Neptunium(III) bromide

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Neptunium(III) bromide
UCl3 without caption.png
Unit cell of PuBr3.png
Identifiers
3D model (JSmol)
  • InChI=1S/3BrH.Np/h3*1H;/q;;;+3/p-3
    Key: HVGILCLFCSGPEI-UHFFFAOYSA-K
  • [Np+3].[Br-].[Br-].[Br-]
Properties
Br3Np
Molar mass 477 g·mol−1
Appearancegreen solid [1]
Density 6.62 g·cm−3 [2]
Structure
α-NpBr3: hexagonal

β-NpBr3: orthorhombic

α-NpBr3: P63/m (No. 176)

β-NpBr3: Ccmm (No. 63)

a = 791.7 pm (α), 411 pm (β), b = 791.7 pm (α), 1265 pm (β), c = 438.2 pm (α), 915 pm (β)
Related compounds
Other anions
neptunium(III) fluoride
neptunium(III) chloride
neptunium(III) iodide
Other cations
uranium(III) bromide
plutonium(III) bromide
Related compounds
neptunium(IV) bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Neptunium(III) bromide is a bromide of neptunium, with the chemical formula of NpBr3.

Contents

Preparation

Neptunium(III) bromide can be prepared by reacting neptunium dioxide and aluminium bromide: [3]

6 NpO2 + 8 AlBr3 → 6 NpBr3 + 4 Al2O3 + 3 Br2

Properties

Neptunium(III) bromide is a green solid. It can crystallize in two crystal systems:

Neptunium(III) bromide also has a green hexahydrate, which is monoclinic. [3]

Reactions

At 425 °C, neptunium(III) bromide bromide can be further brominated by bromine to form neptunium(IV) bromide. [2]

2 NpBr3 + Br2 → 2 NpBr4

References

  1. Holleman, Arnold Frederik; Wiberg, Egon (2001), Wiberg, Nils (ed.), Inorganic Chemistry, translated by Eagleson, Mary; Brewer, William, San Diego/Berlin: Academic Press/De Gruyter, p. 1969, ISBN   0-12-352651-5
  2. 1 2 3 4 Gmelins Handbuch der anorganischen Chemie , System No. 71, Transurane, Teil C, S. 148–150.
  3. 1 2 Georg Brauer (Hrsg.), unter Mitarbeit von Marianne Baudler u. a.: Handbuch der Präparativen Anorganischen Chemie. 3., umgearbeitete Auflage. Band II, Ferdinand Enke, Stuttgart 1978, ISBN 3-432-87813-3, S. 1268.

External reading