Larimar (Blue Pectolite) | |
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General | |
Category | Inosilicate mineral |
Formula (repeating unit) | NaCa2Si3O8(OH) |
Crystal system | Triclinic |
Crystal class | Pinacoidal (1) (same H-M symbol) |
Space group | P1 |
Unit cell | a = 7.99 Å, b = 7.03 Å, c = 7.03 Å; α = 90.51°, β = 95.21°, γ = 102.53°; Z = 2 |
Identification | |
Color | Shades of blue, blue-green |
Crystal habit | Tabular to acicular, radiating fibrous, spheroidal, or columnar; massive |
Twinning | Twin axis [010] with composition plane [100], common |
Cleavage | Perfect on {100} and {001} |
Fracture | Uneven |
Tenacity | Brittle; tough when compact |
Mohs scale hardness | 4.5 - 5 |
Luster | Silky, subvitreous |
Diaphaneity | Translucent to opaque |
Specific gravity | 2.84 - 2.90 |
Optical properties | Biaxial (+) |
Refractive index | nα = 1.594 - 1.610 nβ = 1.603 - 1.614 nγ = 1.631 - 1.642 |
Birefringence | δ = 0.037 |
2V angle | Measured: 50° to 63°, Calculated: 42° to 60° |
Dispersion | r > v weak to very strong |
References | [1] [2] [3] |
Larimar is the tradename for a rare blue variety of the silicate mineral pectolite found only in Dominican Republic, around the city of Barahona. [4] Its coloration varies from bluish white, light-blue, light-green, green-blue, turquoise blue, turquoise green, turquoise blue-green, deep green, dark green, to deep blue, dark blue and purple, violet and indigo and the larimar can come in many varieties and color mixes. [5] [6]
Dominican Republic's Ministry of Mining records show that Father Miguel Domingo Fuertes Loren of the Barahona Parish requested permission on 22 November 1916 to explore and exploit the mine of a certain blue rock that he had discovered. Pectolites were not yet known in Dominican Republic, and the request was rejected. [6] [7]
Miguel Méndez and Peace Corps volunteer Norman Rilling rediscovered Larimar in 1974 on a beach at the foot of the Bahoruco Mountain Range, the coastal province of Barahona. Natives believed that the stone came from the sea, and they called the gem Blue Stone. Méndez took his young daughter's name Larissa and the Spanish word for sea (mar) and formed Larimar, to suggest the colors of the Caribbean Sea where it was found. The few stones that they found were alluvial sediment, washed into the sea by the Bahoruco River. An upstream search revealed the in situ outcrops in the range and soon the Los Chupaderos mine was formed. [6] [7]
Larimar is a type of pectolite or a rock composed largely of pectolite, an acid silicate hydrate of calcium and sodium. Pectolite is found in many locations, but larimar has a unique volcanic blue coloration, which is the result of copper substitution for calcium. [8]
Miocene volcanic rocks, andesites and basalts, erupted within the limestones of the south coast of the island. These rocks contained cavities or vugs which were later filled with a variety of minerals, including the blue pectolite. These pectolite cavity fillings are a secondary occurrence within the volcanic flows, dikes, and plugs. When these rocks erode, the pectolite fillings are carried down the slope to end up in the alluvium and the beach gravels. The Bahoruco River carried the pectolite-bearing sediments to the sea. [6] The tumbling action along the streambed provided the natural polishing to the blue larimar, which makes them stand out in contrast to the dark gravels of the streambed. [7]
The most important outcrop of blue pectolite is located at Los Chupaderos in the section of Los Checheses, about 10 km (6.2 mi) southwest of the city of Barahona in the southwestern region of Dominican Republic. It is a single mountainside now perforated with approximately 2,000 vertical shafts, surrounded by rainforest vegetation and deposits of blue-colored mine tailings. [6] [7]
Larimar jewelry is offered to the public in Dominican Republic, and elsewhere in the Caribbean as a local specialty. Most jewelry produced is set in silver, but sometimes high-grade larimar is also set in gold.
Quality grading is according to coloration and the typical mineral crystal configuration in the stone. Larimar also comes in green and can have red spots, brown strikes, etc., due to the presence of other minerals or oxidation. The more intense the blue color and the contrast in the stone, the higher and rarer is the quality. The blue color is photosensitive and fades with time if exposed to too much light and heat. [7]
Dominican jewelry designers such as Mónica Varela [9] and Joarla Caridad [10] have contributed to the popularization of larimar internationally.
Agate is a variety of chalcedony, which comes in a wide variety of colors. Agates are primarily formed within volcanic and metamorphic rocks. The ornamental use of agate was common in ancient Greece, in assorted jewelry and in the seal stones of Greek warriors, while bead necklaces with pierced and polished agate date back to the 3rd millennium BCE in the Indus Valley civilisation.
Amazonite, also known as amazonstone, is a green tectosilicate mineral, a variety of the potassium feldspar called microcline. Its chemical formula is KAlSi3O8, which is polymorphic to orthoclase.
Topaz is a silicate mineral made of aluminum and fluorine with the chemical formula Al2SiO4(F, OH)2. It is used as a gemstone in jewelry and other adornments. Common topaz in its natural state is colorless, though trace element impurities can make it pale blue or golden brown to yellow-orange. Topaz is often treated with heat or radiation to make it a deep blue, reddish-orange, pale green, pink, or purple.
Tourmaline is a crystalline silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. This gemstone comes in a wide variety of colors.
Turquoise is an opaque, blue-to-green mineral that is a hydrous phosphate of copper and aluminium, with the chemical formula CuAl6(PO4)4(OH)8·4H2O. It is rare and valuable in finer grades and has been prized as a gemstone for millennia due to its hue.
Serpentine subgroup are greenish, brownish, or spotted minerals commonly found in serpentinite. They are used as a source of magnesium and asbestos, and as decorative stone. The name comes from the greenish color and smooth or scaly appearance from the Latin serpentinus, meaning "snake-like".
Variscite is a hydrated aluminium phosphate mineral (AlPO4·2H2O). It is a relatively rare phosphate mineral. It is sometimes confused with turquoise; however, variscite is usually greener in color. The green color results from the presence of small amounts of trivalent chromium (Cr3+
).
Chrysocolla ( KRIS-ə-KOL-ə) is a hydrous copper phyllosilicate mineral and mineraloid with the formula Cu
2 – xAl
x(H
2Si
2O
5)(OH)
4⋅nH
2O (x < 1) or (Cu, Al)
2H
2Si
2O
5(OH)
4⋅nH
2O).
Diopside is a monoclinic pyroxene mineral with composition MgCaSi
2O
6. It forms complete solid solution series with hedenbergite and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull green crystals in the monoclinic prismatic class. It has two distinct prismatic cleavages at 87 and 93° typical of the pyroxene series. It has a Mohs hardness of six, a Vickers hardness of 7.7 GPa at a load of 0.98 N, and a specific gravity of 3.25 to 3.55. It is transparent to translucent with indices of refraction of nα=1.663–1.699, nβ=1.671–1.705, and nγ=1.693–1.728. The optic angle is 58° to 63°.
Turquoise is a cyan color, based on the mineral of the same name. The word turquoise dates to the 17th century and is derived from the French turquois, meaning 'Turkish', because the mineral was first brought to Europe through Turkey from mines in the historical Khorasan province of Iran (Persia) and Afghanistan today. The first recorded use of turquoise as a color name in English was in 1573.
Chrysoprase, chrysophrase or chrysoprasus is a gemstone variety of chalcedony that contains small quantities of nickel. Its color is normally apple-green, but varies from turquoise-like cyan to deep green. The darker varieties of chrysoprase are also referred to as prase.
Barahona, also known as Santa Cruz de Barahona, is the main city of the Barahona Province, in the southwest of the Dominican Republic. It has one of the most active ports in the region, as well as many ecotourism attractions. The city is a centre of sugar production and industry. Barahona is also known for being the only place where the rare Larimar stone can be found.
The Bahoruco Mountain Range—Sierra de Bahoruco is a mountain range located in the far southwestern region of the Dominican Republic. It is within Pedernales, Independencia, Barahona, and Bahoruco Provinces. A large part of the area is protected within the Sierra de Bahoruco National Park, also a Biosphere reserve.
Howlite, a calcium borosilicate hydroxide (Ca2B5SiO9(OH)5), is a borate mineral found in evaporite deposits.
Népouite is a rare nickel silicate mineral which has the apple green color typical of such compounds. It was named by the French mining engineer Edouard Glasser in 1907 after the place where it was first described, the Népoui Mine, Népoui, Poya Commune, North Province, New Caledonia. The ideal formula is Ni3(Si2O5)(OH)4, but most specimens contain some magnesium, and (Ni,Mg)3(Si2O5)(OH)4 is more realistic. There is a similar mineral called lizardite in which all of the nickel is replaced by magnesium, formula Mg3(Si2O5)(OH)4. These two minerals form a series; intermediate compositions are possible, with varying proportions of nickel to magnesium.
Plancheite is a hydrated copper silicate mineral with the formula Cu8Si8O22(OH)4•(H2O). It is closely related to shattuckite in structure and appearance, and the two minerals are often confused.
Serandite is a mineral with formula Na(Mn2+,Ca)2Si3O8(OH). The mineral was discovered in Guinea in 1931 and named for J. M. Sérand. Serandite is generally red, brown, black or colorless. The correct name lacks an accent.
Pyrometamorphism is a type of metamorphism in which rocks are rapidly changed by heat, e.g. coming from a rapidly emplaced extrusive or intrusive igneous rock or from a fossil fuel fire. The rocks produced by pyrometamorphism include buchite, clinker and paralava, formed due to melting and/or recrystallisation of sedimentary rocks. Both natural and anthropogenic examples of sites with active pyrometamorphism are known. One well-known area of natural pyrometamorphic rocks is the Hatrurim Formation with outcrops all around the Dead Sea Basin: in the Negev Desert in Israel, in the Judaean Desert on the West Bank, and in western Jordan. Xenoliths of sedimentary rocks trapped in volcanic lava may undergo pyrometamorphic transformation, as can some contact wallrocks. Anthropogenic pyrometamorphic rocks are found in burning coal-mining dumps. A great number of minerals, sometimes very rare, are found within these rocks. Of the silicate minerals, the typical ones are especially cordierite, indialite, fayalite, mullite, tridymite and cristobalite, and sekaninaite. Oxide minerals include corundum, hematite, hercynite, magnesioferrite, and magnetite. Some rare minerals typical of meteorites, like oldhamite, are also found in pyrometamorphic rocks.
The Sierra de Bahoruco National Park is an environmentally protected national park located in the South-western region of Dominican Republic. It was created in 1983 by Presidential Decree during the presidency of Salvador Jorge Blanco.