Rhodium(IV) fluoride

Last updated
Rhodium(IV) fluoride
Names
Other names
Rhodium tetrafluoride
Identifiers
  • 60617-65-4 Yes check.svgY
3D model (JSmol)
PubChem CID
  • InChI=1S/4FH.Rh/h4*1H;/q;;;;+4/p-4
    Key: NEZZNADHMSRTOQ-UHFFFAOYSA-J
  • F[Rh](F)(F)F
Properties
RhF4
Appearancepurple-red solid [1]
Related compounds
Other anions
rhodium dioxide
Related compounds
rhodium(III) fluoride
rhodium(V) fluoride
rhodium(VI) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Rhodium(IV) fluoride is a chemical compound of rhodium and fluorine. It is formed when rhodium(III) bromide reacts with bromine trifluoride. [1] Iridium(IV) fluoride, palladium(IV) fluoride and platinum(IV) fluoride have the same crystal structure. [2]

Related Research Articles

Rhodium Chemical element, symbol Rh and atomic number 45

Rhodium is a chemical element with the symbol Rh and atomic number 45. It is an extraordinarily rare, silvery-white, hard, corrosion-resistant, and chemically inert transition metal. It is a noble metal and a member of the platinum group. It has only one naturally occurring isotope, which is 103Rh. Naturally occurring rhodium is usually found as a free metal, as an alloy with similar metals, and rarely as a chemical compound in minerals such as bowieite and rhodplumsite. It is one of the rarest and most valuable precious metals.

Manganese(III) fluoride Chemical compound

Manganese(III) fluoride (also known as Manganese trifluoride) is the inorganic compound with the formula MnF3. This red/purplish solid is useful for converting hydrocarbons into fluorocarbons, i.e., it is a fluorination agent. It forms a hydrate and many derivatives.

Plutonium tetrafluoride Chemical compound

Plutonium(IV) fluoride is a chemical compound with the formula (PuF4). It is a brown solid but can appear a variety of colors depending on the grain size, purity, moisture content, lighting, and presence of contaminants. Its primary use in the United States has been as an intermediary product in the production of plutonium metal for nuclear weapons usage.

Rhodium(III) oxide Chemical compound

Rhodium(III) oxide (or Rhodium sesquioxide) is the inorganic compound with the formula Rh2O3. It is a gray solid that is insoluble in ordinary solvents.

Vanadium(IV) fluoride (VF4) is an inorganic compound of vanadium and fluorine. It is paramagnetic yellow-brown solid that is very hygroscopic. Unlike the corresponding vanadium tetrachloride, the tetrafluoride is not volatile because it adopts a polymeric structure. It decomposes before melting.

Indium(III) fluoride Chemical compound

Indium(III) fluoride or indium trifluoride is the inorganic compound with the formula InF3. It is a white solid.

Iridium(V) fluoride Chemical compound

Iridium(V) fluoride, IrF5, is a chemical compound of iridium and fluorine. A highly reactive yellow low melting solid, it has a tetrameric structure, Ir4F20, which contains octahedrally coordinated iridium atoms. This structure is shared with RuF5 and OsF5. It can be prepared by the controlled decomposition of IrF6 or the reduction of IrF6 with silicon powder or H2 in anhydrous HF.

Tin(IV) fluoride Chemical compound

Tin(IV) fluoride is a chemical compound of tin and fluorine with the chemical formula SnF4 and is a white solid with a melting point above 700 °C.

Palladium(II) fluoride Chemical compound

Palladium(II) fluoride, also known as palladium difluoride, is the chemical compound of palladium and fluorine with the formula PdF2.

Palladium(II,IV) fluoride Chemical compound

Palladium(II,IV) fluoride, also known as palladium trifluoride, is a chemical compound of palladium and fluorine. It has the empirical formula PdF3, but is better described as the mixed-valence compound palladium(II) hexafluoropalladate(IV), PdII[PdIVF6], and is often written as Pd[PdF6] or Pd2F6.

Palladium tetrafluoride Chemical compound

Palladium(IV) fluoride, also known as palladium tetrafluoride, is the chemical compound of palladium and fluorine with the chemical formula PdF4. The palladium atoms in PdF4 are in the +4 oxidation state.

Rhodium hexafluoride Chemical compound

Rhodium hexafluoride, also rhodium(VI) fluoride, (RhF6) is the inorganic compound of rhodium and fluorine. A black volatile solid, it is a highly reactive material, and a rare example of a rhodium(VI) compound. It is one of seventeen known binary hexafluoride.

Germanium tetrafluoride Chemical compound

Germanium tetrafluoride (GeF4) is a chemical compound of germanium and fluorine. It is a colorless gas.

Lead tetrafluoride Chemical compound

Lead tetrafluoride is a compound of lead and fluorine. The yellow solid is the only room-temperature stable tetrahalide of lead. Lead tetrafluoride is isostructural with tin(IV) fluoride and contains planar layers of octahedrally coordinated lead, where the octahedra share four corners and there are two terminal, unshared, fluorine atoms trans to one another.

Chromium(IV) fluoride Chemical compound

Chromium(IV) fluoride is an inorganic compound with the chemical formula CrF4. It has a dark greenish-black color when solid. It rapidly hydrolysizes in presence of moisture in air or directly in water.

Platinum tetrafluoride Chemical compound

Platinum tetrafluoride is the inorganic compound with the chemical formula PtF
4
. In the solid state, the compound features platinum(IV) in octahedral coordination geometry.

Neptunium(IV) fluoride Chemical compound

Neptunium(IV) fluoride or neptunium tetrafluoride is a inorganic compound with the formula NpF4. It is a green salt and is isostructural with UF4.

Rhodium pentafluoride Chemical compound

Rhodium pentafluoride is an inorganic compound with the formula Rh4F20. It is a red solid. It is prepared by fluorination of rhodium trifluoride at 400 °C.

Rhodium(III) bromide Chemical compound

Rhodium(III) bromide refers to inorganic compounds of the formula RhBr3(H2O)n where n = 0 or approximately three. Both forms are brown solids. The hydrate is soluble in water and lower alcohols. It is used to prepare rhodium bromide complexes. Rhodium bromides are similar to the chlorides, but have attracted little academic or commercial attention.

Praseodymium(IV) fluoride Chemical compound

Praseodymium(IV) fluoride (also praseodymium tetrafluoride) is a binary inorganic compound, a highly oxidised metal salt of praseodymium and fluoride with the chemical formula PrF4. The compound forms light yellow crystals.

References

  1. 1 2 Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 1119–1120. ISBN   978-0-08-037941-8.
  2. Wells A.F. (1984) Structural Inorganic Chemistry 5th edition Oxford Science Publications ISBN   0-19-855370-6