Bromyl fluoride

Last updated
Bromyl fluoride
Names
Other names
Bromine fluoride dioxide
Identifiers
3D model (JSmol)
PubChem CID
  • InChI=1S/BrFO2/c2-1(3)4
    Key: MQCDGGKZTTYBRJ-UHFFFAOYSA-N
  • O=Br(=O)F
Properties
BrFO2
Molar mass 130.900 g·mol−1
Appearancecolorless liquid
Melting point −9 °C (16 °F; 264 K)
reacts with water
Related compounds
Related compounds
Iodyl fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Bromyl fluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula BrO2F. [1] [2]

Contents

Synthesis

BrF5 + 2H2O → BrO2F + 4HF

Physical properties

The compound forms a colorless volatile liquid that decomposes at temperatures above 10°C. Corrodes glass at room temperature. Highly reactive and unstable. [4]

Chemical properties

3BrO2F → BrF3 + Br2 + 3O2
BrO2F + H2O → HBrO3 + HF
BrO2F + 2NaOH → NaBrO3 + NaF + H2O

Related Research Articles

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In chemistry, an interhalogen compound is a molecule which contains two or more different halogen atoms and no atoms of elements from any other group.

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<span class="mw-page-title-main">Oxygen fluoride</span> Any binary compound of oxygen and fluorine

Oxygen fluorides are compounds of elements oxygen and fluorine with the general formula OnF2, where n = 1 to 6. Many different oxygen fluorides are known:

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Bromine trifluoride is an interhalogen compound with the formula BrF3. At room temperature, it is a straw-coloured liquid with a pungent odor which decomposes violently on contact with water and organic compounds. It is a powerful fluorinating agent and an ionizing inorganic solvent. It is used to produce uranium hexafluoride (UF6) in the processing and reprocessing of nuclear fuel.

<span class="mw-page-title-main">Bromine pentafluoride</span> Chemical compound

Bromine pentafluoride, BrF5, is an interhalogen compound and a fluoride of bromine. It is a strong fluorinating agent.

<span class="mw-page-title-main">Xenon hexafluoride</span> Chemical compound

Xenon hexafluoride is a noble gas compound with the formula XeF6. It is one of the three binary fluorides of xenon that have been studied experimentally, the other two being XeF2 and XeF4. All known are exergonic and stable at normal temperatures. XeF6 is the strongest fluorinating agent of the series. It is a colorless solid that readily sublimes into intensely yellow vapors.

Bromine compounds are compounds containing the element bromine (Br). These compounds usually form the -1, +1, +3 and +5 oxidation states. Bromine is intermediate in reactivity between chlorine and iodine, and is one of the most reactive elements. Bond energies to bromine tend to be lower than those to chlorine but higher than those to iodine, and bromine is a weaker oxidising agent than chlorine but a stronger one than iodine. This can be seen from the standard electrode potentials of the X2/X couples (F, +2.866 V; Cl, +1.395 V; Br, +1.087 V; I, +0.615 V; At, approximately +0.3 V). Bromination often leads to higher oxidation states than iodination but lower or equal oxidation states to chlorination. Bromine tends to react with compounds including M–M, M–H, or M–C bonds to form M–Br bonds.

<span class="mw-page-title-main">Dioxygenyl</span> Chemical compound

The dioxygenyl ion, O+
2
, is a rarely-encountered oxycation in which both oxygen atoms have a formal oxidation state of +1/2. It is formally derived from oxygen by the removal of an electron:

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Bromous acid is the inorganic compound with the formula of HBrO2. It is an unstable compound, although salts of its conjugate base – bromites – have been isolated. In acidic solution, bromites decompose to bromine.

<span class="mw-page-title-main">Fluorine perchlorate</span> Chemical compound

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4
F
or FOClO
3
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2
O
6
, which is correct for its gaseous state. However, in liquid or solid form, this chlorine oxide ionizes into the dark red ionic compound chloryl perchlorate [ClO
2
]+
[ClO
4
]
, which may be thought of as the mixed anhydride of chloric and perchloric acids.

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2
NiF
6
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<span class="mw-page-title-main">Iodyl fluoride</span> Chemical compound

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References

  1. Christe, Karl O.; Curtis, E. C.; Jacob, Eberhard (1 October 1978). "Bromyl fluoride. Vibrational spectra, force field, and thermodynamic properties". Inorganic Chemistry . 17 (10): 2744–2749. doi:10.1021/ic50188a011. ISSN   0020-1669 . Retrieved 5 June 2023.
  2. Baran, Enrique J. (January 1976). "Vibrational Properties of Bromyl Fluoride". Spectroscopy Letters . 9 (6): 323–327. doi:10.1080/00387017608067443. ISSN   0038-7010 . Retrieved 5 June 2023.
  3. 1 2 Gillespie, Ronald J.; Spekkens, Paul H. (1 January 1977). "Bromyl fluoride and bromosyl trifluoride: preparation and chemical and spectroscopic properties". Journal of the Chemical Society, Dalton Transactions (16): 1539–1546. doi:10.1039/DT9770001539. ISSN   1364-5447 . Retrieved 5 June 2023.
  4. Seppelt, Konrad (19 December 2019). "Reactions of Bromine Fluoride Dioxide, BrO 2 F, for the Generation of the Mixed‐Valent Bromine Oxygen Cations Br 3 O 4 + and Br 3 O 6 +". Angewandte Chemie International Edition . 58 (52): 18928–18930. doi:10.1002/anie.201912271. ISSN   1433-7851. PMC   6973041 . Retrieved 5 June 2023.