Zincite

Last updated
Zincite
Zincite from Arizona.jpg
Crystal blades of zincite
General
CategoryOxide mineral
Formula
(repeating unit)
(Zn,Mn)O
IMA symbol Znc [1]
Strunz classification 4.AB.20
Dana classification04.02.02.01
Crystal system Hexagonal
Crystal class Dihexagonal pyramidal (6mm)
H-M symbol: (6mm)
Space group P63mc
Identification
ColorOrange, yellow-orange to deep red, red, rarely yellow, rarely green and colorless to white
Crystal habit Disseminated – occurs in small, distinct particles dispersed in matrix.
Twinning On {0001}
Cleavage On {1010}, perfect; parting on {0001}
Fracture Conchoidal
Tenacity Brittle
Mohs scale hardness4
Luster Subadamantine to resinous
Streak Yellowish orange
Diaphaneity Translucent, transparent in thin fragments
Specific gravity 5.64–5.68
Optical propertiesUniaxial (+)
Refractive index nω = 2.013, nε = 2.029
Birefringence δ = 0.016
References [2] [3]

Zincite is the mineral form of zinc oxide (Zn O). Its crystal form is rare in nature; a notable exception to this is at the Franklin and Sterling Hill Mines in New Jersey, an area also famed for its many fluorescent minerals. It has a hexagonal crystal structure and a color that depends on the presence of impurities. The zincite found at the Franklin Furnace is red-colored, mostly due to iron and manganese dopants, and associated with willemite and franklinite.

Contents

Microscopic image of Zincite and Franklinite under normal light Zincite and Franklinite under NL.jpg
Microscopic image of Zincite and Franklinite under normal light

Zincite crystals can be grown artificially, and synthetic zincite crystals are available as a by-product of zinc smelting. Synthetic crystals can be colorless or can range in color from dark red, orange, or yellow to light green.

Synthetic zincite crystals Zincite.JPG
Synthetic zincite crystals

Both natural and synthetic zincite crystals are significant for their early use as semiconductor crystal detectors in the early development of crystal radios before the advent of vacuum tubes. As an early radio detector it was used in conjunction with another mineral, galena, and this device was known as the cat's-whisker detector.

See also

Related Research Articles

<span class="mw-page-title-main">Corundum</span> Oxide mineral

Corundum is a crystalline form of aluminium oxide typically containing traces of iron, titanium, vanadium, and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the presence of transition metal impurities in its crystalline structure. Corundum has two primary gem varieties: ruby and sapphire. Rubies are red due to the presence of chromium, and sapphires exhibit a range of colors depending on what transition metal is present. A rare type of sapphire, padparadscha sapphire, is pink-orange.

<span class="mw-page-title-main">Chrysoberyl</span> Mineral or gemstone of beryllium aluminate

The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula BeAl2O4. The name chrysoberyl is derived from the Greek words χρυσός chrysos and βήρυλλος beryllos, meaning "a gold-white spar". Despite the similarity of their names, chrysoberyl and beryl are two completely different gemstones, although they both contain beryllium. Chrysoberyl is the third-hardest frequently encountered natural gemstone and lies at 8.5 on the Mohs scale of mineral hardness, between corundum (9) and topaz (8).

<span class="mw-page-title-main">Dolomite (mineral)</span> Carbonate mineral - CaMg(CO₃)₂

Dolomite is an anhydrous carbonate mineral composed of calcium magnesium carbonate, ideally CaMg(CO3)2. The term is also used for a sedimentary carbonate rock composed mostly of the mineral dolomite (see Dolomite (rock)). An alternative name sometimes used for the dolomitic rock type is dolostone.

<span class="mw-page-title-main">Sphalerite</span> Zinc-iron sulfide mineral

Sphalerite is a sulfide mineral with the chemical formula (Zn,Fe)S. It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in sedimentary exhalative, Mississippi-Valley type, and volcanogenic massive sulfide deposits. It is found in association with galena, chalcopyrite, pyrite, calcite, dolomite, quartz, rhodochrosite, and fluorite.

<span class="mw-page-title-main">Rhodochrosite</span> Mineral of manganese carbonate

Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its pure form (rare), it is typically a rose-red colour, but it can also be shades of pink to pale brown. It streaks white, and its Mohs hardness varies between 3.5 and 4.5. Its specific gravity is between 3.45 and 3.6. The crystal system of rhodochrosite is trigonal, with a lattice structure and cleavage in the carbonate rhombohedral system. The carbonate ions (CO2−
3
) are arranged in a triangular planar configuration, and the manganese ions (Mn2–) are surrounded by six oxygen ions in an octahedral arrangement. The MnO6 octahedra and CO3 triangles are linked together to form a three-dimensional structure. Crystal twinning is often present. It can be confused with the manganese silicate rhodonite, but is distinctly softer. Rhodochrosite is formed by the oxidation of manganese ore, and is found in South Africa, China, and the Americas. It is one of the national symbols of Argentina.

<span class="mw-page-title-main">Greenleaf Whittier Pickard</span>

Greenleaf Whittier Pickard was a United States radio pioneer. Pickard was a researcher in the early days of wireless. While not the earliest discoverer of the rectifying properties of contact between certain solid materials, he was largely responsible and most famous for the development of the crystal detector, the earliest type of diode detector. The crystal detector was the central component in many early radio receivers from around 1906 until about 1920. Pickard also experimented with antennas, radio wave propagation and noise suppression. On August 30, 1906 he filed a patent for a silicon crystal detector, which was granted on November 20, 1906. On June 10, 1907 he filed a patent for a Magnetic Aerial which was granted on January 21, 1908. Pickard's loop antenna had directional properties that could be used to reduce interference to the intended wireless communications. On June 21, 1911 he filed a patent on a crystal detector incorporating a springy low inertia wire of about 24 gauge formed with a loop or helix and pointed to make contact with the crystal. Crystal detectors incorporating this construction would become the most widely used and popularly known by the term cat whisker detector. This patent was granted on July 21, 1914. Greenleaf Whittier Pickard was named after his great-uncle, the American Quaker John Greenleaf Whittier (1807-1892). Pickard was president of the Institute of Radio Engineers in 1913.

<span class="mw-page-title-main">Erythrite</span> Hydrated cobalt arsenate mineral

Erythrite or red cobalt is a secondary hydrated cobalt arsenate mineral with the formula Co
3
(AsO
4
)
2
•8H
2
O
. Erythrite and annabergite, chemical formula Ni
3
(AsO
4
)
2
•8H
2
O
, or nickel arsenate form a complete series with the general formula (Co,Ni)
3
(AsO
4
)
2
•8H
2
O
.

<span class="mw-page-title-main">Franklinite</span>

Franklinite is an oxide mineral belonging to the normal spinel subgroup's iron (Fe) series, with the formula Zn2+Fe23+O4.

<span class="mw-page-title-main">Rhodonite</span> Single chain manganese inosilicate (MnSiO3)

Rhodonite is a manganese inosilicate, with the formula (Mn, Fe, Mg, Ca)SiO3, and member of the pyroxenoid group of minerals, crystallizing in the triclinic system. It commonly occurs as cleavable to compact masses with a rose-red color (its name comes from Ancient Greek ῥόδον (rhódon) 'rose'), often tending to brown due to surface oxidation. The rose-red hue is caused by the manganese cation (Mn2+).

<span class="mw-page-title-main">Tephroite</span>

Tephroite is the manganese endmember of the olivine group of nesosilicate minerals with the formula Mn2SiO4. A solid solution series exists between tephroite and its analogues, the group endmembers fayalite and forsterite. Divalent iron or magnesium may readily replace manganese in the olivine crystal structure.

<span class="mw-page-title-main">Willemite</span> Nesosilicate mineral

Willemite is a zinc silicate mineral and a minor ore of zinc. It is highly fluorescent (green) under shortwave ultraviolet light. It occurs in a variety of colors in daylight, in fibrous masses and apple-green gemmy masses. Troostite is a variant in which part of the zinc is partly replaced by manganese, it occurs in solid brown masses.

<span class="mw-page-title-main">Hardystonite</span>

Hardystonite is a rare calcium zinc silicate mineral first described from the Franklin, New Jersey, U.S. zinc deposits. It often contains lead, which was detrimental to the zinc smelting process, so it was not a useful ore mineral. Like many of the famous Franklin minerals, hardystonite responds to short wave ultraviolet light, emitting a fluorescence from dark purple to bright violet blue. In daylight, it is white to gray to light pink in color, sometimes with a vitreous or greasy luster. It is very rarely found as well formed crystals, and these are usually rectangular in appearance and rock-locked.

<span class="mw-page-title-main">Crystal detector</span> Early radio receiver component

A crystal detector is an obsolete electronic component used in some early 20th century radio receivers that consists of a piece of crystalline mineral which rectifies the alternating current radio signal. It was employed as a detector (demodulator) to extract the audio modulation signal from the modulated carrier, to produce the sound in the earphones. It was the first type of semiconductor diode, and one of the first semiconductor electronic devices. The most common type was the so-called cat's whisker detector, which consisted of a piece of crystalline mineral, usually galena, with a fine wire touching its surface.

<span class="mw-page-title-main">Clinohedrite</span>

Clinohedrite is a rare silicate mineral. Its chemical composition is a hydrous calcium-zinc silicate; CaZn(SiO4)·H2O. It crystallizes in the monoclinic system and typically occurs as veinlets and fracture coatings. It is commonly colorless, white to pale amethyst in color. It has perfect cleavage and the crystalline habit has a brilliant luster. It has a Mohs hardness of 5.5 and a specific gravity of 3.28–3.33.

<span class="mw-page-title-main">Fluorapatite</span> Phosphate mineral

Fluorapatite, often with the alternate spelling of fluoroapatite, is a phosphate mineral with the formula Ca5(PO4)3F (calcium fluorophosphate). Fluorapatite is a hard crystalline solid. Although samples can have various color (green, brown, blue, yellow, violet, or colorless), the pure mineral is colorless, as expected for a material lacking transition metals. Along with hydroxylapatite, it can be a component of tooth enamel, but for industrial use both minerals are mined in the form of phosphate rock, whose usual mineral composition is primarily fluorapatite but often with significant amounts of the other.

Jarosewichite is a rare manganese arsenate mineral with formula: Mn2+3Mn3+(AsO4)(OH)6. It was first described in Franklin, New Jersey which is its only reported occurrence. Its chemical composition and structure are similar to chlorophoenicite. This mineral is orthorhombic with 2/m2/m2/m point group. Its crystals are prismatic or barrel-shaped. The color of jarosewichite is dark red to black. It has subvitreous luster of fracture surfaces and reddish-orange streak. This mineral occurs with flinkite, franklinite, andradite and cahnite.

<span class="mw-page-title-main">Jerrygibbsite</span>

Jerrygibbsite is a rare silicate mineral with the chemical formula (Mn,Zn)9(SiO4)4(OH)2. Jerrygibbsite was originally discovered by Pete J. Dunn in 1984, who named it after mineralogist Gerald V. Gibbs. It has only been reported from the type locality of Franklin Furnace, New Jersey, United States, and in Namibia's Otjozondjupa region. Jerrygibbsite is member of the leucophoenite family of the humite group. It is always found with these two minerals. It is a dimorph of sonolite.

<span class="mw-page-title-main">Hodgkinsonite</span> Nesosilicate mineral

Hodgkinsonite is a rare zinc manganese silicate mineral Zn2MnSiO4(OH)2. It crystallizes in the monoclinic system and typically forms radiating to acicular prismatic crystals with variable color from pink, yellow-red to deep red. Hodgkinsonite was discovered in 1913 by H. H. Hodgkinson, for whom it is named in Franklin, New Jersey, and it is only found in that area.

<span class="mw-page-title-main">Ganophyllite</span> Silicate mineral

Ganophyllite is a phyllosilicate mineral. It was named by Axel Hamberg in 1890 from the Greek words for leaf (φύλλον) and luster (γανωμα); the latter one was chosen due to the lustrous cleavages. The mineral was approved by the IMA in 1959, and it is a grandfathered mineral, meaning its name is still believed to refer to an existing species until this day. Tamaite is the calcium analogue, while eggletonite is the natrium analogue of said mineral.

Hendricksite is a member of the trioctahedral micas group. The mineral was named by Clifford Frondel and Jun Ito in honor of Sterling Brown Hendricks, who studied micas. It was approved in 1966 by the IMA.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Zincite. Handbook of Mineralogy
  3. Zincite. Mindat