Holmium(III) bromide

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Holmium(III) bromide
Names
IUPAC name
Tribromoholmium
Systematic IUPAC name
Holmium tribromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.099 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 237-524-6
PubChem CID
UNII
UN number 12141606
  • InChI=1S/3BrH.Ho/h3*1H;/q;;;+3/p-3
    Key: MZNSYJWLQLXLHE-UHFFFAOYSA-K
  • Br[Ho](Br)B
Properties
Br3Ho
Molar mass 404.64 [1]
AppearanceYellow Crystalline Solid
Density 4.85 g/cm3 [1]
Melting point 919 °C (1,686 °F; 1,192 K) [1]
Boiling point 1,470 °C (2,680 °F; 1,740 K) [2]
Will dissolve
log P 2.53680
Thermochemistry
50.1 kJ/mol [3]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Irritant to eyes, and skin, and internal organs.
GHS labelling:
GHS-pictogram-exclam.svg
Warning
H315, H319, H335 [1]
P261, P305+P351+P338 [1] P271, P280, P302+P352, P304+P340, P362, P403+P233 [4] P405, P501 [5]
NFPA 704 (fire diamond)
2
0
0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Holmium(III) bromide is a crystalline compound made of one holmium atom and three bromine atoms. Holmium bromide is a yellow powder at room temperature. [2] Holmium bromide is hygroscopic. [6] Holmium bromide is odorless. [5]

Reactions

Holmium(III) bromide is formed as a result of the reaction: [7]

2 Ho(s) + 3 Br2(g) → 2 HoBr3(s)

Holmium(III) bromide reacts with strong oxidising agents. When involved in a fire, holmium bromide may release hydrogen bromide, and metal oxide fumes. [5]

Related Research Articles

Bromine Chemical element, symbol Br and atomic number 35

Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest halogen and is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig and Antoine Jérôme Balard, its name was derived from the Ancient Greek βρῶμος, referring to its sharp and pungent smell.

Dysprosium Chemical element, symbol Dy and atomic number 66

Dysprosium is the chemical element with the symbol Dy and atomic number 66. It is a rare-earth element in the lanthanide series with a metallic silver luster. Dysprosium is never found in nature as a free element, though, like other lanthanides, it is found in various minerals, such as xenotime. Naturally occurring dysprosium is composed of seven isotopes, the most abundant of which is 164Dy.

Holmium Chemical element, symbol Ho and atomic number 67

Holmium is a chemical element with the symbol Ho and atomic number 67. It is a rare-earth element and the eleventh member of the lanthanide series. It is a relatively soft, silvery, fairly corrosion-resistant and malleable metal. Like a lot of other lanthanides, holmium is too reactive to be found in native form, as pure holmium slowly forms a yellowish oxide coating when exposed to air. When isolated, holmium is relatively stable in dry air at room temperature. However, it reacts with water and corrodes readily, and also burns in air when heated.

Thulium Chemical element, symbol Tm and atomic number 69

Thulium is a chemical element with the symbol Tm and atomic number 69. It is the thirteenth and third-last element in the lanthanide series. Like the other lanthanides, the most common oxidation state is +3, seen in its oxide, halides and other compounds; however, the +2 oxidation state can also be stable. In aqueous solution, like compounds of other late lanthanides, soluble thulium compounds form coordination complexes with nine water molecules.

Arsenic tribromide Chemical compound

Arsenic tribromide is the inorganic compound with the formula AsBr3. This pyramidal molecule is the only known binary arsenic bromide. AsBr3 is noteworthy for its very high refractive index of approximately 2.3. It also has a very high diamagnetic susceptibility. The compound exists as colourless deliquescent crystals that fume in moist air.

Gold(III) bromide Chemical compound

Gold(III) bromide is a dark-red to black crystalline solid. It has the empirical formula AuBr3, but exists primarily as a dimer with the molecular formula Au2Br6 in which two gold atoms are bridged by two bromine atoms. It is commonly referred to as gold(III) bromide, gold tribromide, and rarely but traditionally auric bromide, and sometimes as digold hexabromide. As is similar with the other gold halides, this compound is unique for being a coordination complex of a group 11 transition metal that is stable in an oxidation state of +3 whereas copper or silver complexes persist in oxidation states of +1 or +2.

Yttrium(III) bromide Chemical compound

Yttrium(III) bromide is an inorganic compound with the chemical formula YBr3. It is a white solid. Anhydrous yttrium(III) bromide can be produced by reacting yttrium oxide or yttrium(III) bromide hydrate and ammonium bromide. The reaction proceeds via the intermediate (NH4)3YBr6. Another method is to react yttrium carbide (YC2) and elemental bromine. Yttrium(III) bromide can be reduced by yttrium metal to YBr or Y2Br3. It can react with osmium to produce Y4Br4Os.

Indium(III) bromide Chemical compound

Indium(III) bromide, (indium tribromide), InBr3, is a chemical compound of indium and bromine. It is a Lewis acid and has been used in organic synthesis.

Bismuth tribromide Chemical compound

Bismuth tribromide is an inorganic compound of bismuth and bromine with the chemical formula BiBr3.

Praseodymium(III) bromide is a crystalline compound of one praseodymium atom and three bromine atoms.

Neodymium(III) bromide Chemical compound

Neodymium(III) bromide is an inorganic salt of bromine and neodymium the formula NdBr3. The anhydrous compound is an off-white to pale green solid at room temperature, with an orthorhombic PuBr3-type crystal structure. The material is hydroscopic and forms a hexahydrate in water (NdBr3· 6H2O), similar to the related neodymium(III) chloride.

Samarium(II) bromide Chemical compound

Samarium(II) bromide is an inorganic compound with the chemical formula SmBr
2
. It is a brown solid that is insoluble in most solvents but degrades readily in air.

Samarium(III) bromide is a crystalline compound of one samarium and three bromine atoms with the chemical formula of SmBr3. Samarium(III) bromide is a dark brown powder at room temperature. The compound has a crystal structure isotypic to that of plutonium(III) bromide.

Europium(II) bromide Chemical compound

Europium(II) bromide is a crystalline compound of one europium atom and two bromine atoms. Europium(II) bromide is a white powder at room temperature, and odorless. Europium dibromide is hygroscopic.

Europium(III) bromide is a crystalline compound, a salt, made of one europium and three bromine atoms. Europium tribromide is a grey powder at room temperature. It is odorless. Europium tribromide is hygroscopic.

Gadolinium(III) bromide is a crystalline compound of gadolinium atoms and three bromine atoms. This salt is hygroscopic.

Thulium(III) bromide is a crystalline compound of one thulium atom and three bromine atoms. The salt is a white powder at room temperature. It is hygroscopic.

Lutetium(III) bromide is a crystalline compound made of one lutetium atom and three bromine atoms. It takes the form of a white powder at room temperature. It is hygroscopic. It is odorless.

Zirconium(III) bromide Chemical compound

Zirconium(III) bromide is an inorganic compound with the formula ZrBr3.

Zirconium(III) iodide Chemical compound

Zirconium(III) iodide is an inorganic compound with the formula ZrI3.

References

  1. 1 2 3 4 5 "Holmium(III) bromide anhydrous, powder, 99.99% trace metals basis | Sigma-Aldrich". www.sigmaaldrich.com. Retrieved 21 December 2016.
  2. 1 2 Elements, American. "Holmium Bromide". American Elements. Retrieved 21 December 2016.
  3. Haynes, William M. (2013). CRC handbook of chemistry and physics : a ready-reference book of chemical and physical data (94th ed.). CRC Press. p. 148. ISBN   9781466571150.
  4. "Holmium Bromide | ProChem, Inc". prochemonline.com. Retrieved 21 December 2016.
  5. 1 2 3 "Holmium(III) bromide". Fischersci. Retrieved 21 December 2016.
  6. "HOLMIUM BROMIDE | 13825-76-8". www.chemicalbook.com. Retrieved 21 December 2016.
  7. Winter, Mark. "Holmium»reactions of elements [WebElements Periodic Table]". www.webelements.com. Retrieved 21 December 2016.