Lithium hexafluorotitanate

Lithium hexafluorotitanate

Names
Other names dilithium hexafluorotitanate, titanium lithium hexafluoride
Identifiers
CAS Number	19193-50-1  Y
3D model (JSmol)	Interactive image
ChemSpider	11511486
EC Number	242-866-4
PubChem CID	22639608
InChI InChI=1S/6FH-C.2Li.Ti/h6*1H;;;/q;;;;;;2*+1;+4/p-6 Key: AHARGQJTTQNBPT-UHFFFAOYSA-H
SMILES [Li+].[Li+].F[Ti-2](F)(F)(F)(F)F
Properties
Chemical formula	F6Li2Ti
Molar mass	175.74 g·mol−1
Appearance	solid
Density	2.89 g/cm3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Lithium hexafluorotitanate is an inorganic compound of lithium, fluorine, and titanium with the chemical formula Li₂TiF₆. ^{[1] [2]}

Synthesis

Interaction of titanium hydroxide or oxide and lithium fluoride with hydrofluoric acid. ^[3]

Physical properties

The compound forms crystals of tetragonal crystal system with a space group of P42/mnm (no. 136). ^[4]

Chemical properties

The compound forms hydrates Li₃TiF₆*xH₂O. ^{[5] [6]}

References

1. "Lithium Hexafluorotitanate". American Elements. American Elements . Retrieved 16 February 2024.
2. "LITHIUM HEXAFLUOROTITANATE". chemsrc.com. Retrieved 16 February 2024.
3. Tikhomirova, E. L.; Nesterov, D. P.; Gromov, O. G.; Lokshin, E. P.; Kalinnikov, V. T. (1 June 2013). "Synthesis of lithium hexafluorotitanate" . Russian Journal of Applied Chemistry. 86 (6): 831–835. doi:10.1134/S1070427213060074. ISSN   1608-3296. S2CID   97687706 . Retrieved 16 February 2024.
4. "mp-7603". Materials Project . Retrieved 16 February 2024.
5. Marseglia, E. A.; Brown, I. D. (15 June 1973). "Lithium hexafluorotitanate dihydrate and lithium hexafluorostannate dihydrate" . Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry . 29 (6): 1352–1354. Bibcode:1973AcCrB..29.1352M. doi:10.1107/S0567740873004498. ISSN   0567-7408 . Retrieved 16 February 2024.
6. Nyquist, Richard A.; Putzig, Curtis L.; Kagel, Ronald O.; Leugers, M. Anne (28 December 1971). Handbook of Infrared and Raman Spectra of Inorganic Compounds and Organic Salts: Infrared Spectra of Inorganic Compounds. Academic Press. p. 32. ISBN   978-0-12-523450-4 . Retrieved 16 February 2024.