Selenide borate

Last updated October 05, 2025

Selenide borates, officially known as borate selenides, are chemical mixed anion compounds that contain any kind of borate and selenide ions. They are distinct from selenoborates in which selenium atoms replace oxygen in borates. There are also analogous borate sulfides, with sulfur ions instead of selenium.

List

chem	mw	crystal system	space group	unit cell	volume	density	comments	references
Zn₈Se₂[BO₂]₁₂			I43m	a=7.6749 b=7.6749 c=7.6749			band gap 4.42 eV SHG 0.14xKDP	^[1]^[2]
YSeBO₂	210.68	orthorhombic	Cmc2₁	a=5.6617 b=16.5858 c=1.441 Z=4	389.15	3.596	band gap 3.45 eV	^[3]
Sm₆Ta₂MgSeB₈O₂₆	1869.75	trigonal	P3	a=8.089 c=8.6765 Z=1	491.70	6.314		^[4]
Eu₆Ta₂MgSeB₈O₂₆	1879.41	trigonal	P3	a=8.0717 c=8.6491 Z=1	488.01	6.395		^[4]
Gd₆Ta₂MgSeB₈O₂₆	1911.15	trigonal	P3	a=8.0536 c=8.6296 Z=1	484.73	6.547		^[4]

References

↑ Zhou, Wenfeng; Li, Xiao-Hui; Yao, Wen-Dong; Xue, Huaiguo; Guo, Sheng-Ping (2020), CSD 1999764: Experimental Crystal Structure Determination, FIZ Karlsruhe - Leibniz Institute for Information Infrastructure, doi:10.5517/ccdc.csd.cc253xjr , retrieved 2021-03-13
↑ Zhou, Wenfeng; Li, Xiao-Hui; Yao, Wen-Dong; Xue, Huaiguo; Guo, Sheng-Ping (October 2020). "Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis" . Journal of Solid State Chemistry. 290 121572. Bibcode:2020JSSCh.29021572Z. doi:10.1016/j.jssc.2020.121572. S2CID 224876635.
↑ Lu, Zhen-Tao; Fan, Wen-Jing; Wang, Zhi-Qian; Gu, Ning; Yue, Zeng-Hao; Xue, Huai-Guo; Guo, Sheng-Ping (2020-06-15). "Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO 2: Featuring a [YSeBO 2 ] n Planar Belt" . Inorganic Chemistry. 59 (12): 7905–7909. doi:10.1021/acs.inorgchem.0c00753. ISSN 0020-1669. PMID 32469211. S2CID 218984948.
1 2 3 Shi, Zhi-Hui; Chi, Yang; Yang, Mei; Liu, Wenlong; Guo, Sheng-Ping (2020-03-16). "A Series of Chalcogenide Borates RE 6 Ta 2 MgQB 8 O 26 (RE = Sm, Eu, Gd; Q = S, Se) Featuring a B 4 O 10 Cluster" . Inorganic Chemistry. 59 (6): 3532–3536. doi:10.1021/acs.inorgchem.0c00086. ISSN 0020-1669. PMID 32090554. S2CID 211263182.

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[1] Zhou, Wenfeng; Li, Xiao-Hui; Yao, Wen-Dong; Xue, Huaiguo; Guo, Sheng-Ping (2020), CSD 1999764: Experimental Crystal Structure Determination, FIZ Karlsruhe - Leibniz Institute for Information Infrastructure, doi:10.5517/ccdc.csd.cc253xjr , retrieved 2021-03-13

[2] Zhou, Wenfeng; Li, Xiao-Hui; Yao, Wen-Dong; Xue, Huaiguo; Guo, Sheng-Ping (October 2020). "Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis" . Journal of Solid State Chemistry. 290 121572. Bibcode:2020JSSCh.29021572Z. doi:10.1016/j.jssc.2020.121572. S2CID 224876635.

[3] Lu, Zhen-Tao; Fan, Wen-Jing; Wang, Zhi-Qian; Gu, Ning; Yue, Zeng-Hao; Xue, Huai-Guo; Guo, Sheng-Ping (2020-06-15). "Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO 2: Featuring a [YSeBO 2 ] n Planar Belt" . Inorganic Chemistry. 59 (12): 7905–7909. doi:10.1021/acs.inorgchem.0c00753. ISSN 0020-1669. PMID 32469211. S2CID 218984948.

[:0-4] 1 2 3 Shi, Zhi-Hui; Chi, Yang; Yang, Mei; Liu, Wenlong; Guo, Sheng-Ping (2020-03-16). "A Series of Chalcogenide Borates RE 6 Ta 2 MgQB 8 O 26 (RE = Sm, Eu, Gd; Q = S, Se) Featuring a B 4 O 10 Cluster" . Inorganic Chemistry. 59 (6): 3532–3536. doi:10.1021/acs.inorgchem.0c00086. ISSN 0020-1669. PMID 32090554. S2CID 211263182.

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