Keatite

Last updated
Keatite
Keatite.svg
Crystal structure
General
Category Silicate mineral
Formula
(repeating unit)
SiO2
Strunz classification 4.DA.45
Crystal system Tetragonal
Identification
Crystal habit Microscopic inclusions

Keatite is a silicate mineral with the chemical formula Si O 2 (silicon dioxide) that was discovered in nature in 2013. It is a tetragonal polymorph of silica first known as a synthetic phase. [1] It was reported as minute inclusions within clinopyroxene (diopside) crystals in an ultra high pressure garnet pyroxenite body. The host rock is part of the Kokchetav Massif in Kazakhstan. [2]

Keatite was synthesized in 1954 and named for Paul P. Keat who discovered it while studying the role of soda in the crystallization of amorphous silica. [3] Keatite was well known before 1970 as evidenced in few studies from that era. [4] [5]

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Akdalaite (IMA symbol: Akd) is a very rare mineral found in Kazakhstan and has the formula 5Al2O3·H2O. It was formerly believed to be 4Al2O3·H2O. It is therefore the same as tohdite an artificially produced phase. Studies on the crystal structure and spectra indicate that this is an aluminium oxide hydroxide.

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<span class="mw-page-title-main">Gyrolite</span> Rare phyllosilicate mineral crystallizing in spherules

Gyrolite, NaCa16(Si23Al)O60(OH)8·14H2O, is a rare silicate mineral (basic sodium calcium silicate hydrate: N-C-S-H, in cement chemist notation) belonging to the class of phyllosilicates. Gyrolite is also often associated with zeolites. It is most commonly found as spherical or radial formations in hydrothermally altered basalt and basaltic tuffs. These formations can be glassy, dull or fibrous in appearance.

References

  1. Ralph, Jolyon, and Ida Ralph. "Keatite: Keatite Mineral Information and Data." MinDat. 2013. Aug. 2013
  2. Abstract Hill, Tina R., Hiromi Konishi, and Huifang Xu, Natural occurrence of keatite precipitates in UHP clinopyroxene from the Kokchetav Massif: A TEM investigation, American Mineralogist, Volume 98, pages 187–196, 2013
  3. Science 120 (27 Aug1954) pp 328-330 with the title "A new crystalline silica.
  4. Li, C. T. (1971). "Transformation mechanism between high-quartz and keatite phases of LiAlSi2O6 composition". Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry. 27 (6): 1132–1140. doi:10.1107/S0567740871003649.
  5. Martin, Brigitte (December 1995). "Keatite; II, Hydrothermal synthesis from silica-glass". European Journal of Mineralogy. 7 (6): 1389–1397. Bibcode:1995EJMin...7.1389M. doi:10.1127/ejm/7/6/1389.