Names | |
---|---|
IUPAC name Tribromoholmium | |
Systematic IUPAC name Holmium tribromide | |
Identifiers | |
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.034.099 |
EC Number |
|
PubChem CID | |
UNII | |
UN number | 12141606 |
CompTox Dashboard (EPA) | |
| |
| |
Properties | |
Br3Ho | |
Molar mass | 404.64 [1] |
Appearance | Yellow Crystalline Solid |
Density | 4.85 g/cm3 [1] |
Melting point | 919 °C (1,686 °F; 1,192 K) [1] |
Boiling point | 1,470 °C (2,680 °F; 1,740 K) [2] |
Will dissolve | |
log P | 2.53680 |
Thermochemistry | |
Std enthalpy of formation (ΔfH⦵298) | 50.1 kJ/mol [3] |
Hazards | |
Occupational safety and health (OHS/OSH): | |
Main hazards | Irritant to eyes, and skin, and internal organs. |
GHS labelling: | |
Warning | |
H315, H319, H335 [1] | |
P261, P305+P351+P338 [1] P271, P280, P302+P352, P304+P340, P362, P403+P233 [4] P405, P501 [5] | |
NFPA 704 (fire diamond) | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Holmium(III) bromide is a crystalline compound made of one holmium atom and three bromine atoms. Holmium bromide is a yellow powder at room temperature. [2] Holmium bromide is hygroscopic. [6] Holmium bromide is odorless. [5]
Holmium(III) bromide is formed as a result of the reaction: [7]
Holmium(III) bromide reacts with strong oxidising agents. When involved in a fire, holmium bromide may release hydrogen bromide, and metal oxide fumes. [5]
Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest halogen and is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig and Antoine Jérôme Balard, its name was derived from the Ancient Greek βρῶμος, referring to its sharp and pungent smell.
Dysprosium is the chemical element with the symbol Dy and atomic number 66. It is a rare-earth element in the lanthanide series with a metallic silver luster. Dysprosium is never found in nature as a free element, though, like other lanthanides, it is found in various minerals, such as xenotime. Naturally occurring dysprosium is composed of seven isotopes, the most abundant of which is 164Dy.
Holmium is a chemical element with the symbol Ho and atomic number 67. It is a rare-earth element and the eleventh member of the lanthanide series. It is a relatively soft, silvery, fairly corrosion-resistant and malleable metal. Like a lot of other lanthanides, holmium is too reactive to be found in native form, as pure holmium slowly forms a yellowish oxide coating when exposed to air. When isolated, holmium is relatively stable in dry air at room temperature. However, it reacts with water and corrodes readily, and also burns in air when heated.
Thulium is a chemical element with the symbol Tm and atomic number 69. It is the thirteenth and third-last element in the lanthanide series. Like the other lanthanides, the most common oxidation state is +3, seen in its oxide, halides and other compounds; however, the +2 oxidation state can also be stable. In aqueous solution, like compounds of other late lanthanides, soluble thulium compounds form coordination complexes with nine water molecules.
Arsenic tribromide is the inorganic compound with the formula AsBr3. This pyramidal molecule is the only known binary arsenic bromide. AsBr3 is noteworthy for its very high refractive index of approximately 2.3. It also has a very high diamagnetic susceptibility. The compound exists as colourless deliquescent crystals that fume in moist air.
Gold(III) bromide is a dark-red to black crystalline solid. It has the empirical formula AuBr3, but exists primarily as a dimer with the molecular formula Au2Br6 in which two gold atoms are bridged by two bromine atoms. It is commonly referred to as gold(III) bromide, gold tribromide, and rarely but traditionally auric bromide, and sometimes as digold hexabromide. As is similar with the other gold halides, this compound is unique for being a coordination complex of a group 11 transition metal that is stable in an oxidation state of +3 whereas copper or silver complexes persist in oxidation states of +1 or +2.
Yttrium(III) bromide is an inorganic compound with the chemical formula YBr3. It is a white solid. Anhydrous yttrium(III) bromide can be produced by reacting yttrium oxide or yttrium(III) bromide hydrate and ammonium bromide. The reaction proceeds via the intermediate (NH4)3YBr6. Another method is to react yttrium carbide (YC2) and elemental bromine. Yttrium(III) bromide can be reduced by yttrium metal to YBr or Y2Br3. It can react with osmium to produce Y4Br4Os.
Indium(III) bromide, (indium tribromide), InBr3, is a chemical compound of indium and bromine. It is a Lewis acid and has been used in organic synthesis.
Bismuth tribromide is an inorganic compound of bismuth and bromine with the chemical formula BiBr3.
Praseodymium(III) bromide is a crystalline compound of one praseodymium atom and three bromine atoms.
Neodymium(III) bromide is an inorganic salt of bromine and neodymium the formula NdBr3. The anhydrous compound is an off-white to pale green solid at room temperature, with an orthorhombic PuBr3-type crystal structure. The material is hydroscopic and forms a hexahydrate in water (NdBr3· 6H2O), similar to the related neodymium(III) chloride.
Samarium(II) bromide is an inorganic compound with the chemical formula SmBr
2. It is a brown solid that is insoluble in most solvents but degrades readily in air.
Samarium(III) bromide is a crystalline compound of one samarium and three bromine atoms with the chemical formula of SmBr3. Samarium(III) bromide is a dark brown powder at room temperature. The compound has a crystal structure isotypic to that of plutonium(III) bromide.
Europium(II) bromide is a crystalline compound of one europium atom and two bromine atoms. Europium(II) bromide is a white powder at room temperature, and odorless. Europium dibromide is hygroscopic.
Europium(III) bromide is a crystalline compound, a salt, made of one europium and three bromine atoms. Europium tribromide is a grey powder at room temperature. It is odorless. Europium tribromide is hygroscopic.
Gadolinium(III) bromide is a crystalline compound of gadolinium atoms and three bromine atoms. This salt is hygroscopic.
Thulium(III) bromide is a crystalline compound of one thulium atom and three bromine atoms. The salt is a white powder at room temperature. It is hygroscopic.
Lutetium(III) bromide is a crystalline compound made of one lutetium atom and three bromine atoms. It takes the form of a white powder at room temperature. It is hygroscopic. It is odorless.
Zirconium(III) bromide is an inorganic compound with the formula ZrBr3.
Zirconium(III) iodide is an inorganic compound with the formula ZrI3.