molecules that are present inside crystals. Water is often incorporated in the formation of crystals from aqueous solutions. In some contexts, water of crystallization is the total mass of water in a substance at a given temperature and is mostly present in a definite (stoichiometric) ratio. Classically, "water of crystallization" refers to water that is found in the crystalline framework of a metal complex or a salt, which is not directly bonded to the metal cation.

Tin(IV) chloride, also known as tin tetrachloride or stannic chloride, is an inorganic compound of tin and chlorine with the formula SnCl4. It is a colorless hygroscopic liquid, which fumes on contact with air. It is used as a precursor to other tin compounds. It was first discovered by Andreas Libavius (1550–1616) and was known as spiritus fumans libavii.

<span class="mw-page-title-main">Aluminium chloride</span> Chemical compound

Aluminium chloride, also known as aluminium trichloride, is an inorganic compound with the formula AlCl3. It forms a hexahydrate with the formula [Al(H2O)6]Cl3, containing six water molecules of hydration. Both the anhydrous form and the hexahydrate are colourless crystals, but samples are often contaminated with iron(III) chloride, giving them a yellow colour.

<span class="mw-page-title-main">Chromium(III) chloride</span> Chemical compound

Chromium(III) chloride (also called chromic chloride) is an inorganic chemical compound with the chemical formula CrCl3. It forms several hydrates with the formula CrCl3·nH2O, among which are hydrates where n can be 5 (chromium(III) chloride pentahydrate CrCl3·5H2O) or 6 (chromium(III) chloride hexahydrate CrCl3·6H2O). The anhydrous compound with the formula CrCl3 are violet crystals, while the most common form of the chromium(III) chloride are the dark green crystals of hexahydrate, CrCl3·6H2O. Chromium chlorides find use as catalysts and as precursors to dyes for wool.

<span class="mw-page-title-main">Nickel(II) chloride</span> Chemical compound

Nickel(II) chloride (or just nickel chloride) is the chemical compound NiCl2. The anhydrous salt is yellow, but the more familiar hydrate NiCl2·6H2O is green. Nickel(II) chloride, in various forms, is the most important source of nickel for chemical synthesis. The nickel chlorides are deliquescent, absorbing moisture from the air to form a solution. Nickel salts have been shown to be carcinogenic to the lungs and nasal passages in cases of long-term inhalation exposure.

A bromide ion is the negatively charged form (Br) of the element bromine, a member of the halogens group on the periodic table. Most bromides are colorless. Bromides have many practical roles, being found in anticonvulsants, flame-retardant materials, and cell stains. Although uncommon, chronic toxicity from bromide can result in bromism, a syndrome with multiple neurological symptoms. Bromide toxicity can also cause a type of skin eruption, see potassium bromide. The bromide ion has an ionic radius of 196 pm.

<span class="mw-page-title-main">Nickel(II) iodide</span> Chemical compound

Nickel(II) iodide is an inorganic compound with the formula NiI2. This paramagnetic black solid dissolves readily in water to give bluish-green solutions, from which crystallizes the aquo complex [Ni(H2O)6]I2 (image above). This bluish-green colour is typical of hydrated nickel(II) compounds. Nickel iodides find some applications in homogeneous catalysis.

Tin(II) bromide is a chemical compound of tin and bromine with a chemical formula of SnBr2. Tin is in the +2 oxidation state. The stability of tin compounds in this oxidation state is attributed to the inert pair effect.

<span class="mw-page-title-main">Iron(II) bromide</span> Chemical compound

Iron(II) bromide refers to inorganic compounds with the chemical formula FeBr2(H2O)x. The anhydrous compound (x = 0) is a yellow or brownish-colored paramagnetic solid. The tetrahydrate is also known, all being pale colored solids. They are common precursor to other iron compounds.

<span class="mw-page-title-main">Magnesium iodide</span> Chemical compound

Magnesium iodide is an inorganic compound with the chemical formula MgI2. It forms various hydrates MgI2·xH2O. Magnesium iodide is a salt of magnesium and hydrogen iodide. These salts are typical ionic halides, being highly soluble in water.

<span class="mw-page-title-main">Beryllium bromide</span> Chemical compound

Beryllium bromide is the chemical compound with the formula BeBr2. It is very hygroscopic and dissolves well in water. The compound is a polymer with tetrahedral coordinated Be centres.

<span class="mw-page-title-main">Cobalt(II) bromide</span> Chemical compound

Cobalt(II) bromide (CoBr2) is an inorganic compound. In its anhydrous form, it is a green solid that is soluble in water, used primarily as a catalyst in some processes.

<span class="mw-page-title-main">Nickel(II) bromide</span> Chemical compound

Nickel(II) bromide is the name for the inorganic compounds with the chemical formula NiBr2(H2O)x. The value of x can be 0 for the anhydrous material, as well as 2, 3, or 6 for the three known hydrate forms. The anhydrous material is a yellow-brown solid which dissolves in water to give blue-green hexahydrate (see picture).

<span class="mw-page-title-main">Cobalt(II) iodide</span> Chemical compound

Cobalt(II) iodide or cobaltous iodide are the inorganic compounds with the formula CoI2 and the hexahydrate CoI2(H2O)6. These salts are the principal iodides of cobalt.

Nickel compounds are chemical compounds containing the element nickel which is a member of the group 10 of the periodic table. Most compounds in the group have an oxidation state of +2. Nickel is classified as a transition metal with nickel(II) having much chemical behaviour in common with iron(II) and cobalt(II). Many salts of nickel(II) are isomorphous with salts of magnesium due to the ionic radii of the cations being almost the same. Nickel forms many coordination complexes. Nickel tetracarbonyl was the first pure metal carbonyl produced, and is unusual in its volatility. Metalloproteins containing nickel are found in biological systems.

Nickel is one of the metals that can form Tutton's salts. The singly charged ion can be any of the full range of potassium, rubidium, cesium, ammonium (), or thallium. As a mineral the ammonium nickel salt, (NH4)2Ni(SO4)2 · 6 H2O, can be called nickelboussingaultite. With sodium, the double sulfate is nickelblödite Na2Ni(SO4)2 · 4 H2O from the blödite family. Nickel can be substituted by other divalent metals of similar sized to make mixtures that crystallise in the same form.

Cobalt compounds are chemical compounds formed by cobalt with other elements.

References

  1. Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, Florida: CRC Press. pp. 4–67. ISBN   0-8493-0594-2.
  2. 1 2 3 Gruyter, W. Concise Encyclopedia Chemistry, Walter de Gruyter & Company: Berlin, 1993; 612
  3. 1 2 Lewis, R.J. Hawley’s Condensed Chemical Dictionary, 15th ed.; John Wiley & Sons Inc.:New York, 2007; 777
  4. Fischer, Reinald; Görls, Helmar; Meisinger, Philippe R.; Suxdorf, Regina; Westerhausen, Matthias (2019). "Structure–Solubility Relationship of 1,4-Dioxane Complexes of Di(hydrocarbyl)magnesium". Chemistry – A European Journal. 25 (55): 12830–12841. doi:10.1002/chem.201903120. PMC   7027550 . PMID   31328293.
  5. Evans, David A.; Tedrow, Jason S.; Shaw, Jared T.; Downey, C. Wade (2002). "Diastereoselective Magnesium Halide-Catalyzed anti-Aldol Reactions of Chiral N-Acyloxazolidinones". Journal of the American Chemical Society. 124 (3): 392–393. doi:10.1021/ja0119548. PMID   11792206.
  6. Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN   0-07-049439-8
  7. Bouzide, Abderrahim (2002). "Magnesium Bromide Mediated Highly Diastereoselective Heterogeneous Hydrogenation of Olefins". Organic Letters. 4 (8): 1347–50. doi:10.1021/ol020032m. PMID   11950359.
  8. Mostashari, S. M.; Fayyaz, F. (2008). "XRD characterization of the ashes from a burned cellulosic fabric impregnated with magnesium bromide hexahydrate as flame-retardant". Journal of Thermal Analysis and Calorimetry. 92 (3): 845. doi:10.1007/s10973-007-8928-4. S2CID   94416902.
  9. Seeger, Margarete; Otto, Walter; Flick, Wilhelm; Bickelhaupt, Friedrich; Akkerman, Otto S. (2000). "Magnesium Compounds". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a15_595. ISBN   3-527-30673-0.
  10. Hennings, Erik; Schmidt, Horst; Voigt, Wolfgang (2013). "Crystal Structures of Hydrates of Simple Inorganic Salts. I. Water-Rich Magnesium Halide Hydrates MgCl2·8H2O, MgCl2·12H2O, MgBr2·6H2O, MgBr2·9H2O, MgI2·8H2O and MgI2·9H2O". Acta Crystallographica Section C Crystal Structure Communications. 69 (11): 1292–1300. doi:10.1107/S0108270113028138. PMID   24192174.