Plutonium selenide

Last updated
Plutonium selenide
Names
Other names
Plutonium monoselenide, Plutonium(II) selenide
Identifiers
3D model (JSmol)
  • InChI=1S/Pu.Se
    Key: IJHCCJHFYQUWOM-UHFFFAOYSA-N
  • [Pu].[Se]
Properties
PtSe
Molar mass 323.024
AppearanceBlack crystals
Melting point 2,075 °C (3,767 °F; 2,348 K)
insoluble
Hazards
GHS labelling:
Warning
Related compounds
Other anions
Plutonium sulfide
Plutonium telluride
Other cations
Magnesium selenide
Strontium selenide
Barium selenide
Iron(II) selenide
Iron(III) selenide
Lead(II) selenide
Praseodymium selenide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Plutonium selenide is a binary inorganic compound of plutonium and selenium with the chemical formula PuSe. [1] [2] The compound forms black crystals and does not dissolve in water.

Contents

Synthesis

Reaction of diplutonium triselenide and plutonium trihydride:

Fusion of stoichiometric amounts of pure substances:

Properties

Plutonium selenide forms black crystals of a cubic system, space group Fm3m, cell parameters a = 0.57934 nm, Z = 4, structure of the NaCl type. [3] [4]

With increasing pressure, two phase transitions occur: at 20 GPa into the trigonal system and at 35 GPa into the cubic system, a structure of the CsCl type.

Its magnetic susceptibility follows the Curie-Weiss law. [5]

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<span class="mw-page-title-main">Curium</span> Chemical element, symbol Cm and atomic number 96

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<span class="mw-page-title-main">Neptunium</span> Chemical element, symbol Np and atomic number 93

Neptunium is a chemical element; it has symbol Np and atomic number 93. A radioactive actinide metal, neptunium is the first transuranic element. Its position in the periodic table just after uranium, named after the planet Uranus, led to it being named after Neptune, the next planet beyond Uranus. A neptunium atom has 93 protons and 93 electrons, of which seven are valence electrons. Neptunium metal is silvery and tarnishes when exposed to air. The element occurs in three allotropic forms and it normally exhibits five oxidation states, ranging from +3 to +7. Like all actinides, it is radioactive, poisonous, pyrophoric, and capable of accumulating in bones, which makes the handling of neptunium dangerous.

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<span class="mw-page-title-main">Cubic crystal system</span> Crystallographic system where the unit cell is in the shape of a cube

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<span class="mw-page-title-main">Plutonium(III) fluoride</span> Chemical compound

Plutonium(III) fluoride or plutonium trifluoride is the chemical compound composed of plutonium and fluorine with the formula PuF3. This salt forms violet crystals. Plutonium(III) fluoride has the LaF3 structure where the coordination around the plutonium atoms is complex and usually described as tri-capped trigonal prismatic.

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Neodymium(III) bromide is an inorganic salt of bromine and neodymium the formula NdBr3. The anhydrous compound is an off-white to pale green solid at room temperature, with an orthorhombic PuBr3-type crystal structure. The material is hygroscopic and forms a hexahydrate in water (NdBr3· 6H2O), similar to the related neodymium(III) chloride.

Plutonium silicide is a binary inorganic compound of plutonium and silicon with the chemical formula PuSi. The compound forms gray crystals.

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Plutonium arsenide is a binary inorganic compound of plutonium and arsenic with the formula PuAs.

<span class="mw-page-title-main">Selenosulfide</span>

In chemistry, a selenosulfide refers to distinct classes of inorganic and organic compounds containing sulfur and selenium. The organic derivatives contain Se-S bonds, whereas the inorganic derivatives are more variable.

Neptunium compounds are compounds containg the element neptunium (Np). Neptunium has five ionic oxidation states ranging from +3 to +7 when forming chemical compounds, which can be simultaneously observed in solutions. It is the heaviest actinide that can lose all its valence electrons in a stable compound. The most stable state in solution is +5, but the valence +4 is preferred in solid neptunium compounds. Neptunium metal is very reactive. Ions of neptunium are prone to hydrolysis and formation of coordination compounds.

<span class="mw-page-title-main">Strontium selenide</span> Chemical compound

Strontium selenide is an inorganic compound with the chemical formula SrSe.

<span class="mw-page-title-main">Plutonium nitride</span> Chemical compound

Plutonium nitride is a binary inorganic compound of plutonium and nitrogen with the chemical formula PuN.

References

  1. Eyring, LeRoy; O'Keeffe, Michael (1970). The Chemistry of Extended Defects in Non-metallic Solids: Proceedings of the Institute for Advanced Study on the Chemistry of Extended Defects in Non-Metallic Solids, Casa Blanca Inn, Scottsdale, Arizona, April 16-26, 1969. North-Holland Publishing Company. p. 140. ISBN   978-0-7204-0164-6 . Retrieved 6 August 2021.
  2. Burke, Robert (17 June 2013). Hazardous Materials Chemistry for Emergency Responders. CRC Press. p. 85. ISBN   978-1-4398-4986-6 . Retrieved 6 August 2021.
  3. Gensini, M.; Gering, E.; Heathman, S.; Benedict, U.; Spirlet, J. C. (1 April 1990). "High-pressure phases of plutonium monoselenide studied by X-ray diffraction". High Pressure Research. 2 (5–6): 347–359. Bibcode:1990HPR.....2..347G. doi:10.1080/08957959008203187. ISSN   0895-7959 . Retrieved 6 August 2021.
  4. "WebElements Periodic Table » Plutonium » plutonium selenide". webelements.com. Retrieved 6 August 2021.
  5. Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 3783. ISBN   978-0-412-30120-9 . Retrieved 6 August 2021.