Cobalt(II) chlorate

Last updated
Cobalt(II) chlorate
Names
Other names
cobaltous chlorate
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/2ClHO3.Co/c2*2-1(3)4;/h2*(H,2,3,4);/q;;+2/p-2 Yes check.svgY
    Key: IQYVXTLKMOTJKI-UHFFFAOYSA-L Yes check.svgY
  • InChI=1S/2ClHO3.Co/c2*2-1(3)4;/h2*(H,2,3,4);/q;;+2/p-2
    Key: IQYVXTLKMOTJKI-NUQVWONBAD
  • Key: IQYVXTLKMOTJKI-UHFFFAOYSA-L
  • [Co+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O
Properties
Co(ClO3)2
Molar mass 225.9 g/mol
Appearancepink crystals
soluble in water
Related compounds
Other cations
nickel chlorate

iron chlorate

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Cobalt(II) chlorate is a chemical compound with the formula Co(ClO3)2. It is an oxidant, as are all chlorates.

Preparation

Cobalt(II) chlorate is formed by a double displacement reaction between cobalt(II) sulfate and barium chlorate, barium sulfate precipitates and cobalt chlorate can be crystallized out of the filtrate: [1]

CoSO4 + Ba(ClO3)2 → BaSO4 + Co(ClO3)2

It is also possible to make it by the reaction of any chlorate with a cobalt(II) salt, however the pure product is harder to separate.

Related Research Articles

<span class="mw-page-title-main">Barium sulfate</span> Inorganic chemical compound

Barium sulfate (or sulphate) is the inorganic compound with the chemical formula BaSO4. It is a white crystalline solid that is odorless and insoluble in water. It occurs as the mineral barite, which is the main commercial source of barium and materials prepared from it. Its opaque white appearance and its high density are exploited in its main applications.

<span class="mw-page-title-main">Barium chloride</span> Chemical compound

Barium chloride is an inorganic compound with the formula BaCl2. It is one of the most common water-soluble salts of barium. Like most other water-soluble barium salts, it is a white powder, highly toxic, and imparts a yellow-green coloration to a flame. It is also hygroscopic, converting to the dihydrate BaCl2·2H2O, which are colourless crystals with a bitter salty taste. It has limited use in the laboratory and industry.

<span class="mw-page-title-main">Chloric acid</span> Chemical compound

Chloric acid, HClO3, is an oxoacid of chlorine, and the formal precursor of chlorate salts. It is a strong acid (pKa ≈ −2.7) and an oxidizing agent.

Lithopone, C.I. Pigment White 5, is a mixture of inorganic compounds, widely used as a white pigment powder. It is composed of a mixture of barium sulfate and zinc sulfide. These insoluble compounds blend well with organic compounds and confer opacity. It was made popular by the cheap production costs, greater coverage. Related white pigments include titanium dioxide, zinc oxide, zinc sulfide, and white lead.

<span class="mw-page-title-main">Triflate</span> Chemical group (–OSO2CF3) or anion (charge –1)

In organic chemistry, triflate, is a functional group with the formula R−OSO2CF3 and structure R−O−S(=O)2−CF3. The triflate group is often represented by −OTf, as opposed to −Tf, which is the triflyl group, R−SO2CF3. For example, n-butyl triflate can be written as CH3CH2CH2CH2OTf.

<span class="mw-page-title-main">Sodium chlorate</span> Chemical compound

Sodium chlorate is an inorganic compound with the chemical formula NaClO3. It is a white crystalline powder that is readily soluble in water. It is hygroscopic. It decomposes above 300 °C to release oxygen and leaves sodium chloride. Several hundred million tons are produced annually, mainly for applications in bleaching pulp to produce high brightness paper.

<span class="mw-page-title-main">Chlorous acid</span> Chemical compound

Chlorous acid is an inorganic compound with the formula HClO2. It is a weak acid. Chlorine has oxidation state +3 in this acid. The pure substance is unstable, disproportionating to hypochlorous acid (Cl oxidation state +1) and chloric acid (Cl oxidation state +5):

<span class="mw-page-title-main">Ammonium chlorate</span> Chemical compound

Ammonium chlorate is an inorganic compound with the formula NH4ClO3.

<span class="mw-page-title-main">Bromic acid</span> Chemical compound

Bromic acid, also known as hydrogen bromate, is an oxoacid with the molecular formula HBrO3. It only exists in aqueous solution. It is a colorless solution that turns yellow at room temperature as it decomposes to bromine. Bromic acid and bromates are powerful oxidizing agents and are common ingredients in Belousov–Zhabotinsky reactions. Belousov-Zhabotinsky reactions are a classic example of non-equilibrium thermodynamics.

Calcium chlorate is the calcium salt of chloric acid, with the chemical formula Ca(ClO3)2. Like other chlorates, it is a strong oxidizer.

<span class="mw-page-title-main">Barium chlorate</span> Chemical compound

Barium chlorate, Ba(ClO3)2, is the barium salt of chloric acid. It is a white crystalline solid, and like all soluble barium compounds, irritant and toxic. It is sometimes used in pyrotechnics to produce a green color. It also finds use in the production of chloric acid.

<span class="mw-page-title-main">Cobalt(II) thiocyanate</span> Chemical compound

Cobalt(II) thiocyanate is an inorganic compound with the formula Co(SCN)2. The anhydrous compound is a coordination polymer with a layered structure. The trihydrate, Co(SCN)2(H2O)3, is a isothiocyanate complex used in the cobalt thiocyanate test (or Scott test) for detecting cocaine. The test has been responsible for widespread false positives and false convictions.

<span class="mw-page-title-main">Cobalt(II) sulfate</span> Inorganic compound

Cobalt(II) sulfate is any of the inorganic compounds with the formula CoSO4(H2O)x. Usually cobalt sulfate refers to the hexa- or heptahydrates CoSO4.6H2O or CoSO4.7H2O, respectively. The heptahydrate is a red solid that is soluble in water and methanol. Since cobalt(II) has an odd number of electrons, its salts are paramagnetic.

Barium perchlorate is a powerful oxidizing agent, with the formula Ba(ClO4)2. It is used in the pyrotechnic industry.

Barium permanganate is a chemical compound, with the formula Ba(MnO4)2. It forms violet to brown crystals that are sparingly soluble in water.

Copper(II) chlorate is a chemical compound of the transition metal copper and the chlorate anion with basic formula Cu(ClO3)2. Copper chlorate is an oxidiser. It commonly forms the tetrahydrate, Cu(ClO3)2·4H2O.

Manganese(II) chlorate is an unstable chemical compound with the formula Mn(ClO3)2. It is unstable even in dilute solution. As a hexahydrate, it is solid below −18°C. Above this it melts, to form an extremely explosive pink liquid.

<span class="mw-page-title-main">Nickel(II) perchlorate</span> Compound of nickel

Nickel(II) perchlorate is a inorganic compound with the chemical formula of Ni(ClO4)2, and it is a strong oxidizing agent. Its colours are different depending on water. For example, the hydrate forms cyan crystals, the pentahydrate forms green crystals, but the hexahydrate (Ni(ClO4)2·6H2O) forms blue crystals.

References

  1. 《无机化学丛书》.第九卷 锰分族 铁系 铂系. P303. 卤酸钴和高卤酸钴