Bromyl fluoride

Last updated
Bromyl fluoride
Bromyl fluoride.svg
Names
Other names
Bromine fluoride dioxide
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/BrFO2/c2-1(3)4
    Key: MQCDGGKZTTYBRJ-UHFFFAOYSA-N
  • O=Br(=O)F
Properties
BrFO2
Molar mass 130.900 g·mol−1
Appearancecolorless liquid
Melting point −9 °C (16 °F; 264 K)
reacts with water
Related compounds
Related compounds
Iodyl fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Bromyl fluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula BrO2F. [1] [2]

Contents

Synthesis

BrF5 + 2 H2O → BrO2F + 4 HF

Physical properties

The compound forms a colorless volatile liquid that decomposes at temperatures above 10 °C. It is highly reactive and unstable, [4] and corrodes glass at room temperature.

Chemical properties

3 BrO2F → BrF3 + Br2 + 3 O2
BrO2F + H2O → HBrO3 + HF
BrO2F + 2 NaOH → NaBrO3 + NaF + H2O

Related Research Articles

<span class="mw-page-title-main">Dinitrogen pentoxide</span> Chemical compound

Dinitrogen pentoxide is the chemical compound with the formula N2O5. It is one of the binary nitrogen oxides, a family of compounds that contain only nitrogen and oxygen. It exists as colourless crystals that sublime slightly above room temperature, yielding a colorless gas.

<span class="mw-page-title-main">Tungsten hexafluoride</span> Chemical compound

Tungsten(VI) fluoride, also known as tungsten hexafluoride, is an inorganic compound with the formula WF6. It is a toxic, corrosive, colorless gas, with a density of about 13 kg/m3 (22 lb/cu yd). It is the only known gaseous transition metal compound and the densest known gas under standard ambient temperature and pressure. WF6 is commonly used by the semiconductor industry to form tungsten films, through the process of chemical vapor deposition. This layer is used in a low-resistivity metallic "interconnect". It is one of seventeen known binary hexafluorides.

In chemistry, an interhalogen compound is a molecule which contains two or more different halogen atoms and no atoms of elements from any other group.

<span class="mw-page-title-main">Oxygen fluoride</span> Any binary compound of oxygen and fluorine

Oxygen fluorides are compounds of elements oxygen and fluorine with the general formula OnF2, where n = 1 to 6. Many different oxygen fluorides are known:

<span class="mw-page-title-main">Bromine trifluoride</span> Chemical compound

Bromine trifluoride is an interhalogen compound with the formula BrF3. At room temperature, it is a straw-coloured liquid with a pungent odor which decomposes violently on contact with water and organic compounds. It is a powerful fluorinating agent and an ionizing inorganic solvent. It is used to produce uranium hexafluoride (UF6) in the processing and reprocessing of nuclear fuel.

<span class="mw-page-title-main">Bromine pentafluoride</span> Chemical compound

Bromine pentafluoride, BrF5, is an interhalogen compound and a fluoride of bromine. It is a strong fluorinating agent.

<span class="mw-page-title-main">Xenon hexafluoride</span> Chemical compound

Xenon hexafluoride is a noble gas compound with the formula XeF6. It is one of the three binary fluorides of xenon that have been studied experimentally, the other two being XeF2 and XeF4. All known are exergonic and stable at normal temperatures. XeF6 is the strongest fluorinating agent of the series. It is a colorless solid that readily sublimes into intensely yellow vapors.

An inorganic nonaqueous solvent is a solvent other than water, that is not an organic compound. These solvents are used in chemical research and industry for reactions that cannot occur in aqueous solutions or require a special environment. Inorganic nonaqueous solvents can be classified into two groups, protic solvents and aprotic solvents. Early studies on inorganic nonaqueous solvents evaluated ammonia, hydrogen fluoride, sulfuric acid, as well as more specialized solvents, hydrazine, and selenium oxychloride.

Bromine compounds are compounds containing the element bromine (Br). These compounds usually form the -1, +1, +3 and +5 oxidation states. Bromine is intermediate in reactivity between chlorine and iodine, and is one of the most reactive elements. Bond energies to bromine tend to be lower than those to chlorine but higher than those to iodine, and bromine is a weaker oxidising agent than chlorine but a stronger one than iodine. This can be seen from the standard electrode potentials of the X2/X couples (F, +2.866 V; Cl, +1.395 V; Br, +1.087 V; I, +0.615 V; At, approximately +0.3 V). Bromination often leads to higher oxidation states than iodination but lower or equal oxidation states to chlorination. Bromine tends to react with compounds including M–M, M–H, or M–C bonds to form M–Br bonds.

<span class="mw-page-title-main">Chloryl fluoride</span> Chemical compound

Chloryl fluoride is the chemical compound with the formula ClO2F. It is commonly encountered as side-product in reactions of chlorine fluorides with oxygen sources. It is the acyl fluoride of chloric acid.

<span class="mw-page-title-main">Bromous acid</span> Chemical compound

Bromous acid is the inorganic compound with the formula of HBrO2. It is an unstable compound, although salts of its conjugate base – bromites – have been isolated. In acidic solution, bromites decompose to bromine.

<span class="mw-page-title-main">Dichlorine hexoxide</span> Chemical compound

Dichlorine hexoxide is the chemical compound with the molecular formula Cl
2
O
6
, which is correct for its gaseous state. However, in liquid or solid form, this chlorine oxide ionizes into the dark red ionic compound chloryl perchlorate [ClO
2
]+
[ClO
4
]
, which may be thought of as the mixed anhydride of chloric and perchloric acids. This compound is a notable perchlorating agent.

<span class="mw-page-title-main">Bromine dioxide</span> Chemical compound

Bromine dioxide is the chemical compound composed of bromine and oxygen with the formula BrO2. It forms unstable yellow to yellow-orange crystals. It was first isolated by R. Schwarz and M. Schmeißer in 1937 and is hypothesized to be important in the atmospheric reaction of bromine with ozone. It is similar to chlorine dioxide, the dioxide of its halogen neighbor one period higher on the periodic table.

<span class="mw-page-title-main">Potassium hexafluoronickelate(IV)</span> Chemical compound

Potassium hexafluoronickelate(IV) is an inorganic compound with the chemical formula K
2
NiF
6
. It can be produced through the reaction of potassium fluoride, nickel dichloride, and fluorine.

In chemistry, molecular oxohalides (oxyhalides) are a group of chemical compounds in which both oxygen and halogen atoms are attached to another chemical element A in a single molecule. They have the general formula AOmXn, where X is a halogen. Known oxohalides have fluorine (F), chlorine (Cl), bromine (Br), and/or iodine (I) in their molecules. The element A may be a main group element, a transition element, a rare earth element or an actinide. The term oxohalide, or oxyhalide, may also refer to minerals and other crystalline substances with the same overall chemical formula, but having an ionic structure.

<span class="mw-page-title-main">Chlorine trifluoride oxide</span> Chemical compound

Chlorine oxide trifluoride or chlorine trifluoride oxide is a corrosive liquid molecular compound with formula ClOF3. It was developed secretly as a rocket fuel oxidiser.

<span class="mw-page-title-main">Protactinium(V) fluoride</span> Chemical compound

Protactinium(V) fluoride is a fluoride of protactinium with the chemical formula PaF5.

Neptunium compounds are compounds containing the element neptunium (Np). Neptunium has five ionic oxidation states ranging from +3 to +7 when forming chemical compounds, which can be simultaneously observed in solutions. It is the heaviest actinide that can lose all its valence electrons in a stable compound. The most stable state in solution is +5, but the valence +4 is preferred in solid neptunium compounds. Neptunium metal is very reactive. Ions of neptunium are prone to hydrolysis and formation of coordination compounds.

Bromosyl trifluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula BrOF3.

Pentafluoroselenium hypofluorite is a selenium compound with the chemical formula SeOF6. It was discovered at 1959.

References

  1. Christe, Karl O.; Curtis, E. C.; Jacob, Eberhard (1 October 1978). "Bromyl fluoride. Vibrational spectra, force field, and thermodynamic properties". Inorganic Chemistry . 17 (10): 2744–2749. doi:10.1021/ic50188a011. ISSN   0020-1669.
  2. Baran, Enrique J. (January 1976). "Vibrational Properties of Bromyl Fluoride". Spectroscopy Letters . 9 (6): 323–327. Bibcode:1976SpecL...9..323B. doi:10.1080/00387017608067443. ISSN   0038-7010.
  3. 1 2 Gillespie, Ronald J.; Spekkens, Paul H. (1 January 1977). "Bromyl fluoride and bromosyl trifluoride: preparation and chemical and spectroscopic properties". Journal of the Chemical Society, Dalton Transactions (16): 1539–1546. doi:10.1039/DT9770001539. ISSN   1364-5447.
  4. Seppelt, Konrad (19 December 2019). "Reactions of Bromine Fluoride Dioxide, BrO2F, for the Generation of the Mixed-Valent Bromine Oxygen Cations Br3O4+ and Br3O6+". Angewandte Chemie International Edition . 58 (52): 18928–18930. doi:10.1002/anie.201912271. ISSN   1433-7851. PMC   6973041 . PMID   31622009.