Magnesium chlorate

Last updated
Magnesium chlorate
Mg(aq6(ClO3)2.svg
Names
IUPAC name
Magnesium dichlorate hexahydrate
Systematic IUPAC name
Magnesium dichlorate
Other names
  • Magnesium(II) chlorate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.634 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 233-711-1
PubChem CID
UNII
UN number 2723
  • InChI=1S/2ClHO3.Mg/c2*2-1(3)4;/h2*(H,2,3,4);/q;;+2/p-2
    Key: NNNSKJSUQWKSAM-UHFFFAOYSA-L
  • (dihydrate):InChI=1S/2ClHO3.Mg.2H2O/c2*2-1(3)4;;;/h2*(H,2,3,4);;2*1H2/q;;+2;;/p-2
    Key: YTXOASNCVSJHNM-UHFFFAOYSA-L
  • (hexahydrate):InChI=1S/2ClHO3.Mg.6H2O/c2*2-1(3)4;;;;;;;/h2*(H,2,3,4);;6*1H2/q;;+2;;;;;;/p-2
    Key: XKPLAISKKLSAQQ-UHFFFAOYSA-L
  • Cl(=O)(=O)[O-].Cl(=O)(=O)[O-].[Mg+2]
  • (dihydrate):O.O.[Mg+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O
  • (hexahydrate):O.O.O.O.O.O.[O-]Cl(=O)=O.[O-]Cl(=O)=O.[Mg+2]
Properties
Mg(ClO3)2
Molar mass 191.20 g/mol
AppearanceWhite crystalline solid
Density 1.747 g/cm3 (hexahydrate) [1]
Melting point 35 °C (95 °F; 308 K) [2]
Boiling point 120 °C (248 °F; 393 K) [2] (decomposition)
114 g/100 ml (0 °C)
123 g/100 ml (10 °C)
135 g/100 ml (20 °C)
155 g/100 ml (30 °C)
178 g/100 ml (50 °C)
242 g/100 ml (60 °C)
268 g/100 ml (100 °C) [2]
Solubility in acetoneSoluble
Structure [1]
Monoclinic
P21/c
a = 6.39 Å, b = 6.51 Å, c = 13.90 Å
α = 90°, β = 100.3°, γ = 90°
590.1 Å3
Hazards
GHS labelling:
GHS-pictogram-exclam.svg
Warning
H302, H332
Lethal dose or concentration (LD, LC):
6348 mg/kg (rat, oral)
Related compounds
Other cations
Calcium chlorate
Strontium chlorate
Barium chlorate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Magnesium chlorate refers to inorganic compounds with the chemical formula Mg(ClO3)2(H2O)x. The anhydrous (x = 0), dihydrate (x = 2), and hexahydrate (x = 6) are known. These are thermally labile white solids. The hexahydrate has been identified on the Martian surface. [3]

Contents

Production

Samples of magnesium chlorate were first claimed in 1920 as the result of treating magnesium oxide with chlorine. A more modern method involves electrolysis of magnesium chloride. [4] The magnesium chlorate can be purified by exploiting its solubility in acetone. [4]

Properties

The hexahydrate Mg(ClO3)2·6H2O decomposes to the tetrahydrate at 35 °C. At 65 °C, it dehydrates to the dihydrate, then at 80 °C forms a basic salt. If further heated to 120 °C it decomposes to water, oxygen, chlorine, and magnesium oxide. [2]

As confirmed by X-ray crystallography, the di- and hexahydrates feature octahedral Mg2+ centers. The other ligands are water, exclusively in the hexahydrate. In the dihydrate, chlorate is also coordinated and functions as a bridging ligand. [1]

Uses

Magnesium(II) chlorate is used as a powerful desiccant and a defoliant for cotton, potato, and rice. It is also found as a lubricant in eye drops as an inactive ingredient. [5]

Hazards

Magnesium chlorate is an oxidizer and can in principle form explosive mixtures.

Related Research Articles

<span class="mw-page-title-main">Chlorine</span> Chemical element, symbol Cl and atomic number 17

Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity on the revised Pauling scale, behind only oxygen and fluorine.

<span class="mw-page-title-main">Sodium hypochlorite</span> Chemical compound (known in solution as bleach)

Sodium hypochlorite, commonly known in a dilute solution as (chlorine) bleach, is an inorganic chemical compound with the formula NaOCl, consisting of a sodium cation and a hypochlorite anion. It may also be viewed as the sodium salt of hypochlorous acid. The anhydrous compound is unstable and may decompose explosively. It can be crystallized as a pentahydrate NaOCl·5H
2
O
, a pale greenish-yellow solid which is not explosive and is stable if kept refrigerated.

<span class="mw-page-title-main">Potassium chlorate</span> Chemical compound

Potassium chlorate is a compound containing potassium, chlorine and oxygen, with the molecular formula KClO3. In its pure form, it is a white crystalline substance. After sodium chlorate, it is the second most common chlorate in industrial use. It is a strong oxidizing agent and its most important application is in safety matches. In other applications it is mostly obsolete and has been replaced by safer alternatives in recent decades. It has been used

<span class="mw-page-title-main">Chlorate</span> Anion and term for chemical compounds containing it

Chlorate is the common name of the ClO
3
anion, whose chlorine atom is in the +5 oxidation state. The term can also refer to chemical compounds containing this anion, with chlorates being the salts of chloric acid. Other oxyanions of chlorine can be named "chlorate" followed by a Roman numeral in parentheses denoting the oxidation state of chlorine: e.g., the ClO
4
ion commonly called perchlorate can also be called chlorate(VII).

<span class="mw-page-title-main">Hypochlorite</span> Ion

In chemistry, hypochlorite, or chloroxide is an anion with the chemical formula ClO. It combines with a number of cations to form hypochlorite salts. Common examples include sodium hypochlorite and calcium hypochlorite. The Cl-O distance in ClO is 1.69 Å.

<span class="mw-page-title-main">Cobalt(II) chloride</span> Chemical compound

Cobalt(II) chloride is an inorganic compound of cobalt and chlorine, with the formula CoCl
2
. The compound forms several hydrates CoCl
2
·nH
2
O
, for n = 1, 2, 6, and 9. Claims of the formation of tri- and tetrahydrates have not been confirmed. The anhydrous form is a blue crystalline solid; the dihydrate is purple and the hexahydrate is pink. Commercial samples are usually the hexahydrate, which is one of the most commonly used cobalt compounds in the lab.

<span class="mw-page-title-main">Sodium chlorate</span> Chemical compound

Sodium chlorate is an inorganic compound with the chemical formula NaClO3. It is a white crystalline powder that is readily soluble in water. It is hygroscopic. It decomposes above 300 °C to release oxygen and leaves sodium chloride. Several hundred million tons are produced annually, mainly for applications in bleaching pulp to produce high brightness paper.

<span class="mw-page-title-main">Copper(II) chloride</span> Chemical compound

Copper(II) chloride, also known as cupric chloride, is an inorganic compound with the chemical formula CuCl2. The monoclinic yellowish-brown anhydrous form slowly absorbs moisture to form the orthorhombic blue-green dihydrate CuCl2·2H2O, with two water molecules of hydration. It is industrially produced for use as a co-catalyst in the Wacker process.

<span class="mw-page-title-main">Magnesium nitrate</span> Chemical compound

Magnesium nitrate refers to inorganic compounds with the formula Mg(NO3)2(H2O)x, where x = 6, 2, and 0. All are white solids. The anhydrous material is hygroscopic, quickly forming the hexahydrate upon standing in air. All of the salts are very soluble in both water and ethanol.

<span class="mw-page-title-main">Sodium perchlorate</span> Chemical compound

Sodium perchlorate is the inorganic compound with the chemical formula NaClO4. It is a white crystalline, hygroscopic solid that is highly soluble in water and in alcohol. It is usually encountered as the monohydrate. The compound is noteworthy as the most water-soluble of the common perchlorate salts.

<span class="mw-page-title-main">Vanadium(III) chloride</span> Chemical compound

Vanadium(III) chloride is the inorganic compound with the formula VCl3 which forms the hexahydrate, [VCl2(H2O)4]Cl·2H2O. This hygroscopic purple salt is a common precursor to other vanadium(III) complexes.

Magnesium compounds are compounds formed by the element magnesium (Mg). These compounds are important to industry and biology, including magnesium carbonate, magnesium chloride, magnesium citrate, magnesium hydroxide, magnesium oxide, magnesium sulfate, and magnesium sulfate heptahydrate.

Calcium chlorate is the calcium salt of chloric acid, with the chemical formula Ca(ClO3)2. Like other chlorates, it is a strong oxidizer.

Magnesium hydroxychloride is the traditional term for several chemical compounds of magnesium, chlorine, oxygen, and hydrogen whose general formula xMgO·yMgCl
2
·zH
2
O
, for various values of x, y, and z; or, equivalently, Mg
x+y
(OH)
2x
Cl
2y
(H
2
O)
zx
. The simple chemical formula that is often used is MgClOH, which appears in high school subject, for example.Other names for this class are magnesium chloride hydroxide, magnesium oxychloride, and basic magnesium chloride. Some of these compounds are major components of Sorel cement.

Nickel compounds are chemical compounds containing the element nickel which is a member of the group 10 of the periodic table. Most compounds in the group have an oxidation state of +2. Nickel is classified as a transition metal with nickel(II) having much chemical behaviour in common with iron(II) and cobalt(II). Many salts of nickel(II) are isomorphous with salts of magnesium due to the ionic radii of the cations being almost the same. Nickel forms many coordination complexes. Nickel tetracarbonyl was the first pure metal carbonyl produced, and is unusual in its volatility. Metalloproteins containing nickel are found in biological systems.

Copper(II) chlorate is a chemical compound of the transition metal copper and the chlorate anion with basic formula Cu(ClO3)2. Copper chlorate is an oxidiser. It commonly forms the tetrahydrate, Cu(ClO3)2·4H2O.

<span class="mw-page-title-main">Nickel oxyacid salts</span>

The Nickel oxyacid salts are a class of chemical compounds of nickel with an oxyacid. The compounds include a number of minerals and industrially important nickel compounds.

Manganese(II) chlorate is an unstable chemical compound with the formula Mn(ClO3)2. It is unstable even in dilute solution. As a hexahydrate, it is solid below −18°C. Above this it melts, to form an extremely explosive pink liquid.

Silver chlorite is a chemical compound with the formula AgClO2. This slightly yellow solid is shock sensitive and has an orthorhombic crystal structure.

Magnesium permanganate is an inorganic compound with the chemical formula Mg(MnO4)2. It can be used as an oxidant.

References

  1. 1 2 3 Kossev, K; Tsvetanova, L.; Dimowa, L.; Nikolova, R.; Shivachev, B. (2013). "Synthesis and Crystal Structure of Magnesium Chlorate Dihydrate and Magnesium Chlorate Hexahydrate". Bulgarian Chemical Communications. 45: 543–548.
  2. 1 2 3 4 Joseph William Mellor (1922). Supplement to Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry: suppl. 3. K, Rb, Cs, Fr. Longmans, Green and Company.
  3. Ojha, Lujendra; Wilhelm, Mary Beth; Murchie, Scott L.; McEwen, Alfred S.; Wray, James J.; Hanley, Jennifer; Massé, Marion; Chojnacki, Matt (2015). "Spectral evidence for hydrated salts in recurring slope lineae on Mars". Nature Geoscience. 8 (11): 829–832. Bibcode:2015NatGe...8..829O. doi:10.1038/ngeo2546.
  4. 1 2 Herbert Maxim (1948). The electrolytic production of magnesium chlorate and perchlorate. the Department of Chemical Engineering: University of Southern California.
  5. "MAGNESIUM CHLORATE". National Center for Advancing Translational Sciences. U.S. Department of Health & Human Services. Retrieved 27 August 2021.