Borate fluoride

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The borate fluorides or fluoroborates are compounds containing borate or complex borate ions along with fluoride ions that form salts with cations such as metals. They are in the broader category of mixed anion compounds. They are not to be confused with tetrafluoroborates (BF4) or the fluorooxoborates which have fluorine bonded to boron.

Examples

formulanamemwsystemspace groupunit cell Åvolume Å3densitycommentreferences
Be2(BO3)(OH,F) · H2O Berborite trigonalP3a = 4.434, c = 5.33490.82colourless

Uniaxial (-) nω = 1.580 nε = 1.485

Max birefringence δ = 0.095

[1]

γ-Be2BO3Fγ-BBF95.83trigonalR32a=4.4418 c=19.909 Z=3340.171.946Uniaxial (-) SHG 2.3 × KDP
NH4Be2BO3F2ABBF132.87trigonalR32a=4.4398 c=12.4697 Z=3212.872.243Uniaxial (-) no=1.49389 ne=1.41919 at 636 nm [2]
NaBe2BO3F2 sodium beryllium borate fluoride (NBBF)C2a=12.643 b=8.729 c=7.591 β=113.6°768double layers of borate rings sandwiching barium atoms. Between pairs of double layers are sodium ions with fluoride. [3]
Mg2(BO3)(F,OH) Pertsevite-(F)orthorhombicPna21a = 20.49, b = 4.571, c = 11.89 Z=161,113.6Density 3.12

transparent

Biaxial (+) nα = 1.609 nβ = 1.620 nγ = 1.642

2V: 65°

Max birefringence: δ = 0.033

 [4]
Mg3(BO3)(F,OH)3 Fluoborite hexagonala = 8.8, c = 3.1208colourless

Uniaxial (-) nω = 1.570 nε = 1.534

Max birefringence δ = 0.036

 [5]
Mg3(OH)[B(OH)4]2(SO4)F sulfoborite orthorhombicPnmaa=10.132 b=12.537 c=7.775987.6Biaxial (-) nα = 1.527 nβ = 1.536 nγ = 1.551

2V 79°

Max birefringence δ = 0.024

 [6]
Na6Mg3B10O18F6monoclinicP21/ca=13.420 b=6.400 c=10.701 β=90.693°band gap 5.40 eV; birefringence Δn = 0.039 at 1064 nm [7]
NaMgBe2(BO3)2FNMBBFP3c1a=4.5408 c=13.439birefringence 0.081 at 546.1 nm [8]
Al6(BO3)5F3

Jeremejevite

hexagonal

P63/m

a = 8.5591, c = 8.1814

519

density 3.28

Uniaxial (-) nω = 1.653 nε = 1.640

Max birefringence δ = 0.013

 [9] [10]
Al8(BO3)4(B2O5)F8704.7tetragonalP42/mmca=9.134 c=19.112 Z=41,595density 2.935 colourless [9]
Na(Mg3)Al6(Si6O18)(BO3)3(OH)3F Fluor-dravite trigonalR3ma = 15.955, c = 7.153 Z=31,577density 3.120

dark brown

Uniaxial (-) nω = 1.645(2) nε = 1.621(2)

Max birefringence δ = 0.024

 [11]
Na(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3F Fluor-elbaite trigonalR3ma = 15.8933, c = 7.12221,558blue green

Uniaxial (-)

 [12]
K6B12O19F4744.32orthorhombicPnmaa =15.291 b =7.707 c =8.672 Z=21022.02.419 [13]
KBe2BO3F2 KBBF hexagonalR32a=4.427 c=18.744318.32.40Be2BO6F2 rings SHG 1.2 × KDP; UV cutoff 147 nm [14]
Ca5(BO3)3F [15]
Li3CaB2O5F363.04orthorhombicPnmaa=25.685 b=3.4697 c=5.4404 Z=2484.842.487colourless [16]
Li5Ca9(BO3)7F2P1
NaCaBe2B2O6F [17]
KCaBe2B2O6F467.64P3_1ca=4.705 c=14.554 Z=2279.12.783 [18]
Ca(Li2Al)Al6(Si6O18)(BO3)3(OH)3F Fluor-liddicoatite trigonalR3ma = 15.875, c = 7.126 Z=31,555density 3.02

Uniaxial (-) nω = 1.637 nε = 1.621

Max birefringence δ = 0.016

 [19]
CaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3F Fluor-uvite trigonalR3ma = 15.954, c = 7.214 Z=31,590black

Uniaxial nω = 1.637 - 1.668 nε = 1.619 - 1.639

Max birefringence δ = 0.018 - 0.029

 [20]
KCaBe2B2O6F
Sc2F2(B2O5)229.54orthorhombicPbama=9.667 b=14.199 c=4.0395 Z=4554.42.750colourless [21]
K11Sc5(B5O10)4F6orthorhombicFdd2a 56.769 b 12.207 c 12.6088transparent to <190 nm [22]
Na(Mn2+)3Al6(Si6O18)(BO3)3(OH)3F Fluor-tsilaisite trigonalR3ma = 15.9398, c = 7.13631,570greenish yellow

Uniaxial (-)

 [23]
NaFe3Al6Si6B3O30F [9]
Na(Fe2+3)Al6(Si6O18)(BO3)3(OH)3F Fluor-schorl trigonalR3ma = 16.005, c = 7.176 Z=31,591.9black

Uniaxial (-) nω = 1.660 - 1.661 nε = 1.636 - 1.637

Max birefringence δ = 0.024

 [24]
Na(Fe3+3)Al6(Si6O18)(BO3)3O3F Fluor-buergerite trigonalR3ma = 15.8692, c = 7.18821,568density 3.311

brown

Uniaxial (-) nω = 1.735 nε = 1.655

Birefringence 0.080

 [25]
Ca(Fe2+)3MgAl5(Si6O18)(BO3)3(OH)3F Fluor-feruvite [26]
KCaZn2(BO3)2F
Li6RbB2O6F263.73orthorhombicPnmaa=8.41 b=15.96 c=5.08 Z=26822.568 [27]
RbBe2BO3F2RBBFTrigonalR32a=4.434 c=19.758 z=3also contains BeO3F tetrahedra and BO3. It transmits radiation from 180 to 3500 nm. [28]
Rb18Mg6(B5O10)3(B7O14)2FmonoclinicC2/ca=11.06 b=19.70 c=31.01 β=90.13° [29]
RbCaBe2B2O6FTrigonalR32 [30]
KSrBe2B2O6F [17]
LiSr3Be3B3O9F4 [31]
NaSr3Be3B3O9F4 [32]
K3Sr3Li2Al4B6O20FSHG 4 × KDP; 170 nm UV cutoff [9]
Ca(Y,REE,Ca,Na,Mn)15Fe2+(P,Si)Si6B3O34F14 Proshchenkoite-(Y) trigonalR3ma = 10.7527, c = 27.40022,743.6brownish [33]
(Y,REE,Ca,Na)15(Al,Fe3+)(CaxAs3+1−x)(Si,As5+)Si6B3(O,F)48 Hundholmenite-(Y) trigonalR3ma = 10.675, c = 27.02 Z=32,667density 5.206

brownish

Uniaxial (-)

 [34]
(Na,Ca)3(Y,Ce)12Si6B2O27F14 Okanoganite-(Y) trigonalR3ma = 10.7108, c = 27.0404.35Tan coloured

Uniaxial (-) nω = 1.753 nε = 1.740

Max birefringence δ = 0.013

 [35]
? Y5(SiO4,BO4)3(O,OH,F) Tritomite-(Y) ?hexagonala = 9.32, c = 6.843.05-3.4isotropic

n = 1.627 - 1.685

Cd8B5O15F1212.25cubicFd3ma = 13.972 Z = 82,7275.904colourless [36]
CdZn2KB2O6F
Li3Cs6Al2B14O28F1490.58orthorhombicPnmaa=21.8412 b=19.8875 c=7.1577 Z=43109.13.184 [37]
CsBe2BO3F2247.74trigonalR32a=4.4575 c=21.310 Z=3366.73.366colourless [38]
Cs18Mg6(B5O10)3(B7O14)2FmonoclinicC2/ca=11.234 b=20.11 c=32.12 β=90.225° [29]
CsCaBe2B2O6FtrigonalR32 [39]
BaBOF3221.15monoclinicP21/ca = 4.620 b = 15.186 c = 4.426 β = 92.045° Z=4310.3contains chains of -OB(F2)- and a double chain of BaF [40]
Ba5(BO3)3F [41]
Li2BaSc(BO3)2F332.80hexagonalP63/ma=4.895 c=14.346297.73.713 [42]
LiBa12(BO3)7F4I4/mcm
BaBe2BO3F3271.16hexagonalP63a=7.628 c=13.990 Z=6704.93.832UV cutoff <185 nm; birefringence 0,081 at 200 nm [43]
NaBa12(BO3)7F4I4/mcm
BaMgBe2(BO3)2F2BMBBF335.283trigonalP3c1a=4.5898 c=15.348280.013.976colourless [Be2B3O6F2]∞ [44]
Ba3.75MgB7O14F2.5886.50monoclinicC2/ca 16.611 b 13.677 c 15.141 β 121.239° Z=82941.04.004transparent > 203 nm; birefringence 0.081@546 nm [45]
BaAl(BO3)F2hexagonalP6a=4.8879 c=9.403 Z=2194.5UV cutoff 165 nm [46]
K3Ba3Li2Al4B6O20F [9]
K5Ba10(BO3)8FtrigonalR3ca = 15.293, c = 22.699 Z = 6 [47]
KBa7Mg2B14O28F5monoclinicC2/ca = 16.638 b = 13.609 c = 15.214 β = 121.309° Z=42943.33.934colourless [48]
BaCaBe2(BO3)2F2BCBBFtrigonalP3c1a=4.6931 c=16.049306.123.808colourless [Be2B3O6F2]∞ [44]
Li2BaSc(BO3)2FhexagonalP63/ma=4.895 c=14.346 [49]
Ba3Zn(BO3)(B2O5)F656.82monoclinicP21/ca = 15.179 b = 7.0064 c = 8.763 β = 100.15° Z=4917.44.755colourless [50]
Ba4Zn2(BO3)2(B2O5)F2937.34monoclinicC2/ca=20.39 b=4.998 c=13.068 β = 192.59 Z=441,3314.679colourless [50]
BaZnBe2(BO3)2F2376.35trigonalP3a = 4.5998, c = 7.7037 Z = 1141.164.427colourless [51]
Rb3Ba3Li2Al4B6O20F [9]
BaCdBe2(BO3)2F2BDBBFP3c1a=4.6808 c=15.788 [8]
Ba1.09Pb0.91Be2(BO3)2F2BPBBFtrigonalP3m1a = 4.7478 c = 8.386, Z = 1163.70UV absorption edge=279.1 nm; birefringence 0.054 at 546.1 nm; 2D [Be3B3O6F3]∞ layer [52]
LiBa2Pb(BO3)2ForthorhombicPmmna=5.487 b=15.96 c=4.034 [49]
KNa3Na6Ca2Ba6Mn6(Ti4+,Nb)6B12Si36O114(O,OH,F)11 Tienshanite hexagonalP6/ma = 16.785, c = 10.454 Z=12,551pale olive green

Uniaxial (-) nω = 1.666 nε = 1.653

Max birefringence δ = 0.013

 [53]
Ca6(Fe2+,Mn2+)Y3REE7(SiO4)3(PO4)(B3Si3O18)(BO3)F11 Laptevite-(Ce) trigonalR3ma = 10.804, c = 27.726 Z=32,803density 4.61

dark brown

Uniaxial (-) nω = 1.741(3) nε = 1.720(3)

Max birefringence δ = 0.021

 [54]
Ba(Y,Ce)6Si3B6O24F2 Cappelenite-(Y) trigonalP3a = 10.67, c = 4.68 Z=14614.407greenish brown [55]
CaMg[(Ce7Y3)Ca5](SiO4)4(Si2B3AsO18)(BO3)F11 Arrheniusite-(Ce) trigonalR3ma = 10.8082, c = 27.5196 [56]
Gd4(BO2)O5ForthorhombicPmmna=15.746 b=3.8142 c=6.609 Z=2396.96.45colourless [57]
Gd2(BO3)F3
Gd3(BO3)2F3
Gd4[B4O11]F2
Ba2Gd(BO3)2ForthorhombicPnmaa = 7.571 b = 10.424 c = 8.581 Z = 2 [58]
Eu5(BO3)3ForthorhombicPnmaa=7.225 b=14.124 c=9.859 Z=41006.16.306yellow [59]
TlBe2BO3F2TrigonalR32a=4.4387 c=19.942 Z=3340.274.673colourless [60]
LiBa2Pb(BO3)2ForthorhombicPmmna=5.487 b=15.97 c=4.034353.45.887colourless [61]
(Ca,Ce,La,Th)15As5+(As3+0.5,Na0.5)Fe3+Si6B4O40F7 Vicanite-(Ce) trigonalR3ma=10.881 c=27.332,7664.82greenish yellow

Uniaxial (-) nω = 1.757 nε = 1.722

Max birefringence δ = 0.035

 [62]

References

  1. ↑ "Berborite". www.mindat.org. Retrieved 2020-12-15.
  2. ↑ Peng, Guang; Ye, Ning; Lin, Zheshuai; Kang, Lei; Pan, Shilie; Zhang, Min; Lin, Chensheng; Long, Xifa; Luo, Min; Chen, Yu; Tang, Yu-Huan (2018-07-16). "NH 4 Be 2 BO 3 F 2 and γ-Be 2 BO 3 F: Overcoming the Layering Habit in KBe 2 BO 3 F 2 for the Next-Generation Deep-Ultraviolet Nonlinear Optical Materials". Angewandte Chemie. 130 (29): 9106–9110. Bibcode:2018AngCh.130.9106P. doi:10.1002/ange.201803721. S2CID   242082788.
  3. ↑ Mei, Linfeng; Wang, Yebin; Chen, Chunagtian (January 1994). "Crystal structure of sodium beryllium borate fluoride". Materials Research Bulletin. 29 (1): 81–87. doi:10.1016/0025-5408(94)90108-2.
  4. ↑ "Pertsevite-(F)". www.mindat.org. Retrieved 2020-12-14.
  5. ↑ "Fluoborite". www.mindat.org. Retrieved 2020-12-14.
  6. ↑ "Sulfoborite". www.mindat.org. Retrieved 2020-12-15.
  7. ↑ Cheng, Bingliang; Ma, Wenjuan; Tudi, Abudukadi; Liu, Changyou; Long, Xifa; Yang, Yun (2023-07-26). "Introduction of the [B–O/F] Units Enhances the Band Gap and Birefringence from Na 6 Mg 3 B 10 O 18 F 6 to K 3 NaB 10 O 16 F 2". Inorganic Chemistry. 62 (31): 12187–12191. doi:10.1021/acs.inorgchem.3c01954. ISSN   0020-1669. PMID   37494127. S2CID   260200530.
  8. 1 2 Guo, Ruixin; Jiang, Xingxing; Guo, Shu; Xia, Mingjun; Liu, Lijuan; Lin, Zheshuai; Wang, Xiaoyang (2022-05-16). "Realization of Enlarged Birefringence from BaCdBe 2 (BO 3 ) 2 F 2 to NaMgBe 2 (BO 3 ) 2 F via the Cation Size Effect as a Potential Deep-Ultraviolet Birefringent Material". Inorganic Chemistry. 61 (19): 7624–7630. doi:10.1021/acs.inorgchem.2c00880. ISSN   0020-1669. PMID   35500273.
  9. 1 2 3 4 5 6 Wang, Ya; Han, Jian; Huang, Junben; Yang, Zhihua; Pan, Shilie (2020-01-06). "Al 8 (BO 3 ) 4 (B 2 O 5 )F 8 : A F-Containing Aluminum Borate Featuring Two Types of Isolated B–O Groups". Inorganic Chemistry. 59 (1): 810–817. doi:10.1021/acs.inorgchem.9b03067. ISSN   0020-1669. PMID   31877030. S2CID   209489879.
  10. ↑ "Jeremejevite". www.mindat.org. Retrieved 2020-12-14.
  11. ↑ "Fluor-dravite". www.mindat.org. Retrieved 2020-12-15.
  12. ↑ "Fluor-elbaite". www.mindat.org. Retrieved 2020-12-15.
  13. ↑ Huang, Shuzhao; Zhu, Liang; Kruglov, Ivan; Yang, Yun; Yang, Zhihua; Pan, Shilie (2023-05-09). "Two Ultraviolet Optical Crystals K 6 B 12 O 19 F 4 and K 12 B 28 O 48 : The Effects of Metal Cations Size and the F Ions on the Structure". Inorganic Chemistry. 62 (20): 7599–7604. doi:10.1021/acs.inorgchem.3c00519. ISSN   0020-1669. PMID   37158437. S2CID   258567100.
  14. ↑ Mei, L.; Huang, X.; Wang, Y.; Wu, Q.; Wu, B.; Chen, C. (January 1995). "Crystal structure of KBe 2 BO 3 F 2". Zeitschrift für Kristallographie. 210 (2): 93–95. Bibcode:1995ZK....210...93M. doi:10.1524/zkri.1995.210.2.93. ISSN   0044-2968.
  15. ↑ Xiao, Xue; Li, Zhongliang; Zou, Haifeng; Sun, Qi; Song, Yanhua; Tao, Qianyu; Li, Liang; Zou, Bo (2024-03-01). "Synthesis Design and Properties of Ca 5 (BO 3 ) 3 F: Bi 3+ /Eu 3+ : Insight into Luminescence, Temperature, and Pressure Sensing". Inorganic Chemistry. 63 (11): 5175–5184. doi:10.1021/acs.inorgchem.4c00133. ISSN   0020-1669. PMID   38427020.
  16. ↑ Ding, Mengmeng; Xu, JingJing; Wu, Hongping; Yu, Hongwei; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng (2020). "Li 3 CaB 2 O 5 F: a unique sandwich-like structure with diverse and wide Li ion diffusion pathways". Dalton Transactions. 49 (35): 12184–12188. doi:10.1039/D0DT02423F. ISSN   1477-9226. PMID   32930685. S2CID   221723666.
  17. 1 2 Huang, Hongwei; Yao, Jiyong; Lin, Zheshuai; Wang, Xiaoyang; He, Ran; Yao, Wenjiao; Zhai, Naixia; Chen, Chuangtian (2011-12-27). "Molecular Engineering Design to Resolve the Layering Habit and Polymorphism Problems in Deep UV NLO Crystals: New Structures in MM′Be 2 B 2 O 6 F (M═Na, M′═Ca; M═ K, M′═Ca, Sr)". Chemistry of Materials. 23 (24): 5457–5463. doi:10.1021/cm202870q. ISSN   0897-4756.
  18. ↑ Huang, Hongwei; Yao, Jiyong; Lin, Zheshuai; Wang, Xiaoyang; He, Ran; Yao, Wenjiao; Zhai, Naixia; Chen, Chuangtian (2011-12-27). "Molecular Engineering Design to Resolve the Layering Habit and Polymorphism Problems in Deep UV NLO Crystals: New Structures in MM′Be 2 B 2 O 6 F (M═Na, M′═Ca; M═ K, M′═Ca, Sr)". Chemistry of Materials. 23 (24): 5457–5463. doi:10.1021/cm202870q. ISSN   0897-4756.
  19. ↑ "Fluor-liddicoatite". www.mindat.org. Retrieved 2020-12-15.
  20. ↑ "Fluor-uvite". www.mindat.org. Retrieved 2020-12-15.
  21. ↑ Tang, Ru-Ling; Xu, Wei; Xie, Wei-Jie; Hu, Chun-Li (2022). "Sc 2 F 2 (B 2 O 5 ): a deep ultraviolet scandium borate fluoride exhibiting large birefringence induced by the synergistic effect of B 2 O 5 and ScO n F 2 groups". Inorganic Chemistry Frontiers. 9 (20): 5153–5160. doi:10.1039/D2QI01484J. ISSN   2052-1553. S2CID   251431496.
  22. ↑ Zhang, Qianzhen; An, Ran; Tudi, Abudukadi; Yang, Zhihua; Long, Xifa; Yang, Yun (2023-09-04). "Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge". Inorganic Chemistry. 62 (37): 15206–15214. doi:10.1021/acs.inorgchem.3c02367. ISSN   0020-1669. PMID   37665686. S2CID   261527346.
  23. ↑ "Fluor-tsilaisite". www.mindat.org. Retrieved 2020-12-15.
  24. ↑ "Fluor-schorl". www.mindat.org. Retrieved 2020-12-15.
  25. ↑ "Fluor-buergerite". www.mindat.org. Retrieved 2020-12-15.
  26. ↑ "Fluor-feruvite". www.mindat.org. Retrieved 2020-12-15.
  27. ↑ Wu, Hongping; Yu, Hongwei; Bian, Qiang; Yang, Zhihua; Han, Shujuan; Pan, Shilie (2014-12-15). "Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method". Inorganic Chemistry. 53 (24): 12686–12688. doi:10.1021/ic502625b. ISSN   0020-1669. PMID   25437774.
  28. ↑ Chen, Chuangtian; Luo, Siyang; Wang, Xiaoyang; Wang, Guiling; Wen, Xiaohong; Wu, Huaxing; Zhang, Xin; Xu, Zuyan (8 July 2009). "Deep UV nonlinear optical crystal:RbBe_2(BO_3)F_2". Journal of the Optical Society of America B. 26 (8): 1519. Bibcode:2009JOSAB..26.1519C. doi:10.1364/JOSAB.26.001519.
  29. 1 2 Wang, Zheng; Zhang, Min; Su, Xin; Pan, Shilie; Yang, Zhihua; Zhang, Hui; Liu, Lu (2015-01-19). "Q 18 Mg 6 (B 5 O 10 ) 3 (B 7 O 14 ) 2 F (Q=Rb and Cs): New Borates Containing Two Large Isolated Polyborate Anions with Similar Topological Structures". Chemistry - A European Journal. 21 (4): 1414–1419. doi:10.1002/chem.201404738. PMID   25414057.
  30. ↑ Liu, Lili; Yang, Yun; Jing, Qun; Dong, Xiaoyu; Yang, Zhihua; Pan, Shilie; Wu, Kui (2016-08-25). "K 5 Ba 10 (BO 3 ) 8 F: A New Potassium Barium Borate Fluoride with a Perovskite-Like Structure". The Journal of Physical Chemistry C. 120 (33): 18763–18770. doi:10.1021/acs.jpcc.6b05489. ISSN   1932-7447.
  31. ↑ Guo, Ruixin; Bai, Lei; Wu, Tong; Fan, Feidi; Liu, Lijuan; Wang, Xiaoyang (January 2023). "Growth and characterizations of a new nonlinear optical crystal for 266 nm laser generation: LiSr3Be3B3O9F4". Journal of Crystal Growth. 602: 126971. Bibcode:2023JCrGr.60226971G. doi:10.1016/j.jcrysgro.2022.126971.
  32. ↑ Liu, Lijuan; Wang, Lirong; Guo, Ruixin; Hou, Zhanyu; Fang, Zhi; Wang, Xiaoyang (July 2020). "NaSr3Be3B3O9F4 crystal growth and fourth harmonic generation at 266 nm". Journal of Crystal Growth. 542: 125689. Bibcode:2020JCrGr.54225689L. doi:10.1016/j.jcrysgro.2020.125689. S2CID   219020372.
  33. ↑ "Proshchenkoite-(Y)". www.mindat.org. Retrieved 2020-12-14.
  34. ↑ "Hundholmenite-(Y)". www.mindat.org. Retrieved 2020-12-14.
  35. ↑ "Okanoganite-(Y)". www.mindat.org. Retrieved 2020-12-14.
  36. ↑ Yang, Yun; Dong, Xiaoyu; Pan, Shilie (2016). "New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method". Dalton Transactions. 45 (16): 7008–7013. doi:10.1039/C6DT00621C. ISSN   1477-9226. PMID   26988597.
  37. ↑ Li, Xingqi; Chu, Dongdong; Jin, Wenqi; Yang, Zhihua; Pan, Shilie; Mutailipu, Miriding (2022-08-08). "Rearrangement of [B 2 O 5 ] Dimers within [B 7 O 14 ] Clusters Enables Enhanced Optical Anisotropy in Li 3 Cs 6 Al 2 B 14 O 28 F". Inorganic Chemistry. 61 (31): 12067–12072. doi:10.1021/acs.inorgchem.2c02347. ISSN   0020-1669. PMID   35894746. S2CID   251102413.
  38. ↑ McMillen, Colin D.; Hu, Jia; VanDerveer, Donald; Kolis, Joseph W. (2009-08-01). "Trigonal structures of A Be 2 BO 3 F 2 ( A = Rb, Cs, Tl) crystals". Acta Crystallographica Section B Structural Science. 65 (4): 445–449. doi:10.1107/S0108768109024161. ISSN   0108-7681. PMID   19617679.
  39. ↑ Liu, Lili; Yang, Yun; Jing, Qun; Dong, Xiaoyu; Yang, Zhihua; Pan, Shilie; Wu, Kui (2016-08-25). "K 5 Ba 10 (BO 3 ) 8 F: A New Potassium Barium Borate Fluoride with a Perovskite-Like Structure". The Journal of Physical Chemistry C. 120 (33): 18763–18770. doi:10.1021/acs.jpcc.6b05489. ISSN   1932-7447.
  40. ↑ Jiang, Dequan; Wang, Ying; Li, Hao; Yang, Zhihua; Pan, Shilie (2018). "BaBOF3 : a new aurivillius-like borate containing two types of F atoms". Dalton Transactions. 47 (15): 5157–5160. doi:10.1039/C8DT00403J. PMID   29557465.
  41. ↑ Rashchenko, Sergey V.; Bekker, Tatyana B.; Bakakin, Vladimir V.; Seryotkin, Yurii V.; Kokh, Alexander E.; Gille, Peter; Popov, Arthur I.; Fedorov, Pavel P. (4 July 2013). "A new mechanism of anionic substitution in fluoride borates". Journal of Applied Crystallography. 46 (4): 1081–1084. doi:10.1107/S0021889813015756.
  42. ↑ Chen, Yanna; Zhang, Min; Hu, Cong; Wu, Hongping; Yang, Zhihua; Pan, Shilie (2018-10-17). "Li 2 BaSc(BO 3 ) 2 F and LiBa 2 Pb(BO 3 ) 2 F with Layered Structures featuring Special Li−O/F Configurations". Chemistry - A European Journal. 24 (58): 15477–15481. doi:10.1002/chem.201804126. PMID   30230058.
  43. ↑ Guo, Shu; Jiang, Xingxing; Liu, Lijuan; Xia, Mingjun; Fang, Zhi; Wang, Xiaoyang; Lin, Zheshuai; Chen, Chuangtian (2016-12-27). "BaBe 2 BO 3 F 3 : A KBBF-Type Deep-Ultraviolet Nonlinear Optical Material with Reinforced [Be 2 BO 3 F 2 ] ∞ Layers and Short Phase-Matching Wavelength". Chemistry of Materials. 28 (24): 8871–8875. doi:10.1021/acs.chemmater.6b04403. ISSN   0897-4756.
  44. 1 2 Guo, Shu; Jiang, Xingxing; Xia, Mingjun; Liu, Lijuan; Fang, Zhi; Huang, Qian; Wu, Ruofei; Wang, Xiaoyang; Lin, Zheshuai; Chen, Chuangtian (2017-10-02). "Structural Design of Two Fluorine–Beryllium Borates BaMBe2(BO3)2F2 (M = Mg, Ca) Containing Flexible Two-Dimensional [Be3B3O6F3]∞ Single Layers without Structural Instability Problems". Inorganic Chemistry. 56 (19): 11451–11454. doi:10.1021/acs.inorgchem.7b01627. ISSN   0020-1669. PMID   28885824.
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  49. 1 2 Chen, Yanna; Zhang, Min; Hu, Cong; Wu, Hongping; Yang, Zhihua; Pan, Shilie (2018-10-17). "Li 2 BaSc(BO 3 ) 2 F and LiBa 2 Pb(BO 3 ) 2 F with Layered Structures featuring Special Li−O/F Configurations". Chemistry – A European Journal. 24 (58): 15477–15481. doi:10.1002/chem.201804126. ISSN   0947-6539. PMID   30230058. S2CID   52294586.
  50. 1 2 Mutailipu, Miriding; Su, Xin; Zhang, Min; Yang, Zhihua; Pan, Shilie (2017). "Ba n+2 Zn n (BO 3 ) n (B 2 O 5 )F n (n = 1, 2): new members of the zincoborate fluoride series with two kinds of isolated B–O units". Inorganic Chemistry Frontiers. 4 (2): 281–288. doi:10.1039/C6QI00467A. ISSN   2052-1553.
  51. ↑ Guo, Ruixin; Liu, Xiaomeng; Tao, Ce; Tang, Changcheng; Xia, Mingjun; Liu, Lijuan; Lin, Zheshuai; Wang, Xiaoyang (2021). "BaZnBe 2 (BO 3 ) 2 F 2 : a novel zinc-beryllium borate with SBBO-type structure overcoming the polymorphism problem". Dalton Transactions. 50 (6): 2138–2142. doi:10.1039/D0DT04153J. ISSN   1477-9226. PMID   33491694. S2CID   231701941.
  52. ↑ Guo, Ruixin; Guo, Shu; Xia, Mingjun; Liu, Lijuan; Li, Minjuan; Zhao, Sangen; Wang, Xiaoyang (2023-02-20). "Ba 1.09 Pb 0.91 Be 2 (BO 3 ) 2 F 2 : The First Pb-Containing Beryllium Borate Fluoride with Trigonal Prismatic PbO 6 and 2D [Be 3 B 3 O 6 F 3 ] ∞ Layers". Inorganic Chemistry. 62 (9): 3860–3865. doi:10.1021/acs.inorgchem.2c04122. ISSN   0020-1669. PMID   36802565. S2CID   257067883.
  53. ↑ "Tienshanite". www.mindat.org. Retrieved 2020-12-14.
  54. ↑ "Laptevite-(Ce)". www.mindat.org. Retrieved 2020-12-14.
  55. ↑ "Cappelenite-(Y)". www.mindat.org. Retrieved 2020-12-14.
  56. ↑ "Arrheniusite-(Ce)". www.mindat.org. Retrieved 2020-12-14.
  57. ↑ Höppe, Henning A. (1 November 2015). "Gd4(BO2)O5F – a gadolinium borate fluoride oxide comprising a linear BO2 moiety". Zeitschrift für Naturforschung B. 70 (11): 769–774. doi:10.1515/znb-2015-0112. S2CID   197372271.
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  59. ↑ Kazmierczak, Karolina; Höppe, Henning A. (June 2010). "Synthesis, Crystal Structure and Optical Spectra of Europium Borate Fluoride Eu5(BO3)3F". European Journal of Inorganic Chemistry. 2010 (18): 2678–2681. doi:10.1002/ejic.201000105.
  60. ↑ McMillen, Colin D.; Hu, Jia; VanDerveer, Donald; Kolis, Joseph W. (2009-08-01). "Trigonal structures of A Be 2 BO 3 F 2 ( A = Rb, Cs, Tl) crystals". Acta Crystallographica Section B Structural Science. 65 (4): 445–449. doi:10.1107/S0108768109024161. ISSN   0108-7681. PMID   19617679.
  61. ↑ Chen, Yanna; Zhang, Min; Hu, Cong; Wu, Hongping; Yang, Zhihua; Pan, Shilie (2018-10-17). "Li 2 BaSc(BO 3 ) 2 F and LiBa 2 Pb(BO 3 ) 2 F with Layered Structures featuring Special Li−O/F Configurations". Chemistry - A European Journal. 24 (58): 15477–15481. doi:10.1002/chem.201804126. PMID   30230058.
  62. ↑ "Vicanite-(Ce)". www.mindat.org. Retrieved 2020-12-14.
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