Names | |
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IUPAC name Cobalt(II) carbonate | |
Other names Cobaltous carbonate; cobalt(II) salt | |
Identifiers | |
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3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.007.428 |
PubChem CID | |
UNII |
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CompTox Dashboard (EPA) | |
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Properties | |
CoCO3 | |
Molar mass | 118.941 g/mol |
Appearance | pink solid |
Density | 4.13 g/cm3 |
Melting point | 427 °C (801 °F; 700 K) [1] decomposes before melting to cobalt(II) oxide (anhydrous) 140 °C (284 °F; 413 K) decomposes (hexahydrate) |
0.000142 g/100 mL (20 °C) [2] | |
Solubility product (Ksp) | 1.0·10−10 [3] |
Solubility | soluble in acid negligible in alcohol, methyl acetate insoluble in ethanol |
Refractive index (nD) | 1.855 |
Structure | |
Rhombohedral (anhydrous) Trigonal (hexahydrate) | |
Thermochemistry | |
Std molar entropy (S⦵298) | 79.9 J/mol·K [1] |
Std enthalpy of formation (ΔfH⦵298) | −722.6 kJ/mol [1] |
Gibbs free energy (ΔfG⦵) | -651 kJ/mol [1] |
Hazards | |
GHS labelling: | |
[4] | |
Warning | |
H302, H315, H317, H319, H335, H351 [4] | |
P261, P280, P305+P351+P338 [4] | |
NFPA 704 (fire diamond) | |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose) | 640 mg/kg (oral, rats) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Cobalt(II) carbonate is the inorganic compound with the formula CoCO3. This pink paramagnetic solid is an intermediate in the hydrometallurgical purification of cobalt from its ores. It is an inorganic pigment, and a precursor to catalysts. [5] Cobalt(II) carbonate also occurs as the rare red/pink mineral spherocobaltite. [6]
It is prepared by combining solutions cobaltous sulfate and sodium bicarbonate:
This reaction is used in the precipitation of cobalt from an extract of its roasted ores. [5]
CoCO3 adopts a structure like calcite, consisting of cobalt in an octahedral coordination geometry. [7]
Like most transition metal carbonates, cobalt carbonate is insoluble in water, but is readily attacked by mineral acids:
It is used to prepare many coordination complexes. The reaction of cobalt(II) carbonate and acetylacetone in the presence of hydrogen peroxide gives tris(acetylacetonato)cobalt(III). [8]
Heating the carbonate proceeds in a typical way for calcining, except that the product becomes partially oxidized:
The resulting Co3O4 converts reversibly to CoO at high temperatures. [9]
Cobalt carbonate is a precursor to cobalt carbonyl and various cobalt salts. It is a component of dietary supplements since cobalt is an essential element. It is a precursor to blue pottery glazes, famously in the case of Delftware.
At least two cobalt(II) carbonate-hydroxides are known: Co2(CO3)(OH)2 and Co6(CO3)2(OH)8·H2O. [10]
The moderately rare spherocobaltite is a natural form of cobalt carbonate, with good specimens coming especially from the Republic of Congo. "Cobaltocalcite" is a cobaltiferous calcite variety that is quite similar in habit to spherocobaltite. [6]
Toxicity has rarely been observed. Animals, including humans, require trace amounts of cobalt, a component of vitamin B12. [5]
Basic copper carbonate is a chemical compound, more properly called copper(II) carbonate hydroxide. It can be classified as a coordination polymer or a salt. It consists of copper(II) bonded to carbonate and hydroxide with formula Cu2(CO3)(OH)2. It is a green solid that occurs in nature as the mineral malachite. It has been used since antiquity as a pigment, and it is still used as such in artist paints, sometimes called verditer, green bice, or mountain green.
Magnesium carbonate, MgCO3, is an inorganic salt that is a colourless or white solid. Several hydrated and basic forms of magnesium carbonate also exist as minerals.
Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite. It is a product of copper mining and the precursor to many other copper-containing products and chemical compounds.
Manganese carbonate is a compound with the chemical formula MnCO3. Manganese carbonate occurs naturally as the mineral rhodochrosite but it is typically produced industrially. It is a pale pink, water-insoluble solid. Approximately 20,000 metric tonnes were produced in 2005.
Nickel(II) carbonate describes one or a mixture of inorganic compounds containing nickel and carbonate. From the industrial perspective, an important nickel carbonate is basic nickel carbonate with the formula Ni4CO3(OH)6(H2O)4. Simpler carbonates, ones more likely encountered in the laboratory, are NiCO3 and its hexahydrate. All are paramagnetic green solids containing Ni2+ cations. The basic carbonate is an intermediate in the hydrometallurgical purification of nickel from its ores and is used in electroplating of nickel.
Manganese(II) sulfate usually refers to the inorganic compound with the formula MnSO4·H2O. This pale pink deliquescent solid is a commercially significant manganese(II) salt. Approximately 260,000 tonnes of manganese(II) sulfate were produced worldwide in 2005. It is the precursor to manganese metal and many other chemical compounds. Manganese-deficient soil is remediated with this salt.
Trimagnesium phosphate describes inorganic compounds with formula Mg3(PO4)2.xH2O. They are magnesium acid salts of phosphoric acid, with varying amounts of water of crystallization: x = 0, 5, 8, 22.
Cobalt(II) sulfate is any of the inorganic compounds with the formula CoSO4(H2O)x. Usually cobalt sulfate refers to the hexa- or heptahydrates CoSO4.6H2O or CoSO4.7H2O, respectively. The heptahydrate is a red solid that is soluble in water and methanol. Since cobalt(II) has an odd number of electrons, its salts are paramagnetic.
Copper(II) phosphate are inorganic compounds with the formula Cu3(PO4)2. They can be regarded as the cupric salts of phosphoric acid. Anhydrous copper(II) phosphate and a trihydrate are blue solids.
Aluminium carbonate (Al2(CO3)3), is a carbonate of aluminium. It is not well characterized; one authority says that simple carbonates of aluminium are not known. However related compounds are known, such as the basic sodium aluminium carbonate mineral dawsonite (NaAlCO3(OH)2) and hydrated basic aluminium carbonate minerals scarbroite (Al5(CO3)(OH)13•5(H2O)) and hydroscarbroite (Al14(CO3)3(OH)36•nH2O).
Manganese(II) nitrate refers to the inorganic compounds with formula Mn(NO3)2·(H2O)n. These compounds are nitrate salts containing varying amounts of water. A common derivative is the tetrahydrate, Mn(NO3)2·4H2O, but mono- and hexahydrates are also known as well as the anhydrous compound. Some of these compounds are useful precursors to the oxides of manganese. Typical of a manganese(II) compound, it is a paramagnetic pale pink solid.
Nickel(II) acetate is the name for the coordination compounds with the formula Ni(CH3CO2)2·x H2O where x can be 0, 2, and 4. The green tetrahydrate Ni(CH3CO2)2·4 H2O is most common. It is used for electroplating.
The Nickel oxyacid salts are a class of chemical compounds of nickel with an oxyacid. The compounds include a number of minerals and industrially important nickel compounds.
A carbonate fluoride, fluoride carbonate, fluorocarbonate or fluocarbonate is a double salt containing both carbonate and fluoride. The salts are usually insoluble in water, and can have more than one kind of metal cation to make more complex compounds. Rare-earth fluorocarbonates are particularly important as ore minerals for the light rare-earth elements lanthanum, cerium and neodymium. Bastnäsite is the most important source of these elements. Other artificial compounds are under investigation as non-linear optical materials and for transparency in the ultraviolet, with effects over a dozen times greater than Potassium dideuterium phosphate.
The carbonate oxalates are mixed anion compounds that contain both carbonate (CO3) and oxalate (C2O4) anions. Most compounds incorporate large trivalent metal ions, such as the rare earth elements. Some carbonate oxalate compounds of variable composition are formed by heating oxalates.
Carbonatobis(ethylenediamine)cobalt(III) chloride is a salt with the formula [CoCO3(en)2]Cl (en = ethylenediamine). It is a red diamagnetic solid that is soluble in water. It is the monochloride salt of a cationic carbonate complex [CoCO3(en)2]+. The chloride ion in this salt readily undergoes ion exchange. The compound is synthesized by the oxidation of a mixture of cobalt(II) chloride, lithium hydroxide, and ethylenediamine in the presence of carbon dioxide:
Cobalt compounds are chemical compounds formed by cobalt with other elements.
Sodium tris(carbonato)cobalt(III) is the inorganic compound with the formula Na3Co(CO3)3•3H2O. The salt contains an olive-green metastable cobalt(III) coordination complex. The salt, a homoleptic metal carbonato complex, is sometimes referred to as the “Field-Durrant precursor” and is prepared by the “Field-Durrant synthesis”. It is used in the synthesis of other cobalt(III) complexes. Otherwise cobalt(III) complexes are generated from cobalt(II) precursors, a process that requires an oxidant.
Transition metal carbonate and bicarbonate complexes are coordination compounds containing carbonate (CO32-) and bicarbonate (HCO3-) as ligands. The inventory of complexes is large, enhanced by the fact that the carbonate ligand can bind metal ions in a variety of bonding modes. They illustrate the fate of low valent complexes when exposed to air.
Carbonate nitrates are mixed anion compounds containing both carbonate and nitrate ions.