Povondraite

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Povondraite
Povondraite-657308.jpg
The crystals here are black, lustrous, and 1-2mm in size. They richly cover one side of the matrix, and the povondraite winds its way through the fissures in the rock.
General
CategoryCyclosilicates
Formula
(repeating unit)
NaFe3+3(Mg2Fe3+4)(Si6O18)(BO3)3(OH)3O
IMA symbol Pov [1]
Strunz classification 8/E.19-75
Dana classification61.3.1.6
Crystal system Hexagonal-Rhomboidal
Crystal class Hemimorphic trigonal
Space group R3m (No. 160)
Unit cell a=16.18Å, c=7.44Å
Identification
Formula mass 1156.50 gm
ColourDark brown to brown-black, black
Crystal habit Prismatic, striated
Cleavage None observed
Fracture Irregular, conchoidal
Tenacity Brittle
Mohs scale hardness7
Luster Resinous
Streak Brown
Diaphaneity Translucent
Refractive index 1.74 - 1.82
Birefringence 0.069
Common impuritiesK,Mg,Al,Cu,Pb,Sn,Ti,V,H2O

Povondraite is a rare silicate mineral from the tourmaline group with formula: NaFe3+3(Fe3+4,Mg2)(BO3)3Si6O18(OH)3O. [2] It is a dark brown to black nearly opaque mineral with a resinous to splendent luster. It crystallizes in the trigonal crystal system as equant, distorted prisms with trigonal pyramid terminations. [3] [2]

It occurs as rare fracture and cavity encrustations within schists derived from sedimentary rocks. Associated minerals include quartz, potassium feldspar, muscovite, schorl, riebeckite and magnesite. [3]

Discovered at the San Francisco mine, near Villa Tunari (in Alto Chapare), Bolivia, in 1976, originally it was called ferridravite, for the composition and the assumed relationship to dravite, i.e., "ferric dravite". [4] However later investigations yielded a new empirical formula which had no relation to the dravite. This called for renaming, and the new name, after Pavel Povondra (1924–2013), [5] a mineralogist at the Charles University in Prague, was approved by the International Mineralogical Association in the 1990s. [6]

Related Research Articles

<span class="mw-page-title-main">Tourmaline</span> Cyclosilicate mineral group

Tourmaline is a crystalline silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. This gemstone comes in a wide variety of colors.

<span class="mw-page-title-main">Allanite</span> Rare-earth enriched sorosilicate mineral

Allanite (also called orthite) is a sorosilicate group of minerals within the broader epidote group that contain a significant amount of rare-earth elements. The mineral occurs mainly in metamorphosed clay-rich sediments and felsic igneous rocks. It has the general formula A2M3Si3O12[OH], where the A sites can contain large cations such as Ca2+, Sr2+, and rare-earth elements, and the M sites admit Al3+, Fe3+, Mn3+, Fe2+, or Mg2+ among others. However, a large amount of additional elements, including Th, U, Be, Zr, P, Ba, Cr and others may be present in the mineral. The International Mineralogical Association lists four minerals in the allanite group, each recognized as a unique mineral: allanite-(Ce), allanite-(La), allanite-(Nd), and allanite-(Y), depending on the dominant rare earth present: cerium, lanthanum, neodymium or yttrium.

<span class="mw-page-title-main">Elbaite</span>

Elbaite, a sodium, lithium, aluminium boro-silicate, with the chemical composition Na(Li1.5Al1.5)Al6Si6O18(BO3)3(OH)4, is a mineral species belonging to the six-member ring cyclosilicate tourmaline group.

<span class="mw-page-title-main">Digenite</span> Copper sulfide mineral

Digenite is a copper sulfide mineral with formula: Cu9S5. Digenite is a black to dark blue opaque mineral that crystallizes with a trigonal - hexagonal scalenohedral structure. In habit it is usually massive, but does often show pseudo-cubic forms. It has poor to indistinct cleavage and a brittle fracture. It has a Mohs hardness of 2.5 to 3 and a specific gravity of 5.6. It is found in copper sulfide deposits of both primary and supergene occurrences. It is typically associated with and often intergrown with chalcocite, covellite, djurleite, bornite, chalcopyrite and pyrite. The type locality is Sangerhausen, Thuringia, Germany, in copper slate deposits.

<span class="mw-page-title-main">Microlite</span>

Microlite was once known as a pale-yellow, reddish-brown, or black isometric mineral composed of sodium calcium tantalum oxide with a small amount of fluorine. Its chemical formula is(Na,Ca)2Ta2O6(O,OH,F). Today it is a name of a group of oxide minerals of a similar stoichiometry having tantalum prevailing over titanium and niobium. The microlite group belongs to a large pyrochlore supergroup that occurs in pegmatites and constitutes an ore of tantalum. It has a Mohs hardness of 5.5 and a variable specific gravity of 4.2 to 6.4. It occurs as disseminated microscopic subtranslucent to opaque octahedral crystals with a refractive index of 2.0 to 2.2. Microlite is also called djalmaite, but both names are now obsolete.

<span class="mw-page-title-main">Aheylite</span>

Aheylite is a rare phosphate mineral with formula (Fe2+Zn)Al6[(OH)4|(PO4)2]2·4(H2O). It occurs as pale blue to pale green triclinic crystal masses. Aheylite was made the newest member of the turquoise group in 1984 by International Mineralogical Association Commission on New Minerals and Mineral Names.

<span class="mw-page-title-main">Fluor-buergerite</span>

Fluor-buergerite, originally named buergerite, is a mineral species belonging to the tourmaline group. It was first described for an occurrence in rhyolitic cavities near Mexquitic, San Luis Potosi, Mexico. It was approved as a mineral in 1966 by the IMA and named in honor of Martin J. Buerger (1903–1986), professor of mineralogy at the Massachusetts Institute of Technology. It has also been reported from Minas Gerais, Brazil, and the Central Bohemia Region of the Czech Republic.

<span class="mw-page-title-main">Cabalzarite</span>

Cabalzarite is a rare arsenate mineral with the chemical formula Ca(Mg,Al,Fe3+
)
2
[AsO
4
]
2
•2(H
2
O,OH)
. It is a member of the tsumcorite group. It crystallizes in the monoclinic system and typically occurs as clusters of crystals or granular aggregates.

Cleusonite is a member of the crichtonite group of minerals with the chemical formula (Pb,Sr)(U4+
,U6+
)(Fe2+
,Zn)
2
(Ti,Fe2+
,Fe3+
)
18
(O,OH)
38
. This group of minerals contains approximately thirteen complex metal titanates. The structures of minerals of this group is complicated by frequent fine-scale twinning and metamictization due to radioactive elements. The crichtonite group consists of members of related mineral species of the type A{BC2D6E12}O38 which are characterized by their predominant cations (as seen in crichtonite (Sr), senaite (Pb), davidite (REE + U), landauite (Na), loveringite (Ca), lindsleyite (Ba), and mathiasite (K).

<span class="mw-page-title-main">Hureaulite</span>

Hureaulite is a manganese phosphate with the formula Mn2+5(PO3OH)2(PO4)2·4H2O. It was discovered in 1825 and named in 1826 for the type locality, Les Hureaux, Saint-Sylvestre, Haute-Vienne, Limousin, France. It is sometimes written as huréaulite, but the IMA does not recommend this for English language text.

<span class="mw-page-title-main">Zemannite</span>

Zemannite is a very rare oxide mineral with the chemical formula Mg0.5ZnFe3+[TeO3]3·4.5H2O. It crystallizes in the hexagonal crystal system and forms small prismatic brown crystals. Because of the rarity and small crystal size, zemannite has no applications and serves as a collector's item.

<span class="mw-page-title-main">Beudantite</span> Secondary mineral of the alunite group

Beudandite is a secondary mineral occurring in the oxidized zones of polymetallic deposits. It is a lead, iron, arsenate, sulfate with endmember formula: PbFe3(OH)6SO4AsO4.

<span class="mw-page-title-main">Fluor-liddicoatite</span>

Fluor-liddicoatite is a rare member of the tourmaline group of minerals, elbaite subgroup, and the theoretical calcium endmember of the elbaite-fluor-liddicoatite series; the pure end-member has not yet been found in nature. Fluor-liddicoatite is indistinguishable from elbaite by X-ray diffraction techniques. It forms a series with elbaite and probably also with olenite. Liddiocoatite is currently a non-approved mineral name, but Aurisicchio et al. (1999) and Breaks et al. (2008) found OH-dominant species. Formulae are

<span class="mw-page-title-main">Walfordite</span>

Walfordite is a very rare tellurite mineral that was discovered in Chile in 1999. The mineral is described as orange with orange-yellow streak, and is determined to have a chemical formula of Fe3+,Te6+Te4+3O8 with minor titanium and magnesium substitution resulting in an approximate empirical formula of (Fe3+,Te6+,Ti4+,Mg)(Te4+)3O8.

<span class="mw-page-title-main">Fluor-uvite</span>

Fluor-uvite is a tourmaline mineral with the chemical formula CaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3F. It is a rare mineral that is found in calcium rich contact metamorphic rocks with increased amounts of boron. Uvite is trigonal hexagonal, which means that it has three equal length axes at 120 degrees, all perpendicular to its fourth axis which has a different length. Uvite is part of the space group 3m. Uvite's hardness has been measured to be 7.5 on the Mohs hardness scale. The color of uvite widely varies, depending on the sample, but is mostly deep green or brown. In regard to uvite's optical properties, it is uniaxial (-) and anisotropic, meaning that the velocity of light in the mineral depends on the path that it takes. In plane polarized light, uvite is colorless to pale yellow and shows weak pleochroism.

Feklichevite is a rare mineral of the eudialyte group with the formula Na11Ca9(Fe3+,Fe2+)2Zr3NbSi(Si3O9)2(Si9O27)2. The original formula was extended to show the presence of cyclic silicate groups and presence of silicon at the M4 site, according to the nomenclature of eudialyte group. When compared to other minerals of the group, feklichevite characterizes in the presence of ferric iron (thus similar to ikranite, mogovidite and fengchengite) and dominance of calcium at the N4 site. Calcium is ordered in the structure and is also present at the M1 site. Other iron-bearing minerals of the group are eudialyte, ferrokentbrooksite, georgbarsanovite, khomyakovite, labyrinthite, oneillite and rastsvetaevite, but they rather contain ferrous iron Feklichevite name honors Russian mineralogist and crystallographer, V. G. Feklichev.

Arakiite (IMA symbol: Ark) is a rare mineral with the formula (Zn,Mn2+)(Mn2+,Mg)12(Fe3+,Al)2(As3+O3)(As5+O4)2(OH)23. It is both arsenate and arsenite mineral, a combination that is rare in the world of minerals. Arakiite is stoichiometrically similar to hematolite. It is one of many rare minerals coming from the famous Långban manganese skarn deposit in Sweden. Other minerals bearing both arsenite and zinc include kraisslite and mcgovernite.

<span class="mw-page-title-main">Lucchesiite</span>

Lucchesiite is a new member of tourmaline-group of minerals. Lucchesiite has the formula CaFe3Al6(Si6O18)(BO3)3(OH)3O. It is the calcium and oxygen-analogue of schorl. It has two co-type localizations, one in Czech Republic and the other in Sri Lanka. As the other members of the tourmaline group, it is trigonal.

Filipstadite is a very rare mineral of the spinel group, with the formula (Mn,Mg)(Sb5+0.5Fe3+0.5)O4. It is isometric, although it was previously though to be orthorhombic. When compared to a typical spinel, both the octahedral and tetrahedral sites are split due to cation ordering. Filipstadite is chemically close to melanostibite. The mineral comes from Långban, Sweden, a manganese skarn deposit famous for many rare minerals.

<span class="mw-page-title-main">Foitite</span> Tourmaline mineral

Foitite is a mineral in the tourmaline group, it is a vacancy-dominant member of the group. Foitite is in the 'vacancy' group, due to the absence of atoms in the X site.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 "Povondraite" on Mindat.org
  3. 1 2 Handbook of Mineralogy
  4. Kurt Valenta, Pete J. Dunn, "Ferridravite, a new mineral of the tourmaline group from Bolivia", American Mineralogist, Volume 64, pages 945-948, 1979
  5. "Povondra, Pavel, 1924-2013 - Portaro - katalog knihovny". katalog.vsb.cz. Retrieved 2021-03-19.
  6. Joel, D. Grice, T. Scott Encit, Frank C. Hawthorne,"Povondraite. a redefinition of the tourmaline ferridravite", American Mineralogist, Volume 78, pages 433-436, 1993