Ametrine

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Ametrine
Ametrin from Bolivia.jpg
Ametrine containing amethyst and citrine, from Bolivia
General
Category Silicate mineral
Formula
(repeating unit)
Silica (silicon dioxide, Si O 2)
Crystal system Hexagonal
Identification
Formula mass 60.08 g/mol
Color Purple, Yellow
Crystal habit 6-sided prism ending in 6-sided pyramid (typical)
Twinning Dauphine law and Brazil law
Cleavage none
Fracture Conchoidal
Mohs scale hardness7
Lustre Vitreous
Streak white
Diaphaneity Transparent to translucent
Specific gravity 2.65
Optical propertiesUnixal (+)
Refractive index nω = 1.543–1.553
nε = 1.552–1.554
Birefringence +0.009
Pleochroism Amethyst section shows weak to moderate purple/reddish purple
Citrine section shows very weak yellow/orange [1]
Melting point 1650±75 °C
Diagnostic featuresDistinct segments that are purple and yellow
Solubility Insoluble in common solvents
Common impurities Iron

Ametrine, also known as trystine or by its trade name as bolivianite, is a naturally occurring variety of quartz. It is a mixture of amethyst and citrine with zones of purple and yellow or orange. Almost all commercially available ametrine is mined in Bolivia.

Contents

The colour of the zones visible within ametrine are due to differing oxidation states of iron within the crystal. The citrine segments have oxidized iron while the amethyst segments are unoxidized. The different oxidation states occur due to there being a temperature gradient across the crystal during its formation. Artificial ametrine is grown with the hydrothermal method using solutions doped with specific elements, followed by irradiation of the created crystals. [2]

Ametrine in the low price segment may stem from synthetic material. Green-yellow or golden-blue ametrine does not exist naturally.

Structure

Ametrine Emerald Cut Ametrine cut.jpg
Ametrine Emerald Cut

Ametrine is composed of silicon dioxide (SiO2) and it is a tectosilicate, which means it has a silicate framework linked together through shared oxygen atoms.

History

Legend has it that ametrine was first introduced to Europe by a conquistador's gifts to the Spanish Queen in the 1600s, after he received a mine in Bolivia as a dowry when he married a princess from the native Ayoreos tribe. [3]

See also

Related Research Articles

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<span class="mw-page-title-main">Gemstone</span> Piece of mineral crystal used to make jewelry

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Garnets are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.

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<span class="mw-page-title-main">Vivianite</span> Fe(II) phosphate mineral

Vivianite (Fe(II)
3
(PO
4
)
2
·8H
2
O
) is a hydrated iron(II) phosphate mineral found in a number of geological environments. Small amounts of manganese Mn2+, magnesium Mg2+, and calcium Ca2+ may substitute for iron Fe2+ in its structure. Pure vivianite is colorless, but the mineral oxidizes very easily, changing the color, and it is usually found as deep blue to deep bluish green prismatic to flattened crystals. Vivianite crystals are often found inside fossil shells, such as those of bivalves and gastropods, or attached to fossil bone. Vivianite can also appear on the iron coffins or on the corpses of humans as a result of a chemical reaction of the decomposing body with the iron enclosure.

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Benitoite is a rare blue barium titanium cyclosilicate mineral, found in hydrothermally altered serpentinite. It forms in low temperature, high pressure environments typical of subduction zones at convergent plate boundaries. Benitoite fluoresces under short wave ultraviolet light, appearing bright blue to bluish white in color. The more rarely seen clear to white benitoite crystals fluoresce red under long-wave UV light.

<span class="mw-page-title-main">Cordierite</span> Mg, Fe, Al cyclosilicate mineral

Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present, and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: (Mg,Fe)2Al3(Si5AlO18) to (Fe,Mg)2Al3(Si5AlO18). A high-temperature polymorph exists, indialite, which is isostructural with beryl and has a random distribution of Al in the (Si,Al)6O18 rings. Cordierite is also synthesized and used in high temperature applications such as catalytic converters and pizza stones.

<span class="mw-page-title-main">Chrysoprase</span> Gemstone variety of chalcedony

Chrysoprase, chrysophrase or chrysoprasus is a gemstone variety of chalcedony that contains small quantities of nickel. Its color is normally apple-green, but varies from turquoise-like cyan to deep green. The darker varieties of chrysoprase are also referred to as prase.

<span class="mw-page-title-main">Spessartine</span> Nesosilicate, manganese aluminium garnet species

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<span class="mw-page-title-main">Prasiolite</span> Mineral, quartz variety

Prasiolite is a green variety of quartz.

<span class="mw-page-title-main">Red beryl</span> Rare variety of beryl

Red beryl, formerly known as bixbite and marketed as red emerald or scarlet emerald, is an extremely rare variety of beryl as well as one of the rarest minerals on Earth. The gem gets its red color from manganese ions embedded inside of beryllium aluminium cyclosilicate crystals. The color of red beryl is stable up to 1,000 °C (1,830 °F). Red beryl can come in various tints like strawberry, bright ruby, cherry, and orange.

References

  1. "Ametrine Value, Price, and Jewelry Information". International Gem Society. Retrieved 2019-09-14.
  2. Vladimir S. Balitsky; Taijin Lu; George R. Rossman; Irina B. Makhina; Anatolii A. Mar’in; James E. Shigley; Shane Elen; Boris A. Dorogovin. "Russian Synthetic Ametrine," Gems and Gemology, Summer 1999, p. 122-134
  3. Vasconcelos, Paolo; Wenk, Hanz-Rudolf; Rossman, George. "The Anahí Ametrine Mine, Bolivia," Gems and Gemology, Spring 1994, p. 4-23