Fluorocyclopropane

Fluorocyclopropane

Names
Preferred IUPAC name Fluorocyclopropane
Other names Cyclopropyl fluoride, cyclopropylfluoride
Identifiers
CAS Number	1959-79-1  Y
3D model (JSmol)	Interactive image
ChemSpider	10328768
EC Number	212-459-6
PubChem CID	15248120
CompTox Dashboard (EPA)	DTXSID70570447
InChI InChI=1S/C3H5F/c4-3-1-2-3/h3H,1-2H2 Key: XAVRRVJJYIFROR-UHFFFAOYSA-N
SMILES C1CC1F
Properties
Chemical formula	C3H5F
Molar mass	60.071 g·mol−1
Density	g/cm3
Solubility in water	Insoluble
Related compounds
Related compounds	Chlorocyclopropane Bromocyclopropane Iodocyclopropane
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Fluorocyclopropane is an organofluorine compound with the chemical formula C₃H₅F. The compound is a member of haloalkane family. ^[1]

Synthesis

The compound can be produced by reacting imidazolylidene cyclopropyl group with xenon difluoride. ^[2]

Also, a reaction of enantioselective cyclopropanation of fluoro-substituted allylic alcohols using zinc carbenoids. ^[3]

See also

• Fluoroalkanes
• Fluorocyclohexane

References

1. Kerr, J. A.; Kirk, A. W.; O'Grady, B. V.; Phillips, D. C.; Trotman-Dickenson, A. F. (1967). "Kinetics of decomposition of chemically activated alkyl fluorides" . Discussions of the Faraday Society . 44: 263. doi:10.1039/DF9674400263 . Retrieved 29 May 2023.
2. Mankad, Neal P.; Toste, F. Dean (2012). "C(sp 3 )–F reductive elimination from alkylgold( iii ) fluoride complexes". Chem. Sci. 3 (1): 72–76. doi:10.1039/C1SC00515D. PMC   3474378 . Retrieved 29 May 2023.
3. Delion, Laëtitia; Poisson, Thomas; Jubault, Philippe; Pannecoucke, Xavier; Charette, André B. (September 2020). "Synthesis of fluorocyclopropanes via the enantioselective cyclopropanation of fluoro-substituted allylic alcohols using zinc carbenoids" . Canadian Journal of Chemistry . 98 (9): 516–523. doi:10.1139/cjc-2020-0036. ISSN   0008-4042 . Retrieved 29 May 2023.

Extra reading

• Dall'O, L.; Heydtmann, H. (January 1987). "Kinetic Study of Chemically Activated Fluorocyclopropane". Berichte der Bunsengesellschaft für physikalische Chemie. 91 (1): 24–30. doi:10.1002/bbpc.19870910107.
• Casas, F.; Kerr, J. A.; Trotman-Dickenson, A. F. (1964). "706. Fluorinated cyclopropanes. Part II. The thermal isomerization of monofluorocyclopropane". Journal of the Chemical Society (Resumed): 3655. doi:10.1039/JR9640003655.