Carbonate nitrate

Last updated

Carbonate nitrates are mixed anion compounds containing both carbonate and nitrate ions.

Hydrotalcite can contain carbonate and nitrate ions between its layers. Magnesium can be substituted by nickel, cobalt or copper. [1]

Oxycarbonitrates containing an alkaline earth metal and cuprate and nitrate and carbonate anions in layers, form a family of superconducting materials. [2]

List

nameformularatioformula

weight

crystal

system

space

group

unit cell Åvolumedensitycommentref
Tetraammine(carbonato-κ2O,O′)cobalt(III) nitrate(Co(NH3)5(CO3))(NO3)·H2O1:1monoclinicP21/ca = 7.8520 b = 6.7922 c = 17.5394 β = 95.440° Z = 4931.2 [3]
(Co(NH3)4CO3)(NO3)·(H2O)0.51:1monoclinicP21/na=7.4319 b=22.647 c=10.4103 β=92.052° Z=817561.95violet-red; loses water at 125°C [4] [5]
(Co(NH3)4(CO3)(NO3))2·H2O1:1monoclinicP21/na=7.4960 b=22.673 c=10.513 β=91.41° Z=41786.121.915 [6]
[Co(NH3)5CO3]NO3·1/2H2O1:1monoclinicP21/ma=7.6661 b=9.6212 c=7.0725 β=106.261° Z=2500.781.82pink [7]
[Co(NH3)5CO3]NO3·H2O1:1monoclinicP21a = 7.6733 b = 9.6398 c = 7.0852 β = 106.195°1.87pink [8]
Tetraammine(carbonato-κ2O,O′)cobalt(III) nitrate(Co(CO3)(NH3)4)(NO3)1:1monoclinicP21/ca = 7.8520 b = 6.7922 c = 17.5394 β = 95.440° Z = 4931.2pink [9]
[(NH3)3Co(μ-OH)2(μ-CO3)Co(NH3)3][NO3]2·H2O1:2triclinicP1a=7.7038 b=9.672 c=10.861 α=104.826° β=109.405° γ=91.553° [10]
cis-(Carbonato-O,O')-bis(2,2'-bipyridine)-cobalt(iii) nitrate pentahydrate[Co(C10H8N2)2(CO3)]NO3·5H2OmonoclinicC2/ca=10.931 b=16.039 c=14.435β=101.94° Z=42476 [11]
Na3Rb6(CO3)3(NO3)2Cl·(H2O)63:21029.39hexagonalP63/mcma = 9.5732 c = 15.820 Z=21255.62.723UV cut off 231 nm;

(-) uniaxial;

birefringence 0.14 @ 546 nm

 [12]
Na3Rb6(CO3)3(NO3)2Br·6H2O3:2hexagonalP63/mcma=9.6086 c=15.864 Z=2 [13]
N0.2C0.8Sr3Cu2O7.0 [2]
C0.8N0.2Sr2CuO5.3 [14]
N0.5C0.5Sr3Cu2O7.4Tc=33 [2]
N0.5C0.5Sr2CaCu2O7.45Tc=91 [2]
N0.5C0.5Sr2.7Ca1.3Cu3O9.5Tc=91 [2]
N0.5C0.5Sr2.7Ca1.3Cu3O9.8Tc=101 [2]
N0.5C0.5Sr2.7Ca1.3Cu3O9.85Tc=101 [2]
N0.5C0.5Sr2Ca2Cu3O10.0 [2]
N0.5C0.5Sr2Ca3Cu4O10.0 [2]
N0.5C0.5Sr2Ca3Cu4O11.8Tc=99K [2]
N0.5C0.5Sr2Ca3Cu4O11.9Tc=101K [2]
N0.5C0.5Sr3.4Ca1.6Cu4O12.0Tc=105K [2]
YCaBa4Cu5(NO3)0.3(CO3)0.7O11superconductor Tc=82k [15]
hexakis(μ4-(R)-N2-(2-Oxybenzyl)asparaginato)-(μ3-carbonato-O,O,O',O',O'',O'')-diaqua-pentakis(methanol)-methoxy-hexakis(nitrato-O,O')-hepta-lanthanum(iii) methanol solvate tetrahydratemonoclinicP21a=15.6719 b=25.570 c=16.472 β=101.838°colourless [16]
hexakis(μ4-(S)-N2-(2-Oxybenzyl)asparaginato)-(μ3-carbonato-O,O,O',O',O'',O'')-heptakis(methanol)-methoxy-hexakis(nitrato-O,O')-hepta-lanthanum(iii) methanol solvate pentahydratemonoclinicP21a=15.662 b=25.624 c=16.460 β=101.924° [16]
pentakis(μ3-Glycine hydroxamato)-tetraaqua-(nitrato-O)-(nitrato-O,O')-penta-copper(ii)-europium(iii) tetrahydrate[EuCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.5H2OtriclinicP1a=11.163 b=11.524 c=13.323 α=93.85° β=94.79° γ=107.14° Z=216242.425 [17]
pentakis(μ-2-amino-N-oxidoethanimidato)-(carbonato)-nitrato-penta-aqua-penta-copper(ii)-gadolinium(iii) hydrate[GdCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.5H2OtriclinicP1a=11.206 b=11.505 c=13.298 α=94.026° β=94.942° γ=107.558° Z=21620.22.440dark blue [17]
pentakis(μ-2-amino-N-oxidoethanimidato)-(carbonato)-nitrato-penta-aqua-penta-copper(ii)-dysprosium(iii) hydrate[DyCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.28H2OtriclinicP1a=11.1083 b=11.4991 c=13.2894 α=93.923° β=94.771° γ=107.147° Z=21608.72.460dark blue [17]
[HoCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.445H2OtriclinicP1a=11.2027 b=11.4955 c=13.247 α=94.001° β=94.784° γ=107.518° Z=21613.02.467dark blue [17]
bis(μ4-carbonato-O,O,O',O')-tetrakis(diammineplatinum(II))

tetranitrate trihydrate

((Pt(NH3)2)4(CO3)2)(NO3)4·(H2O)32:4triclinicP1a=11.324 b=12.151 c=10.926 α=103.792° β=111.266° γ=75.845°blue [18]
(Tl5/6Cr1/6)Sr4Cu2(CO3)1/2(NO3)1/2O7tetragonala = 3.8320 c = 16.4112 [19]
[Pb6O4](OH)(NO3)(CO3)1:1orthorhombicPnmaa=30.557 b=5.809 c=7.183 Z=41274.9 [20]

References

  1. ↑ Chmielarz, Lucjan; Kuśtrowski, Piotr; Rafalska-Łasocha, Alicja; Dziembaj, Roman (2002). "Influence of Cu, Co and Ni cations incorporated in brucite-type layers on thermal behaviour of hydrotalcites and reducibility of the derived mixed oxide systems". Thermochimica Acta. 395 (1–2): 225–236. Bibcode:2002TcAc..395..225C. doi:10.1016/S0040-6031(02)00214-9.
  2. 1 2 3 4 5 6 7 8 9 10 11 12 Zhigadlo, N D; Matveev, A T; Anan, Y; Asaka, T; Kimoto, K; Matsui, Y; Takayama-Muromachi, E (2000-08-01). "High-pressure synthesis and properties of a new oxycarbonitrate superconductors in the Sr-Ca-Cu-N-C-O system" . Superconductor Science and Technology. 13 (8): 1246–1251. Bibcode:2000SuScT..13.1246Z. doi:10.1088/0953-2048/13/8/322. ISSN   0953-2048. S2CID   121018578.
  3. ↑ Le Bail, Armel (2013-07-15). "Tetraammine(carbonato-κ 2 O , O ′)cobalt(III) nitrate: a powder X-ray diffraction study". Acta Crystallographica Section E: Structure Reports Online. 69 (7): i42 –i43. doi:10.1107/S1600536813017522. ISSN   1600-5368. PMC   3772400 . PMID   24046543.
  4. ↑ Christensen, A. Nørlund; Hazell, R. G.; Larsen, Mogens; Thorup, Niels; Lönnberg, Harri; Yan, Shi-Ping; Wang, Geng-Lin; Yao, Xin-Kan; Wang, Hong-Gen; Tuchagues, J. -P.; Ögren, Mattias (1999). "X-Ray Crystallographic Study and Thermogravimetric Analysis of Tetrammine-Carbonatocobalt(III) Nitrate Hemihydrate, [Co(NH3)4CO3]NO3.0.5H2O". Acta Chemica Scandinavica. 53: 399–402. doi: 10.3891/acta.chem.scand.53-0399 . ISSN   0904-213X.
  5. ↑ Schlessinger, G.; Simmons, John W.; Jabs, Gerhardt; Chamberlain, Mark M. (January 1960). "Carbonatotetramminecobalt(III) Nitrate". Inorganic Syntheses. Vol. 6. Wiley. pp. 173–175. doi:10.1002/9780470132371.ch55. ISBN   978-0-470-13165-7.{{cite book}}: ISBN / Date incompatibility (help)
  6. ↑ Bernal, Ivan; Cetrullo, James (1990). "The phenomenon of conglomerate crystallization. XVIII. Clavic dissymmetry in coordination compounds. XVI: The crystal structure of racemic {[Co(NH3)4(CO3)]NO3}2•H2O" . Structural Chemistry. 1 (2–3): 227–234. doi:10.1007/BF00674266. ISSN   1040-0400. S2CID   104369327.
  7. ↑ Wu, Hongxiang; Zhu, Jianghai; Ma, Lidun; Shen, Xiaoliang; Shi, Guoshun (March 1998). "Powder diffraction of [ Co ( NH 3 ) 5 CO 3 ] NO 3 ·1/2 H 2 O and [ Co ( NH 3 ) 4 CO 3 ] NO 3 ·1/2 H 2 O" . Powder Diffraction. 13 (1): 32–34. doi:10.1017/S0885715600009726. ISSN   0885-7156. S2CID   94225228.
  8. ↑ Zhu, J.H.; Wu, H.X.; Le Bail, A. (January 1999). "Structure of [Co(NH3)5CO3]NO3·H2O" . Solid State Sciences. 1 (1): 55–62. doi:10.1016/S1293-2558(00)80064-3.
  9. ↑ Le Bail, Armel (2013-07-15). "Tetraammine(carbonato-κ 2 O , O ′)cobalt(III) nitrate: a powder X-ray diffraction study". Acta Crystallographica Section E: Structure Reports Online. 69 (7): i42 –i43. doi:10.1107/S1600536813017522. ISSN   1600-5368. PMC   3772400 . PMID   24046543.
  10. ↑ Junk, Peter C.; Steed, Jonathan W. (December 1999). "Syntheses and X-ray crystal structures of [Co(η2-CO3)(NH3)4](NO3)·0.5H2O and [(NH3)3Co(μ-OH)2(μ-CO3)Co(NH3)3][NO3]2·H2O" . Polyhedron. 18 (27): 3593–3597. doi:10.1016/S0277-5387(99)00293-4.
  11. ↑ Niederhoffer, Eric C.; Martell, Arthur E.; Rudolf, Phil; Clearfield, Abraham (October 1982). "Structures of (carbonato)bis(2,2'-bipyridine)cobalt(III) and (carbonato)bis(1,10-phenanthroline)cobalt(III) complexes" . Inorganic Chemistry. 21 (10): 3734–3741. doi:10.1021/ic00140a028. ISSN   0020-1669.
  12. ↑ Cheng, Meng; Jin, Wenqi; Yang, Zhihua; Pan, Shilie (2022). "Large optical anisotropy-oriented construction of a carbonate-nitrate chloride compound as a potential ultraviolet birefringent material". Chemical Science. 13 (45): 13482–13488. doi:10.1039/D2SC03771H. ISSN   2041-6520. PMC   9685371 . PMID   36507155.
  13. ↑ Hu, Zhaowei; Liu, Lili; Zhang, Ruixin; Jing, Qun; Wang, Huan; Tian, Jindan; Xu, Jiayue; Halasyamani, P. Shiv (2023). "An effective pathway to design and synthesize UV birefringent crystals via rational assembly of π-conjugated [CO 3 ] 2− and [NO 3 ] − triangles" . Journal of Materials Chemistry C. 11 (9): 3325–3333. doi:10.1039/D2TC05374H. ISSN   2050-7526. S2CID   256593719.
  14. ↑ Zhigadlo, Nikolai; Anan, Yoshihiro; Asaka, Toru; Matsui, Yoshio; Takayama-Muromachi, Eiji (2000), Yamashita, Tsutomu; Tanabe, Kei-ichi (eds.), "New oxycarbonitrate superconductors (C1-xNx)Sr2CuO5+y with a 1201-type structure" , Advances in Superconductivity XII, Tokyo: Springer Japan, pp. 98–100, doi:10.1007/978-4-431-66877-0_20, ISBN   978-4-431-70270-2 , retrieved 2024-02-27
  15. ↑ Hervieu, M.; Michel, C.; Raveau, B. (1993-08-01). "New extended defects in the superconductive "123" yttrium calcium barium copper oxycarbonitrate YCaBa4Cu5(NO3)x(CO3)1-xO11: HREM study" . Chemistry of Materials. 5 (8): 1126–1132. doi:10.1021/cm00032a016. ISSN   0897-4756.
  16. 1 2 Tang, Xiao-Liang; Wang, Wen-Hua; Dou, Wei; Jiang, Jie; Liu, Wei-Sheng; Qin, Wen-Wu; Zhang, Guo-Lin; Zhang, Hong-Rui; Yu, Kai-Bei; Zheng, Li-Min (2009-04-27). "Olive-Shaped Chiral Supramolecules: Simultaneous Self-Assembly of Heptameric Lanthanum Clusters and Carbon Dioxide Fixation" . Angewandte Chemie International Edition. 48 (19): 3499–3502. doi:10.1002/anie.200900838. ISSN   1433-7851. PMID   19353611.
  17. 1 2 3 4 Pavlishchuk, A.; Naumova, D.; Zeller, M.; Calderon Cazorla, S.; Addison, A. W. (2019-08-01). "The crystal structures of {LnCu5}3+ (Ln = Gd, Dy and Ho) 15-metallacrown-5 complexes and a reevaluation of the isotypic EuIII analogue". Acta Crystallographica Section E: Crystallographic Communications. 75 (8): 1215–1223. doi:10.1107/S205698901900999X. ISSN   2056-9890. PMC   6690475 . PMID   31417795.
  18. ↑ Mahtani, Hans K.; Chang, Shih Chi; Ruble, John R.; Black, Iona N. L.; Stein, Paul B. (October 1993). "Novel crystal structure of a tetranuclear platinum complex: bis(.mu.4-carbonato-O,O,O',O')-tetrakis(diammineplatinum(II)) tetranitrate trihydrate" . Inorganic Chemistry. 32 (22): 4976–4978. doi:10.1021/ic00074a053. ISSN   0020-1669.
  19. ↑ Barnabé, A.; Letouzé, F.; Pelloquin, D.; Maignan, A.; Hervieu, M.; Raveau, B. (1997-10-01). "A New Superconducting Oxycarbonitrate: (Tl 5/6 Cr 1/6 )Sr 4 Cu 2 (CO 3 ) 1/2 (NO 3 ) 1/2 O 7" . Chemistry of Materials. 9 (10): 2205–2211. doi:10.1021/cm970370v. ISSN   0897-4756.
  20. ↑ Li, Yaping; Krivovichev, Sergey V.; Burns, Peter C. (2000-09-01). "Crystal Chemistry of Lead Oxide Hydroxide Nitrates I. The Crystal Structure of [Pb6O4](OH)(NO3)(CO3)" . Journal of Solid State Chemistry. 153 (2): 365–370. doi:10.1006/jssc.2000.8784. ISSN   0022-4596.
This page is based on this Wikipedia article
Text is available under the CC BY-SA 4.0 license; additional terms may apply.
Images, videos and audio are available under their respective licenses.