Tridymite | |
---|---|
General | |
Category | Oxide mineral (or tectosilicate), quartz group |
Formula (repeating unit) | SiO2 |
IMA symbol | Trd [1] |
Strunz classification | 4.DA.10 |
Crystal system | Orthorhombic (α-tridymite) |
Crystal class | Disphenoidal (222) H–M symbol: (222) |
Space group | C2221 |
Identification | |
Formula mass | 60.08 g/mol |
Color | Colorless, white |
Crystal habit | Platy – sheet forms |
Cleavage | {0001} indistinct, {1010} imperfect |
Fracture | Brittle – conchoidal |
Mohs scale hardness | 7 |
Luster | Vitreous |
Streak | white |
Specific gravity | 2.25–2.28 |
Optical properties | Biaxial (+), 2V = 40–86° |
Refractive index | 'nα=1.468–1.482 nβ=1.470–1.484 nγ=1.474–1.486 |
Birefringence | δ < 0.004 |
Pleochroism | Colorless |
Other characteristics | non-radioactive, non-magnetic; fluorescent, short UV=dark red |
References | [2] [3] |
Tridymite is a high-temperature polymorph of silica and usually occurs as minute tabular white or colorless pseudo-hexagonal crystals, or scales, in cavities in felsic volcanic rocks. Its chemical formula is Si O 2. Tridymite was first described in 1868 and the type location is in Hidalgo, Mexico. The name is from the Greek tridymos for triplet as tridymite commonly occurs as twinned crystal trillings [2] (compound crystals comprising three twinned crystal components).
Tridymite can occur in seven crystalline forms. Two of the most common at standard pressure are known as α and β. The α-tridymite phase is favored at elevated temperatures (above 870 °C) and it converts to β-cristobalite at 1,470 °C. [4] [5] However, tridymite does usually not form from pure β-quartz, one needs to add trace amounts of certain compounds to achieve this. [6] Otherwise the β-quartz-tridymite transition is skipped and β-quartz transitions directly to cristobalite at 1,050 °C without occurrence of the tridymite phase.
Name | Symmetry | Space group | Temp. (°C) |
---|---|---|---|
HP (β) | Hexagonal | P63/mmc | 460 |
LHP | Hexagonal | P6322 | 400 |
OC (α) | Orthorhombic | C2221 | 220 |
OS | Orthorhombic | 100–200 | |
OP | Orthorhombic | P212121 | 155 |
MC | Monoclinic | Cc | 22 |
MX | Monoclinic | C1 | 22 |
In the table, M, O, H, C, P, L and S stand for monoclinic, orthorhombic, hexagonal, centered, primitive, low (temperature) and superlattice. T indicates the temperature, at which the corresponding phase is relatively stable, though the interconversions between phases are complex and sample dependent, and all these forms can coexist at ambient conditions. [5] Mineralogy handbooks often arbitrarily assign tridymite to the triclinic crystal system, yet use hexagonal Miller indices because of the hexagonal crystal shape (see image). [2]
In December 2015, the team behind NASA's Mars Science Laboratory announced the discovery of large amounts of tridymite in Marias Pass on the slope of Aeolis Mons, popularly known as Mount Sharp, on the planet Mars. [7] This discovery was unexpected given the rarity of the mineral on Earth and the apparent lack of volcanic activity where it was discovered, and at the time of discovery no explanation for how it was formed was forthcoming. Its discovery was serendipitous: two teams, responsible for two different instruments on the Curiosity rover, both happened to report what in isolation were relatively uninteresting findings related to their instruments: the ChemCam team reported a region of high silica while the DAN team reported high neutron readings in what turned out to be the same area. Neither team would have been aware of the other's findings had it not been for a fortuitous Mars conjunction in July 2015, during which the various international teams took advantage of the downtime to meet in Paris and discuss their scientific findings.
DAN's high neutron readings would normally have been interpreted as meaning the region was hydrogen-rich, and ChemCam's high-silica readings were not surprising given the ubiquity of silica-rich deposits on Mars, but taken together it was clear that further study of the region was needed. Following conjunction, NASA directed the Curiosity rover back to the area where the readings had been taken and discovered that large amounts of tridymite were present. How they were formed was unknown, as of December 2015 [update] . [8]
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical formula of SiO2. Quartz is, therefore, classified structurally as a framework silicate mineral and compositionally as an oxide mineral. Quartz is the second most abundant mineral in Earth's continental crust, behind feldspar.
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula SiO2, commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant families of materials, existing as a compound of several minerals and as a synthetic product. Examples include fused quartz, fumed silica, opal, and aerogels. It is used in structural materials, microelectronics, and as components in the food and pharmaceutical industries. All forms are white or colorless, although impure samples can be colored.
The mineral olivine is a magnesium iron silicate with the chemical formula (Mg,Fe)2SiO4. It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickly on the surface. Olivine has many uses, such as the gemstone peridot, as well as industrial applications like metalworking processes.
Orthoclase, or orthoclase feldspar (endmember formula KAlSi3O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture", because its two cleavage planes are at right angles to each other. It is a type of potassium feldspar, also known as K-feldspar. The gem known as moonstone (see below) is largely composed of orthoclase.
Opal is a hydrated amorphous form of silica (SiO2·nH2O); its water content may range from 3% to 21% by weight, but is usually between 6% and 10%. Due to its amorphous property, it is classified as a mineraloid, unlike crystalline forms of silica, which are considered minerals. It is deposited at a relatively low temperature and may occur in the fissures of almost any kind of rock, being most commonly found with limonite, sandstone, rhyolite, marl, and basalt.
Goethite is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the α-polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient times for its use as a pigment. Evidence has been found of its use in paint pigment samples taken from the caves of Lascaux in France. It was first described in 1806 based on samples found in the Hollertszug Mine in Herdorf, Germany. The mineral was named after the German polymath and poet Johann Wolfgang von Goethe (1749–1832).
The pyroxenes are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula XY(Si,Al)2O6, where X represents calcium (Ca), sodium (Na), iron or magnesium (Mg) and more rarely zinc, manganese or lithium, and Y represents ions of smaller size, such as chromium (Cr), aluminium (Al), magnesium (Mg), cobalt (Co), manganese (Mn), scandium (Sc), titanium (Ti), vanadium (V) or even iron. Although aluminium substitutes extensively for silicon in silicates such as feldspars and amphiboles, the substitution occurs only to a limited extent in most pyroxenes. They share a common structure consisting of single chains of silica tetrahedra. Pyroxenes that crystallize in the monoclinic system are known as clinopyroxenes and those that crystallize in the orthorhombic system are known as orthopyroxenes.
Sekaninaite ((Fe+2,Mg)2Al4Si5O18) is a silicate mineral, the iron-rich analogue of cordierite.
Nepheline, also called nephelite (from Ancient Greek νεφέλη (nephélē) 'cloud'), is a rock-forming mineral in the feldspathoid group – a silica-undersaturated aluminosilicate, Na3KAl4Si4O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites. It is used in glass and ceramic manufacturing and other industries, and has been investigated as an ore of aluminium.
Cristobalite is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, SiO2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the quartz group, which also include coesite, tridymite and stishovite. It is named after Cerro San Cristóbal in Pachuca Municipality, Hidalgo, Mexico.
Coesite is a form (polymorph) of silicon dioxide (SiO2) that is formed when very high pressure (2–3 gigapascals), and moderately high temperature (700 °C, 1,300 °F), are applied to quartz. Coesite was first synthesized by Loring Coes, Jr., a chemist at the Norton Company, in 1953.
Stishovite is an extremely hard, dense tetragonal form (polymorph) of silicon dioxide. It is very rare on the Earth's surface; however, it may be a predominant form of silicon dioxide in the Earth, especially in the lower mantle.
Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal system. Orthoclase is a monoclinic polymorph stable at lower temperatures. At yet lower temperatures, microcline, a triclinic polymorph of potassium feldspar, is stable.
Pyroxferroite (Fe2+,Ca)SiO3 is a single chain inosilicate. It is mostly composed of iron, silicon and oxygen, with smaller fractions of calcium and several other metals. Together with armalcolite and tranquillityite, it is one of the three minerals which were discovered on the Moon during the 1969 Apollo 11 mission. It was then found in Lunar and Martian meteorites as well as a mineral in the Earth's crust. Pyroxferroite can also be produced by annealing synthetic clinopyroxene at high pressures and temperatures. The mineral is metastable and gradually decomposes at ambient conditions, but this process can take billions of years.
The room-temperature form of quartz, α-quartz, undergoes a reversible change in crystal structure at 573 °C to form β-quartz. This phenomenon is called an inversion, and for the α to β quartz inversion is accompanied by a linear expansion of 0.45%. This inversion can lead to cracking of ceramic ware if cooling occurs too quickly through the inversion temperature. This is called dunting, and the resultant faults are known as dunts. To avoid such thermal shock faults, cooling rates not exceeding 50 °C/hour have been recommended.
The Aeolis quadrangle is one of a series of 30 quadrangle maps of Mars used by the United States Geological Survey (USGS) Astrogeology Research Program. The Aeolis quadrangle is also referred to as MC-23 . The Aeolis quadrangle covers 180° to 225° W and 0° to 30° south on Mars, and contains parts of the regions Elysium Planitia and Terra Cimmeria. A small part of the Medusae Fossae Formation lies in this quadrangle.
Colimaite, the naturally occurring analog of synthetic K3VS4, is a sulfide mineral discovered in southwestern Mexico. The potassium-vanadium sulfide was collected from the crater of the Colima volcano. The mineral colimaite is named after the locality of this volcano and has been approved in 2007, along with its mineral name, by the Commission on New Minerals, Nomenclature and Classification (CNMNC). It has been given the International Mineralogical Association number of IMA 2007–045.
Seifertite is a silicate mineral with the formula SiO2 and is one of the densest polymorphs of silica. It has only been found in Martian and lunar meteorites, where it is presumably formed from either tridymite or cristobalite – other polymorphs of quartz – as a result of heating during the atmospheric re-entry and impact to the Earth, at an estimated minimal pressure of 35 GPa. It can also be produced in the laboratory by compressing cristobalite in a diamond anvil cell to pressures above 40 GPa. The mineral is named after Friedrich Seifert (born 1941), the founder of the Bayerisches Geoinstitut at University of Bayreuth, Germany, and is officially recognized by the International Mineralogical Association.
The composition of Mars covers the branch of the geology of Mars that describes the make-up of the planet Mars.