Willemite | |
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General | |
Category | Silicate mineral |
Formula (repeating unit) | Zn2SiO4 |
IMA symbol | Wlm [1] |
Strunz classification | 9.AA.05 (10 ed) 8/A.01-20 (8 ed) |
Dana classification | 51.1.1.2 |
Crystal system | Trigonal |
Crystal class | Rhombohedral (3) (same H-M symbol) |
Space group | R3 |
Identification | |
Color | Colorless to white, gray, black, flesh-red, burgundy-red, pink, brown, dark brown, mahogany-brown, honey-yellow, yellow, apple-green, blue, pastel green, light blue, azure-blue |
Crystal habit | Fibrous, botryoidal to massive |
Cleavage | {0001}, {1120} – imperfect |
Fracture | Irregular to conchoidal |
Mohs scale hardness | 5.5 |
Luster | Vitreous to resinous |
Diaphaneity | Transparent to opaque |
Specific gravity | 3.9 –4.2 |
Optical properties | Uniaxial (+) |
Refractive index | nω = 1.691 –1.694 nε = 1.719 –1.725 |
Birefringence | δ = 0.028 |
Other characteristics | Strongly fluorescent; may be phosphorescent |
References | [2] [3] [4] |
Major varieties | |
troostite | zinc is partly replaced by manganese |
Willemite is a zinc silicate mineral ( Zn 2 Si O 4) and a minor ore of zinc. It is highly fluorescent (green) under shortwave ultraviolet light. It occurs in a variety of colors in daylight, in fibrous masses and apple-green gemmy masses. Troostite is a variant in which part of the zinc is partly replaced by manganese, it occurs in solid brown masses.
It was discovered in 1829 in the Belgian Vieille-Montagne mine. Armand Lévy was shown samples by a student at the university where he was teaching. Lévy named it after William I of the Netherlands [5] (it is occasionally spelled villemite). [6] [7] [8] The troostite variety is named after Dutch-American mineralogist Gerard Troost. [9]
Willemite is usually formed as an alteration of previously existing sphalerite ore bodies, and is usually associated with limestone. It is also found in marble and may be the result of a metamorphism of earlier hemimorphite or smithsonite. [10] Crystals have the form of hexagonal prisms terminated by rhombohedral planes: there are distinct cleavages parallel to the prism-faces and to the base. Granular and cleavage masses are of more common occurrence. [11] It occurs in many places, but is best known from Arizona and the zinc, iron, manganese deposits at Franklin and Sterling Hill Mines in New Jersey. It often occurs with red zincite (zinc oxide) and franklinite ( Fe,Mn,Zn)(Fe,Mn)2O4 (an iron rich zinc mineral occurring in sharp black isometric octahedral crystals and masses). Franklinite and zincite are not fluorescent.
Artificial willemite was used as the basis of first-generation fluorescent tube phosphors. Doped with manganese-II, it fluoresces with a broad white emission band. Some versions had some of the zinc replaced with beryllium. In the 1940s it was largely replaced by the second-generation halophosphors based on the fluorapatite structure. These, in turn have been replaced by the third-generation TriPhosphors. [12] [13]
Vieille Montagne was a zinc mine in Kelmis, a town in Belgium between Liège and Aachen. The mine's name is French for "old mountain" or "old mine", and this is also reflected in its German name, Altenberg. The mine was once a bone of contention between Prussia on the one side and the United Kingdom of the Netherlands on the other, that resulted in a piece of land that became the territory of Neutral Moresnet.
Neutral Moresnet was a small Belgian–Prussian condominium in western Europe that existed from 1816 to 1921 and was administered jointly by the United Kingdom of the Netherlands and the Kingdom of Prussia. It was 1.5 kilometres (1 mi) wide and five kilometres (3 mi) long, with an area of 360 hectares. After 1830, the territory's northernmost border point at Vaalserberg connected it to a quadripoint shared additionally with the Dutch Province of Limburg, the Prussian Rhine Province, and the Belgian Liège Province. Its former location is represented presently by the Three-Country Point, the meeting place of the borders of Belgium, Germany, and the Netherlands.
Kelmis is a municipality located in the Belgian province of Liège, named for the historical deposits of calamine nearby. As of 2011, the population was 10,881; the area is 18.1 square kilometres (7.0 sq mi) and the population density is 601.2 inhabitants per square kilometre (1,557/sq mi).
Zincite is the mineral form of zinc oxide (ZnO). Its crystal form is rare in nature; a notable exception to this is at the Franklin and Sterling Hill Mines in New Jersey, an area also famed for its many fluorescent minerals. It has a hexagonal crystal structure and a color that depends on the presence of impurities. The zincite found at the Franklin Furnace is red-colored, mostly due to iron and manganese dopants, and associated with willemite and franklinite.
Smithsonite, also known as zinc spar, is the mineral form of zinc carbonate (ZnCO3). Historically, smithsonite was identified with hemimorphite before it was realized that they were two different minerals. The two minerals are very similar in appearance and the term calamine has been used for both, leading to some confusion. The distinct mineral smithsonite was named in 1832 by François Sulpice Beudant in honor of English chemist and mineralogist James Smithson (c. 1765–1829), who first identified the mineral in 1802.
Antoine François Alfred Lacroix was a French mineralogist and geologist. He was born in Mâcon, Saône-et-Loire.
Franklinite is an oxide mineral belonging to the normal spinel subgroup's iron (Fe) series, with the formula Zn2+Fe23+O4.
Franklin Furnace, also known as the Franklin Mine, is a famous mineral location for rare zinc, iron, manganese minerals in old mines in Franklin, Sussex County, New Jersey, United States. This locale produced more species of minerals and more different fluorescent minerals than any other location. The mineral association (assemblage) from Franklin includes willemite, zincite and franklinite.
Todorokite is a complex hydrous manganese oxide mineral with generic chemical formula (Na,Ca,K,Ba,Sr)
1-x(Mn,Mg,Al)
6O
12·3-4H
2O. It was named in 1934 for the type locality, the Todoroki mine, Hokkaido, Japan. It belongs to the prismatic class 2/m of the monoclinic crystal system, but the angle β between the a and c axes is close to 90°, making it seem orthorhombic. It is a brown to black mineral which occurs in massive or tuberose forms. It is quite soft with a Mohs hardness of 1.5, and a specific gravity of 3.49 – 3.82. It is a component of deep ocean basin manganese nodules.
Fraipontite is a zinc aluminium silicate mineral with a formula of (Zn,Al)3(Si,Al)2O5(OH)4.
Jean-Jacques Daniël Dony was an inventor and industrialist. He invented a procedure for the production of pure zinc, and opened a mine in Moresnet.
Fluorapatite, often with the alternate spelling of fluoroapatite, is a phosphate mineral with the formula Ca5(PO4)3F (calcium fluorophosphate). Fluorapatite is a hard crystalline solid. Although samples can have various color (green, brown, blue, yellow, violet, or colorless), the pure mineral is colorless, as expected for a material lacking transition metals. Along with hydroxylapatite, it can be a component of tooth enamel, but for industrial use both minerals are mined in the form of phosphate rock, whose usual mineral composition is primarily fluorapatite but often with significant amounts of the other.
Jerrygibbsite is a rare silicate mineral with the chemical formula (Mn,Zn)9(SiO4)4(OH)2. Jerrygibbsite was originally discovered by Pete J. Dunn in 1984, who named it after mineralogist Gerald V. Gibbs. It has only been reported from the type locality of Franklin Furnace, New Jersey, United States, and in Namibia's Otjozondjupa region. Jerrygibbsite is member of the leucophoenite family of the humite group. It is always found with these two minerals. It is a dimorph of sonolite.
Bustamite is a calcium manganese inosilicate (chain silicate) and a member of the wollastonite group. Magnesium, zinc and iron are common impurities substituting for manganese. Bustamite is the high-temperature polymorph of CaMnSi2O6 and johannsenite is the low temperature polymorph. The inversion takes place at 830 °C (1,530 °F), but may be very slow.
Bustamite could be confused with light-colored rhodonite or pyroxmangite, but both these minerals are biaxial (+) whereas bustamite is biaxial (−).
Tsumcorite is a rare hydrated lead arsenate mineral that was discovered in 1971, and reported by Geier, Kautz and Muller. It was named after the TSUMeb CORporation mine at Tsumeb, in Namibia, in recognition of the Corporation's support for mineralogical investigations of the orebody at its Mineral Research Laboratory.
Sonolite is a mineral with formula Mn9(SiO4)4(OH,F)2. The mineral was discovered in 1960 in the Sono mine in Kyoto Prefecture, Japan. In 1963, it was identified as a new mineral and named after the Sono mine.
Serve-Dieu Abailard "Armand" Lévy was a French mathematician and mineralogist. He is remembered in the Haüy-Lévy notation for describing mineral crystal structures.
Neu-Moresnet is a village and sub-municipality of Kelmis in the German-speaking community of the province of Liège, Wallonia, Belgium. The village was founded as Prussian-Moresnet as part of the Lower Rhine Province. In 1919, after World War I, it was awarded to Belgium, and renamed Neu-Moresnet. In 1940, it was annexed by Nazi Germany, and in 1944, it was returned to Belgium. Neu-Moresnet was an independent municipality until 1977 when it was merged into Kelmis.
Moresnet is a village and sub-municipality of Plombières in the province of Liège, Wallonia, Belgium. It was originally a German speaking village. Nowadays French is the official language.
Gilles Joseph Gustave Dewalque was a Belgian physician, geologist, paleontologist, and mineralogist.
En 1829, [Armand Lévy] décrivit la willémite [...], nouvelle espèce minérale découverte à la Vieille-Montagne à Moresnet, et la dédia à Guillaume (Willem) 1er des Pays-Bas (Lévy, 1830; Lacroix, 1919; Buttgenbach, 1947a). « Ce minéral, très-abondant à Moresnet, avait échappé à l'attention des minéralogistes qui avaient visité cette localité, lorsqu'un élève de l'université de Liége en apporta plusieurs morceaux qui me parurent appartenir à une espèce différente de celles que je connaissais; en conséquence je me rendis sur les lieux, et, après avoir mûrement examiné les nombreux échantillons que j'y rencontrai, je fus convaincu que ma conjecture était fondée » (Lévy, 1843).(Translation: "In 1829, [Lévy] described willemite, a new mineral discovered at Moresnet's Vieille-Montagne and dedicated to William I of the Netherlands. "The mineral—quite abundant in Moresnet—went unnoticed by mineralogists who had visited this location. A student of the University of Liège brought me several pieces that I was unfamiliar with, so I went to these places. After carefully examining the many samples that I came across, I was convinced that my supposition was founded.")
Syn. Wihlemite, williamsite, troostite. [...] dans les amas de calamine de la Vieille-Montagne
Ainsi s'explique qu'en 1829 il ait dédié au roi des Pays-Bas, Wilhem I, la villemite, qu'il venait de découvrir à la Vieille-Montagne.("[...] in 1829 he dedicated to the king of the Netherlands, William I, the villemite, which he had just discovered at Vieille-Montagne.")