Plutonium(III) bromide

Last updated
Plutonium(III) bromide
Names
IUPAC name
Plutonium tribromide
Other names
Plutonium(III) bromide
Identifiers
3D model (JSmol)
PubChem CID
  • InChI=1S/3BrH.Pu/h3*1H;/p-3
    Key: LNRFBKZOZNXTON-UHFFFAOYSA-K
  • [Br-].[Br-].[Br-].[Pu]
Properties
Br3Pu
Molar mass 484 g·mol−1
AppearanceGreen [1]
Melting point 767 °C (1,413 °F; 1,040 K) [1]
Boiling point 1,463 °C (2,665 °F; 1,736 K)
Water soluble
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Plutonium(III) bromide is an inorganic salt of bromine and plutonium with the formula PuBr3. This radioactive green solid has few uses, however its crystal structure is often used as a structural archetype in crystallography.

Crystal structure

Kristallstruktur Plutonium(III)-bromid.png
Crystal structure
Unit cell of PuBr3.png
Unit cell
PuBr3:   Pt3+  Br

The PuBr3 crystal structure was first published in 1948 by William Houlder Zachariasen. [2] The compound forms orthorhombic crystals, a type of square antiprism, within which the Pu atoms adopt an 8-coordinate bicapped trigonal prismatic arrangement. Its Pearson symbol is oS16 with the corresponding space group No. 63 (in International Union of Crystallography classification) or Cmcm (in Hermann–Mauguin notation). The majority of trivalent chloride and bromide salts of lanthanide and actinides crystallise in the PuBr3 structure.

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<span class="mw-page-title-main">Curium</span> Chemical element, symbol Cm and atomic number 96

Curium is a synthetic chemical element; it has symbol Cm and atomic number 96. This transuranic actinide element was named after eminent scientists Marie and Pierre Curie, both known for their research on radioactivity. Curium was first intentionally made by the team of Glenn T. Seaborg, Ralph A. James, and Albert Ghiorso in 1944, using the cyclotron at Berkeley. They bombarded the newly discovered element plutonium with alpha particles. This was then sent to the Metallurgical Laboratory at University of Chicago where a tiny sample of curium was eventually separated and identified. The discovery was kept secret until after the end of World War II. The news was released to the public in November 1947. Most curium is produced by bombarding uranium or plutonium with neutrons in nuclear reactors – one tonne of spent nuclear fuel contains ~20 grams of curium.

<span class="mw-page-title-main">Indium(III) bromide</span> Chemical compound

Indium(III) bromide, (indium tribromide), InBr3, is a chemical compound of indium and bromine. It is a Lewis acid and has been used in organic synthesis.

There are three sets of Indium halides, the trihalides, the monohalides, and several intermediate halides. In the monohalides the oxidation state of indium is +1 and their proper names are indium(I) fluoride, indium(I) chloride, indium(I) bromide and indium(I) iodide.

<span class="mw-page-title-main">Plutonium(III) chloride</span> Chemical compound

Plutonium(III) chloride is a chemical compound with the formula PuCl3. This ionic plutonium salt can be prepared by reacting the metal with hydrochloric acid.

<span class="mw-page-title-main">Cerium(III) bromide</span> Chemical compound

Cerium(III) bromide is an inorganic compound with the formula CeBr3. This white hygroscopic solid is of interest as a component of scintillation counters.

William Houlder Zachariasen, more often known as W. H. Zachariasen, was a Norwegian-American physicist, specializing in X-ray crystallography and famous for his work on the structure of glass.

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Actinide chemistry is one of the main branches of nuclear chemistry that investigates the processes and molecular systems of the actinides. The actinides derive their name from the group 3 element actinium. The informal chemical symbol An is used in general discussions of actinide chemistry to refer to any actinide. All but one of the actinides are f-block elements, corresponding to the filling of the 5f electron shell; lawrencium, a d-block element, is also generally considered an actinide. In comparison with the lanthanides, also mostly f-block elements, the actinides show much more variable valence. The actinide series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium.

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Neodymium(III) bromide is an inorganic salt of bromine and neodymium the formula NdBr3. The anhydrous compound is an off-white to pale green solid at room temperature, with an orthorhombic PuBr3-type crystal structure. The material is hygroscopic and forms a hexahydrate in water (NdBr3· 6H2O), similar to the related neodymium(III) chloride.

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References

  1. 1 2 Greenwood, N. N. (2001). Chemistry of the elements (2nd ed.). Boston, Mass. p. 1270. ISBN   0750633654.{{cite book}}: CS1 maint: location missing publisher (link)
  2. Zachariasen, W. H. (2 November 1948). "Crystal chemical studies of the 5f-series of elements. I. New structure types". Acta Crystallographica. 1 (5): 265–268. Bibcode:1948AcCry...1..265Z. doi: 10.1107/S0365110X48000703 .