Names | |
---|---|
IUPAC name Magnesium dichlorate hexahydrate | |
Systematic IUPAC name Magnesium dichlorate | |
Other names
| |
Identifiers | |
| |
3D model (JSmol) |
|
ChemSpider | |
ECHA InfoCard | 100.030.634 |
EC Number |
|
PubChem CID | |
UNII | |
UN number | 2723 |
CompTox Dashboard (EPA) |
|
| |
| |
Properties | |
Mg(ClO3)2 | |
Molar mass | 191.20 g/mol |
Appearance | White crystalline solid |
Density | 1.747 g/cm3 (hexahydrate) [1] |
Melting point | 35 °C (95 °F; 308 K) [2] |
Boiling point | 120 °C (248 °F; 393 K) [2] (decomposition) |
114 g/100 ml (0 °C) 123 g/100 ml (10 °C) 135 g/100 ml (20 °C) 155 g/100 ml (30 °C) 178 g/100 ml (50 °C) 242 g/100 ml (60 °C) 268 g/100 ml (100 °C) [2] | |
Solubility in acetone | Soluble |
Structure [1] | |
Monoclinic | |
P21/c | |
a = 6.39 Å, b = 6.51 Å, c = 13.90 Å α = 90°, β = 100.3°, γ = 90° | |
Lattice volume (V) | 590.1 Å3 |
Hazards | |
GHS labelling: | |
Warning | |
H302, H332 | |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose) | 6348 mg/kg (rat, oral) |
Related compounds | |
Other cations | Calcium chlorate Strontium chlorate Barium chlorate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Magnesium chlorate refers to inorganic compounds with the chemical formula Mg(ClO3)2(H2O)x. The anhydrous (x = 0), dihydrate (x = 2), and hexahydrate (x = 6) are known. These are thermally labile white solids. The hexahydrate has been identified on the Martian surface. [3]
Samples of magnesium chlorate were first claimed in 1920 as the result of treating magnesium oxide with chlorine. A more modern method involves electrolysis of magnesium chloride. [4] The magnesium chlorate can be purified by exploiting its solubility in acetone. [4]
The hexahydrate Mg(ClO3)2·6H2O decomposes to the tetrahydrate at 35 °C. At 65 °C, it dehydrates to the dihydrate, then at 80 °C forms a basic salt. If further heated to 120 °C it decomposes to water, oxygen, chlorine, and magnesium oxide. [2]
As confirmed by X-ray crystallography, the di- and hexahydrates feature octahedral Mg2+ centers. The other ligands are water, exclusively in the hexahydrate. In the dihydrate, chlorate is also coordinated and functions as a bridging ligand. [1]
Magnesium(II) chlorate is used as a powerful desiccant and a defoliant for cotton, potato, and rice. It is also found as a lubricant in eye drops as an inactive ingredient. [5]
Magnesium chlorate is an oxidizer and can in principle form explosive mixtures.
Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity on the revised Pauling scale, behind only oxygen and fluorine.
Sodium hypochlorite, commonly known in a dilute solution as (chlorine) bleach, is an inorganic chemical compound with the formula NaOCl, consisting of a sodium cation and a hypochlorite anion. It may also be viewed as the sodium salt of hypochlorous acid. The anhydrous compound is unstable and may decompose explosively. It can be crystallized as a pentahydrate NaOCl·5H
2O, a pale greenish-yellow solid which is not explosive and is stable if kept refrigerated.
Potassium chlorate is a compound containing potassium, chlorine and oxygen, with the molecular formula KClO3. In its pure form, it is a white crystalline substance. After sodium chlorate, it is the second most common chlorate in industrial use. It is a strong oxidizing agent and its most important application is in safety matches. In other applications it is mostly obsolete and has been replaced by safer alternatives in recent decades. It has been used
Chlorate is the common name of the ClO−
3 anion, whose chlorine atom is in the +5 oxidation state. The term can also refer to chemical compounds containing this anion, with chlorates being the salts of chloric acid. Other oxyanions of chlorine can be named "chlorate" followed by a Roman numeral in parentheses denoting the oxidation state of chlorine: e.g., the ClO−
4 ion commonly called perchlorate can also be called chlorate(VII).
In chemistry, hypochlorite, or chloroxide is an anion with the chemical formula ClO−. It combines with a number of cations to form hypochlorite salts. Common examples include sodium hypochlorite and calcium hypochlorite. The Cl-O distance in ClO− is 1.69 Å.
Cobalt(II) chloride is an inorganic compound of cobalt and chlorine, with the formula CoCl
2. The compound forms several hydrates CoCl
2·nH
2O, for n = 1, 2, 6, and 9. Claims of the formation of tri- and tetrahydrates have not been confirmed. The anhydrous form is a blue crystalline solid; the dihydrate is purple and the hexahydrate is pink. Commercial samples are usually the hexahydrate, which is one of the most commonly used cobalt compounds in the lab.
Sodium chlorate is an inorganic compound with the chemical formula NaClO3. It is a white crystalline powder that is readily soluble in water. It is hygroscopic. It decomposes above 300 °C to release oxygen and leaves sodium chloride. Several hundred million tons are produced annually, mainly for applications in bleaching pulp to produce high brightness paper.
Copper(II) chloride, also known as cupric chloride, is an inorganic compound with the chemical formula CuCl2. The monoclinic yellowish-brown anhydrous form slowly absorbs moisture to form the orthorhombic blue-green dihydrate CuCl2·2H2O, with two water molecules of hydration. It is industrially produced for use as a co-catalyst in the Wacker process.
Magnesium nitrate refers to inorganic compounds with the formula Mg(NO3)2(H2O)x, where x = 6, 2, and 0. All are white solids. The anhydrous material is hygroscopic, quickly forming the hexahydrate upon standing in air. All of the salts are very soluble in both water and ethanol.
Sodium perchlorate is the inorganic compound with the chemical formula NaClO4. It is a white crystalline, hygroscopic solid that is highly soluble in water and in alcohol. It is usually encountered as the monohydrate. The compound is noteworthy as the most water-soluble of the common perchlorate salts.
Vanadium(III) chloride is the inorganic compound with the formula VCl3 which forms the hexahydrate, [VCl2(H2O)4]Cl·2H2O. This hygroscopic purple salt is a common precursor to other vanadium(III) complexes.
Magnesium compounds are compounds formed by the element magnesium (Mg). These compounds are important to industry and biology, including magnesium carbonate, magnesium chloride, magnesium citrate, magnesium hydroxide, magnesium oxide, magnesium sulfate, and magnesium sulfate heptahydrate.
Calcium chlorate is the calcium salt of chloric acid, with the chemical formula Ca(ClO3)2. Like other chlorates, it is a strong oxidizer.
Magnesium hydroxychloride is the traditional term for several chemical compounds of magnesium, chlorine, oxygen, and hydrogen whose general formula xMgO·yMgCl
2·zH
2O, for various values of x, y, and z; or, equivalently, Mg
x+y(OH)
2xCl
2y(H
2O)
z−x. The simple chemical formula that is often used is MgClOH, which appears in high school subject, for example.Other names for this class are magnesium chloride hydroxide, magnesium oxychloride, and basic magnesium chloride. Some of these compounds are major components of Sorel cement.
Nickel compounds are chemical compounds containing the element nickel which is a member of the group 10 of the periodic table. Most compounds in the group have an oxidation state of +2. Nickel is classified as a transition metal with nickel(II) having much chemical behaviour in common with iron(II) and cobalt(II). Many salts of nickel(II) are isomorphous with salts of magnesium due to the ionic radii of the cations being almost the same. Nickel forms many coordination complexes. Nickel tetracarbonyl was the first pure metal carbonyl produced, and is unusual in its volatility. Metalloproteins containing nickel are found in biological systems.
Copper(II) chlorate is a chemical compound of the transition metal copper and the chlorate anion with basic formula Cu(ClO3)2. Copper chlorate is an oxidiser. It commonly forms the tetrahydrate, Cu(ClO3)2·4H2O.
The Nickel oxyacid salts are a class of chemical compounds of nickel with an oxyacid. The compounds include a number of minerals and industrially important nickel compounds.
Manganese(II) chlorate is an unstable chemical compound with the formula Mn(ClO3)2. It is unstable even in dilute solution. As a hexahydrate, it is solid below −18°C. Above this it melts, to form an extremely explosive pink liquid.
Silver chlorite is a chemical compound with the formula AgClO2. This slightly yellow solid is shock sensitive and has an orthorhombic crystal structure.
Magnesium permanganate is an inorganic compound with the chemical formula Mg(MnO4)2. It can be used as an oxidant.