A crystal detector is an obsoleteelectronic component in some early 20th century radio receivers that used a piece of crystalline mineral as a detector (demodulator) to rectify the alternating current radio signal to extract the audio modulation which produced the sound in the earphones. It was the first type of semiconductor diode, and one of the first semiconductor electronic devices. The most common type was the so-called cat whisker detector, which consisted of a piece of crystalline mineral, usually galena (lead sulfide), with a fine wire touching its surface. The "asymmetric conduction" of electric current across electrical contacts between a crystal and a metal was discovered in 1874 by Karl Ferdinand Braun. Crystals were first used as radio wave detectors in 1894 by Jagadish Chandra Bose in his microwave experiments. who first patented a crystal detector in 1901. The crystal detector was developed into a practical radio component mainly by G. W. Pickard, who began research on detector materials in 1902 and found hundreds of substances that could be used in forming rectifying junctions. The physical principles by which they worked were not understood at the time they were used, but subsequent research into these primitive point contact semiconductor junctions in the 1930s and 1940s led to the development of modern semiconductor electronics.
An electronic component is any basic discrete device or physical entity in an electronic system used to affect electrons or their associated fields. Electronic components are mostly industrial products, available in a singular form and are not to be confused with electrical elements, which are conceptual abstractions representing idealized electronic components.
In radio communications, a radio receiver, also known as a receiver, wireless or simply radio is an electronic device that receives radio waves and converts the information carried by them to a usable form. It is used with an antenna. The antenna intercepts radio waves and converts them to tiny alternating currents which are applied to the receiver, and the receiver extracts the desired information. The receiver uses electronic filters to separate the desired radio frequency signal from all the other signals picked up by the antenna, an electronic amplifier to increase the power of the signal for further processing, and finally recovers the desired information through demodulation.
A mineral is, broadly speaking, a solid chemical compound that occurs naturally in pure form. Minerals are most commonly associated with rocks due to the presence of minerals within rocks. These rocks may consist of one type of mineral, or may be an aggregate of two or more different types of minerals, spacially segregated into distinct phases. Compounds that occur only in living beings are usually excluded, but some minerals are often biogenic and/or are organic compounds in the sense of chemistry. Moreover, living beings often synthesize inorganic minerals that also occur in rocks.
The unamplified radio receivers that used crystal detectors were called crystal radios.The crystal radio was the first type of radio receiver that was used by the general public, and became the most widely used type of radio until the 1920s. It became obsolete with the development of vacuum tube receivers around 1920, but continued to be used until World War 2.
An amplifier, electronic amplifier or (informally) amp is an electronic device that can increase the power of a signal. It is a two-port electronic circuit that uses electric power from a power supply to increase the amplitude of a signal applied to its input terminals, producing a proportionally greater amplitude signal at its output. The amount of amplification provided by an amplifier is measured by its gain: the ratio of output voltage, current, or power to input. An amplifier is a circuit that has a power gain greater than one.
A crystal radio receiver, also called a crystal set, is a simple radio receiver, popular in the early days of radio. It uses only the power of the received radio signal to produce sound, needing no external power. It is named for its most important component, a crystal detector, originally made from a piece of crystalline mineral such as galena. This component is now called a diode.
In electronics, a vacuum tube, an electron tube, or valve or, colloquially, a tube, is a device that controls electric current flow in a high vacuum between electrodes to which an electric potential difference has been applied.
The contact between two dissimilar materials at the surface of the detector's semiconducting crystal forms a crude semiconductor diode, which acts as a rectifier, conducting electric current in only one direction and resisting current flowing in the other direction.In a crystal radio, it was connected between the tuned circuit, which passed on the oscillating current induced in the antenna from the desired radio station, and the earphone. Its function was to act as a demodulator, rectifying the radio signal, converting it from alternating current to a pulsing direct current, to extract the audio signal (modulation) from the radio frequency carrier wave. The audio frequency current produced by the detector passed through the earphone causing the earphone's diaphragm to vibrate, pushing on the air to create sound waves. This diagram shows a simplified explanation of how it works:
A rectifier is an electrical device that converts alternating current (AC), which periodically reverses direction, to direct current (DC), which flows in only one direction.
An electric current is the rate of flow of electric charge past a point or region. An electric current is said to exist when there is a net flow of electric charge through a region. In electric circuits this charge is often carried by electrons moving through a wire. It can also be carried by ions in an electrolyte, or by both ions and electrons such as in an ionized gas (plasma).
In radio engineering, an antenna is the interface between radio waves propagating through space and electric currents moving in metal conductors, used with a transmitter or receiver. In transmission, a radio transmitter supplies an electric current to the antenna's terminals, and the antenna radiates the energy from the current as electromagnetic waves. In reception, an antenna intercepts some of the power of a radio wave in order to produce an electric current at its terminals, that is applied to a receiver to be amplified. Antennas are essential components of all radio equipment.
Crystal radios had no amplifying components to increase the loudness of the radio signal; the sound power produced by the earphone came solely from the radio waves of the radio station being received, intercepted by the antenna. Therefore, the sensitivity of the detector was a major factor determining the sensitivity and reception range of the receiver, motivating much research into finding sensitive detectors.
In addition to its main use in crystal radios, crystal detectors were also used as radio wave detectors in scientific experiments, in which the DC output current of the detector was registered by a sensitive galvanometer, and in test instruments such as wavemeters used to calibrate the frequency of radio transmitters.
A galvanometer is an electromechanical instrument used for detecting and indicating an electric current. A galvanometer works as an actuator, by producing a rotary deflection, in response to electric current flowing through a coil in a constant magnetic field. Early galvanometers were not calibrated, but their later developments were used as measuring instruments, called ammeters, to measure the current flowing through an electric circuit.
The crystal detector consisted of an electrical contact between the surface of a semiconducting crystalline mineral and either a metal or another crystal.Since at the time they were used no one knew how they worked, crystal detectors evolved by trial and error. The construction of the detector depended on the type of crystal used, as it was found different minerals varied in how much contact area and pressure on the crystal surface was needed to make a sensitive rectifying contact. Crystals that required a light pressure like galena were used with the wire cat whisker contact; silicon was used with a heavier point contact, while silicon carbide (carborundum) could tolerate the heaviest pressure. Another type used two crystals of different minerals with their surfaces touching, the most common being the "Perikon" detector. Since the detector would only function when the contact was made at certain spots on the crystal surface, the contact point was almost always made adjustable. Below are the major categories of crystal detectors used during the early 20th century:
Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver.
Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard and brittle crystalline solid with a blue-grey metallic lustre; and it is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic table: carbon is above it; and germanium, tin, and lead are below it. It is relatively unreactive. Because of its high chemical affinity for oxygen, it was not until 1823 that Jöns Jakob Berzelius was first able to prepare it and characterize it in pure form. Its melting and boiling points of 1414 °C and 3265 °C respectively are the second-highest among all the metalloids and nonmetals, being only surpassed by boron. Silicon is the eighth most common element in the universe by mass, but very rarely occurs as the pure element in the Earth's crust. It is most widely distributed in dusts, sands, planetoids, and planets as various forms of silicon dioxide (silica) or silicates. More than 90% of the Earth's crust is composed of silicate minerals, making silicon the second most abundant element in the Earth's crust after oxygen.
Silicon carbide (SiC), also known as carborundum, is a semiconductor containing silicon and carbon. It occurs in nature as the extremely rare mineral moissanite. Synthetic SiC powder has been mass-produced since 1893 for use as an abrasive. Grains of silicon carbide can be bonded together by sintering to form very hard ceramics that are widely used in applications requiring high endurance, such as car brakes, car clutches and ceramic plates in bulletproof vests. Electronic applications of silicon carbide such as light-emitting diodes (LEDs) and detectors in early radios were first demonstrated around 1907. SiC is used in semiconductor electronics devices that operate at high temperatures or high voltages, or both. Large single crystals of silicon carbide can be grown by the Lely method and they can be cut into gems known as synthetic moissanite.
Patented by Braunand Pickard in 1906, this was the most common type of crystal detector, mainly used with galena but also other crystals. It consisted of a pea-size piece of crystalline mineral in a metal holder, with its surface touched by a fine metal wire or needle (the "cat whisker"). The contact between the tip of the wire and the surface of the crystal formed a crude unstable point-contact metal–semiconductor junction, forming a Schottky barrier diode. The wire whisker is the anode, and the crystal is the cathode; current can flow from the wire into the crystal but not in the other direction.
Only certain sites on the crystal surface functioned as rectifying junctions.The device was very sensitive to the exact geometry and pressure of contact between wire and crystal, and the contact could be disrupted by the slightest vibration. Therefore, a usable point of contact had to be found by trial and error before each use. The wire was suspended from a moveable arm and was dragged across the crystal face by the user until the device began functioning. In a crystal radio, the user would tune the radio to a strong local station if possible and then adjust the cat whisker until the station or radio noise (a static hissing noise) was heard in the radio's earphones. This required some skill and a lot of patience. An alternative method of adjustment was to use a battery-operated buzzer connected to the radio's ground wire or inductively coupled to the tuning coil, to generate a test signal. The spark produced by the buzzer's contacts functioned as a weak radio transmitter whose radio waves could be received by the detector, so when a rectifying spot had been found on the crystal the buzz could be heard in the earphones, at which time the buzzer was turned off.
The detector consisted of two parts mounted next to each other on a flat nonconductive base:
Invented in 1906 by Henry H. C. Dunwoody,this consisted of a piece of silicon carbide (SiC, then known by the trade name carborundum), either clamped between two flat metal contacts, or mounted in fusible alloy in a metal cup with a contact consisting of a hardened steel point pressed firmly against it with a spring. Carborundum, an artificial product of electric furnaces produced in 1893, required a heavier pressure than the cat whisker contact. The carborundum detector was popular because its sturdy contact did not require readjustment each time it was used, like the delicate cat whisker devices. Some carborundum detectors were adjusted at the factory and then sealed and did not require adjustment by the user. It was not sensitive to vibration and so was used in shipboard wireless stations where the ship was rocked by waves, and military stations where vibration from gunfire could be expected. Another advantage was that it was tolerant of high currents, and could not be "burned out" by atmospheric electricity from the antenna. Therefore, it was the most common type used in commercial radiotelegraphy stations.
Carborundum is a semiconductor with a wide band gap of 3 eV, so to make the detector more sensitive a forward bias voltage of several volts was usually applied across the junction by a battery and potentiometer. The voltage was adjusted with the potentiometer until the sound was loudest in the earphone. The bias moved the operating point to the curved "knee" of the device's current-voltage curve, which produced the largest rectified current.
Patented and first manufactured in 1906 by Pickard,this was the first type of crystal detector to be commercially produced. Silicon required more pressure than the cat whisker contact, although not as much as carborundum. A flat piece of silicon was embedded in fusible alloy in a metal cup, and a metal point, usually brass or gold, was pressed against it with a spring. The surface of the silicon was usually ground flat and polished. Silicon was also used with antimony and arsenic contacts. The silicon detector had some of the same advantages as carborundum; its firm contact could not be jarred loose by vibration, so it was used in commercial and military radiotelegraphy stations.
The "Perikon" detector, invented 1908 by Pickardconsisted of two crystals in metal holders, mounted face to face with their surfaces touching, forming a crystal-to-crystal contact. One crystal was zincite (zinc oxide, ZnO), the other was a copper iron sulfide, either bornite (Cu5FeS4) or chalcopyrite (CuFeS2). In Pickard's commercial detector (see picture), multiple zincite crystals were mounted in a fusible alloy in a round cup (on right), while the chalcopyrite crystal was mounted in a cup on an adjustable arm facing it (on left). The chalcopyrite crystal was moved forward until it touched the surface of one of the zincite crystals. When a sensitive spot was located, the arm was locked in place with the setscrew. Multiple zincite pieces were provided because the fragile zincite crystal could be damaged by excessive currents and tended to "burn out" due to atmospheric electricity from the wire antenna or currents leaking into the receiver from the powerful spark transmitters used at the time. This detector was also sometimes used with a small forward bias voltage of around 0.2V from a battery to make it more sensitive.
Although the zincite-chalcopyrite "Perikon" was the most widely used crystal-to-crystal detector, other crystal pairs were also used. Zincite was also used with carbon, galena, and tellurium. Silicon was used with arsenic,antimony and tellurium crystals.
During the first three decades of radio, from 1888 to 1918, called the wireless telegraphy or "spark" era, primitive radio transmitters called spark gap transmitters were used, which generated radio waves by an electric spark.These transmitters were unable to produce the continuous sinusoidal waves which are used to transmit audio (sound) in modern AM or FM radio transmission. Instead spark gap transmitters transmitted information by wireless telegraphy; the user turned the transmitter on and off rapidly by tapping on a telegraph key, producing pulses of radio waves which spelled out text messages in Morse code. Therefore, the radio receivers of this era did not have to demodulate the radio wave, extract an audio signal from it as modern receivers do, they merely had to detect the presence or absence of the radio waves, to make a sound in the earphone when the radio wave was present to represent the "dots" and "dashes" of Morse code. The device which did this was called a detector . The crystal detector was the most successful of many detector devices invented during this era.
The crystal detector evolved from an earlier device,the first primitive radio wave detector, called a coherer , developed in 1890 by Édouard Branly and used in the first radio receivers in 1894–96 by Marconi and Oliver Lodge. Made in many forms, the coherer consisted of a high resistance electrical contact, composed of conductors touching with a thin resistive surface film, usually oxidation, between them. Radio waves changed the resistance of the contact, causing it to conduct a DC current. The most common form consisted of a glass tube with electrodes at each end, containing loose metal filings in contact with the electrodes. Before a radio wave was applied, this device had a high electrical resistance, in the megohm range. When a radio wave from the antenna was applied across the electrodes it caused the filings to "cohere" or clump together and the coherer's resistance fell, causing a DC current from a battery to pass through it, which rang a bell or produced a mark on a paper tape representing the "dots" and "dashes" of Morse code. Most coherers had to be tapped mechanically between each pulse of radio waves to return them to a nonconductive state.
The coherer was a very poor detector, motivating much research to find better detectors.It worked by complicated thin film surface effects, so scientists of the time didn't understand how it worked, except for a vague idea that radio wave detection depended on some mysterious property of "imperfect" electrical contacts. Researchers investigating the effect of radio waves on various types of "imperfect" contacts to develop better coherers, invented crystal detectors.
The "unilateral conduction" of crystals was discovered by Karl Ferdinand Braun, a German physicist, in 1874 at the University of Würzburg.He studied copper pyrite (Cu5FeS4), iron pyrite (iron sulfide, FeS2), galena (PbS) and copper antimony sulfide (Cu3S4Sb). This was before radio waves had been discovered, and Braun did not apply these devices practically but was interested in the nonlinear current–voltage characteristic that these sulfides exhibited. Graphing the current as a function of voltage across a contact made by a piece of mineral touched by a wire cat whisker, he found the result was a line that was flat for current in one direction but curved upward for current in the other direction, instead of a straight line, showing that these substances did not obey Ohm's law. Due to this characteristic, some crystals had up to twice as much resistance to current in one direction as they did to current in the other. In 1877 and 1878 he reported further experiments with psilomelane, (Ba,H2O)2Mn5O10). Braun did investigations which ruled out several possible causes of asymmetric conduction, such as electrolytic action and some types of thermoelectric effects.
Thirty years after these discoveries, after Bose's experiments, Braun began experimenting with his crystalline contacts as radio wave detectors.In 1906 he obtained a German patent on a galena cat whisker detector, but was too late to obtain patents in other countries.
The first person to use crystals for radio wave detection was Indian physicist Jagadish Chandra Bose of the University of Calcutta in his landmark 60 GHz microwave optics experiments from 1894 to 1900. Like other scientists since Hertz, Bose was investigating the similarity between radio waves and light by duplicating classic optics experiments with radio waves. He first used a coherer consisting of a steel spring pressing against a metal surface with a current passing through it. Unsatisfied with this detector, around 1897 Bose measured the change in resistivity of dozens of metals and metal compounds exposed to microwaves, finding that in some the resistivity increased and in some it decreased. He experimented with many substances as contact detectors, focusing on galena. His detectors consisted of a small galena crystal with a metal point contact pressed against it with a thumbscrew, mounted inside a closed waveguide ending in a horn antenna to collect the microwaves. Bose passed a current from a battery through the crystal, and used a galvanometer to measure it. When microwaves struck the crystal the galvanometer registered a drop in resistance of the detector. He found these detectors were also sensitive to visible light and ultraviolet, leading him to call them an artificial retina. Thomas Lee points out that Bose's detectors did not function as diodes, rectifying the radio waves as later galena detectors did, but as thermal bolometer detectors. Most sources do not make this distinction and credit Bose with inventing the galena detector. He patented the detector 30 September 1901. This is often considered the first patent on a semiconductor device.
Greenleaf Whittier Pickard may be the person most responsible for making the crystal detector a practical device. Pickard, an engineer with the American Wireless Telephone and Telegraph Co. invented the rectifying contact detector,discovering rectification of radio waves in 1902 while experimenting with a coherer detector consisting of a carbon block resting across two steel knife edge contacts. On 29 May 1902 he was operating this device, listening to a radiotelegraphy station. Coherers required an external current source to operate, so he had the coherer and telephone earphone connected in series with a 3 cell battery to provide power to operate the earphone. Annoyed by background "frying" noise caused by the current through the carbon, he reached over to cut two of the battery cells out of the circuit to reduce the current
The frying ceased, and the signals, though much weakened, became materially clearer through being freed of their background of microphonic noise. Glancing over at my circuit, I discovered to my great surprise that instead of cutting out two of the cells I had cut out all three; so, therefore, the telephone diaphragm was being operated solely by the energy of the receiver signals. A contact detector operating without local battery seemed so contrary to all my previous experience that ... I resolved at once to thoroughly investigate the phenomenon.
The generation of an audio signal without a DC bias battery made Pickard realize the device was acting as a rectifier. During the next four years, Pickard conducted an exhaustive search to find which substances formed the most sensitive detecting contacts, eventually testing thousands of minerals,and discovered about 250 rectifying crystals. In 1906 he obtained a sample of fused silicon, an artificial product recently synthesized in electric furnaces, and it outperformed all other substances. He patented the silicon detector 30 August 1906. In 1907 he formed a company to manufacture his detectors, Wireless Specialty Products Co., and the silicon detector was the first crystal detector to be sold commercially. Pickard went on to produce other detectors using the crystals he had discovered; the more popular being the iron pyrite "Pyron" detector and the zincite–chalcopyrite crystal-to-crystal "Perikon" detector in 1908, which stood for "PERfect pIcKard cONtact".
Guglielmo Marconi developed the first practical wireless telegraphy transmitters and receivers in 1896, and radio began to be used for communication around 1899. The coherer was used as detector for the first 10 years, until around 1906.During the wireless telegraphy era prior to 1920, there was virtually no broadcasting; radio served as a point-to-point text messaging service. Until the triode vacuum tube began to be used around World War 1, radio receivers had no amplification and were powered only by the radio waves picked up by their antennae. Long distance radio communication depended on high power transmitters (up to 1 MW), huge wire antennas, and a receiver with a sensitive detector.
Crystal detectors were invented by several researchers at about the same time.Braun began to experiment with crystal detectors around 1899, around when Bose patented his galena detector. Pickard invented his silicon detector in 1906. Also in 1906 Henry Harrison Chase Dunwoody, a retired general in the U.S. Army Signal Corps, patented the silicon carbide (carborundum) detector, Braun patented a galena cat whisker detector in Germany, and L. W. Austin invented a silicon–tellurium detector.
Around 1907 crystal detectors replaced the coherer and electrolytic detector to become the most widely used form of radio detector.Until the triode vacuum tube began to be used during World War 1, crystals were the best radio reception technology, used in sophisticated receivers in wireless telegraphy stations, as well as in homemade crystal radios. In transoceanic radiotelegraphy stations elaborate inductively coupled crystal receivers fed by mile long wire antennas were used to receive transatlantic telegram traffic. Much research went into finding better detectors and many types of crystals were tried. The goal of researchers was to find rectifying crystals that were less fragile and sensitive to vibration than galena and pyrite. Another desired property was tolerance of high currents; many crystals would become insensitive when subjected to discharges of atmospheric electricity from the outdoor wire antenna, or current from the powerful spark transmitter leaking into the receiver. Carborundum proved to be the best of these; it could rectify when clamped firmly between flat contacts. Therefore, carborundum detectors were used in shipboard wireless stations where waves caused the floor to rock, and military stations where gunfire was expected.
In 1907–1909, George Washington Pierce at Harvard conducted research into how crystal detectors worked.Using the new cathode ray tube, he produced the first pictures of the waveforms in a working detector, proving that it did rectify the radio wave. During this era, before modern solid-state physics, most scientists believed that crystal detectors operated by some thermoelectric effect. Although Pierce didn't discover the mechanism by which it worked, he did prove that the existing theories were wrong; his oscilloscope waveforms showed there was no phase delay between the voltage and current in the detector, ruling out thermal explanations. Pierce originated the name crystal rectifier.
Between about 1905 and 1915 new types of radio transmitters were developed which produced continuous sinusoidal waves: the arc converter (Poulsen arc) and the Alexanderson alternator. These slowly replaced the old damped wave spark transmitters. Besides having a longer transmission range, these transmitters could be modulated with an audio signal to transmit sound by amplitude modulation (AM). It was found that, unlike the coherer, the rectifying action of the crystal detector allowed it to demodulate an AM radio signal, producing audio (sound).Although other detectors used at the time, the electrolytic detector, Fleming valve and the triode could also rectify AM signals, crystals were the simplest, cheapest AM detector. As more and more radio stations began experimenting with transmitting sound after World War 1, a growing community of radio listeners built or bought crystal radios to listen to them. Use continued to grow until the 1920s when vacuum tube radios replaced them.
Some semiconductor diodes have a property called negative resistance which means the current through them decreases as the voltage increases over a part of their I–V curve. This allows a diode, normally a passive device, to function as an amplifier or oscillator. For example, when connected to a resonant circuit and biased with a DC voltage, the negative resistance of the diode can cancel the positive resistance of the circuit, creating a circuit with zero AC resistance, in which spontaneous oscillating currents arise.
This property was first observed in crystal detectors around 1909 by William Henry Ecclesand Pickard. They noticed that when their detectors were biased with a DC voltage to improve their sensitivity, they would sometimes break into spontaneous oscillations. However these researchers just published brief accounts and didn't pursue the effect.
The first person to exploit negative resistance practically was self-taught Russian physicist Oleg Losev, who devoted his career to the study of crystal detectors. In 1922 working at the new Nizhny Novgorod Radio Laboratory he discovered negative resistance in biased zincite (zinc oxide) point contact junctions.He realized that amplifying crystals could be an alternative to the fragile, expensive, energy-wasting vacuum tube. He used biased negative resistance crystal junctions to build solid-state amplifiers, oscillators, and amplifying and regenerative radio receivers, 25 years before the invention of the transistor. Later he even built a superheterodyne receiver. However his achievements were overlooked because of the success of vacuum tubes. His technology was dubbed "Crystodyne" by science publisher Hugo Gernsback one of the few people in the West who paid attention to it. After ten years he abandoned research into this technology and it was forgotten.
The negative resistance diode was rediscovered with the invention of the tunnel diode in 1957, for which Leo Esaki won the 1973 Nobel Prize in Physics. Today, negative resistance diodes such as the Gunn diode and IMPATT diode are widely used as microwave oscillators in such devices as radar speed guns and garage door openers.
In 1907 British Marconi engineer Henry Joseph Round noticed that when direct current was passed through a silicon carbide (carborundum) point contact junction, a spot of greenish, bluish, or yellowish light was given off at the contact point.Round had constructed a light emitting diode (LED). However he just published a brief two paragraph note about it and did no further research.
While investigating crystal detectors in the mid-1920s at Nizhny Novgorod, Oleg Losev independently discovered that biased carborundum and zincite junctions emitted light.Losev was the first to analyze this device, investigate the source of the light, propose a theory of how it worked, and envision practical applications. He published his experiments in 1927 in a Russian journal, and the 16 papers he published on LEDs between 1924 and 1930 constitute a comprehensive study of this device. Losev did extensive research into the mechanism of light emission. He measured rates of evaporation of benzine from the crystal surface and found it was not accelerated when light was emitted, concluding that the luminescence was a "cold" light not caused by thermal effects. He theorized correctly that the explanation of the light emission was in the new science of quantum mechanics, speculating that it was the inverse of the photoelectric effect discovered by Albert Einstein in 1905. He wrote to Einstein about it, but did not receive a reply. Losev designed practical carborundum electroluminescent lights, but found no one interested in commercially producing these weak light sources.
Losev died in World War 2. Due partly to the fact that his papers were published in Russian and German, and partly to his lack of reputation (his upper class birth barred him from a college education or career advancement in Soviet society, so he never held an official position higher than technician) his work is not well known in the West.
In the 1920s, the amplifying triode vacuum tube, invented in 1907 by Lee De Forest, replaced earlier technology in both radio transmitters and receivers.AM radio broadcasting spontaneously arose around 1920, and radio listening exploded to become a hugely popular pastime. The initial listening audience for the new broadcasting stations was probably largely owners of crystal radios. But lacking amplification, crystal radios had to be listened to with earphones, and could only receive nearby local stations. The amplifying vacuum tube radios which began to be mass-produced in 1921 had greater reception range, did not require the fussy adjustment of a cat whisker, and produced enough audio output power to drive loudspeakers, allowing the entire family to listen comfortably together, or dance to Jazz Age music.
So during the 1920s vacuum tube receivers replaced crystal radios in all except poor households.Commercial and military wireless telegraphy stations had already switched to more sensitive vacuum tube receivers. Vacuum tubes temporarily put an end to crystal detector research. The temperamental, unreliable action of the crystal detector had always been a barrier to its acceptance as a standard component in commercial radio equipment and was one reason for its rapid replacement. Frederick Seitz, an early semiconductor researcher, wrote:
Such variability, bordering on what seemed the mystical, plagued the early history of crystal detectors and caused many of the vacuum tube experts of a later generation to regard the art of crystal rectification as being close to disreputable.
The crystal radio became a cheap alternative receiver used in emergencies and by people who couldn't afford tube radios:teenagers, the poor, and those in developing countries. Building a crystal set remained a popular educational project to introduce people to radio, used by organizations like the Boy Scouts. The galena detector, the most widely used type among amateurs, became virtually the only detector used in crystal radios from this point on. The carborundum junction saw some use as a detector in early vacuum tube radios because it was more sensitive than the triode grid-leak detector. Crystal radios were kept as emergency backup radios on ships. During World War 2 in Nazi-occupied Europe the radio saw use as an easily constructed, easily concealed clandestine radio by Resistance groups. After World War 2, the development of modern semiconductor diodes finally made the galena cat whisker detector obsolete.
Semiconductor devices like the crystal detector work by quantum mechanical principles; their operation cannot be explained by classical physics. The birth of quantum mechanics in the 1920s was the necessary foundation for the development of semiconductor physics in the 1930s, during which physicists arrived at an understanding of how the crystal detector worked.The German word halbleiter, translated into English as "semiconductor", was first used in 1911 to describe substances whose conductivity fell between conductors and insulators, such as the crystals in crystal detectors. Felix Bloch and Rudolf Peierls around 1930 applied quantum mechanics to create a theory of how electrons move through a crystal. In 1931, Alan Wilson created quantum band theory which explains the electrical conductivity of solids. Werner Heisenberg conceived the idea of a hole , a vacancy in a crystal lattice where an electron should be, which can move about the lattice like a positive particle; both electrons and holes conduct current in semiconductors.
A breakthrough came when it was realized that the rectifying action of crystalline semiconductors was not due to the crystal alone but to the presence of impurity atoms in the crystal lattice.In 1930 Bernhard Gudden and Wilson established that electrical conduction in semiconductors was due to trace impurities in the crystal, a "pure" semiconductor did not act as a semiconductor, but as an insulator (at low temperatures). The maddeningly variable activity of different pieces of crystal when used in a detector, and the presence of "active sites" on the surface, was due to natural variations in the concentration of these impurities throughout the crystal. Nobel Laureate Walter Brattain, coinventor of the transistor, noted:
At that time you could get a chunk of silicon... put a cat whisker down on one spot, and it would be very active and rectify very well in one direction. You moved it around a little bit-maybe a fraction, a thousandth of an inch-and you might find another active spot, but here it would rectify in the other direction.
The "metallurgical purity" chemicals used by scientists to make synthetic experimental detector crystals had about 1% impurities which were responsible for such inconsistent results.During the 1930s progressively better refining methods were developed, allowing scientists to create ultrapure semiconductor crystals into which they introduced precisely controlled amounts of trace elements (called doping). This for the first time created semiconductor junctions with reliable, repeatable characteristics, allowing scientists to test their theories, and later making manufacture of modern diodes possible.
The theory of rectification in a metal-semiconductor junction, the type used in a cat whisker detector, was developed in 1938 independently by Walter Schottkyat Siemens & Halske research laboratory in Germany and Nevill Mott at Bristol University, UK. Mott received the 1977 Nobel Prize for Physics. In 1949 at Bell Labs William Shockley derived the Shockley diode equation which gives the nonlinear exponential current-voltage curve of a crystal detector, observed by scientists since Braun and Bose, which is responsible for rectification .
The development of microwave technology during the 1930s run up to World War 2 for use in radar led to the resurrection of the point contact crystal detector.Microwave radar receivers required a nonlinear device that could act as a mixer, to mix the incoming microwave signal with a local oscillator signal, to shift the microwave signal down to a lower intermediate frequency (IF) at which it could be amplified. The vacuum tubes used as mixers at lower frequencies in superheterodyne receivers could not function at microwave frequencies due to excessive capacitance. In the mid-1930s George Southworth at Bell Labs, working on this problem, bought an old cat whisker detector and found it worked at microwave frequencies. Hans Hollmann in Germany made the same discovery. The MIT Radiation Laboratory launched a project to develop microwave detector diodes, focusing on silicon, which had the best detecting properties. By about 1942 point-contact silicon crystal detectors for radar receivers such as the 1N21 and 1N23 were being mass-produced, consisting of a slice of boron-doped silicon crystal with a tungsten wire point pressed firmly against it. The cat whisker contact did not require adjustment, and these were sealed units. A second parallel development program at Purdue University produced germanium diodes. Such point-contact diodes are still being manufactured, and may be considered the first modern diodes.
After the war, germanium diodes replaced galena cat whisker detectors in the few crystal radios being made. Germanium diodes are more sensitive than silicon diodes as detectors, because germanium has a lower forward voltage drop than silicon (0.3 vs 0.7 volts). Today a few galena cat whisker detectors are still being made, but only for antique replica crystal radios or devices for science education.
A diode is a two-terminal electronic component that conducts current primarily in one direction ; it has low resistance in one direction, and high resistance in the other. A diode vacuum tube or thermionic diode is a vacuum tube with two electrodes, a heated cathode and a plate, in which electrons can flow in only one direction, from cathode to plate. A semiconductor diode, the most commonly used type today, is a crystalline piece of semiconductor material with a p–n junction connected to two electrical terminals. Semiconductor diodes were the first semiconductor electronic devices. The discovery of asymmetric electrical conduction across the contact between a crystalline mineral and a metal was made by German physicist Ferdinand Braun in 1874. Today, most diodes are made of silicon, but other materials such as gallium arsenide and germanium are used.
Microwaves are a form of electromagnetic radiation with wavelengths ranging from about one meter to one millimeter; with frequencies between 300 MHz (1 m) and 300 GHz (1 mm). Different sources define different frequency ranges as microwaves; the above broad definition includes both UHF and EHF bands. A more common definition in radio engineering is the range between 1 and 100 GHz. In all cases, microwaves include the entire SHF band at minimum. Frequencies in the microwave range are often referred to by their IEEE radar band designations: S, C, X, Ku, K, or Ka band, or by similar NATO or EU designations.
A semiconductor device is an electronic component that exploits the electronic properties of semiconductor material, principally silicon, germanium, and gallium arsenide, as well as organic semiconductors. Semiconductor devices have replaced vacuum tubes in most applications. They use electrical conduction in the solid state rather than the gaseous state or thermionic emission in a vacuum.
The coherer was a primitive form of radio signal detector used in the first radio receivers during the wireless telegraphy era at the beginning of the 20th century. Its use in radio was based on the 1890 findings of French physicist Edouard Branly and adapted by other physicists and inventors over the next ten years. The device consists of a tube or capsule containing two electrodes spaced a small distance apart with loose metal filings in the space between. When a radio frequency signal is applied to the device, the metal particles would cling together or "cohere", reducing the initial high resistance of the device, thereby allowing a much greater direct current to flow through it. In a receiver, the current would activate a bell, or a Morse paper tape recorder to make a record of the received signal. The metal filings in the coherer remained conductive after the signal (pulse) ended so that the coherer had to be "decohered" by tapping it with a clapper actuated by an electromagnet, each time a signal was received, thereby restoring the coherer to its original state. Coherers remained in widespread use until about 1907, when they were replaced by more sensitive electrolytic and crystal detectors.
The Audion was an electronic detecting or amplifying vacuum tube invented by American electrical engineer Lee de Forest in 1906. It was the first triode, consisting of an evacuated glass tube containing three electrodes: a heated filament, a grid, and a plate. It is important in the history of technology because it was the first widely used electronic device which could amplify; a small electrical signal applied to the grid could control a larger current flowing from the filament to plate.
Greenleaf Whittier Pickard was a United States radio pioneer. Pickard was a researcher in the early days of wireless. While not the earliest discoverer of the rectifying properties of contact between certain solid materials, he was largely responsible and most famous for the development of the crystal detector, the earliest type of diode detector. The crystal detector was the central component in many early radio receivers from around 1906 until about 1920. Pickard also experimented with antennas, radio wave propagation and noise suppression. On August 30, 1906 he filed a patent for a silicon crystal detector, which was granted on November 20, 1906. On June 10, 1907 he filed a patent for a Magnetic Aerial which was granted on January 21, 1908. Pickard's loop antenna had directional properties that could be used to reduce interference to the intended wireless communications. On June 21, 1911 he filed a patent on a crystal detector incorporating a springy low inertia wire of about 24 gauge formed with a loop or helix and pointed to make contact with the crystal. Crystal detectors incorporating this construction would become the most widely used and popularly known by the term cat whisker detector. This patent was granted on July 21, 1914. Greenleaf Whittier Pickard was named after his great-uncle, the American Quaker John Greenleaf Whittier (1807-1892). Pickard was president of the Institute of Radio Engineers in 1913.
Zincite is the mineral form of zinc oxide (ZnO). Its crystal form is rare in nature; a notable exception to this is at the Franklin and Sterling Hill Mines in New Jersey, an area also famed for its many fluorescent minerals. It has a hexagonal crystal structure and a color that depends on the presence of impurities. The zincite found at the Franklin Furnace is red-colored, mostly due to iron and manganese dopants, and associated with willemite and franklinite.
The magnetic detector or Marconi magnetic detector, sometimes called the "Maggie", was an early radio wave detector used in some of the first radio receivers to receive Morse code messages during the wireless telegraphy era around the turn of the 20th century. Developed in 1902 by radio pioneer Guglielmo Marconi from a method invented in 1895 by New Zealand physicist Ernest Rutherford it was used in Marconi wireless stations until around 1912, when it was superseded by vacuum tubes. It was widely used on ships because of its reliability and insensitivity to vibration. A magnetic detector was part of the wireless apparatus in the radio room of the RMS Titanic which was used to summon help during its famous 15 April 1912 sinking.
The electrolytic detector, or liquid barretter, was a type of detector (demodulator) used in early radio receivers. First used by Canadian radio researcher Reginald Fessenden in 1903, it was used until about 1913, after which it was superseded by crystal detectors and vacuum tube detectors such as the Fleming valve and Audion (triode). It was considered very sensitive and reliable compared to other detectors available at the time such as the magnetic detector and the coherer. It was one of the first rectifying detectors, able to receive AM (sound) transmissions. On December 24, 1906, US Naval ships with radio receivers equipped with Fessendon's electrolytic detectors received the first AM radio broadcast from Fessenden's Brant Rock, Massachusetts transmitter, consisting of a program of Christmas music.
In radio, a detector is a device or circuit that extracts information from a modulated radio frequency current or voltage. The term dates from the first three decades of radio (1888-1918). Unlike modern radio stations which transmit sound on an uninterrupted carrier wave, early radio stations transmitted information by radiotelegraphy. The transmitter was switched on and off to produce long or short periods of radio waves, spelling out text messages in Morse code. Therefore, early radio receivers had only to distinguish between the presence or absence of a radio signal. The device that performed this function in the receiver circuit was called a detector. A variety of different detector devices, such as the coherer, electrolytic detector, magnetic detector and the crystal detector, were used during the wireless telegraphy era until superseded by vacuum tube technology.
A reflex radio receiver, occasionally called a reflectional receiver, is a radio receiver design in which the same amplifier is used to amplify the high-frequency radio signal (RF) and low-frequency audio (sound) signal (AF). It was first invented in 1914 by German scientists Wilhelm Schloemilch and Otto von Bronk, and rediscovered and extended to multiple tubes in 1917 by Marius Latour and William H. Priess. The radio signal from the antenna and tuned circuit passes through an amplifier, is demodulated in a detector which extracts the audio signal from the radio carrier, and the resulting audio signal passes again through the same amplifier for audio amplification before being applied to the earphone or loudspeaker. The reason for using the amplifier for "double duty" was to reduce the number of active devices, vacuum tubes or transistors, required in the circuit, to reduce the cost. The economical reflex circuit was used in inexpensive vacuum tube radios in the 1920s, and was revived again in simple portable tube radios in the 1930s.
The Fleming valve, also called the Fleming oscillation valve, was a thermionic valve or vacuum tube invented in 1904 by Englishman John Ambrose Fleming as a detector for early radio receivers used in electromagnetic wireless telegraphy. It was the first practical vacuum tube and the first thermionic diode, a vacuum tube whose purpose is to conduct current in one direction and block current flowing in the opposite direction. The thermionic diode was later widely used as a rectifier — a device which converts alternating current (AC) into direct current (DC) — in the power supplies of a wide range of electronic devices, until beginning to be replaced by the selenium rectifier in the early 1930s and almost completely replaced by the semiconductor diode in the 1960s. The Fleming valve was the forerunner of all vacuum tubes, which dominated electronics for 50 years. The IEEE has described it as "one of the most important developments in the history of electronics", and it is on the List of IEEE Milestones for electrical engineering.
Oleg Vladimirovich Losev was a Russian scientist and inventor, who made significant discoveries in the field of semiconductor junctions.
A tikker, alternately spelled ticker, was a vibrating interrupter used in early wireless telegraphy radio receivers such as crystal radio receivers in order to receive continuous wave (CW) radiotelegraphy signals.
In solid-state physics, a metal–semiconductor (M–S) junction is a type of electrical junction in which a metal comes in close contact with a semiconductor material. It is the oldest practical semiconductor device. M–S junctions can either be rectifying or non-rectifying. The rectifying metal–semiconductor junction forms a Schottky barrier, making a device known as a Schottky diode, while the non-rectifying junction is called an ohmic contact.
A foxhole radio is a makeshift radio that was built by soldiers in World War II for entertainment, to listen to local radio stations. They were first reported at the Battle of Anzio, Italy, spreading later across the European and Pacific theaters. The foxhole radio was a crude crystal radio which used a safety razor blade as a radio wave detector with the blade acting as the crystal, and a wire, safety pin, or, later, a pencil serving as the cat's whisker. Other versions were similar to the microphone detector of David Edward Hughes used in the early days of radio. Foxhole radios were constructed because soldiers were not allowed to have ordinary vacuum tube radios, because the regenerative and superheterodyne receivers of the time radiated radio waves which could give away their position to the enemy. The foxhole radio had no power source and ran off the power received from the radio station, so it did not emit radio waves. They were named, likely by the press, for the foxhole, a defensive fighting position used during the war. There are also accounts of prisoners of war in World War II and in the Vietnam War having constructed foxhole radios.
Known in his own time for his work with the Army's Weather Bureau, Henry Harrison Chase Dunwoody invented the carborundum radio detector in 1906. It was the first practical mineral radio wave detector and the first commercial semiconductor device.
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