Names | |
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IUPAC name Tribromoscandium | |
Other names Scandium tribromide | |
Identifiers | |
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.033.349 |
EC Number |
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PubChem CID | |
CompTox Dashboard (EPA) | |
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Properties | |
ScBr3 | |
Molar mass | 284.67 g/mol |
Appearance | anhydrous powder |
Density | 3.914 g/cm3 |
Melting point | 904 °C (1,659 °F; 1,177 K) [1] [2] [3] |
soluble | |
Solubility | soluble in ethanol |
Thermochemistry | |
Std enthalpy of formation (ΔfH⦵298) | -2.455 kJ/g |
Hazards | |
NFPA 704 (fire diamond) | |
Related compounds | |
Other anions | Scandium fluoride Scandium chloride Scandium triiodide |
Other cations | Yttrium(III) bromide Lutetium(III) bromide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Scandium bromide, or ScBr3, is a trihalide, hygroscopic, water-soluble chemical compound of scandium and bromine.
ScBr3 is produced through the burning of scandium in bromine gas. [4]
Scandium bromide can also be prepared by reacting excess hydrobromic acid with scandium oxide, and the hexahydrate can be crystallized from the solution. The thermal decomposition of hexahydrate can only yield scandium oxybromide (ScOBr) and scandium oxide. [5] The anhydrous form can be produced by the reaction of bromine, scandium oxide and graphite in nitrogen gas. [6]
Heating reaction between ammonium bromide and scandium oxide or scandium bromide hexahydrate, through (NH4)3ScBr6 intermediate, decomposes to obtain anhydrous scandium bromide. [7]
Scandium bromide is used for solid state synthesis of unusual clusters such as Sc19Br28Z4, (Z=Mn, Fe, Os or Ru). These clusters are of interest for their structure and magnetic properties. [8]
Bromine is a chemical element; it has symbol Br and atomic number 35. It is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig and Antoine Jérôme Balard, its name was derived from the Ancient Greek βρῶμος (bromos) meaning "stench", referring to its sharp and pungent smell.
Vanadium(III) chloride describes the inorganic compound with the formula VCl3 and its hydrates. It forms a purple anhydrous form and a green hexahydrate [VCl2(H2O)4]Cl·2H2O. These hygroscopic salts are common precursors to other vanadium(III) complexes and is used as a mild reducing agent.
Yttrium(III) bromide is an inorganic compound with the chemical formula YBr3. It is a white solid. Anhydrous yttrium(III) bromide can be produced by reacting yttrium oxide or yttrium(III) bromide hydrate and ammonium bromide. The reaction proceeds via the intermediate (NH4)3YBr6. Another method is to react yttrium carbide (YC2) and elemental bromine. Yttrium(III) bromide can be reduced by yttrium metal to YBr or Y2Br3. It can react with osmium to produce Y4Br4Os.
Ytterbium(III) bromide (YbBr3) is an inorganic chemical compound.
Terbium(III) bromide (TbBr3) is a crystalline chemical compound.
Bromine compounds are compounds containing the element bromine (Br). These compounds usually form the -1, +1, +3 and +5 oxidation states. Bromine is intermediate in reactivity between chlorine and iodine, and is one of the most reactive elements. Bond energies to bromine tend to be lower than those to chlorine but higher than those to iodine, and bromine is a weaker oxidising agent than chlorine but a stronger one than iodine. This can be seen from the standard electrode potentials of the X2/X− couples (F, +2.866 V; Cl, +1.395 V; Br, +1.087 V; I, +0.615 V; At, approximately +0.3 V). Bromination often leads to higher oxidation states than iodination but lower or equal oxidation states to chlorination. Bromine tends to react with compounds including M–M, M–H, or M–C bonds to form M–Br bonds.
Magnesium compounds are compounds formed by the element magnesium (Mg). These compounds are important to industry and biology, including magnesium carbonate, magnesium chloride, magnesium citrate, magnesium hydroxide, magnesium oxide, magnesium sulfate, and magnesium sulfate heptahydrate.
Calcium bromide is the name for compounds with the chemical formula CaBr2(H2O)x. Individual compounds include the anhydrous material (x = 0), the hexahydrate (x = 6), and the rare dihydrate (x = 2). All are white powders that dissolve in water, and from these solutions crystallizes the hexahydrate. The hydrated form is mainly used in some drilling fluids.
Cerium(III) bromide is an inorganic compound with the formula CeBr3. This white hygroscopic solid is of interest as a component of scintillation counters.
Bismuth tribromide is an inorganic compound of bismuth and bromine with the chemical formula BiBr3.
Neodymium(III) bromide is an inorganic salt of bromine and neodymium the formula NdBr3. The anhydrous compound is an off-white to pale green solid at room temperature, with an orthorhombic PuBr3-type crystal structure. The material is hygroscopic and forms a hexahydrate in water (NdBr3· 6H2O), similar to the related neodymium(III) chloride.
Samarium(III) bromide is a crystalline compound of one samarium and three bromine atoms with the chemical formula of SmBr3. Samarium(III) bromide is a dark brown powder at room temperature. The compound has a crystal structure isotypic to that of plutonium(III) bromide.
Rhodium(III) bromide refers to inorganic compounds of the formula RhBr3(H2O)n where n = 0 or approximately three. Both forms are brown solids. The hydrate is soluble in water and lower alcohols. It is used to prepare rhodium bromide complexes. Rhodium bromides are similar to the chlorides, but have attracted little academic or commercial attention.
Lanthanide trichlorides are a family of inorganic compound with the formula LnCl3, where Ln stands for a lanthanide metal. The trichlorides are standard reagents in applied and academic chemistry of the lanthanides. They exist as anhydrous solids and as hydrates.
Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.
Dysprosium(III) bromide is an inorganic compound of bromine and dysprosium, with the chemical formula of DyBr3.
Promethium(III) bromide is an inorganic compound, with the chemical formula of PmBr3. It is radioactive salt. It is a crystal of the hexagonal crystal system, with the space group of P63/mc (No. 176).
Erbium compounds are compounds containing the element erbium (Er). These compounds are usually dominated by erbium in the +3 oxidation state, although the +2, +1 and 0 oxidation states have also been reported.
Tungsten hexabromide, also known as tungsten(VI) bromide, is a chemical compound of tungsten and bromine with the formula WBr6. It is an air-sensitive dark grey powder that decomposes above 200 °C to tungsten(V) bromide and bromine.
Iridium(III) bromide is a bromide of iridium(III), with the chemical formula of IrBr3.