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Names | |||
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IUPAC name Hydrogen selenide | |||
Other names Hydroselenic acid selane selenium hydride | |||
Identifiers | |||
3D model (JSmol) | |||
ChEBI | |||
ChemSpider | |||
ECHA InfoCard | 100.029.071 | ||
EC Number |
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KEGG | |||
PubChem CID | |||
RTECS number |
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UNII | |||
UN number | 2202 | ||
CompTox Dashboard (EPA) | |||
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Properties | |||
H2Se | |||
Molar mass | 80.98 g/mol | ||
Appearance | Colorless gas | ||
Odor | decayed horseradish [1] | ||
Density | 3.553 g/dm3 | ||
Melting point | −65.73 °C (−86.31 °F; 207.42 K) | ||
Boiling point | −41.25 °C (−42.25 °F; 231.90 K) | ||
0.70 g/100 mL | |||
Solubility | soluble in CS2, phosgene | ||
Vapor pressure | 9.5 atm (21°C) [1] | ||
Acidity (pKa) | 3.89 | ||
Conjugate acid | Selenonium | ||
Conjugate base | Selenide | ||
Structure | |||
Bent | |||
Hazards | |||
Occupational safety and health (OHS/OSH): | |||
Main hazards | Extremely toxic and flammable | ||
GHS labelling: | |||
Danger | |||
H220, H330, H410 | |||
P210, P260, P271, P273, P284, P304+P340, P310, P320, P377, P381, P391, P403, P403+P233, P405, P410+P403, P501 | |||
NFPA 704 (fire diamond) | |||
Flash point | flammable gas | ||
Lethal dose or concentration (LD, LC): | |||
LCLo (lowest published) | 0.3 ppm (guinea pig, 8 hr) 5.9 ppm (rat, 1 hr) [2] | ||
NIOSH (US health exposure limits): | |||
PEL (Permissible) | TWA 0.05 ppm (0.2 mg/m3) [1] | ||
REL (Recommended) | TWA 0.05 ppm (0.2 mg/m3) [1] | ||
IDLH (Immediate danger) | 1 ppm [1] | ||
Safety data sheet (SDS) | ICSC 0284 | ||
Related compounds | |||
Other anions | H2O H2S H2Te H2Po | ||
Other cations | Na2Se Ag2Se | ||
Related compounds | Arsine | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Hydrogen selenide is an inorganic compound with the formula H2Se. This hydrogen chalcogenide is the simplest and most commonly encountered hydride of selenium. H2Se is a colorless, flammable gas under standard conditions. It is the most toxic selenium compound [3] with an exposure limit of 0.05 ppm over an 8-hour period. [4] [5] Even at extremely low concentrations, this compound has a very irritating smell resembling that of decayed horseradish or "leaking gas", but smells of rotten eggs at higher concentrations.
H2Se adopts a bent structure with a H−Se−H bond angle of 91°[ citation needed ]. Consistent with this structure, three IR-active vibrational bands are observed: 2358, 2345, and 1034 cm−1. [6]
The properties of H2S and H2Se are similar, although the selenide is more acidic with pKa = 3.89 and the second pKa = 11, [6] or 15.05 ± 0.02 at 25 °C. [7]
Industrially, it is produced by treating elemental selenium at T > 300 °C with hydrogen gas. [8] A number of routes to H2Se have been reported, which are suitable for both large and small scale preparations. In the laboratory, H2Se is usually prepared by the action of water on Al2Se3, concomitant with formation of hydrated alumina. A related reaction involves the acid hydrolysis of FeSe. [9]
H2Se can also be prepared by means of different methods based on the in situ generation in aqueous solution using boron hydride, Marsh test and Devarda's alloy. According to the Sonoda method, H2Se is generated from the reaction of H2O and CO on Se in the presence of Et3N. [10] H2Se can be purchased in cylinders.
Elemental selenium can be recovered from H2Se through a reaction with aqueous sulfur dioxide (SO2).
Its decomposition is used to prepare the highly pure element.
H2Se is commonly used in the synthesis of Se-containing compounds. It adds across alkenes. Illustrative is the synthesis of selenoureas from cyanamides: [11]
H2Se gas is used to dope semiconductors with selenium.
Hydrogen selenide is hazardous, being the most toxic selenium compound [3] and far more toxic than its congener hydrogen sulfide. The threshold limit value is 0.05 ppm. The gas acts as an irritant at concentrations higher than 0.3 ppm, which is the main warning sign of exposure; below 1 ppm, this is "insufficient to prevent exposure", while at 1.5 ppm the irritation is "intolerable". [5] Exposure at high concentrations, even for less than a minute, causes the gas to attack the eyes and mucous membranes; this causes cold-like symptoms for at least a few days afterwards. In Germany, the limit in drinking water is 0.008 mg/L, and the US EPA recommends a maximum contamination of 0.01 mg/L. [8] [12]
Despite being extremely toxic, no human fatalities have yet been reported. It is suspected that this is due to the gas' tendency to oxidise to form red selenium in mucous membranes; elemental selenium is less toxic than selenides are. [4]
Selenium is a chemical element; it has the symbol Se and atomic number 34. It has various physical appearances, including a brick-red powder, a vitreous black solid, and a grey metallic-looking form. It seldom occurs in this elemental state or as pure ore compounds in Earth's crust. Selenium was discovered in 1817 by Jöns Jacob Berzelius, who noted the similarity of the new element to the previously discovered tellurium.
1,2-Dibromoethane, also known as ethylene dibromide (EDB), is an organobromine compound with the chemical formula C
2H
4Br
2. Although trace amounts occur naturally in the ocean, where it is probably formed by algae and kelp, substantial amounts are produced industrially. It is a dense colorless liquid with a faint, sweet odor, detectable at 10 ppm. It is a widely used and sometimes-controversial fumigant. The combustion of 1,2-dibromoethane produces hydrogen bromide gas that is significantly corrosive.
Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula PH3, classed as a pnictogen hydride. Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane (P2H4). With traces of P2H4 present, PH3 is spontaneously flammable in air (pyrophoric), burning with a luminous flame. Phosphine is a highly toxic respiratory poison, and is immediately dangerous to life or health at 50 ppm. Phosphine has a trigonal pyramidal structure.
Pentaborane(9) is an inorganic compound with the formula B5H9. It is one of the most common boron hydride clusters, although it is a highly reactive compound. Because of its high reactivity with oxygen, it was once evaluated as rocket or jet fuel. Like many of the smaller boron hydrides, pentaborane is colourless, diamagnetic, and volatile. It is related to pentaborane(11).
Oxygen difluoride is a chemical compound with the formula OF2. As predicted by VSEPR theory, the molecule adopts a bent molecular geometry. It is a strong oxidizer and has attracted attention in rocketry for this reason. With a boiling point of −144.75 °C, OF2 is the most volatile (isolable) triatomic compound. The compound is one of many known oxygen fluorides.
Ethylbenzene is an organic compound with the formula C6H5CH2CH3. It is a highly flammable, colorless liquid with an odor similar to that of gasoline. This monocyclic aromatic hydrocarbon is important in the petrochemical industry as a reaction intermediate in the production of styrene, the precursor to polystyrene, a common plastic material. In 2012, more than 99% of ethylbenzene produced was consumed in the production of styrene.
Phosphorus trichloride is an inorganic compound with the chemical formula PCl3. A colorless liquid when pure, it is an important industrial chemical, being used for the manufacture of phosphites and other organophosphorus compounds. It is toxic and reacts readily with water to release hydrogen chloride.
Selenium dioxide is the chemical compound with the formula SeO2. This colorless solid is one of the most frequently encountered compounds of selenium. It is used in making specialized glasses as well as a reagent in organic chemistry.
Allyl alcohol is an organic compound with the structural formula CH2=CHCH2OH. Like many alcohols, it is a water-soluble, colourless liquid. It is more toxic than typical small alcohols. Allyl alcohol is used as a precursor to many specialized compounds such as flame-resistant materials, drying oils, and plasticizers. Allyl alcohol is the smallest representative of the allylic alcohols.
2-Chloroethanol (also called ethylene chlorohydrin or glycol chlorohydrin) is an organic chemical compound with the chemical formula HOCH2CH2Cl and the simplest beta-halohydrin (chlorohydrin). This colorless liquid has a pleasant ether-like odor. It is miscible with water. The molecule is bifunctional, consisting of both an alkyl chloride and an alcohol functional group.
Tellurium hexafluoride is the inorganic compound of tellurium and fluorine with the chemical formula TeF6. It is a colorless, highly toxic gas with an unpleasant odor.
Selenium oxydichloride is the inorganic compound with the formula SeOCl2. It is a colorless liquid. With a high dielectric constant (55) and high specific conductance, it is an attractive solvent. Structurally, it is a close chemical relative of thionyl chloride SOCl2, being a pyramidal molecule.
Carbonyl fluoride is a chemical compound with the formula COF2. It is a carbon oxohalide. This gas, like its analog phosgene, is colourless and highly toxic. The molecule is planar with C2v symmetry, bond lengths of 1.174 Å (C=O) and 1.312 Å (C–F), and an F–C–F bond angle of 108.0°.
Selenium compounds are compounds containing the element selenium (Se). Among these compounds, selenium has various oxidation states, the most common ones being −2, +4, and +6. Selenium compounds exist in nature in the form of various minerals, such as clausthalite, guanajuatite, tiemannite, crookesite etc., and can also coexist with sulfide minerals such as pyrite and chalcopyrite. For many mammals, selenium compounds are essential. For example, selenomethionine and selenocysteine are selenium-containing amino acids present in the human body. Selenomethionine participates in the synthesis of selenoproteins. The reduction potential and pKa (5.47) of selenocysteine are lower than those of cysteine, making some proteins have antioxidant activity. Selenium compounds have important applications in semiconductors, glass and ceramic industries, medicine, metallurgy and other fields.
n-Butylamine is an organic compound (specifically, an amine) with the formula CH3(CH2)3NH2. This colourless liquid is one of the four isomeric amines of butane, the others being sec-butylamine, tert-butylamine, and isobutylamine. It is a liquid having the fishy, ammonia-like odor common to amines. The liquid acquires a yellow color upon storage in air. It is soluble in all organic solvents. Its vapours are heavier than air and it produces toxic oxides of nitrogen during combustion.
Selenium hexafluoride is the inorganic compound with the formula SeF6. It is a very toxic colourless gas described as having a "repulsive" odor. It is not widely encountered and has no commercial applications.
Sterilant gas monitoring is the detection of hazardous gases used by health care and other facilities to sterilize medical supplies that cannot be sterilized by heat or steam methods. The current FDA approved sterilant gases are ethylene oxide, hydrogen peroxide and ozone. Other liquid sterilants, such as peracetic acid, may also be used for sterilization and may raise similar occupational health issues. Sterilization means the complete destruction of all biological life, and sterilization efficacy is typically considered adequate if less than one in a million microbes remain viable.
Chloroacetaldehyde is an organic compound with the formula ClCH2CHO. Like some related compounds, it is highly electrophilic reagent and a potentially dangerous alkylating agent. The compound is not normally encountered in the anhydrous form, but rather as the hemiacetal (ClCH2CH(OH))2O.
Manure management refers to capture, storage, treatment, and utilization of animal manures in an environmentally sustainable manner. It can be retained in various holding facilities. Animal manure can occur in a liquid, slurry, or solid form. It is utilized by distribution on fields in amounts that enrich soils without causing water pollution or unacceptably high levels of nutrient enrichment. Manure management is a component of nutrient management.
Inhalation is a major route of exposure that occurs when an individual breathes in polluted air which enters the respiratory tract. Identification of the pollutant uptake by the respiratory system can determine how the resulting exposure contributes to the dose. In this way, the mechanism of pollutant uptake by the respiratory system can be used to predict potential health impacts within the human population.
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