Europium(III) nitrate

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Europium(III) nitrate
Europium nitrate.jpg
Names
IUPAC name
Europium trinitrate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.333 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
  • InChI=1S/Eu.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1;;;;;;
    Key: JVYYYCWKSSSCEI-UHFFFAOYSA-N
  • [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.O.[Eu+3]
Properties
Eu(NO3)3
Molar mass 337.985 g/mol
446.081 g/mol (hexahydrate)
Melting point 65 [1]  °C (149 °F; 338 K) (hexahydrate) decomposes
Soluble
Hazards
GHS labelling:
GHS-pictogram-rondflam.svg GHS-pictogram-exclam.svg
Warning
H272, H315, H319, H335
P210, P220, P221, P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P405, P501
Related compounds
Other anions
Europium(III) phosphate
Europium(III) arsenate
Other cations
Samarium(III) nitrate
Gadolinium(III) nitrate
Related compounds
Europium(II) nitrate
Europium(III) oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Europium(III) nitrate hexahydrate under fluorescent lamp (left) and UV light (right). Europium nitrate UV comparison.jpg
Europium(III) nitrate hexahydrate under fluorescent lamp (left) and UV light (right).

Europium(III) nitrate is an inorganic compound with the formula Eu(NO3)3·x(H2O). The hexahydrate is a common salt. It forms colorless hygroscopic crystals.

Contents

Preparation

The salt is usually obtained by dissolving europium(III) oxide (Eu2O3) in nitric acid produces europium(III) nitrate. [2]

Eu2O3 + 6 HNO3 → 2 Eu(NO3)3 + 3 H2O

Structure

Like all trinitates of the lanthanides, dilute (<0.01 M) solutions of consists of the aquo complex [Eu(H2O)x]3+ where x = 8 or 9. At higher concentrations, the binding of nitrate to Eu is observed. [3]

Complexes

Europium(III) nitrate reacts with anions and other Lewis bases to form complexes. For example, with 1,3,5-trimesic acid, europium metal-organic framework, a coordination polymer, under hydrothermal conditions. [4]

Related Research Articles

<span class="mw-page-title-main">Europium</span> Chemical element, symbol Eu and atomic number 63

Europium is a chemical element; it has symbol Eu and atomic number 63. Europium is a silvery-white metal of the lanthanide series that reacts readily with air to form a dark oxide coating. It is the most chemically reactive, least dense, and softest of the lanthanide elements. It is soft enough to be cut with a knife. Europium was isolated in 1901 and named after the continent of Europe. Europium usually assumes the oxidation state +3, like other members of the lanthanide series, but compounds having oxidation state +2 are also common. All europium compounds with oxidation state +2 are slightly reducing. Europium has no significant biological role and is relatively non-toxic compared to other heavy metals. Most applications of europium exploit the phosphorescence of europium compounds. Europium is one of the rarest of the rare-earth elements on Earth.

The lanthanide or lanthanoid series of chemical elements comprises at least the 14 metallic chemical elements with atomic numbers 57–70, from lanthanum through ytterbium. In the periodic table, they fill the 4f orbitals. Lutetium is also sometimes considered a lanthanide, despite being a d-block element and a transition metal.

<span class="mw-page-title-main">Copper(II) nitrate</span> Chemical compound

Copper(II) nitrate describes any member of the family of inorganic compounds with the formula Cu(NO3)2(H2O)x. The hydrates are blue solids. Anhydrous copper nitrate forms blue-green crystals and sublimes in a vacuum at 150-200 °C. Common hydrates are the hemipentahydrate and trihydrate.

In chemistry, water(s) of crystallization or water(s) of hydration are water molecules that are present inside crystals. Water is often incorporated in the formation of crystals from aqueous solutions. In some contexts, water of crystallization is the total mass of water in a substance at a given temperature and is mostly present in a definite (stoichiometric) ratio. Classically, "water of crystallization" refers to water that is found in the crystalline framework of a metal complex or a salt, which is not directly bonded to the metal cation.

<span class="mw-page-title-main">Europium(III) chloride</span> Chemical compound

Europium(III) chloride is an inorganic compound with the formula EuCl3. The anhydrous compound is a yellow solid. Being hygroscopic it rapidly absorbs water to form a white crystalline hexahydrate, EuCl3·6H2O, which is colourless. The compound is used in research.

<span class="mw-page-title-main">Iron(III) nitrate</span> Chemical compound

Iron(III) nitrate, or ferric nitrate, is the name used for a series of inorganic compounds with the formula Fe(NO3)3.(H2O)n. Most common is the nonahydrate Fe(NO3)3.(H2O)9. The hydrates are all pale colored, water-soluble paramagnetic salts.

<span class="mw-page-title-main">Cerium nitrates</span> Chemical compound

Cerium nitrate refers to a family of nitrates of cerium in the +3 or +4 oxidation state. Often these compounds contain water, hydroxide, or hydronium ions in addition to cerium and nitrate. Double nitrates of cerium also exist.

<span class="mw-page-title-main">Thorium(IV) nitrate</span> Chemical compound

Thorium(IV) nitrate is a chemical compound, a salt of thorium and nitric acid with the formula Th(NO3)4. A white solid in its anhydrous form, it can form tetra- and pentahydrates. As a salt of thorium it is weakly radioactive.

<span class="mw-page-title-main">Yttrium(III) nitrate</span> Chemical compound

Yttrium(III) nitrate is an inorganic compound, a salt with the formula Y(NO3)3. The hexahydrate is the most common form commercially available.

<span class="mw-page-title-main">Terbium(III) nitrate</span> Chemical compound

Terbium(III) nitrate is an inorganic chemical compound, a salt of terbium and nitric acid, with the formula Tb(NO3)3. The hexahydrate crystallizes as triclinic colorless crystals with the formula [Tb(NO3)3(H2O)4]·2H2O. It can be used to synthesize materials with green emission.

Nitrate chlorides are mixed anion compounds that contain both nitrate (NO3) and chloride (Cl) ions. Various compounds are known, including amino acid salts, and also complexes from iron group, rare-earth, and actinide metals. Complexes are not usually identified as nitrate chlorides, and would be termed chlorido nitrato complexes.

<span class="mw-page-title-main">Iron(II) nitrate</span> Chemical compound

Iron(II) nitrate is the nitrate salt of iron(II). It is commonly encountered as the green hexahydrate, Fe(NO3)2·6H2O, which is a metal aquo complex, however it is not commercially available unlike iron(III) nitrate due to its instability to air. The salt is soluble in water serves as a ready source of ferrous ions.

Lutetium(III) nitrate is an inorganic compound, a salt of lutetium and nitric acid with the chemical formula Lu(NO3)3. The compound forms colorless crystals, dissolves in water, and also forms crystalline hydrates. The compound is poisonous.

<span class="mw-page-title-main">Europium(III) acetate</span> Chemical compound

Europium(III) acetate is an inorganic salt of europium and acetic acid with the chemical formula of Eu(CH3COO)3. In this compound, europium exhibits the +3 oxidation state. It can exist in the anhydrous form, sesquihydrate and tetrahydrate. Its hydrate molecule is a dimer.

Europium(III) chromate is a chemical compound composed of europium, chromium and oxygen with europium in the +3 oxidation state, chromium in the +5 oxidation state and oxygen in the −2 oxidation state. It has the chemical formula of EuCrO4.

<span class="mw-page-title-main">Europium compounds</span> Chemical compounds

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

<span class="mw-page-title-main">Terbium compounds</span> Chemical compounds with at least one terbium atom

Terbium compounds are compounds formed by the lanthanide metal terbium (Tb). Terbium generally exhibits the +3 oxidation state in these compounds, such as in TbCl3, Tb(NO3)3 and Tb(CH3COO)3. Compounds with terbium in the +4 oxidation state are also known, such as TbO2 and BaTbF6. Terbium can also form compounds in the 0, +1 and +2 oxidation states.

Europium(III) iodide is an inorganic compound containing europium and iodine with the chemical formula EuI3.

Cobalt compounds are chemical compounds formed by cobalt with other elements.

Europium(III) carbonate is an inorganic compound with the chemical formula Eu2(CO3)3.

References

  1. Melnikov, P.; Arkhangelsky, I. V.; Nascimento, V. A.; De Oliveira, L. C. S.; Silva, A. F.; Zanoni, L. Z. (2017). "Thermal properties of europium nitrate hexahydrate Eu(NO3)3·6H2O" (PDF). Journal of Thermal Analysis and Calorimetry. 128 (3): 1353–1358. doi:10.1007/s10973-016-6047-9. S2CID   99674207.
  2. Odent, Guy; Charetteur, Elisabeth; Duperray, Marie H. Crystallization, radiocrystallographic characterization, and infrared absorption spectra of hexahydrates and pentahydrates of nitrates and lanthanides. Revue de Chimie Minerale, 1975. 12 (1): 17-23.
  3. Yatsenko, Alexandr V.; Gloriozov, Igor P.; Zhokhova, Nelly I.; Paseshnichenko, Ksenia A.; Aslanov, Leonid A.; Ustynyuk, Yuri A. (2021). "Structure of lanthanide nitrates in solution and in the solid state: DFT modelling of hydration effects". Journal of Molecular Liquids. 323. doi:10.1016/j.molliq.2020.115005.
  4. Habimana, Fabien; Huo, Yanxia; Jiang, Sai; Ji, Shengfu. Synthesis of europium metal-organic framework (Eu-MOF) and its performance in adsorptive desulfurization. Adsorption, 2016. 22 (8): 1147-1155. DOI:10.1007/s10450-016-9838-1.