Elbaite | |
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General | |
Category | Cyclosilicate |
Formula (repeating unit) | Na(Li1.5Al1.5)Al6Si6O18(BO3)3(OH)4 |
IMA symbol | Elb [1] |
Strunz classification | 9.CK.05 |
Crystal system | Trigonal |
Crystal class | Ditrigonal pyramidal (3m) H–M symbol: (3m) |
Space group | R3m |
Identification | |
Color | Green, red to pink, blue, orange, yellow, colorless, multicolored |
Crystal habit | Prismatic; striated |
Cleavage | Poor/indistinct on {1120} and {1011} |
Fracture | Sub-conchoidal |
Mohs scale hardness | 7+1⁄2 |
Luster | Vitreous |
Streak | White |
Diaphaneity | Transparent to opaque |
Density | 2.9–3.2 |
Optical properties | Uniaxial (−); moderate relief |
Refractive index | nω = 1.635–1.650, nε = 1.615–1.632 |
Birefringence | δ = 0.020 |
Other characteristics | piezoelectric and pyroelectric |
References | [2] [3] |
Major varieties | |
Achroite | colorless |
Indicolite | blue |
Rubellite | red to pink |
Verdelite | green |
Elbaite, a sodium, lithium, aluminium boro-silicate, with the chemical composition Na(Li1.5Al1.5)Al6Si6O18(BO3)3(OH)4, [4] is a mineral species belonging to the six-member ring cyclosilicate tourmaline group.
Elbaite forms three series, with dravite, with fluor-liddicoatite, and with schorl. Due to these series, specimens with the ideal endmember formula are not found occurring naturally.
As a gemstone, elbaite is a desirable member of the tourmaline group because of the variety and depth of its colours and quality of the crystals. Originally discovered on the island of Elba, Italy in 1913, it has since been found in many parts of the world. In 1994, a major locality was discovered in Canada, at O'Grady Lakes in the Yukon.
Elbaite forms in igneous and metamorphic rocks and veins in association with lepidolite, microcline, and spodumene in granite pegmatites; with andalusite and biotite in schist; and with molybdenite and cassiterite in massive hydrothermal replacement deposits.
Elbaite is allochromatic, meaning trace amounts of impurities can tint crystals, and it can be strongly pleochroic. Every color of the rainbow may be represented by elbaite, some exhibiting multicolor zonation. Microscopic acicular inclusions in some elbaite crystals show the cat's eye effect in polished cabochons.
Beryl ( BERR-əl) is a mineral composed of beryllium aluminium silicate with the chemical formula Be3Al2Si6O18. Well-known varieties of beryl include emerald and aquamarine. Naturally occurring hexagonal crystals of beryl can be up to several meters in size, but terminated crystals are relatively rare. Pure beryl is colorless, but it is frequently tinted by impurities; possible colors are green, blue, yellow, pink, and red (the rarest). It is an ore source of beryllium.
Spinel is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl
2O
4 in the cubic crystal system. Its name comes from the Latin word spinella, a diminutive form of spine, in reference to its pointed crystals.
Tourmaline is a crystalline silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. This gemstone comes in a wide variety of colors.
Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4 tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.
Pleochroism is an optical phenomenon in which a substance has different colors when observed at different angles, especially with polarized light.
Lepidolite is a lilac-gray or rose-colored member of the mica group of minerals with chemical formula K(Li,Al)3(Al,Si,Rb)4O10(F,OH)2. It is the most abundant lithium-bearing mineral and is a secondary source of this metal. It is the major source of the alkali metal rubidium.
Petalite, also known as castorite, is a lithium aluminum tektosilicate mineral LiAlSi4O10, crystallizing in the monoclinic system. Petalite occurs as colorless, pink, grey, yellow, yellow grey, to white tabular crystals and columnar masses. It occurs in lithium-bearing pegmatites with spodumene, lepidolite, and tourmaline. Petalite is an important ore of lithium, and is converted to spodumene and quartz by heating to ~500 °C and under 3 kbar of pressure in the presence of a dense hydrous alkali borosilicate fluid with a minor carbonate component. Petalite (and secondary spodumene formed from it) is lower in iron than primary spodumene, making it a more useful source of lithium in, e.g., the production of glass. The colorless varieties are often used as gemstones.
Zincite is the mineral form of zinc oxide (ZnO). Its crystal form is rare in nature; a notable exception to this is at the Franklin and Sterling Hill Mines in New Jersey, an area also famed for its many fluorescent minerals. It has a hexagonal crystal structure and a color that depends on the presence of impurities. The zincite found at the Franklin Furnace is red-colored, mostly due to iron and manganese dopants, and associated with willemite and franklinite.
Brazilianite, whose name derives from its country of origin, Brazil, is a typically yellow-green phosphate mineral, most commonly found in phosphate-rich pegmatites.
The scapolites are a group of rock-forming silicate minerals composed of aluminium, calcium, and sodium silicate with chlorine, carbonate and sulfate. The two endmembers are meionite and marialite. Silvialite (Ca,Na)4Al6Si6O24(SO4,CO3) is also a recognized member of the group.
Scolecite is a tectosilicate mineral belonging to the zeolite group; it is a hydrated calcium silicate, CaAl2Si3O10·3H2O. Only minor amounts of sodium and traces of potassium substitute for calcium. There is an absence of barium, strontium, iron and magnesium. Scolecite is isostructural (having the same structure) with the sodium-calcium zeolite mesolite and the sodium zeolite natrolite, but it does not form a continuous chemical series with either of them. It was described in 1813, and named from the Greek word, σκώληξ (sko-lecks) = "worm" because of its reaction to the blowpipe flame.
Kornerupine (also called Prismatine) is a rare boro-silicate mineral with the chemical formula (Mg,Fe2+)4(Al,Fe3+)6(SiO4,BO4)5(O,OH)2. It crystallizes in the orthorhombic – dipyramidal crystal system as brown, green, yellow to colorless slender tourmaline like prisms or in massive fibrous forms. It has a Mohs hardness of 7 and a specific gravity of 3.3 to 3.34. Its indices of refraction are nα=1.660 – 1.671, nβ=1.673 – 1.683 and nγ=1.674 – 1.684.
Fluor-liddicoatite is a rare member of the tourmaline group of minerals, elbaite subgroup, and the theoretical calcium endmember of the elbaite-fluor-liddicoatite series; the pure end-member has not yet been found in nature. Fluor-liddicoatite is indistinguishable from elbaite by X-ray diffraction techniques. It forms a series with elbaite and probably also with olenite. Liddiocoatite is currently a non-approved mineral name, but Aurisicchio et al. (1999) and Breaks et al. (2008) found OH-dominant species. Formulae are
Fluorellestadite is a rare nesosilicate of calcium, with sulfate and fluorine, with the chemical formula Ca10(SiO4)3(SO4)3F2. It is a member of the apatite group, and forms a series with hydroxylellestadite.
Serandite is a mineral with formula Na(Mn2+,Ca)2Si3O8(OH). The mineral was discovered in Guinea in 1931 and named for J. M. Sérand. Serandite is generally red, brown, black or colorless. The correct name lacks an accent.
Tarbuttite is a rare phosphate mineral with formula Zn2(PO4)(OH). It was discovered in 1907 in what is now Zambia and named for Percy Coventry Tarbutt.
Zigrasite is a phosphate mineral with the chemical formula of MgZr(PO4)2(H2O)4. Zigrasite was discovered and is only known to occur in the Dunton Quarry at Oxford County, Maine. Zigrasite was specifically found in the giant 1972 gem tourmaline-bearing pocket at the Dunton Quarry. Zigrasite is named after James Zigras who originally discovered and brought the mineral to attention.
Phosphosiderite is a rare mineral named for its main components, phosphate and iron. The siderite at the end of phosphosiderite comes from the word "sideros", the Greek word for iron. It was published in 1890, and has been a valid species since pre-IMA. It is an IMA approved mineral which got grandfathered, meaning its name is still believed to refer to an existing species.
Rubellite is the red or pink variety of tourmaline and is a member of elbaite. Rubellite is also the rarest gem in its family. It is occasionally mistaken for ruby. These gems typically contain inclusions.
Tsilaisite is a manganese rich variety of elbaite tourmaline. It is also known as Tsilaizite. Tsilaisite is related Fluor-tsilaisite. The gem is named after the location it was first found.