Chromium(II) selenide

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Chromium(II) selenide
Names
IUPAC name
Chromium(2+) selenide
Identifiers
3D model (JSmol)
ECHA InfoCard 100.031.805 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 234-999-1
PubChem CID
  • InChI=1S/Cr.Se
    Key: UVZCKRKEVWSRGT-UHFFFAOYSA-N
  • [Cr]=[Se]
Properties
CrSe
Molar mass 130.96 g/mol
Appearancewhite to pale yellow crystalline powder
Density 6.74 g/cm3
Melting point ~1500 °C
insoluble
Structure [1]
NiAs type (hexagonal)
P63/mmc, No. 194
a = 371 pm, c = 603 pm
Hazards
NFPA 704 (fire diamond)
NFPA 704.svgHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
1
1
1
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3 [2]
REL (Recommended)
TWA 0.5 mg/m3 [2]
IDLH (Immediate danger)
250 mg/m3 [2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Chromium(II) selenide is an inorganic compound with the chemical formula CrSe. It crystalizes in a hexagonal structure with space group P63/mmc. [3] It is one of many related Chromium-Selenium phases, including Cr7Se8, Cr3Se4, Cr0.68Se, Cr2Se3, and Cr5Se8. [3] The compound has been described as an antiferromagnet, but its inverse magnetic susceptibility does not match the behavior expected for an antiferromagnet according to the Curie–Weiss law. [1] One suggestion was that the Néel temperature is at 320 K, as the temperature where the compound has maximum specific heat. [4] When synthesized as single atomic layer, CrSe is ferromagnetic, with a Curie Temperature of around 280 K. [5]

Related Research Articles

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<span class="mw-page-title-main">Cadmium selenide</span> Chemical compound

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<span class="mw-page-title-main">Selenium dioxide</span> Chemical compound

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Copper(II) fluoride is an inorganic compound with the chemical formula CuF2. The anhydrous form is a white, ionic, crystalline, hygroscopic solid with a distorted rutile-type crystal structure, similar to other fluorides of chemical formulae MF2 (where M is a metal). The dihydrate, CuF2·2H2O, is blue in colour.

<span class="mw-page-title-main">Chromium(IV) oxide</span> Chemical compound

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<span class="mw-page-title-main">Magnetic structure</span>

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Chromium pentafluoride is the inorganic compound with the chemical formula CrF5. It is a red volatile solid that melts at 34 °C. It is the highest known chromium fluoride, since the hypothetical chromium hexafluoride has not yet been synthesized.

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Chromium(III) boride, also known as chromium monoboride (CrB), is an inorganic compound with the chemical formula CrB. It is one of the six stable binary borides of chromium, which also include Cr2B, Cr5B3, Cr3B4, CrB2, and CrB4. Like many other transition metal borides, it is extremely hard (21-23 GPa), has high strength (690 MPa bending strength), conducts heat and electricity as well as many metallic alloys, and has a high melting point (~2100 °C). Unlike pure chromium, CrB is known to be a paramagnetic, with a magnetic susceptibility that is only weakly dependent on temperature. Due to these properties, among others, CrB has been considered as a candidate material for wear resistant coatings and high-temperature diffusion barriers.

Phosphorus selenides are a relatively obscure group of compounds. There have been some studies of the phosphorus - selenium phase diagram and the glassy amorphous phases are reported. The compounds that have been reported are shown below. While some of phosphorus selenides are similar to their sulfide analogues, there are some new forms, molecular P2Se5 and the polymeric catena-[P4Se4]x. There is also some doubt about the existence of molecular P4Se10.

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<span class="mw-page-title-main">Oxyselenide</span> Class of chemical compounds

Oxyselenides are a group of chemical compounds that contain oxygen and selenium atoms. Oxyselenides can form a wide range of structures in compounds containing various transition metals, and thus can exhibit a wide range of properties. Most importantly, oxyselenides have a wide range of thermal conductivity, which can be controlled with changes in temperature in order to adjust their thermoelectric performance. Current research on oxyselenides indicates their potential for significant application in electronic materials.

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Borate sulfides are chemical mixed anion compounds that contain any kind of borate and sulfide ions. They are distinct from thioborates in which sulfur atoms replace oxygen in borates. There are also analogous borate selenides, with selenium ions instead of sulfur.

Plutonium selenide is a binary inorganic compound of plutonium and selenium with the chemical formula PuSe. The compound forms black crystals and does not dissolve in water.

Corundum is the name for a structure prototype in inorganic solids, derived from the namesake polymorph of aluminum oxide (α-Al2O3). Other compounds, especially among the inorganic solids, exist in corundum structure, either in ambient or other conditions. Corundum structures are associated with metal-insulator transition, ferroelectricity, polar magnetism, and magnetoelectric effects.

Europium monoselenide is a binary inorganic compound of europium and selenium with the chemical formula EuSe. The compound forms black crystals.

References

  1. 1 2 Lotgering, F.K.; Gorter, E.W. (1957). "Solid solutions between ferromagnetic and antiferromagnetic compounds with NiAs structure". Journal of Physics and Chemistry of Solids. Elsevier BV. 3 (3–4): 238–249. doi:10.1016/0022-3697(57)90028-8. ISSN   0022-3697.
  2. 1 2 3 NIOSH Pocket Guide to Chemical Hazards. "#0141". National Institute for Occupational Safety and Health (NIOSH).
  3. 1 2 Wehmeier, F. H.; Keve, E. T.; Abrahams, S. C. (1970). "Preparation, structure, and properties of some chromium selenides. Crystal growth with selenium vapor as a novel transport agent". Inorganic Chemistry. American Chemical Society (ACS). 9 (9): 2125–2131. doi:10.1021/ic50091a032. ISSN   0020-1669.
  4. Tsubokawa, Ichiro (1960). "The Magnetic Properties of Single Crystals of Chromium Selenide". Journal of the Physical Society of Japan. Physical Society of Japan. 15 (12): 2243–2247. doi:10.1143/jpsj.15.2243. ISSN   0031-9015.
  5. Zhang, Yu; Chu, Junwei; Yin, Lei; et al. (2019-03-28). "Ultrathin Magnetic 2D Single‐Crystal CrSe". Advanced Materials. Wiley. 31 (19): 1900056. doi:10.1002/adma.201900056. hdl: 10278/3742833 . ISSN   0935-9648.