Curium(III) fluoride

Last updated
Curium(III) fluoride
Kristallstruktur Lanthanfluorid.png
Crystal structure
Names
IUPAC name
Curium(III) fluoride
Other names
Curium trifluoride
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/Cm.3FH/h;3*1H/q+3;;;/p-3 Yes check.svgY
  • F[Cm](F)F
Properties
CmF3
AppearanceColorless solid [1]
Melting point 1406 ± 20 °C; [1]
~10 mg/L
Structure
Rhombohedral, hR24
P3c1, No. 165 [2]
a = 0.7012 nm, c = 0.7198 nm
0.30650
6
Thermochemistry
Std molar
entropy
(S298)
121 J/mol·K [1]
−1660 kJ/mol [1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Curium(III) fluoride or curium trifluoride is the chemical compound composed of curium and fluorine with the formula CmF3. [3] It is a white, nearly insoluble salt that has the same crystal structure as LaF3. It precipitates as a hydrate when fluoride ions are added to a weakly acidic Cm(III) solution; alternatively it can be synthesized by reacting hydrofluoric acid with Cm(OH)3. The anhydrous form is then obtained by desiccation or by treatment with hydrogen fluoride gas. [1]

Preparation

Curium fluoride can be prepared by in the reaction of curium with fluorine ions in an aqueous solution under weakly acidic conditions:

Another possible preparation is the reaction of curium hydroxide with hydrofluoric acid, which also produces a hydrate of Curium fluoride. [4]

Related Research Articles

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<span class="mw-page-title-main">Curium</span> Chemical element, symbol Cm and atomic number 96

Curium is a synthetic chemical element; it has symbol Cm and atomic number 96. This transuranic actinide element was named after eminent scientists Marie and Pierre Curie, both known for their research on radioactivity. Curium was first intentionally made by the team of Glenn T. Seaborg, Ralph A. James, and Albert Ghiorso in 1944, using the cyclotron at Berkeley. They bombarded the newly discovered element plutonium with alpha particles. This was then sent to the Metallurgical Laboratory at University of Chicago where a tiny sample of curium was eventually separated and identified. The discovery was kept secret until after the end of World War II. The news was released to the public in November 1947. Most curium is produced by bombarding uranium or plutonium with neutrons in nuclear reactors – one tonne of spent nuclear fuel contains ~20 grams of curium.

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<span class="mw-page-title-main">Mendelevium</span> Chemical element, symbol Md and atomic number 101

Mendelevium is a synthetic chemical element; it has symbol Md and atomic number 101. A metallic radioactive transuranium element in the actinide series, it is the first element by atomic number that currently cannot be produced in macroscopic quantities by neutron bombardment of lighter elements. It is the third-to-last actinide and the ninth transuranic element. It can only be produced in particle accelerators by bombarding lighter elements with charged particles. Seventeen isotopes are known; the most stable is 258Md with half-life 51 days; however, the shorter-lived 256Md is most commonly used in chemistry because it can be produced on a larger scale.

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<span class="mw-page-title-main">Berkelium compounds</span> Chemical compounds

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Curium(III) nitrate is an inorganic compound, a salt of curium and nitric acid with the chemical formula Cm(NO3)3.

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<span class="mw-page-title-main">Plutonium pentafluoride</span> Chemical compound

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<span class="mw-page-title-main">Curium(IV) fluoride</span> Chemical compound

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References

  1. 1 2 3 4 5 Haire, Richard G. (2006). "Curium (9.7.3 Halides)". In Morss; Edelstein, Norman M.; Fuger, Jean (eds.). The Chemistry of the Actinide and Transactinide Elements (3rd ed.). Dordrecht, The Netherlands: Springer Science+Business Media. p.  1417. doi:10.1007/1-4020-3598-5_9. ISBN   1-4020-3555-1.
  2. Nave, S. E.; Haire, R. G.; Huray, Paul G. (1983). "Magnetic properties of actinide elements having the 5f6 and 5f7 electronic configurations". Physical Review B. 28 (5): 2317. doi:10.1103/PhysRevB.28.2317.
  3. Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 3046. ISBN   978-0-412-30120-9 . Retrieved 27 June 2023.
  4. Lumetta, Gregg J.; Thompson, Major C.; Penneman, Robert A.; Eller, P. Gary (2006). Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean (eds.). Curium. Dordrecht: Springer Netherlands. pp. 1397–1443. doi:10.1007/1-4020-3598-5_9. ISBN   978-1-4020-3598-2.