Promethium(III) fluoride

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Promethium(III) fluoride
Kristallstruktur Lanthanfluorid.png
Crystal structure
Names
IUPAC name
Promethium(III) fluoride
Other names
Promethium trifluoride
Identifiers
3D model (JSmol)
PubChem CID
  • InChI=1S/3FH.Pm/h3*1H;/q;;;+3/p-3
    Key: GBTXURQYFJSURZ-UHFFFAOYSA-K
  • [F-].[F-].[F-].[Pm+3]
Properties
PmF3
Molar mass 202 g/mol [1]
Appearancepink solid [1]
Melting point 1338 °C [1]
Structure
Rhombohedral, hR24
P3c1, No. 165 [2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Promethium(III) fluoride or promethium trifluoride is a salt of promethium and fluorine with the formula PmF3.

Promethium(III) fluoride is sparingly soluble in water. It reacts with metallic lithium to yield lithium fluoride and metallic promethium: [3]

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<span class="mw-page-title-main">Lithium</span> Chemical element, symbol Li and atomic number 3

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<span class="mw-page-title-main">Promethium</span> Chemical element, symbol Pm and atomic number 61

Promethium is a chemical element with the symbol Pm and atomic number 61. All of its isotopes are radioactive; it is extremely rare, with only about 500–600 grams naturally occurring in Earth's crust at any given time. Promethium is one of only two radioactive elements that are followed in the periodic table by elements with stable forms, the other being technetium. Chemically, promethium is a lanthanide. Promethium shows only one stable oxidation state of +3.

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<span class="mw-page-title-main">Promethium(III) chloride</span> Chemical compound

Promethium(III) chloride is a chemical compound of promethium and chlorine with the formula PmCl3. It is an ionic, water soluble, crystalline salt that glows in the dark with a pale blue or green light due to promethium's intense radioactivity.

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References

  1. 1 2 3 Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 4.84. ISBN   1-4398-5511-0.
  2. Zachariasen, W. H. (1949). "Crystal chemical studies of the 5f-series of elements. XII. New compounds representing known structure types". Acta Crystallographica. 2 (6): 388–390. doi: 10.1107/S0365110X49001016 .
  3. Weigel, F. (1963). "Darstellung von metallischem Promethium". Angewandte Chemie. 75 (10): 451. Bibcode:1963AngCh..75..451W. doi:10.1002/ange.19630751009.