Pertechnetyl fluoride

Last updated
Pertechnetyl fluoride
TcO3F.svg
Identifiers
3D model (JSmol)
  • InChI=1S/FH.3O.Tc/h1H;;;;/q;;;;+1/p-1
    Key: OYCMXSPACZPBDD-UHFFFAOYSA-M
  • O=[Tc](=O)(=O)F
Properties
TcO
3
F
Molar mass 165,00 g/mol
Appearanceyellow substance
Melting point 18.3 °C (64.9 °F; 291.4 K)
Boiling point 100 °C (212 °F; 373 K)
insoluble
Related compounds
Related compounds
Lanthanum oxyfluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Pertechnetyl fluoride is an inorganic compound, a salt of technetium and hydrofluoric acid with the chemical formula TcO
3
F
. The compound was originally synthesized by H. Selig and G. Malm in 1963. [1] [2]

Contents

Synthesis

Physical properties

The compound forms a yellow substance. [4]

Chemical properties

The compound can be hydrolyzed to produce pertechnetic acid and hydrofluoric acid.

It also reacts with arsenic pentafluoride or antimony pentafluoride. [5]

Related Research Articles

<span class="mw-page-title-main">Hydrofluoric acid</span> Solution of hydrogen fluoride in water

Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. It is used to make most fluorine-containing compounds; examples include the commonly used pharmaceutical antidepressant medication fluoxetine (Prozac) and the material PTFE (Teflon). Elemental fluorine is produced from it. It is commonly used to etch glass and silicon wafers.

The Brønsted–Lowry theory (also called proton theory of acids and bases) is an acid–base reaction theory which was first developed by Johannes Nicolaus Brønsted and Thomas Martin Lowry independently in 1923. The basic concept of this theory is that when an acid and a base react with each other, the acid forms its conjugate base, and the base forms its conjugate acid by exchange of a proton (the hydrogen cation, or H+). This theory generalises the Arrhenius theory.

<span class="mw-page-title-main">Potassium fluoride</span> Ionic compound (KF)

Potassium fluoride is the chemical compound with the formula KF. After hydrogen fluoride, KF is the primary source of the fluoride ion for applications in manufacturing and in chemistry. It is an alkali halide salt and occurs naturally as the rare mineral carobbiite. Solutions of KF will etch glass due to the formation of soluble fluorosilicates, although HF is more effective.

<span class="mw-page-title-main">Technetium(VII) oxide</span> Chemical compound

Technetium(VII) oxide is the chemical compound with the formula Tc2O7. This yellow volatile solid is a rare example of a molecular binary metal oxide, the other examples being RuO4, OsO4, and the unstable Mn2O7. It adopts a centrosymmetric corner-shared bi-tetrahedral structure in which the terminal and bridging Tc−O bonds are 167pm and 184 pm respectively and the Tc−O−Tc angle is 180°.

Iodine pentafluoride is an interhalogen compound with chemical formula IF5. It is one of the fluorides of iodine. It is a colorless liquid, although impure samples appear yellow. It is used as a fluorination reagent and even a solvent in specialized syntheses.

<span class="mw-page-title-main">Hydrogen fluoride</span> Chemical compound

Hydrogen fluoride (fluorane) is an inorganic compound with chemical formula HF. It is a very poisonous, colorless gas or liquid that dissolves in water to yield an aqueous solution termed hydrofluoric acid. It is the principal industrial source of fluorine, often in the form of hydrofluoric acid, and is an important feedstock in the preparation of many important compounds including pharmaceuticals and polymers, e.g. polytetrafluoroethylene (PTFE). HF is also widely used in the petrochemical industry as a component of superacids. Due to strong and extensive hydrogen bonding, it boils at near room temperature, much higher than other hydrogen halides.

<span class="mw-page-title-main">Technetium hexafluoride</span> Chemical compound

Technetium hexafluoride or technetium(VI) fluoride (TcF6) is a yellow inorganic compound with a low melting point. It was first identified in 1961. In this compound, technetium has an oxidation state of +6, the highest oxidation state found in the technetium halides. In this respect, technetium differs from rhenium, which forms a heptafluoride, ReF7. Technetium hexafluoride occurs as an impurity in uranium hexafluoride, as technetium is a fission product of uranium (spontaneous fission in natural uranium, possible contamination from induced fission inside the reactor in reprocessed uranium). The fact that the boiling point of the hexafluorides of uranium and technetium are very close to each other presents a problem in using fluoride volatility in nuclear reprocessing.

Osmium compounds are compounds containing the element osmium (Os). Osmium forms compounds with oxidation states ranging from −2 to +8. The most common oxidation states are +2, +3, +4, and +8. The +8 oxidation state is notable for being the highest attained by any chemical element aside from iridium's +9 and is encountered only in xenon, ruthenium, hassium, iridium, and plutonium. The oxidation states −1 and −2 represented by the two reactive compounds Na
2
[Os
4
(CO)
13
]
and Na
2
[Os(CO)
4
]
are used in the synthesis of osmium cluster compounds.

Technetium compounds are chemical compounds containing the chemical element technetium. Technetium can form multiple oxidation states, but often forms in the +4 and +7 oxidation states. Because technetium is radioactive, technetium compounds are extremely rare on Earth.

<span class="mw-page-title-main">Rhenium heptafluoride</span> Chemical compound

Rhenium heptafluoride is the compound with the formula ReF7. It is a yellow low melting solid and is the only thermally stable metal heptafluoride. It has a distorted pentagonal bipyramidal structure similar to IF7, which was confirmed by neutron diffraction at 1.5 K. The structure is non-rigid, as evidenced by electron diffraction studies.

<span class="mw-page-title-main">Fluorine perchlorate</span> Chemical compound

Fluorine perchlorate, also called perchloryl hypofluorite is the rarely encountered chemical compound of fluorine, chlorine, and oxygen with the chemical formula ClO
4
F
or FOClO
3
. It is an extremely unstable gas that explodes spontaneously and has a penetrating odor.

<span class="mw-page-title-main">Chromyl fluoride</span> Chemical compound

Chromyl fluoride is an inorganic compound with the formula CrO2F2. It is a violet-red colored crystalline solid that melts to an orange-red liquid.

<span class="mw-page-title-main">Vanadium pentafluoride</span> Chemical compound

Vanadium(V) fluoride is the inorganic compound with the chemical formula VF5. It is a colorless volatile liquid. It is a highly reactive compound, as indicated by its ability to fluorinate organic substances.

<span class="mw-page-title-main">Actinium(III) fluoride</span> Chemical compound

Actinium(III) fluoride (AcF3) is an inorganic compound, a salt of actinium and fluorine.

<span class="mw-page-title-main">Lutetium(III) fluoride</span> Chemical compound

Lutetium(III) fluoride is an inorganic compound with a chemical formula LuF3.

<span class="mw-page-title-main">Protactinium(V) fluoride</span> Chemical compound

Protactinium(V) fluoride is a fluoride of protactinium with the chemical formula PaF5.

Technetium pentaluoride is a binary inorganic chemical compound of technetium metal and fluorine with the chemical formula TcF
5
.

<span class="mw-page-title-main">Iodyl fluoride</span> Chemical compound

Iodyl fluoride is an inorganic compound of iodine, fluorine, and oxygen with the chemical formula IO2F. The compound was initially synthesized in 1951.

Perbromyl fluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula BrO3F.

<span class="mw-page-title-main">Manganese trioxide fluoride</span> Chemical compound

Manganese trioxide fluoride is an inorganic compound with the formula MnO3F. A green diamagnetic liquid, the compound has no applications, but it is of some academic interest as a rare example of a metal trioxide fluoride.

References

  1. Schmidbaur, Hubert; Schwarz, W. H. Eugen (21 April 2021). "Permanganyl Fluoride: A Brief History of the Molecule MnO 3 F and of Those Who Cared For It". Chemistry – A European Journal . 27 (23): 6848–6859. doi:10.1002/chem.202004759. ISSN   0947-6539. PMC   8247864 . PMID   33219726.
  2. Baran, Enrique J. (1 January 1975). "Vibrational Properties of Pertechnetyl Fluoride". Spectroscopy Letters . 8 (8): 599–603. doi:10.1080/00387017508067365. ISSN   0038-7010 . Retrieved 22 March 2023.
  3. Selig, H.; Malm, J. G. (1 April 1963). "The preparation and properties of pertechnetyl fluoride, TcO3F". Journal of Inorganic and Nuclear Chemistry . 25 (4): 349–351. doi:10.1016/0022-1902(63)80183-9. ISSN   0022-1902 . Retrieved 22 March 2023.
  4. Lawroski, Stephen (1963). "Research and development on nonaqueous processing". Reactor Fuel Processing. U.S. Argonne National Laboratory. 7 (1): 28. Retrieved 22 March 2023.
  5. Supeł, Joanna; Abram, Ulrich; Hagenbach, Adelheid; Seppelt, Konrad (1 July 2007). "Technetium Fluoride Trioxide, TcO 3 F, Preparation and Properties". Inorganic Chemistry . 46 (14): 5591–5595. doi:10.1021/ic070333y. ISSN   0020-1669. PMID   17547395 . Retrieved 22 March 2023.