Names | |
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Other names Sellaite Irtran-1 | |
Identifiers | |
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.029.086 |
EC Number |
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PubChem CID | |
RTECS number |
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UNII | |
CompTox Dashboard (EPA) | |
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Properties | |
MgF2 | |
Molar mass | 62.3018 g/mol |
Appearance | Colorless to white tetragonal crystals |
Density | 3.148 g/cm3 |
Melting point | 1,263 °C (2,305 °F; 1,536 K) |
Boiling point | 2,260 °C (4,100 °F; 2,530 K) |
0.013 g/(100 mL) | |
Solubility product (Ksp) | 5.16⋅10−11 |
Solubility |
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−22.7⋅10−6 cm3/mol | |
Refractive index (nD) | 1.37397 |
Structure | |
Rutile (tetragonal), tP6 | |
P42/mnm, No. 136 | |
Thermochemistry | |
Heat capacity (C) | 61.6 J/(mol⋅K) |
Std molar entropy (S⦵298) | 57.2 J/(mol⋅K) |
Std enthalpy of formation (ΔfH⦵298) | −1124.2 kJ/mol |
Gibbs free energy (ΔfG⦵) | −1071 kJ/mol |
Hazards [2] [3] | |
GHS labelling: | |
Warning | |
H303, H315, H319, H335 | |
P261, P304+P340, P305+P351+P338, P405 | |
NFPA 704 (fire diamond) | |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose) | 2330[ clarification needed ] (rat, oral) |
Safety data sheet (SDS) | ChemicalBook |
Related compounds | |
Other anions | |
Other cations | |
Related compounds | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Magnesium fluoride is an ionically bonded inorganic compound with the formula Mg F 2. The compound is a colorless to white crystalline salt and is transparent over a wide range of wavelengths, with commercial uses in optics that are also used in space telescopes. It occurs naturally as the rare mineral sellaite.
Magnesium fluoride is prepared from magnesium oxide with sources of hydrogen fluoride such as ammonium bifluoride, by the breakdown of it:
Related metathesis reactions are also feasible:
The compound crystallizes as tetragonal birefringent crystals. The structure of the magnesium fluoride is similar to that of rutile, [4] [5] featuring octahedral Mg2+ cations and 3-coordinate F− anions. [6]
Magnesium coordination | Fluorine coordination |
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In the gas phase, monomeric MgF2 molecules adopt a linear molecular geometry. [4] [5]
Magnesium fluoride is transparent over an extremely wide range of wavelengths. Windows, lenses, and prisms made of this material can be used over the entire range of wavelengths from 0.120 μm (vacuum ultraviolet) to 8.0 μm (infrared). High-quality, synthetic magnesium fluoride is one of two materials (the other being lithium fluoride) that will transmit in the vacuum ultraviolet range at 121 nm (Lyman alpha). Lower-grade magnesium fluoride is inferior to calcium fluoride in the infrared range.[ citation needed ]
Magnesium fluoride is tough and polishes well but is slightly birefringent and should therefore be cut with the optic axis perpendicular to the plane of the window or lens. [6] Due to its suitable refractive index of 1.37, magnesium fluoride is commonly applied in thin layers to the surfaces of optical elements as an inexpensive anti-reflective coating.[ citation needed ] Its Verdet constant is 0.00810 arcmin⋅G −1⋅cm−1 at 632.8 nm. [8]
Chronic exposure to magnesium fluoride may affect the skeleton, kidneys, central nervous system, respiratory system, eyes and skin, and may cause or aggravate attacks of asthma. [9]
Ultraviolet (UV) light is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight, and constitutes about 10% of the total electromagnetic radiation output from the Sun. It is also produced by electric arcs, Cherenkov radiation, and specialized lights, such as mercury-vapor lamps, tanning lamps, and black lights.
Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon.
Fused quartz, fused silica or quartz glass is a glass consisting of almost pure silica (silicon dioxide, SiO2) in amorphous (non-crystalline) form. This differs from all other commercial glasses, such as soda-lime glass, lead glass, or borosilicate glass, in which other ingredients are added which change the glasses' optical and physical properties, such as lowering the melt temperature, the spectral transmission range, or the mechanical strength. Fused quartz, therefore, has high working and melting temperatures, making it difficult to form and less desirable for most common applications, but is much stronger, more chemically resistant, and exhibits lower thermal expansion, making it more suitable for many specialized uses such as lighting and scientific applications.
An optical coating is one or more thin layers of material deposited on an optical component such as a lens, prism or mirror, which alters the way in which the optic reflects and transmits light. These coatings have become a key technology in the field of optics. One type of optical coating is an anti-reflective coating, which reduces unwanted reflections from surfaces, and is commonly used on spectacle and camera lenses. Another type is the high-reflector coating, which can be used to produce mirrors that reflect greater than 99.99% of the light that falls on them. More complex optical coatings exhibit high reflection over some range of wavelengths, and anti-reflection over another range, allowing the production of dichroic thin-film filters.
Zinc sulfide is an inorganic compound with the chemical formula of ZnS. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite. Although this mineral is usually black because of various impurities, the pure material is white, and it is widely used as a pigment. In its dense synthetic form, zinc sulfide can be transparent, and it is used as a window for visible optics and infrared optics.
Calcium fluoride is the inorganic compound of the elements calcium and fluorine with the formula CaF2. It is a white solid that is practically insoluble in water. It occurs as the mineral fluorite (also called fluorspar), which is often deeply coloured owing to impurities.
Many ceramic materials, both glassy and crystalline, have found use as optically transparent materials in various forms from bulk solid-state components to high surface area forms such as thin films, coatings, and fibers. Such devices have found widespread use for various applications in the electro-optical field including: optical fibers for guided lightwave transmission, optical switches, laser amplifiers and lenses, hosts for solid-state lasers and optical window materials for gas lasers, and infrared (IR) heat seeking devices for missile guidance systems and IR night vision. In commercial and general knowledge domains, it is commonly accepted that transparent ceramics or ceramic glass are varieties of strengthened glass, such as those used for the screen glass on an iPhone.
A gas laser is a laser in which an electric current is discharged through a gas to produce coherent light. The gas laser was the first continuous-light laser and the first laser to operate on the principle of converting electrical energy to a laser light output. The first gas laser, the Helium–neon laser (HeNe), was co-invented by Iranian engineer and scientist Ali Javan and American physicist William R. Bennett, Jr., in 1960. It produced a coherent light beam in the infrared region of the spectrum at 1.15 micrometres.
Zinc selenide is the inorganic compound with the formula ZnSe. It is a lemon-yellow solid although most samples have a duller color due to the effects of oxidation. It is an intrinsic semiconductor with a band gap of about 2.70 eV at 25 °C (77 °F), equivalent to a wavelength of 459 nm. ZnSe occurs as the rare mineral stilleite, named after Hans Stille.
Beryllium fluoride is the inorganic compound with the formula BeF2. This white solid is the principal precursor for the manufacture of beryllium metal. Its structure resembles that of quartz, but BeF2 is highly soluble in water.
Lithium fluoride is an inorganic compound with the chemical formula LiF. It is a colorless solid that transitions to white with decreasing crystal size. Its structure is analogous to that of sodium chloride, but it is much less soluble in water. It is mainly used as a component of molten salts. Partly because Li and F are both light elements, and partly because F2 is highly reactive, formation of LiF from the elements releases one of the highest energies per mass of reactants, second only to that of BeO.
Iron(II) fluoride or ferrous fluoride is an inorganic compound with the molecular formula FeF2. It forms a tetrahydrate FeF2·4H2O that is often referred to by the same names. The anhydrous and hydrated forms are white crystalline solids.
Copper(II) fluoride is an inorganic compound with the chemical formula CuF2. The anhydrous form is a white, ionic, crystalline, hygroscopic salt with a distorted rutile-type crystal structure, similar to other fluorides of chemical formulae MF2 (where M is a metal). The dihydrate, CuF2·2H2O, is blue in colour.
Strontium fluoride, SrF2, also called strontium difluoride and strontium(II) fluoride, is a fluoride of strontium. It is a brittle white crystalline solid. In nature, it appears as the very rare mineral strontiofluorite.
Barium fluoride is an inorganic compound with the formula BaF2. It is a colorless solid that occurs in nature as the rare mineral frankdicksonite. Under standard conditions it adopts the fluorite structure and at high pressure the PbCl2 structure. Like CaF2, it is resilient to and insoluble in water.
Xenon difluoride is a powerful fluorinating agent with the chemical formula XeF
2, and one of the most stable xenon compounds. Like most covalent inorganic fluorides it is moisture-sensitive. It decomposes on contact with water vapor, but is otherwise stable in storage. Xenon difluoride is a dense, colourless crystalline solid.
Krypton difluoride, KrF2 is a chemical compound of krypton and fluorine. It was the first compound of krypton discovered. It is a volatile, colourless solid at room temperature. The structure of the KrF2 molecule is linear, with Kr−F distances of 188.9 pm. It reacts with strong Lewis acids to form salts of the KrF+ and Kr
2F+
3 cations.
The absorption of electromagnetic radiation by water depends on the state of the water.
Lanthanum trifluoride is a refractory ionic compound of lanthanum and fluorine. The chemical formula is LaF
3.
A carbonate fluoride, fluoride carbonate, fluorocarbonate or fluocarbonate is a double salt containing both carbonate and fluoride. The salts are usually insoluble in water, and can have more than one kind of metal cation to make more complex compounds. Rare-earth fluorocarbonates are particularly important as ore minerals for the light rare-earth elements lanthanum, cerium and neodymium. Bastnäsite is the most important source of these elements. Other artificial compounds are under investigation as non-linear optical materials and for transparency in the ultraviolet, with effects over a dozen times greater than Potassium dideuterium phosphate.