Carbonate nitrate

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Carbonate nitrates are mixed anion compounds containing both carbonate and nitrate ions.

Hydrotalcite can contain carbonate and nitrate ions between its layers. Magnesium can be substituted by nickel, cobalt or copper. [1]

Oxycarbonitrates containing an alkaline earth metal and cuprate and nitrate and carbonate anions in layers, form a family of superconducting materials. [2]

List

nameformularatioformula

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unit cell Åvolumedensitycommentref
Tetraammine(carbonato-κ2O,O′)cobalt(III) nitrate(Co(NH3)5(CO3))(NO3)·H2O1:1monoclinicP21/ca = 7.8520 b = 6.7922 c = 17.5394 β = 95.440° Z = 4931.2 [3]
(Co(NH3)4CO3)(NO3)·(H2O)0.51:1monoclinicP21/na=7.4319 b=22.647 c=10.4103 β=92.052° Z=817561.95violet-red; loses water at 125°C [4] [5]
(Co(NH3)4(CO3)(NO3))2·H2O1:1monoclinicP21/na=7.4960 b=22.673 c=10.513 β=91.41° Z=41786.121.915 [6]
[Co(NH3)5CO3]NO3·1/2H2O1:1monoclinicP21/ma=7.6661 b=9.6212 c=7.0725 β=106.261° Z=2500.781.82pink [7]
[Co(NH3)5CO3]NO3·H2O1:1monoclinicP21a = 7.6733 b = 9.6398 c = 7.0852 β = 106.195°1.87pink [8]
Tetraammine(carbonato-κ2O,O′)cobalt(III) nitrate(Co(CO3)(NH3)4)(NO3)1:1monoclinicP21/ca = 7.8520 b = 6.7922 c = 17.5394 β = 95.440° Z = 4931.2pink [9]
[(NH3)3Co(μ-OH)2(μ-CO3)Co(NH3)3][NO3]2·H2O1:2triclinicP1a=7.7038 b=9.672 c=10.861 α=104.826° β=109.405° γ=91.553° [10]
cis-(Carbonato-O,O')-bis(2,2'-bipyridine)-cobalt(iii) nitrate pentahydrate[Co(C10H8N2)2(CO3)]NO3·5H2OmonoclinicC2/ca=10.931 b=16.039 c=14.435β=101.94° Z=42476 [11]
Na3Rb6(CO3)3(NO3)2Cl·(H2O)63:21029.39hexagonalP63/mcma = 9.5732 c = 15.820 Z=21255.62.723UV cut off 231 nm;

(-) uniaxial;

birefringence 0.14 @ 546 nm

 [12]
Na3Rb6(CO3)3(NO3)2Br·6H2O3:2hexagonalP63/mcma=9.6086 c=15.864 Z=2 [13]
N0.2C0.8Sr3Cu2O7.0 [2]
C0.8N0.2Sr2CuO5.3 [14]
N0.5C0.5Sr3Cu2O7.4Tc=33 [2]
N0.5C0.5Sr2CaCu2O7.45Tc=91 [2]
N0.5C0.5Sr2.7Ca1.3Cu3O9.5Tc=91 [2]
N0.5C0.5Sr2.7Ca1.3Cu3O9.8Tc=101 [2]
N0.5C0.5Sr2.7Ca1.3Cu3O9.85Tc=101 [2]
N0.5C0.5Sr2Ca2Cu3O10.0 [2]
N0.5C0.5Sr2Ca3Cu4O10.0 [2]
N0.5C0.5Sr2Ca3Cu4O11.8Tc=99K [2]
N0.5C0.5Sr2Ca3Cu4O11.9Tc=101K [2]
N0.5C0.5Sr3.4Ca1.6Cu4O12.0Tc=105K [2]
YCaBa4Cu5(NO3)0.3(CO3)0.7O11superconductor Tc=82k [15]
hexakis(μ4-(R)-N2-(2-Oxybenzyl)asparaginato)-(μ3-carbonato-O,O,O',O',O'',O'')-diaqua-pentakis(methanol)-methoxy-hexakis(nitrato-O,O')-hepta-lanthanum(iii) methanol solvate tetrahydratemonoclinicP21a=15.6719 b=25.570 c=16.472 β=101.838°colourless [16]
hexakis(μ4-(S)-N2-(2-Oxybenzyl)asparaginato)-(μ3-carbonato-O,O,O',O',O'',O'')-heptakis(methanol)-methoxy-hexakis(nitrato-O,O')-hepta-lanthanum(iii) methanol solvate pentahydratemonoclinicP21a=15.662 b=25.624 c=16.460 β=101.924° [16]
pentakis(μ3-Glycine hydroxamato)-tetraaqua-(nitrato-O)-(nitrato-O,O')-penta-copper(ii)-europium(iii) tetrahydrate[EuCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.5H2OtriclinicP1a=11.163 b=11.524 c=13.323 α=93.85° β=94.79° γ=107.14° Z=216242.425 [17]
pentakis(μ-2-amino-N-oxidoethanimidato)-(carbonato)-nitrato-penta-aqua-penta-copper(ii)-gadolinium(iii) hydrate[GdCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.5H2OtriclinicP1a=11.206 b=11.505 c=13.298 α=94.026° β=94.942° γ=107.558° Z=21620.22.440dark blue [17]
pentakis(μ-2-amino-N-oxidoethanimidato)-(carbonato)-nitrato-penta-aqua-penta-copper(ii)-dysprosium(iii) hydrate[DyCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.28H2OtriclinicP1a=11.1083 b=11.4991 c=13.2894 α=93.923° β=94.771° γ=107.147° Z=21608.72.460dark blue [17]
[HoCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.445H2OtriclinicP1a=11.2027 b=11.4955 c=13.247 α=94.001° β=94.784° γ=107.518° Z=21613.02.467dark blue [17]
bis(μ4-carbonato-O,O,O',O')-tetrakis(diammineplatinum(II))

tetranitrate trihydrate

((Pt(NH3)2)4(CO3)2)(NO3)4·(H2O)32:4triclinicP1a=11.324 b=12.151 c=10.926 α=103.792° β=111.266° γ=75.845°blue [18]
(Tl5/6Cr1/6)Sr4Cu2(CO3)1/2(NO3)1/2O7tetragonala = 3.8320 c = 16.4112 [19]
[Pb6O4](OH)(NO3)(CO3)1:1orthorhombicPnmaa=30.557 b=5.809 c=7.183 Z=41274.9 [20]

Related Research Articles

In chemistry, water(s) of crystallization or water(s) of hydration are water molecules that are present inside crystals. Water is often incorporated in the formation of crystals from aqueous solutions. In some contexts, water of crystallization is the total mass of water in a substance at a given temperature and is mostly present in a definite (stoichiometric) ratio. Classically, "water of crystallization" refers to water that is found in the crystalline framework of a metal complex or a salt, which is not directly bonded to the metal cation.

<span class="mw-page-title-main">Iron(III) nitrate</span> Chemical compound

Iron(III) nitrate, or ferric nitrate, is the name used for a series of inorganic compounds with the formula Fe(NO3)3.(H2O)n. Most common is the nonahydrate Fe(NO3)3.(H2O)9. The hydrates are all pale colored, water-soluble paramagnetic salts.

<span class="mw-page-title-main">Cobalt(II) nitrate</span> Chemical compound

Cobalt nitrate is the inorganic compound with the formula Co(NO3)2.xH2O. It is cobalt(II)'s salt. The most common form is the hexahydrate Co(NO3)2·6H2O, which is a red-brown deliquescent salt that is soluble in water and other polar solvents.

<span class="mw-page-title-main">Cobalt(II) carbonate</span> Chemical compound

Cobalt(II) carbonate is the inorganic compound with the formula CoCO3. This reddish paramagnetic solid is an intermediate in the hydrometallurgical purification of cobalt from its ores. It is an inorganic pigment, and a precursor to catalysts. Cobalt(II) carbonate also occurs as the rare red/pink mineral spherocobaltite.

<span class="mw-page-title-main">Lithium cobalt oxide</span> Chemical compound

Lithium cobalt oxide, sometimes called lithium cobaltate or lithium cobaltite, is a chemical compound with formula LiCoO
2. The cobalt atoms are formally in the +3 oxidation state, hence the IUPAC name lithium cobalt(III) oxide.

<span class="mw-page-title-main">Cerium nitrates</span> Chemical compound

Cerium nitrate refers to a family of nitrates of cerium in the +3 or +4 oxidation state. Often these compounds contain water, hydroxide, or hydronium ions in addition to cerium and nitrate. Double nitrates of cerium also exist.

Nickel is one of the metals that can form Tutton's salts. The singly charged ion can be any of the full range of potassium, rubidium, cesium, ammonium (), or thallium. As a mineral the ammonium nickel salt, (NH4)2Ni(SO4)2 · 6 H2O, can be called nickelboussingaultite. With sodium, the double sulfate is nickelblödite Na2Ni(SO4)2 · 4 H2O from the blödite family. Nickel can be substituted by other divalent metals of similar sized to make mixtures that crystallise in the same form.

<span class="mw-page-title-main">Nickel oxyacid salts</span>

The Nickel oxyacid salts are a class of chemical compounds of nickel with an oxyacid. The compounds include a number of minerals and industrially important nickel compounds.

<span class="mw-page-title-main">Sulfate carbonate</span> Class of chemical compounds

The sulfate carbonates are a compound carbonates, or mixed anion compounds that contain sulfate and carbonate ions. Sulfate carbonate minerals are in the 7.DG and 5.BF Nickel-Strunz groupings.

The sulfate nitrates are a family of double salts that contain both sulfate and nitrate ions (NO3−, SO42−). They are in the class of mixed anion compounds. A few rare minerals are in this class. Two sulfate nitrates are in the class of anthropogenic compounds, accidentally made as a result of human activities in fertilizers that are a mix of ammonium nitrate and ammonium sulfate, and also in the atmosphere as polluting ammonia, nitrogen dioxide, and sulfur dioxide react with the oxygen and water there to form solid particles. The nitro group (NO3−) can act as a ligand, and complexes containing it can form salts with sulfate.

Nitrate chlorides are mixed anion compounds that contain both nitrate (NO3−) and chloride (Cl−) ions. Various compounds are known, including amino acid salts, and also complexes from iron group, rare-earth, and actinide metals. Complexes are not usually identified as nitrate chlorides, and would be termed chlorido nitrato complexes.

<span class="mw-page-title-main">Transition metal nitrite complex</span> Chemical complexes containing one or more –NO₂ ligands

In organometallic chemistry, transition metal complexes of nitrite describes families of coordination complexes containing one or more nitrite ligands. Although the synthetic derivatives are only of scholarly interest, metal-nitrite complexes occur in several enzymes that participate in the nitrogen cycle.

<span class="mw-page-title-main">Yttrium oxalate</span> Chemical compound

Yttrium oxalate is an inorganic compound, a salt of yttrium and oxalic acid with the chemical formula Y2(C2O4)3. The compound does not dissolve in water and forms crystalline hydrates—colorless crystals.

The carbonate oxalates are mixed anion compounds that contain both carbonate (CO3) and oxalate (C2O4) anions. Most compounds incorporate large trivalent metal ions, such as the rare earth elements. Some carbonate oxalate compounds of variable composition are formed by heating oxalates.

A nitrate nitrite, or nitrite nitrate, is a coordination complex or other chemical compound that contains both nitrite and nitrate anions (NO3− and NO2−). They are mixed-anion compounds, and they are mixed-valence compounds. Some have third anions. Many nitrite nitrate compounds are coordination complexes of cobalt. Such a substance was discovered by Wolcott Gibbs and Frederick Genth in 1857.

An oxalate nitrate is a chemical compound or salt that contains oxalate and nitrate anions (NO3- and C2O42-). These are mixed anion compounds. Some have third anions. Oxalate acts as a ligand, which normally complexes two metal atoms.

<span class="mw-page-title-main">Transition metal nitrate complex</span> Compound of nitrate ligands

A transition metal nitrate complex is a coordination compound containing one or more nitrate ligands. Such complexes are common starting reagents for the preparation of other compounds.

Cobalt compounds are chemical compounds formed by cobalt with other elements.

<span class="mw-page-title-main">Sodium tris(carbonato)cobalt(III)</span> Chemical compound

Sodium tris(carbonato)cobalt(III) is the inorganic compound with the formula Na3Co(CO3)3•3H2O. The salt contains an olive-green metastable cobalt(III) coordination complex. The salt, a homoleptic metal carbonato complex, is sometimes referred to as the “Field-Durrant precursor” and is prepared by the “Field-Durrant synthesis”. It is used in the synthesis of other cobalt(III) complexes. Otherwise cobalt(III) complexes are generated from cobalt(II) precursors, a process that requires an oxidant.

<span class="mw-page-title-main">Transition metal carbonate and bicarbonate complexes</span>

Transition metal carbonate and bicarbonate complexes are coordination compounds containing carbonate (CO32-) and bicarbonate (HCO3-) as ligands. The inventory of complexes is large, enhanced by the fact that the carbonate ligand can bind metal ions in a variety of bonding modes. They illustrate the fate of low valent complexes when exposed to air.

References

  1. ↑ Chmielarz, Lucjan; Kuśtrowski, Piotr; Rafalska-Łasocha, Alicja; Dziembaj, Roman (2002). "Influence of Cu, Co and Ni cations incorporated in brucite-type layers on thermal behaviour of hydrotalcites and reducibility of the derived mixed oxide systems". Thermochimica Acta. 395 (1–2): 225–236. doi:10.1016/S0040-6031(02)00214-9.
  2. 1 2 3 4 5 6 7 8 9 10 11 12 Zhigadlo, N D; Matveev, A T; Anan, Y; Asaka, T; Kimoto, K; Matsui, Y; Takayama-Muromachi, E (2000-08-01). "High-pressure synthesis and properties of a new oxycarbonitrate superconductors in the Sr-Ca-Cu-N-C-O system". Superconductor Science and Technology. 13 (8): 1246–1251. Bibcode:2000SuScT..13.1246Z. doi:10.1088/0953-2048/13/8/322. ISSN   0953-2048. S2CID   121018578.
  3. ↑ Le Bail, Armel (2013-07-15). "Tetraammine(carbonato-κ 2 O , O ′)cobalt(III) nitrate: a powder X-ray diffraction study". Acta Crystallographica Section e Structure Reports Online. 69 (7): i42–i43. doi:10.1107/S1600536813017522. ISSN   1600-5368. PMC   3772400 . PMID   24046543.
  4. ↑ Christensen, A. Nørlund; Hazell, R. G.; Larsen, Mogens; Thorup, Niels; Lönnberg, Harri; Yan, Shi-Ping; Wang, Geng-Lin; Yao, Xin-Kan; Wang, Hong-Gen; Tuchagues, J. -P.; Ögren, Mattias (1999). "X-Ray Crystallographic Study and Thermogravimetric Analysis of Tetrammine-Carbonatocobalt(III) Nitrate Hemihydrate, [Co(NH3)4CO3]NO3.0.5H2O". Acta Chemica Scandinavica. 53: 399–402. doi: 10.3891/acta.chem.scand.53-0399 . ISSN   0904-213X.
  5. ↑ Schlessinger, G.; Simmons, John W.; Jabs, Gerhardt; Chamberlain, Mark M. (January 1960). "Carbonatotetramminecobalt(III) Nitrate". Inorganic Syntheses. Vol. 6. Wiley. pp. 173–175. doi:10.1002/9780470132371.ch55. ISBN   978-0-470-13165-7.
  6. ↑ Bernal, Ivan; Cetrullo, James (1990). "The phenomenon of conglomerate crystallization. XVIII. Clavic dissymmetry in coordination compounds. XVI: The crystal structure of racemic {[Co(NH3)4(CO3)]NO3}2•H2O". Structural Chemistry. 1 (2–3): 227–234. doi:10.1007/BF00674266. ISSN   1040-0400. S2CID   104369327.
  7. ↑ Wu, Hongxiang; Zhu, Jianghai; Ma, Lidun; Shen, Xiaoliang; Shi, Guoshun (March 1998). "Powder diffraction of [ Co ( NH 3 ) 5 CO 3 ] NO 3 ·1/2 H 2 O and [ Co ( NH 3 ) 4 CO 3 ] NO 3 ·1/2 H 2 O". Powder Diffraction. 13 (1): 32–34. doi:10.1017/S0885715600009726. ISSN   0885-7156. S2CID   94225228.
  8. ↑ Zhu, J.H.; Wu, H.X.; Le Bail, A. (January 1999). "Structure of [Co(NH3)5CO3]NO3·H2O". Solid State Sciences. 1 (1): 55–62. doi:10.1016/S1293-2558(00)80064-3.
  9. ↑ Le Bail, Armel (2013-07-15). "Tetraammine(carbonato-κ 2 O , O ′)cobalt(III) nitrate: a powder X-ray diffraction study". Acta Crystallographica Section e Structure Reports Online. 69 (7): i42–i43. doi:10.1107/S1600536813017522. ISSN   1600-5368. PMC   3772400 . PMID   24046543.
  10. ↑ Junk, Peter C.; Steed, Jonathan W. (December 1999). "Syntheses and X-ray crystal structures of [Co(η2-CO3)(NH3)4](NO3)·0.5H2O and [(NH3)3Co(μ-OH)2(μ-CO3)Co(NH3)3][NO3]2·H2O". Polyhedron. 18 (27): 3593–3597. doi:10.1016/S0277-5387(99)00293-4.
  11. ↑ Niederhoffer, Eric C.; Martell, Arthur E.; Rudolf, Phil; Clearfield, Abraham (October 1982). "Structures of (carbonato)bis(2,2'-bipyridine)cobalt(III) and (carbonato)bis(1,10-phenanthroline)cobalt(III) complexes". Inorganic Chemistry. 21 (10): 3734–3741. doi:10.1021/ic00140a028. ISSN   0020-1669.
  12. ↑ Cheng, Meng; Jin, Wenqi; Yang, Zhihua; Pan, Shilie (2022). "Large optical anisotropy-oriented construction of a carbonate-nitrate chloride compound as a potential ultraviolet birefringent material". Chemical Science. 13 (45): 13482–13488. doi:10.1039/D2SC03771H. ISSN   2041-6520. PMC   9685371 . PMID   36507155.
  13. ↑ Hu, Zhaowei; Liu, Lili; Zhang, Ruixin; Jing, Qun; Wang, Huan; Tian, Jindan; Xu, Jiayue; Halasyamani, P. Shiv (2023). "An effective pathway to design and synthesize UV birefringent crystals via rational assembly of π-conjugated [CO 3 ] 2− and [NO 3 ] − triangles". Journal of Materials Chemistry C. 11 (9): 3325–3333. doi:10.1039/D2TC05374H. ISSN   2050-7526. S2CID   256593719.
  14. ↑ Zhigadlo, Nikolai; Anan, Yoshihiro; Asaka, Toru; Matsui, Yoshio; Takayama-Muromachi, Eiji (2000), Yamashita, Tsutomu; Tanabe, Kei-ichi (eds.), "New oxycarbonitrate superconductors (C1-xNx)Sr2CuO5+y with a 1201-type structure", Advances in Superconductivity XII, Tokyo: Springer Japan, pp. 98–100, doi:10.1007/978-4-431-66877-0_20, ISBN   978-4-431-70270-2 , retrieved 2024-02-27
  15. ↑ Hervieu, M.; Michel, C.; Raveau, B. (1993-08-01). "New extended defects in the superconductive "123" yttrium calcium barium copper oxycarbonitrate YCaBa4Cu5(NO3)x(CO3)1-xO11: HREM study". Chemistry of Materials. 5 (8): 1126–1132. doi:10.1021/cm00032a016. ISSN   0897-4756.
  16. 1 2 Tang, Xiao-Liang; Wang, Wen-Hua; Dou, Wei; Jiang, Jie; Liu, Wei-Sheng; Qin, Wen-Wu; Zhang, Guo-Lin; Zhang, Hong-Rui; Yu, Kai-Bei; Zheng, Li-Min (2009-04-27). "Olive-Shaped Chiral Supramolecules: Simultaneous Self-Assembly of Heptameric Lanthanum Clusters and Carbon Dioxide Fixation". Angewandte Chemie International Edition. 48 (19): 3499–3502. doi:10.1002/anie.200900838. ISSN   1433-7851.
  17. 1 2 3 4 Pavlishchuk, A.; Naumova, D.; Zeller, M.; Calderon Cazorla, S.; Addison, A. W. (2019-08-01). "The crystal structures of {LnCu5}3+ (Ln = Gd, Dy and Ho) 15-metallacrown-5 complexes and a reevaluation of the isotypic EuIII analogue". Acta Crystallographica Section E: Crystallographic Communications. 75 (8): 1215–1223. doi:10.1107/S205698901900999X. ISSN   2056-9890. PMC   6690475 . PMID   31417795.
  18. ↑ Mahtani, Hans K.; Chang, Shih Chi; Ruble, John R.; Black, Iona N. L.; Stein, Paul B. (October 1993). "Novel crystal structure of a tetranuclear platinum complex: bis(.mu.4-carbonato-O,O,O',O')-tetrakis(diammineplatinum(II)) tetranitrate trihydrate". Inorganic Chemistry. 32 (22): 4976–4978. doi:10.1021/ic00074a053. ISSN   0020-1669.
  19. ↑ Barnabé, A.; Letouzé, F.; Pelloquin, D.; Maignan, A.; Hervieu, M.; Raveau, B. (1997-10-01). "A New Superconducting Oxycarbonitrate: (Tl 5/6 Cr 1/6 )Sr 4 Cu 2 (CO 3 ) 1/2 (NO 3 ) 1/2 O 7". Chemistry of Materials. 9 (10): 2205–2211. doi:10.1021/cm970370v. ISSN   0897-4756.
  20. ↑ Li, Yaping; Krivovichev, Sergey V.; Burns, Peter C. (2000-09-01). "Crystal Chemistry of Lead Oxide Hydroxide Nitrates I. The Crystal Structure of [Pb6O4](OH)(NO3)(CO3)". Journal of Solid State Chemistry. 153 (2): 365–370. doi:10.1006/jssc.2000.8784. ISSN   0022-4596.
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