Europium monoselenide

Last updated
Europium monoselenide
Names
Other names
Europium selenide, europium(II) selenide, selanylideneeuropium
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.499 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 234-662-9
PubChem CID
  • InChI=1S/Eu.Se
    Key: GCSIELJPGDPWNK-UHFFFAOYSA-N
  • [Eu]=[Se]
Properties
EuSe
Molar mass 230.92
Appearanceblack crystals
Density 6.45 g/cm3
Melting point 1,213 °C (2,215 °F; 1,486 K)
Structure
cubic, Fm3m
Hazards
GHS labelling:
GHS-pictogram-skull.svg GHS-pictogram-silhouette.svg GHS-pictogram-pollu.svg
Danger
H301, H331, H373
P260, P261, P301+P310, P304+P340, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Europium monoselenide is a binary inorganic compound of europium and selenium with the chemical formula EuSe. [1] The compound forms black crystals.

Contents

Synthesis

Eu + Se → EuSe
EuC2O4 + Se + H2 → EuSe + H2O + CO2 + CO

Physical properties

Europium monoselenide forms black (or brown) crystals of cubic syngony, spatial group Fm3m, cell parameters a = 0.6185 nm, Z = 4. [3] [4]

Ferromagnetic at curie temperature 7 K.

Related Research Articles

<span class="mw-page-title-main">Europium(III) chloride</span> Chemical compound

Europium(III) chloride is an inorganic compound with the formula EuCl3. The anhydrous compound is a yellow solid. Being hygroscopic it rapidly absorbs water to form a white crystalline hexahydrate, EuCl3·6H2O, which is colourless. The compound is used in research.

<span class="mw-page-title-main">Antimony triselenide</span> Chemical compound

Antimony triselenide is the chemical compound with the formula Sb2Se3. The material exists as the sulfosalt mineral antimonselite, which crystallizes in an orthorhombic space group. In this compound, antimony has a formal oxidation state +3 and selenium −2. The bonding in this compound has covalent character as evidenced by the black color and semiconducting properties of this and related materials. The low-frequency dielectric constant (ε0) has been measured to be 133 along the c axis of the crystal at room temperature, which is unusually large. Its band gap is 1.18 eV at room temperature.

<span class="mw-page-title-main">Europium(II) sulfide</span> Chemical compound

Europium (II) sulfide is the inorganic compound with the chemical formula EuS. It is a black, air-stable powder. Europium possesses an oxidation state of +II in europium sulfide, whereas the lanthanides exhibit a typical oxidation state of +III. Its Curie temperature (Tc) is 16.6 K. Below this temperature EuS behaves like a ferromagnetic compound, and above it exhibits simple paramagnetic properties. EuS is stable up to 500 °C in air, when it begins to show signs of oxidation. In an inert environment it decomposes at 1470 °C.

Uranium diselenide is a compound of uranium and selenium. It has a β form that has orthorhombic crystal system. The family of crystals it matches is PbCl2. The dimensions of the unit cell are a: 7.455 Å, b: 4.2320 Å, c= 8.964 Å. The compound has the unusual property of ferromagnetism, but only if the temperature is below 14 K.

Chromium(II) selenide is an inorganic compound with the chemical formula CrSe. It crystalizes in a hexagonal structure with space group P63/mmc. It is one of many related Chromium-Selenium phases, including Cr7Se8, Cr3Se4, Cr0.68Se, Cr2Se3, and Cr5Se8. The compound has been described as an antiferromagnet, but its inverse magnetic susceptibility does not match the behavior expected for an antiferromagnet according to the Curie–Weiss law. One suggestion was that the Néel temperature is at 320 K, as the temperature where the compound has maximum specific heat. When synthesized as single atomic layer, CrSe is ferromagnetic, with a Curie Temperature of around 280 K.

<span class="mw-page-title-main">Tungsten diselenide</span> Chemical compound

Tungsten diselenide is an inorganic compound with the formula WSe2. The compound adopts a hexagonal crystalline structure similar to molybdenum disulfide. The tungsten atoms are covalently bonded to six selenium ligands in a trigonal prismatic coordination sphere while each selenium is bonded to three tungsten atoms in a pyramidal geometry. The tungsten–selenium bond has a length of 0.2526 nm, and the distance between selenium atoms is 0.334 nm. It is a well studied example of a layered material. The layers stack together via van der Waals interactions. WSe2 is a very stable semiconductor in the group-VI transition metal dichalcogenides.

Phosphorus selenides are a relatively obscure group of compounds. There have been some studies of the phosphorus - selenium phase diagram and the glassy amorphous phases are reported. The compounds that have been reported are shown below. While some of phosphorus selenides are similar to their sulfide analogues, there are some new forms, molecular P2Se5 and the polymeric catena-[P4Se4]x. There is also some doubt about the existence of molecular P4Se10.

Platinum diselenide is a transition metal dichalcogenide with the formula PtSe2. It is a layered substance that can be split into layers down to three atoms thick. PtSe2 can behave as a metalloid or as a semiconductor depending on the thickness.

An oxyhydride is a mixed anion compound containing both oxide O2− and hydride ions H. These compounds may be unexpected as the hydrogen and oxygen could be expected to react to form water. But if the metals making up the cations are electropositive enough, and the conditions are reducing enough, solid materials can be made that combine hydrogen and oxygen in the negative ion role.

<span class="mw-page-title-main">Europium hydride</span> Chemical compound

Europium hydride is the most common hydride of europium with a chemical formula EuH2. In this compound, europium atom is in the +2 oxidation state and the hydrogen atoms are -1. It is a ferromagnetic semiconductor.

Europium(II) fluoride is an inorganic compound with a chemical formula EuF2. It was first synthesized in 1937.

Plutonium selenide is a binary inorganic compound of plutonium and selenium with the chemical formula PuSe. The compound forms black crystals and does not dissolve in water.

A selenate selenite is a chemical compound or salt that contains selenite and selenate anions (SeO32- and SeO42-). These are mixed anion compounds. Some have third anions.

Europium phosphide is an inorganic compound of europium and phosphorus with the chemical formula EuP. Other phosphides are also known.

<span class="mw-page-title-main">Europium(II) oxide</span> Chemical compound

Europium(II) oxide (EuO) is a chemical compound which is one of the oxides of europium. In addition to europium(II) oxide, there is also europium(III) oxide and the mixed valence europium(II,III) oxide.

Phosphide iodides or iodide phosphides are compounds containing anions composed of iodide (I) and phosphide (P3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the phosphide chlorides, arsenide iodides antimonide iodides and phosphide bromides.

Phosphide bromides or bromide phosphides are compounds containing anions composed of bromide (Br) and phosphide (P3−) anions. Usually phosphorus is covalently connected into more complex structures. They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the phosphide chlorides, phosphide iodides, nitride bromides, arsenide bromides, and antimonide bromides.

<span class="mw-page-title-main">Europium compounds</span> Chemical compounds with at least one europium atom

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

Europium(III) oxalate (Eu2(C2O4)3) is a chemical compound of europium and oxalic acid. There are different hydrates including the decahydrate, hexahydrate and tetrahydrate. Europium(II) oxalate is also known.

Samarium compounds are compounds formed by the lanthanide metal samarium (Sm). In these compounds, samarium generally exhibits the +3 oxidation state, such as SmCl3, Sm(NO3)3 and Sm(C2O4)3. Compounds with samarium in the +2 oxidation state are also known, for example SmI2.

References

  1. "Europium Selenide". American Elements . Retrieved 3 April 2023.
  2. Klemm, Wilhelm; Senff, Heinz (5 May 1939). "Messungen an zwei- und vierwertigen Verbindungen der seltenen Erden. VIII. Chalkogenide des zweiwertigen Europiums". Zeitschrift für anorganische und allgemeine Chemie (in German). 241 (2–3): 259–263. doi:10.1002/zaac.19392410212. ISSN   0863-1786 . Retrieved 3 April 2023.
  3. McGuire, T. R.; Shafer, M. W. (1 March 1964). "Ferromagnetic Europium Compounds". Journal of Applied Physics . 35 (3): 984–988. Bibcode:1964JAP....35..984M. doi:10.1063/1.1713568. ISSN   0021-8979 . Retrieved 3 April 2023.
  4. Subhadra, K. G.; Raghavendra Rao, B.; Sirdeshmukh, D. B. (1 June 1992). "X-ray determination of the Debye-Waller factors and Debye temperatures of europium monochalcogenides". Pramana. 38 (6): 681–683. Bibcode:1992Prama..38..681S. doi:10.1007/BF02875064. ISSN   0973-7111. S2CID   123290263 . Retrieved 3 April 2023.