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Manganosite | |
---|---|
General | |
Category | Oxide mineral |
Formula (repeating unit) | Manganese oxide, MnO |
IMA symbol | Mng [1] |
Strunz classification | 4.AB.25 |
Crystal system | Cubic |
Crystal class | Hexoctahedral (m3m) H-M symbol: (4/m 3 2/m) |
Space group | Fm3m |
Unit cell | a = 4.44 Å; Z = 4 |
Identification | |
Color | Emerald-green, becoming black on exposure to air |
Crystal habit | Granular to massive; Octahedral crystals uncommon |
Cleavage | Perfect on [100], [010] and [001] |
Fracture | Fibrous |
Mohs scale hardness | 5 - 6 |
Luster | Vitreous, adamantine to dull |
Streak | Brown |
Diaphaneity | Transparent to translucent |
Specific gravity | 5.364 |
Optical properties | Isotropic |
Refractive index | n = 2.16–2.17 |
References | [2] [3] [4] [5] |
Manganosite is a rare mineral composed of manganese(II) oxide MnO. It was first described in 1817 for an occurrence in the Harz Mountains, Saxony-Anhalt, Germany. [4] It has also been reported from Langban and Nordmark, Sweden and at Franklin Furnace, New Jersey. It also occurs in Japan, Kyrgyzstan and Burkina Faso. [5]
It occurs in manganese nodules. It also occurs as alteration of manganese minerals such as rhodocrosite during low oxygen metamorphism and metasomatism. [5]
Pyrolusite is a mineral consisting essentially of manganese dioxide (MnO2) and is important as an ore of manganese. It is a black, amorphous appearing mineral, often with a granular, fibrous, or columnar structure, sometimes forming reniform crusts. It has a metallic luster, a black or bluish-black streak, and readily soils the fingers. The specific gravity is about 4.8. Its name is from the Greek for fire and to wash, in reference to its use as a way to remove tints from glass.
Manganite is a mineral composed of manganese oxide-hydroxide, MnO(OH), crystallizing in the monoclinic system (pseudo-orthorhombic). Crystals of manganite are prismatic and deeply striated parallel to their length; they are often grouped together in bundles. The color is dark steel-grey to iron-black, and the luster brilliant and submetallic. The streak is dark reddish brown. The hardness is 4, and the specific gravity is 4.3. There is a perfect cleavage parallel to the brachypinacoid, and less-perfect cleavage parallel to the prism faces. Twinned crystals are not infrequent.
Rhodonite is a manganese inosilicate, (Mn, Fe, Mg, Ca)SiO3 and member of the pyroxenoid group of minerals, crystallizing in the triclinic system. It commonly occurs as cleavable to compact masses with a rose-red color (the name comes from the Greek ῥόδος rhodos, rosy), often tending to brown because of surface oxidation. The rose-red coloring is caused by manganese(2+).
Tephroite is the manganese endmember of the olivine group of nesosilicate minerals with the formula Mn2SiO4. A solid solution series exists between tephroite and its analogues, the group endmembers fayalite and forsterite. Divalent iron or magnesium may readily replace manganese in the olivine crystal structure.
Adamite is a zinc arsenate hydroxide mineral, Zn2AsO4OH. It is a mineral that typically occurs in the oxidized or weathered zone above zinc ore occurrences. Pure adamite is colorless, but usually it possess yellow color due to Fe compounds admixture. Tints of green also occur and are connected with copper substitutions in the mineral structure. Olivenite is a copper arsenate that is isostructural with adamite and there is considerable substitution between zinc and copper resulting in an intermediate called cuproadamite. Zincolivenite is a recently discovered mineral being an intermediate mineral with formula CuZn(AsO4)(OH). Manganese, cobalt, and nickel also substitute in the structure. An analogous zinc phosphate, tarbuttite, is known.
Ferberite is the iron endmember of the manganese - iron wolframite solid solution series. The manganese endmember is hübnerite. Ferberite is a black monoclinic mineral composed of iron(II) tungstate, FeWO4.
Vesuvianite, also known as idocrase, is a green, brown, yellow, or blue silicate mineral. Vesuvianite occurs as tetragonal crystals in skarn deposits and limestones that have been subjected to contact metamorphism. It was first discovered within included blocks or adjacent to lavas on Mount Vesuvius, hence its name. Attractive-looking crystals are sometimes cut as gemstones. Localities which have yielded fine crystallized specimens include Mount Vesuvius and the Ala Valley near Turin, Piedmont.
Tusionite is a rare colorless to transparent to translucent yellow brown trigonal borate mineral with chemical formula: MnSn(BO3)2. The mineral is composed of 18.86% manganese, 40.76% tin, 7.42% boron, and 32.96% oxygen. It is a late stage hydrothermal mineral and occurs rarely in granite pegmatites in miarolitic cavities.
Triploidite is an uncommon manganese iron phosphate mineral with formula: (Mn, Fe)2PO4OH. It crystallizes in the monoclinic crystal system and typically occurs as elongated and striated slender prisms which may be columnar to fibrous. Its crystals may be pinkish to yellowish brown or red-orange.
Galaxite, also known as 'mangan-spinel' is an isometric mineral belonging to the spinel group of oxides with the ideal chemical formula Mn2+Al2O4.
Chloritoid is a silicate mineral of metamorphic origin. It is an iron magnesium manganese alumino-silicate hydroxide with formula (Fe, Mg, Mn)
2Al
4Si
2O
10(OH)
4. It occurs as greenish grey to black platy micaceous crystals and foliated masses. Its Mohs hardness is 6.5, unusually high for a platy mineral, and it has a specific gravity of 3.52 to 3.57. It typically occurs in phyllites, schists and marbles.
Jacobsite is a manganese iron oxide mineral. It is in the spinel group and forms a solid solution series with magnetite. The chemical formula is (Mn,Mg)Fe2O4 or with oxidation states and substitutions: (Mn2+,Fe2+,Mg)(Fe3+,Mn3+)2O4.
Chlorargyrite is the mineral form of silver chloride (AgCl). Chlorargyrite occurs as a secondary mineral phase in the oxidation of silver mineral deposits. It crystallizes in the isometric - hexoctahedral crystal class. Typically massive to columnar in occurrence it also has been found as colorless to variably yellow cubic crystals. The color changes to brown or purple on exposure to light. It is quite soft with a Mohs hardness of 1 to 2 and dense with a specific gravity of 5.55. It is also known as cerargyrite and, when weathered by desert air, as horn silver. Bromian chlorargyrite is also common. Chlorargyrite is water-insoluble.
Portlandite is a hydroxide-bearing mineral typically included in the oxide mineral class. It is the naturally occurring form of calcium hydroxide (Ca(OH)2) and the calcium analogue of brucite (Mg(OH)2).
Neptunite is a silicate mineral with the formula KNa2Li(Fe2+, Mn2+)2Ti2Si8O24. With increasing manganese it forms a series with mangan-neptunite. Watatsumiite is the variety with vanadium replacing the titanium in the formula.
Akhtenskite is a manganese oxide mineral with the chemical formula of MnO2 (or: ε-Mn4+O2) that was named after the Akhtensk deposit in Russia, where it was first discovered and noted in 1979. It can be found in the Akhtensk brown ironstone deposit, in the southern Ural Mountains, on Mt. Zarod, on the Sikhote-Alin Mountains, and in the Primorskiy Krai, all in Russia.
Cryptomelane is a potassium manganese oxide mineral with formula K(Mn4+,Mn2+)8O16.
Sonolite is a mineral with formula Mn9(SiO4)4(OH,F)2. The mineral was discovered in 1960 in the Sono mine in Kyoto Prefecture, Japan. In 1963, it was identified as a new mineral and named after the Sono mine.
Leucophoenicite is a mineral with formula Mn7(SiO4)3(OH)2. Generally brown to red or pink in color, the mineral gets its name from the Greek words meaning "pale purple-red". Leucophoenicite was discovered in New Jersey, US and identified as a new mineral in 1899.
Pyrophanite is a manganese titanium oxide mineral with formula: MnTiO3. It is a member of the ilmenite group. It is a deep red to greenish black mineral which crystallizes in the trigonal system.