Tourmaline | |
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General | |
Category | Cyclosilicate |
Formula (repeating unit) | (Ca,K,Na, ▢)(Al,Fe,Li,Mg,Mn)3(Al,Cr,Fe,V)6 (BO3)3(Si,Al,B)6O18(OH,F)4 [1] [2] |
IMA symbol | Tur [3] |
Crystal system | Trigonal |
Crystal class | Ditrigonal pyramidal (3m) H-M symbol: (3m) |
Space group | R3m (no. 160) |
Identification | |
Color | Most commonly black, but can range from colorless to brown, red, orange, yellow, green, blue, violet, pink, or hues in-between. It can also be bi-colored, or even tri-colored. Rarely, it can be found as neon green or electric blue. |
Crystal habit | Parallel and elongated; acicular prisms, sometimes radiating; massive; scattered grains (in granite) |
Cleavage | Indistinct |
Fracture | Uneven, small conchoidal |
Tenacity | Brittle |
Mohs scale hardness | 7.0–7.5 |
Luster | Vitreous, sometimes resinous |
Streak | White |
Diaphaneity | Translucent to opaque |
Specific gravity | 3.06+0.20–0.06 [1] |
Density | 2.82–3.32 |
Polish luster | Vitreous [1] |
Optical properties | Double-refractive, uniaxial negative [1] |
Refractive index | nω = 1.635–1.675 nε = 1.610–1.650 |
Birefringence | −0.018 to −0.040; typically about −0.020 but in dark stones it may reach −0.040 [1] |
Pleochroism |
|
Dispersion | 0.017 [1] |
Ultraviolet fluorescence | Pink stones; inert to very weak red to violet in long and short wave [1] |
Absorption spectra | Strong narrow band at 498 nm, and almost complete absorption of red down to 640 nm in blue and green stones; red and pink stones show lines at 458 and 451 nm, as well as a broad band in the green spectrum [1] |
Tourmaline ( /ˈtʊərməlɪn,-ˌliːn/ TOOR-mə-lin, -leen) is a crystalline silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. This gemstone comes in a wide variety of colors.
The name is derived from the Sinhalese tōramalli ( ටෝරමල්ලි ), which refers to the carnelian gemstones. [4]
Brightly colored Ceylonese gem tourmalines were brought to Europe in great quantities by the Dutch East India Company to satisfy a demand for curiosities and gems. Tourmaline was sometimes called the "Ceylonese Magnet" because it could attract and then repel hot ashes due to its pyroelectric properties. [5]
Tourmalines were used by chemists in the 19th century to polarize light by shining rays onto a cut and polished surface of the gem. [6]
Commonly encountered species and varieties of tourmaline include the following:
The most common species of tourmaline is schorl, the sodium iron (divalent) endmember of the group. It may account for 95% or more of all tourmaline in nature. The early history of the mineral schorl shows that the name "schorl" was in use prior to 1400 because a village known today as Zschorlau (in Saxony, Germany) was then named "Schorl" (or minor variants of this name), and the village had a nearby tin mine where, in addition to cassiterite, black tourmaline was found. The first description of schorl with the name "schürl" and its occurrence (various tin mines in the Ore Mountains) was written by Johannes Mathesius (1504–1565) in 1562 under the title "Sarepta oder Bergpostill". [7] Up to about 1600, additional names used in the German language were "Schurel", "Schörle", and "Schurl". Beginning in the 18th century, the name Schörl was mainly used in the German-speaking area. In English, the names shorl and shirl were used in the 18th century. In the 19th century the names common schorl, schörl, schorl and iron tourmaline were the English words used for this mineral. [7]
Dravite, also called brown tourmaline, is the sodium magnesium rich tourmaline endmember. Uvite, in comparison, is a calcium magnesium tourmaline. Dravite forms multiple series, with other tourmaline members, including schorl and elbaite. [8]
The name dravite was used for the first time by Gustav Tschermak (1836–1927), Professor of Mineralogy and Petrography at the University of Vienna, in his book Lehrbuch der Mineralogie (published in 1884) for magnesium-rich (and sodium-rich) tourmaline from village Dobrova near Unterdrauburg in the Drava river area, Carinthia, Austro-Hungarian Empire. Today this tourmaline locality (type locality for dravite) at Dobrova (near Dravograd), is a part of the Republic of Slovenia. [9] Tschermak gave this tourmaline the name dravite, for the Drava river area, which is the district along the Drava River (in German: Drau, in Latin: Drave) in Austria and Slovenia. The chemical composition which was given by Tschermak in 1884 for this dravite approximately corresponds to the formula NaMg3(Al,Mg)6B3Si6O27(OH), which is in good agreement (except for the OH content) with the endmember formula of dravite as known today. [9]
Dravite varieties include the deep green chromium dravite and the vanadium dravite. [10]
A lithium-tourmaline elbaite was one of three pegmatitic minerals from Utö, Sweden, in which the new alkali element lithium (Li) was determined in 1818 by Johan August Arfwedson for the first time. [11] Elba Island, Italy, was one of the first localities where colored and colorless Li-tourmalines were extensively chemically analysed. In 1850, Karl Friedrich August Rammelsberg described fluorine (F) in tourmaline for the first time. In 1870, he proved that all varieties of tourmaline contain chemically bound water. In 1889, Scharitzer proposed the substitution of (OH) by F in red Li-tourmaline from Sušice, Czech Republic. In 1914, Vladimir Vernadsky proposed the name Elbait for lithium-, sodium-, and aluminum-rich tourmaline from Elba Island, Italy, with the simplified formula (Li,Na)HAl6B2Si4O21. [11] Most likely the type material for elbaite was found at Fonte del Prete, San Piero in Campo, Campo nell'Elba, Elba Island, Province of Livorno, Tuscany, Italy. [11] In 1933 Winchell published an updated formula for elbaite, H8Na2Li3Al3B6Al12Si12O62, which is commonly used to date written as Na(Li1.5Al1.5)Al6(BO3)3[Si6O18](OH)3(OH). [11] The first crystal structure determination of a Li-rich tourmaline was published in 1972 by Donnay and Barton, performed on a pink elbaite from San Diego County, California, United States.[ citation needed ]
The tourmaline mineral group is chemically one of the most complicated groups of silicate minerals. Its composition varies widely because of isomorphous replacement (solid solution), and its general formula can be written as XY3Z6(T6O18)(BO3)3V3W, where: [12]
Species Name | Ideal Endmember Formula | IMA Number | Symbol |
---|---|---|---|
Adachiite | CaFe2+3Al6(Si5AlO18)(BO3)3(OH)3OH | 2012-101 | Adc |
Alumino-oxy-rossmanite | ▢Al3Al6(Si5AlO18)(BO3)3(OH)3O | 2020-008 | Aorsm |
Bosiite | NaFe3+3(Al4Mg2)Si6O18(BO3)3(OH)3O | 2014-094 | Bos |
Celleriite | ▢(Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH) | 2019-089 | Cll |
Chromium-dravite | NaMg3Cr6Si6O18(BO3)3(OH)3OH | 1982-055 | Cdrv |
Chromo-alumino-povondraite | NaCr3(Al4Mg2)Si6O18(BO3)3(OH)3O | 2013-089 | Capov |
Darrellhenryite | NaLiAl2Al6Si6O18(BO3)3(OH)3O | 2012-026 | Dhry |
Dravite | NaMg3Al6Si6O18(BO3)3(OH)3OH | - 1884 - | Drv |
Dutrowite | Na(Fe2.5Ti0.5)Al6Si6O18(BO3)3(OH)3O | 2019-082 | Dtw |
Elbaite | Na(Li1.5,Al1.5)Al6Si6O18(BO3)3(OH)3OH | - 1913 - | Elb |
Ertlite | NaAl3Al6(Si4B2O18)(BO3)3(OH)3O | 2023-086 | Etl |
Ferro-bosiite | NaFe3+3(Al4Fe2+2)Si6O18(BO3)3(OH)3O | 2022-069 | Fbos |
Feruvite | CaFe2+3(MgAl5)Si6O18(BO3)3(OH)3OH | 1987-057 | Fer |
Fluor-buergerite | NaFe3+3Al6Si6O18(BO3)3O3F | 1965-005 | Fbu |
Fluor-dravite | NaMg3Al6Si6O18(BO3)3(OH)3F | 2009-089 | Fdrv |
Fluor-elbaite | Na(Li1.5,Al1.5)Al6Si6O18(BO3)3(OH)3F | 2011-071 | Felb |
Fluor-liddicoatite | Ca(Li2,Al)Al6Si6O18(BO3)3(OH)3F | 1976-041 [lower-alpha 1] | Fld |
Fluor-rossmanite | ▢(LiAl2)Al6Si6O18(BO3)3(OH)3F | 2023-111 | Frsm |
Fluor-schorl | NaFe2+3Al6Si6O18(BO3)3(OH)3F | 2010-067 | Fsrl |
Fluor-tsilaisite | NaMn2+3Al6Si6O18(BO3)3(OH)3F | 2012-044 | Ftl |
Fluor-uvite | CaMg3(Al5Mg)Si6O18(BO3)3(OH)3F | - 1930 - | Fluvt |
Foitite | ▢(Fe2+2Al)Al6Si6O18(BO3)3(OH)3OH | 1992-034 | Foi |
Lucchesiite | Ca(Fe2+)3Al6Si6O18(BO3)3(OH)3O | 2015-043 | Lcc |
Magnesio-dutrowite | Na(Mg2.5Ti0.5)Al6Si6O18(BO3)3(OH)3O | 2023-015 | Mdtw |
Magnesio-foitite | ▢(Mg2Al)Al6Si6O18(BO3)3(OH)3OH | 1998-037 | Mfoi |
Magnesio-lucchesite | Ca(Mg3Al6Si6O18(BO3)3(OH)3O | 2019-025 | Mlcc |
Maruyamaite | K(MgAl2)(Al5Mg)Si6O18(BO3)3(OH)3O | 2013-123 | Mry |
Olenite | NaAl3Al6Si6O18(BO3)3O3OH | 1985-006 | Ole |
Oxy-chromium-dravite | NaCr3(Mg2Cr4)Si6O18(BO3)3(OH)3O | 2011-097 | Ocdrv |
Oxy-dravite | Na(Al2Mg)(Al5Mg)Si6O18(BO3)3(OH)3O | 2012-004 | Odrv |
Oxy-foitite | ▢(Fe2+Al2)Al6Si6O18(BO3)3(OH)3O | 2016-069 | Ofoi |
Oxy-schorl | Na(Fe2+2Al)Al6Si6O18(BO3)3(OH)3O | 2011-011 | Osrl |
Oxy-vanadium-dravite | NaV3(V4Mg2)Si6O18(BO3)3(OH)3O | 1999-050 | Ovdrv |
Povondraite | NaFe3+3(Fe3+4Mg2)Si6O18(BO3)3(OH)3O | 1979 [lower-alpha 2] | Pov |
Princivalleite | Na(Mn2Al)Al6Si6O18(BO3)3(OH)3O | 2020-056 | Pva |
Rossmanite | ▢(LiAl2)Al6Si6O18(BO3)3(OH)3OH | 1996-018 | Rsm |
Schorl | NaFe2+3Al6Si6O18(BO3)3(OH)3OH | - 1505 - | Srl |
Tsilaisite | NaMn2+3Al6Si6O18(BO3)3(OH)3OH | 2011-047 | Tsl |
Uvite | CaMg3(Al5Mg)Si6O18(BO3)3(OH)3OH | 2000-030 | Uvt |
Vanadio-oxy-chromium-dravite | NaV3(Cr4Mg2)Si6O18(BO3)3(OH)3O | 2012-034 | Vocdrv |
Vanadio-oxy-dravite | NaV3(Al4Mg2)Si6O18(BO3)3(OH)3O | 2012-074 | Vodrv |
Mineral species that were named before the IMA was founded in 1958 do not have an IMA number.
The IMA commission on new mineral names published a list of approved symbols for each mineral species in 2021. [13]
A revised nomenclature for the tourmaline group was published in 2011. [14] [15] [16]
Tourmaline is a six-member ring cyclosilicate having a trigonal crystal system. It occurs as long, slender to thick prismatic and columnar crystals that are usually triangular in cross-section, often with curved striated faces. The style of termination at the ends of crystals is sometimes asymmetrical, called hemimorphism. Small slender prismatic crystals are common in a fine-grained granite called aplite, often forming radial daisy-like patterns. Tourmaline is distinguished by its three-sided prisms; no other common mineral has three sides. Prisms faces often have heavy vertical striations that produce a rounded triangular effect. Tourmaline is rarely perfectly euhedral. An exception was the fine dravite tourmalines of Yinnietharra, in western Australia. The deposit was discovered in the 1970s, but is now exhausted. All hemimorphic crystals are piezoelectric, and are often pyroelectric as well.[ citation needed ]
A crystal of tourmaline is built up of units consisting of a six-member silica ring that binds above to a large cation, such as sodium. The ring binds below to a layer of metal ions and hydroxyls or halogens, which structurally resembles a fragment of kaolin. This in turn binds to three triangular borate ions. Units joined end to end form columns running the length of the crystal. Each column binds with two other columns offset one-third and two-thirds of the vertical length of a single unit to form bundles of three columns. Bundles are packed together to form the final crystal structure. Because the neighboring columns are offset, the basic structural unit is not a unit cell: The actual unit cell of this structure includes portions of several units belonging to adjacent columns. [17] [18]
Tourmaline has a variety of colors. Iron-rich tourmalines are usually black to bluish-black to deep brown, while magnesium-rich varieties are brown to yellow, and lithium-rich tourmalines are almost any color: blue, green, red, yellow, pink, etc. Rarely, it is colorless. Bi-colored and multicolored crystals are common, reflecting variations of fluid chemistry during crystallization. Crystals may be green at one end and pink at the other, or green on the outside and pink inside; this type is called watermelon tourmaline and is prized in jewelry. An excellent example of watermelon tourmaline jewelry is a brooch piece (1969, gold, watermelon tourmaline, diamonds) by Andrew Grima (British, b. Italy, 1921–2007), in the collection of Kimberly Klosterman and on display at the Cincinnati Art Museum. [19] Some forms of tourmaline are dichroic; they change color when viewed from different directions. [20]
The pink color of tourmalines from many localities is the result of prolonged natural irradiation. During their growth, these tourmaline crystals incorporated Mn2+ and were initially very pale. Due to natural gamma ray exposure from radioactive decay of 40K in their granitic environment, gradual formation of Mn3+ ions occurs, which is responsible for the deepening of the pink to red color. [21]
Opaque black schorl and yellow tsilaisite are idiochromatic tourmaline species that have high magnetic susceptibilities due to high concentrations of iron and manganese respectively. Most gem-quality tourmalines are of the elbaite species. Elbaite tourmalines are allochromatic, deriving most of their color and magnetic susceptibility from schorl (which imparts iron) and tsilaisite (which imparts manganese).[ citation needed ]
Red and pink tourmalines have the lowest magnetic susceptibilities among the elbaites, while tourmalines with bright yellow, green and blue colors are the most magnetic elbaites. Dravite species such as green chromium dravite and brown dravite are diamagnetic. A handheld neodymium magnet can be used to identify or separate some types of tourmaline gems from others. For example, blue indicolite tourmaline is the only blue gemstone of any kind that will show a drag response when a neodymium magnet is applied. Any blue tourmaline that is diamagnetic can be identified as paraiba tourmaline colored by copper in contrast to magnetic blue tourmaline colored by iron. [22]
Some tourmaline gems, especially pink to red colored stones, are altered by heat treatment to improve their color. Overly dark red stones can be lightened by careful heat treatment. The pink color in manganese-containing near-colorless to pale pink stones can be greatly increased by irradiation with gamma-rays or electron beams. Irradiation is almost impossible to detect in tourmalines, and does not, currently, affect the value. Heavily included tourmalines, such as rubellite and Brazilian paraiba, are sometimes clarity-enhanced. A clarity-enhanced tourmaline (especially the paraiba variety) is worth much less than an untreated gem of equal clarity. [23]
Tourmaline is found in granite and granite pegmatites and in metamorphic rocks such as schist and marble. Schorl and lithium-rich tourmalines are usually found in granite and granite pegmatite. Magnesium-rich tourmalines, dravites, are generally restricted to schists and marble. Tourmaline is a durable mineral and can be found in minor amounts as grains in sandstone and conglomerate, and is part of the ZTR index for highly weathered sediments. [24]
Gem and specimen tourmaline is mined chiefly in Brazil and many parts of Africa, including Tanzania, Nigeria, Kenya, Madagascar, Mozambique, Malawi, and Namibia. It is also mined in Asia, notably in Pakistan, Afghanistan, and Indonesia as well as in Sri Lanka and India, [25] where some placer material suitable for gem use is found.
Some fine gems and specimen material have been produced in the United States, with the first discoveries in 1822, in the state of Maine. California became a large producer of tourmaline in the early 1900s. The Maine deposits tend to produce crystals in raspberry pink-red as well as minty greens. The California deposits are known for bright pinks, as well as bicolors. During the early 1900s, Maine and California were the world's largest producers of gem tourmalines. The Empress Dowager Cixi of China loved pink tourmaline and bought large quantities for gemstones and carvings from the then new Himalaya Mine, located in San Diego County, California. [26] It is not clear when the first tourmaline was found in California. Native Americans have used pink and green tourmaline as funeral gifts for centuries. The first documented case was in 1890 when Charles Russel Orcutt found pink tourmaline at what later became the Stewart Mine at Pala, California in San Diego County. [27]
Almost every color of tourmaline can be found in Brazil, especially in Minas Gerais and Bahia. The new type of tourmaline, which soon became known as paraiba tourmaline, came in blue and green. Brazilian paraiba tourmaline usually contains abundant inclusions. Much of the paraiba tourmaline from Brazil does not actually come from Paraíba, but the neighboring state of Rio Grande do Norte. Material from Rio Grande do Norte is often somewhat less intense in color, but many fine gems are found there. It was determined that the element copper was important in the coloration of the stone. [28]
A large bluish-green tourmaline from Paraiba, measuring 36.44 mm × 33.75 mm × 21.85 mm (1.43 in × 1.33 in × 0.86 in) and weighing 191.87 carats (1.3536 oz; 38.374 g), is the world's largest cut tourmaline. [29] [30] Owned by Billionaire Business Enterprises, [29] it was presented in Montreal, Quebec, Canada, on 14 October 2009. [30]
In the late 1990s, copper-containing tourmaline was found in Nigeria. The material was generally paler and less saturated than the Brazilian materials, although the material generally was much less included. A more recent African discovery from Mozambique has also produced tourmaline colored by copper, similar to the Brazilian paraiba. The Mozambique paraiba material usually is more intensely colored than the Nigerian and Mozambique Paraiba tourmaline have similar colors to the Brazilian Paraiba, but the prices are relatively cheaper, better clarity and larger sizes. In recent years the pricing of these beautiful gemstones has increased significantly. [31]
Another highly valuable variety is chrome tourmaline, a rare type of dravite tourmaline from Tanzania. Chrome tourmaline is a rich green color due to the presence of chromium atoms in the crystal. Of the standard elbaite colors, blue indicolite gems are typically the most valuable, [32] followed by green verdelite and pink to red rubellite. [33]
Amblygonite is a fluorophosphate mineral, (Li,Na)AlPO4(F,OH), composed of lithium, sodium, aluminium, phosphate, fluoride and hydroxide. The mineral occurs in pegmatite deposits and is easily mistaken for albite and other feldspars. Its density, cleavage and flame test for lithium are diagnostic. Amblygonite forms a series with montebrasite, the low fluorine endmember. Geologic occurrence is in granite pegmatites, high-temperature tin veins, and greisens. Amblygonite occurs with spodumene, apatite, lepidolite, tourmaline, and other lithium-bearing minerals in pegmatite veins. It contains about 10% lithium, and has been utilized as a source of lithium. The chief commercial sources have historically been the deposits of California and France.
Beryl ( BERR-əl) is a mineral composed of beryllium aluminium silicate with the chemical formula Be3Al2Si6O18. Well-known varieties of beryl include emerald and aquamarine. Naturally occurring hexagonal crystals of beryl can be up to several meters in size, but terminated crystals are relatively rare. Pure beryl is colorless, but it is frequently tinted by impurities; possible colors are green, blue, yellow, pink, and red (the rarest). It is an ore source of beryllium.
Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula KAl2(AlSi3O10)(F,OH)2, or (KF)2(Al2O3)3(SiO2)6(H2O). It has a highly perfect basal cleavage yielding remarkably thin laminae (sheets) which are often highly elastic. Sheets of muscovite 5 meters × 3 meters (16.5 feet × 10 feet) have been found in Nellore, India.
Spinel is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl
2O
4 in the cubic crystal system. Its name comes from the Latin word spinella, a diminutive form of spine, in reference to its pointed crystals.
Topaz is a silicate mineral made of aluminum and fluorine with the chemical formula Al2SiO4(F, OH)2. It is used as a gemstone in jewelry and other adornments. Common topaz in its natural state is colorless, though trace element impurities can make it pale blue or golden brown to yellow-orange. Topaz is often treated with heat or radiation to make it a deep blue, reddish-orange, pale green, pink, or purple.
Orthoclase, or orthoclase feldspar (endmember formula KAlSi3O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture", because its two cleavage planes are at right angles to each other. It is a type of potassium feldspar, also known as K-feldspar. The gem known as moonstone (see below) is largely composed of orthoclase.
The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula BeAl2O4. The name chrysoberyl is derived from the Greek words χρυσός chrysos and βήρυλλος beryllos, meaning "a gold-white spar". Despite the similarity of their names, chrysoberyl and beryl are two completely different gemstones, although they both contain beryllium. Chrysoberyl is the third-hardest frequently encountered natural gemstone and lies at 8.5 on the Mohs scale of mineral hardness, between corundum (9) and topaz (8).
Pleochroism is an optical phenomenon in which a substance has different colors when observed at different angles, especially with polarized light.
Lepidolite is a lilac-gray or rose-colored member of the mica group of minerals with chemical formula K(Li,Al)3(Al,Si,Rb)4O10(F,OH)2. It is the most abundant lithium-bearing mineral and is a secondary source of this metal. It is the major source of the alkali metal rubidium.
Spodumene is a pyroxene mineral consisting of lithium aluminium inosilicate, LiAl(SiO3)2, and is a commercially important source of lithium. It occurs as colorless to yellowish, purplish, or lilac kunzite (see below), yellowish-green or emerald-green hiddenite, prismatic crystals, often of great size. Single crystals of 14.3 m (47 ft) in size are reported from the Black Hills of South Dakota, United States.
Petalite, also known as castorite, is a lithium aluminum tektosilicate mineral LiAlSi4O10, crystallizing in the monoclinic system. Petalite occurs as colorless, pink, grey, yellow, yellow grey, to white tabular crystals and columnar masses. It occurs in lithium-bearing pegmatites with spodumene, lepidolite, and tourmaline. Petalite is an important ore of lithium, and is converted to spodumene and quartz by heating to ~500 °C and under 3 kbar of pressure in the presence of a dense hydrous alkali borosilicate fluid with a minor carbonate component. Petalite (and secondary spodumene formed from it) is lower in iron than primary spodumene, making it a more useful source of lithium in, e.g., the production of glass. The colorless varieties are often used as gemstones.
Jadeite is a pyroxene mineral with composition NaAlSi2O6. It is hard (Mohs hardness of about 6.5 to 7.0), very tough, and dense, with a specific gravity of about 3.4. It is found in a wide range of colors, but is most often found in shades of green or white. Jadeite is formed only in the subduction zones of continental margins, where rock undergoes metamorphism at high pressure but relatively low temperature.
Diopside is a monoclinic pyroxene mineral with composition MgCaSi
2O
6. It forms complete solid solution series with hedenbergite and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class. It has two distinct prismatic cleavages at 87 and 93° typical of the pyroxene series. It has a Mohs hardness of six, a Vickers hardness of 7.7 GPa at a load of 0.98 N, and a specific gravity of 3.25 to 3.55. It is transparent to translucent with indices of refraction of nα=1.663–1.699, nβ=1.671–1.705, and nγ=1.693–1.728. The optic angle is 58° to 63°.
Brazilianite, whose name derives from its country of origin, Brazil, is a typically yellow-green phosphate mineral, most commonly found in phosphate-rich pegmatites.
Aegirine is a member of the clinopyroxene group of inosilicate minerals. It is the sodium endmember of the aegirine–augite series. It has the chemical formula NaFeSi2O6, in which the iron is present as the ion Fe3+. In the aegirine–augite series, the sodium is variably replaced by calcium with iron(II) and magnesium replacing the iron(III) to balance the charge. Aluminum also substitutes for the iron(III). Acmite is a fibrous green-colored variety.
Elbaite, a sodium, lithium, aluminium boro-silicate, with the chemical composition Na(Li1.5Al1.5)Al6Si6O18(BO3)3(OH)4, is a mineral species belonging to the six-member ring cyclosilicate tourmaline group.
Richterite is a sodium calcium magnesium silicate mineral belonging to the amphibole group. If iron replaces the magnesium within the structure of the mineral, it is called ferrorichterite; if fluorine replaces the hydroxyl, it is called fluororichterite. Richterite crystals are long and prismatic, or prismatic to fibrous aggregate, or rock-bound crystals. Colors of richterite range from brown, grayish-brown, yellow, brownish- to rose-red, or pale to dark green. Richterite occurs in thermally metamorphosed limestones in contact metamorphic zones. It also occurs as a hydrothermal product in mafic igneous rocks, and in manganese-rich ore deposits. Localities include Mont-Saint-Hilaire, Quebec, and Wilberforce and Tory Hill, Ontario, Canada; Långban and Pajsberg, Sweden; West Kimberley, Western Australia; Sanka, Myanmar; and, in the US, at Iron Hill, Colorado; Leucite Hills, Wyoming; and Libby, Montana. The mineral was named in 1865 for the German mineralogist Hieronymous Theodor Richter (1824–1898).
Fluor-liddicoatite is a rare member of the tourmaline group of minerals, elbaite subgroup, and the theoretical calcium endmember of the elbaite-fluor-liddicoatite series; the pure end-member has not yet been found in nature. Fluor-liddicoatite is indistinguishable from elbaite by X-ray diffraction techniques. It forms a series with elbaite and probably also with olenite. Liddiocoatite is currently a non-approved mineral name, but Aurisicchio et al. (1999) and Breaks et al. (2008) found OH-dominant species. Formulae are
Fluor-uvite is a tourmaline mineral with the chemical formula CaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3F. It is a rare mineral that is found in calcium rich contact metamorphic rocks with increased amounts of boron. Uvite is trigonal hexagonal, which means that it has three equal length axes at 120 degrees, all perpendicular to its fourth axis which has a different length. Uvite is part of the space group 3m. Uvite's hardness has been measured to be 7.5 on the Mohs hardness scale. The color of uvite widely varies, depending on the sample, but is mostly deep green or brown. In regard to uvite's optical properties, it is uniaxial (-) and anisotropic, meaning that the velocity of light in the mineral depends on the path that it takes. In plane polarized light, uvite is colorless to pale yellow and shows weak pleochroism.
Povondraite is a rare silicate mineral from the tourmaline group with formula: NaFe3+3(Fe3+4,Mg2)(BO3)3Si6O18(OH)3O. It is a dark brown to black nearly opaque mineral with a resinous to splendent luster. It crystallizes in the trigonal crystal system as equant, distorted prisms with trigonal pyramid terminations.
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