Plutonium(III) fluoride

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Plutonium(III) fluoride
Kristallstruktur Lanthanfluorid.png
Names
IUPAC name
Plutonium(III) fluoride
Systematic IUPAC name
Plutonium(3+) fluoride
Other names
Plutonic fluoride

Plutonium fluoride

Plutonium trifluoride
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/3FH.Pu/h3*1H;/q;;;+3/p-3 Yes check.svgY
    Key: DBYIUAMLRDFZJJ-UHFFFAOYSA-K Yes check.svgY
  • [F-].[F-].[F-].[Pu+3]
Properties
F3Pu
Molar mass 301 g·mol−1
AppearanceViolet, opaque crystals
Density 9.3 g cm−3
Melting point 1,396 °C (2,545 °F; 1,669 K) [1]
Boiling point 2,000 °C (3,630 °F; 2,270 K) (decomposes) [2]
Related compounds
Other anions
Plutonium(III) chloride
Other cations
Samarium(III) fluoride
Related fluoroplutoniums
Plutonium tetrafluoride

Plutonium hexafluoride

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Plutonium(III) fluoride or plutonium trifluoride is the chemical compound composed of plutonium and fluorine with the formula PuF3. This salt forms violet crystals. Plutonium(III) fluoride has the LaF3 structure where the coordination around the plutonium atoms is complex and usually described as tri-capped trigonal prismatic. [3]

Reactions

A plutonium(III) fluoride precipitation method has been investigated as an alternative to the typical plutonium peroxide method of recovering plutonium from solution, such as that from a nuclear reprocessing plant. [4] A 1957 study by the Los Alamos National Laboratory reported a less effective recovery than the traditional method, [5] while a more recent study sponsored by the United States Office of Scientific and Technical Information found it to be one of the more effective methods. [6]

Plutonium(III) fluoride can be used for manufacture of the plutonium-gallium alloy instead of more difficult to handle metallic plutonium.

Related Research Articles

<span class="mw-page-title-main">Americium</span> Chemical element, symbol Am and atomic number 95

Americium is a synthetic chemical element; it has symbol Am and atomic number 95. It is radioactive and a transuranic member of the actinide series in the periodic table, located under the lanthanide element europium and was thus named after the Americas by analogy.

The actinide or actinoid series encompasses the 14 metallic chemical elements with atomic numbers from 89 to 103, actinium through Lawrencium. The actinide series derives its name from the first element in the series, actinium. The informal chemical symbol An is used in general discussions of actinide chemistry to refer to any actinide.

<span class="mw-page-title-main">Curium</span> Chemical element, symbol Cm and atomic number 96

Curium is a synthetic chemical element; it has symbol Cm and atomic number 96. This transuranic actinide element was named after eminent scientists Marie and Pierre Curie, both known for their research on radioactivity. Curium was first intentionally made by the team of Glenn T. Seaborg, Ralph A. James, and Albert Ghiorso in 1944, using the cyclotron at Berkeley. They bombarded the newly discovered element plutonium with alpha particles. This was then sent to the Metallurgical Laboratory at University of Chicago where a tiny sample of curium was eventually separated and identified. The discovery was kept secret until after the end of World War II. The news was released to the public in November 1947. Most curium is produced by bombarding uranium or plutonium with neutrons in nuclear reactors – one tonne of spent nuclear fuel contains ~20 grams of curium.

<span class="mw-page-title-main">Einsteinium</span> Chemical element, symbol Es and atomic number 99

Einsteinium is a synthetic chemical element; it has symbol Es and atomic number 99. Einsteinium is a member of the actinide series and it is the seventh transuranium element. It was named in honor of Albert Einstein.

<span class="mw-page-title-main">Beryllium fluoride</span> Chemical compound

Beryllium fluoride is the inorganic compound with the formula BeF2. This white solid is the principal precursor for the manufacture of beryllium metal. Its structure resembles that of quartz, but BeF2 is highly soluble in water.

<span class="mw-page-title-main">Bromine trifluoride</span> Chemical compound

Bromine trifluoride is an interhalogen compound with the formula BrF3. At room temperature, it is a straw-coloured liquid with a pungent odor which decomposes violently on contact with water and organic compounds. It is a powerful fluorinating agent and an ionizing inorganic solvent. It is used to produce uranium hexafluoride (UF6) in the processing and reprocessing of nuclear fuel.

<span class="mw-page-title-main">Silver(II) fluoride</span> Chemical compound

Silver(II) fluoride is a chemical compound with the formula AgF2. It is a rare example of a silver(II) compound - silver usually exists in its +1 oxidation state. It is used as a fluorinating agent.

<span class="mw-page-title-main">Plutonium tetrafluoride</span> Chemical compound

Plutonium(IV) fluoride is a chemical compound with the formula (PuF4). This salt is generally a brown solid but can appear a variety of colors depending on the grain size, purity, moisture content, lighting, and presence of contaminants. Its primary use in the United States has been as an intermediary product in the production of plutonium metal for nuclear weapons usage.

<span class="mw-page-title-main">Aluminium fluoride</span> Chemical compound

Aluminium fluoride is an inorganic compound with the formula AlF3. It forms hydrates AlF3·xH2O. Anhydrous AlF3 and its hydrates are all colorless solids. Anhydrous AlF3 is used in the production of aluminium metal. Several occur as minerals.

<span class="mw-page-title-main">Krypton</span> Chemical element, symbol Kr and atomic number 36

Krypton is a chemical element; it has symbol Kr and atomic number 36. It is a colorless, odorless, tasteless noble gas that occurs in trace amounts in the atmosphere and is often used with other rare gases in fluorescent lamps. Krypton is chemically inert.

<span class="mw-page-title-main">Gold(III) fluoride</span> Chemical compound

Gold(III) fluoride, AuF3, is an orange solid that sublimes at 300 °C. It is a powerful fluorinating agent. It is very sensitive to moisture, yielding gold(III) hydroxide and hydrofluoric acid.

<span class="mw-page-title-main">Plutonium hexafluoride</span> Chemical compound

Plutonium hexafluoride is the highest fluoride of plutonium, and is of interest for laser enrichment of plutonium, in particular for the production of pure plutonium-239 from irradiated uranium. This isotope of plutonium is needed to avoid premature ignition of low-mass nuclear weapon designs by neutrons produced by spontaneous fission of plutonium-240.

<span class="mw-page-title-main">Thallium(I) fluoride</span> Chemical compound

Thallium(I) fluoride is the inorganic compound with the formula TlF. It is a white solid, forming orthorhombic crystals. The solid is slightly deliquescent. It has a distorted sodium chloride (rock salt) crystal structure, due to the 6s2 inert pair on Tl+.

<span class="mw-page-title-main">Indium(III) fluoride</span> Chemical compound

Indium(III) fluoride or indium trifluoride is the inorganic compound with the formula InF3. It is a white solid.

<span class="mw-page-title-main">Americium(III) chloride</span> Chemical compound

Americium(III) chloride or americium trichloride is the chemical compound composed of americium and chlorine with the formula AmCl3. This salt forms pink hexagonal crystals. In the solid state each americium atom has nine chlorine atoms as near neighbours, at approximately the same distance, in a tricapped trigonal prismatic configuration.

<span class="mw-page-title-main">Bismuth phosphate process</span>

The bismuth-phosphate process was used to extract plutonium from irradiated uranium taken from nuclear reactors. It was developed during World War II by Stanley G. Thompson, a chemist working for the Manhattan Project at the University of California, Berkeley. This process was used to produce plutonium at the Hanford Site. Plutonium was used in the atomic bomb that was used in the atomic bombing of Nagasaki in August 1945. The process was superseded in the 1950s by the REDOX and PUREX processes.

<span class="mw-page-title-main">Lanthanum trifluoride</span> Chemical compound

Lanthanum trifluoride is a refractory ionic compound of lanthanum and fluorine. The chemical formula is LaF
3
.

<span class="mw-page-title-main">Actinium(III) fluoride</span> Chemical compound

Actinium(III) fluoride (AcF3) is an inorganic compound, a salt of actinium and fluorine.

Praseodymium compounds are compounds formed by the lanthanide metal praseodymium (Pr). In these compounds, praseodymium generally exhibits the +3 oxidation state, such as PrCl3, Pr(NO3)3 and Pr(CH3COO)3. However, compounds with praseodymium in the +2 and +4 oxidation states, and unlike other lanthanides, the +5 oxidation state, are also known.

<span class="mw-page-title-main">Plutonium compounds</span> Chemical compounds containing the element plutonium

Plutonium compounds are compounds containing the element plutonium (Pu). At room temperature, pure plutonium is silvery in color but gains a tarnish when oxidized. The element displays four common ionic oxidation states in aqueous solution and one rare one:

References

  1. Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, p. 113, ISBN   0-8493-0594-2 , retrieved 2008-06-20
  2. Chemistry: Periodic Table: Plutonium: compound data (plutonium (III) fluoride), WebElements, retrieved 2008-06-20[ permanent dead link ]
  3. Wells A.F. (1984) Structural Inorganic Chemistry 5th edition Oxford Science Publications ISBN   0-19-855370-6.
  4. Gupta, C. K.; Mukherjee, T. K. (1990), Hydrometallurgy in Extraction Processes, vol. 2, CRC Press, pp. 206–208, ISBN   0-8493-6805-7, OCLC   21197603 , retrieved 2008-06-20
  5. Winchester, R. S. (1957), Aqueous Decontamination of Plutonium from Fission Product Elements (PDF), Los Alamos, NM: Los Alamos Scientific Laboratory of the University of California (published 1958), pp. 9–10, retrieved 2008-06-20
  6. Martella, L. L.; Saba, M. T.; Campbell, G. K. (1984), Laboratory-scale evaluations of alternative plutonium precipitation methods, United States Office of Scientific and Technical Information, doi:10.2172/5318991, OSTI   5318991