Selenophosphate

A selenophosphate is a chemical compound containing phosphate anions substituted with selenium. Over 7000 compounds are known with a bond between selenium and phosphorus. Compared to phosphorus-sulfur compounds selenophosphates are less thermally stable, and more easily destroyed by water. However they are more stable than tellurophosphates which have an even weaker phosphorus-tellurium bond. ^[1] Selenophosphates have an oxidation number for phosphorus of +5. But in many there are bonds between phosphorus atoms, reducing the oxidation state to +4, Some may be termed selenophosphites. ^[2]

Different structural anions include hexaselenohypodiphosphate [P₂Se₆]⁴⁻ and [P₆Se₁₂]⁴⁻ with decalin structure and [P₄Se₂]²⁻ with dicyclobutane structure. ^[1]

Selenophosphates are coloured, often orange. They are semiconductors.

The first selenodiphosphate was discovered in 1973 by H. Hahn. ^[3]

Selenophosphate compounds may have some or all of the selenium replaced by sulfur. ^[4]

Formation

Selenophosphates can be produced by melting phosphorus selenide with metal selenides.

Molecular biology

Selenocysteine is produced in many organisms from a selenophosphate. In humans and other eucaryotes, this is facilitated by the enzyme selenophosphate synthetase 1. Selenium is connected to phosphorus using a reaction with selenide and adenosine triphosphate ^[5]

List

formula	name	mw	crystal system	space group	unit cell Å	volume	density	comments	references
[(py2Li)]4[P2Se6]·2py								water stable	[6]
(NH4)4(P2Se6)(H2O)2			triclinic	P1	a=7.3306 b=7.3761 c=9.5501 α =70.405° β =74.109° γ =60.681° Z=1	420.37	2.544		[7]
[pyH]4[P2Se6]·H2O								water stable	[6]
(NBu4)2P2Se8	bis(Tetrabutylammonium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide acetonitrile solvate		monoclinic	P21/c	a 9.6284 b 16.9553 c 16.0899 β 96.875°			chair config	[8]
(NBu4)3P9Se14								orange-red	[9]
	bis(1-Butyl-3-methylimidazolium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide		monoclinic	P21/n	a =7.6642 b =10.9948 c =17.0380 β =91.211°			chair config	[8]
	bis(tetrakis(Acetonitrile-N)-lithium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide		orthorhombic	Pbam	a 20.0535(6)Å b 12.1200(5)Å c 15.0831			cradle config	[8]
	bis((Tetrapyridine)-lithium) 3,6-diselenoxo-1,2,4,5-tetraselena-3,6-diphosphacyclohexane 3,6-diselenide		triclinic	P1	a 10.1582 b 10.7716 c 12.750 α 95.271° β 94.847° γ 114.219°			cradle config	[8]
Na2P4Se2								red-brown; P4 bicyclo structure	[10]
Na3PSe4			cubic	I43m	a=7.3094 Z=2		3.53	Na ion conductor 1 mS cm−1	[11]
Na4P2Se6			orthorhombic	Cmca	a = 11.836 b = 13.311 c = 8.061 Z = 4	1270.0	3.283		[12]
Na4(P2Se6)(H2O)6			monoclinic	P21/c	a 26.0636 b 7.2350 c 20.7197 β 113.387° Z=8	3586.13	2.726		[7]
Mg2P2Se6				R3	a = 6.404 c = 20.194 Z=3				[13]
KPSe6			orthorhombic	Pca21	a = 11.49 b = 6.791 c = 11.29 Z = 4			orange; NLO χ(2)≈142.8 pm V−1; band gap 2.1 eV	[14] [15] [16] [17]
K4Sc2(PSe4)2(P2Se6)			monoclinic	C2/c	a=22.668Å b=6.8147Å c=19.828 β=113.91°				[18]
K2P2Se6			trigonal	P3121	a = 7.2728, c = 18.872 Z = 3			at 298 K; SHG 50× AgGaSe2	[19]
K2P2Se6			trigonal	P3121	a = 14.4916 c = 18.7999 Z = 12			at 173 K	[19]
K3PSe4·2Se6			cubic	Fd3	a = 16.415			at 193 K	[20]
K4(P2Se6)(H2O)4			orthorhombic	Cmca	a =11.921 b =12.46 c =11.752 Z=4	1745.6	2.908		[7]
K6P8Se18		1903.66	monoclinic	P21/n	a=9.746 b=8.332 c=23.054 β=90.54° Z=2	1872.1	3.377	orange	[21]
Ca2P2Se6			monoclinic	P21/n	a = 9.664 b = 7.519 c = 6.859 β = 92.02°				[22]
K4Sc2(PSe4)2(P2Se6)		737.82	monoclinic	C2/c	a=22.668 b=6.815 c=19.828 β =113.91° Z=8	2800.2	3.500	orange-yellow; turns red in air; band gap 2.25 eV	[23]
KTiPSe5									[24]
K4Ti2(P2Se9)2(P2Se7)								black	[24]
Cr2P2Se6									[25]
LiCrP2Se6									[26]
MnPSe3			trigonal	R3				band gap 2.5 eV	[27] [28]
K2MnP2Se6			monoclinic	P21/n	a=6.5349 b=12.696 c=7.589 β=102.67° Z=2	614.3			[29]
FePSe3									[27]
Fe2P2Se6			trigonal	R3				band gap 1.3 eV	[13] [28]
K2FeP2Se6			monoclinic	P21/n	a=6.421 b=12.720 c=7.535 β=102.58 Z=2	600.7		red	[29]
CuP2Se								2D semiconductor; metallises under pressure	[30]
m-Cu4P2Se6			monoclinic	P21/c	a 6.370 b 11.780 c 20.013 β 90.03°				[31]
Cu3PSe4			orthorhombic	Pmn21	a=7.700 b=6.677 c=6.385	328.3			[32]
t-Cu4P2Se6			triclinic	P1	a 7.104 b 11.889 c 12.759 α 74.35° β 79.63° γ 80.85°				[31]
Cu4P3Se4			triclinic	P1	a 6.440 b 7.085 c 10.616 α 73.11° β 74.86° γ 77.00°				[31]
Cu4P4Se3			monoclinic	P21/c	a 16.446 b 6.515 c 17.339 β 119.08°				[31]
CuP2Se			orthorhombic	Pbca	a 5.608 b 6.496 c 16.570				[31]
CuAl[P2Se6]			trigonal	R3	a = 6.2795 c = 19.9713 Z =3				[33]
K2Cu2P4Se10		1118.78	monoclinic	P21/n	a=10.627 b=7.767 c=11.966 β=109.125° Z=2	933.2	3.981	red	[34]
K3Cu3P3Se9			monoclinic	P21/c	a = 8.741 b = 10.774, c = 20.033, β = 92.96°				[35] [36]
[Cu12(P2Se6){Se2P(OEt)2}8]	Et=Ethyl; diethyl diselenophosphate hexaselenodiphosphate(IV)								[37]
[Cu12(P2Se6){Se2P(OiPr)2}8]	iPr=isopropyl								[37]
CuCr[P2Se6]			monoclinic	C2/m	a=6.193 b=10.724 c=6.909 β=107.2° Z=2	690.2	4.9	melt 730 °C; dark red	[3]
Zn2P2Se6				R3	a = 6.290 c = 19.93 Z=3				[13]
K2ZnP2Se6			monoclinic	P21/c	a = 12.537 b = 7.274 c = 14.164 β = 109.63° Z = 4	1216		yellow	[38] [39]
LiGaP2Se6									[26]
K4GeP4Se12			orthorhombic	Pca21	a=13.9465 b=7.2435 c=24.0511				[40]
K4Ge4-xPxSe12			monoclinic	P21/c	a = 6.7388 b = 13.489 c = 6.3904 β = 91.025°				[41]
K7As3(P2Se6)4			monoclinic	P21/c	a=25.0706 b=9.5948 c=59.6227 β=93.384°			melt 388 °C	[42]
K6As2(P2Se6)3			monoclinic	P21/c	a 8.0898 b 23.3142 c 12.1919 β 124.809°			melt 410 °C; orange; band gap 2.2 eV	[42]
RbPSe6			orthorhombic	Pca21	a = 11.776 b = 6.858 c = 11.460 Z = 4			NLO χ(2)≈150 pm V−1	[15] [16]
Rb2P2Se6			trigonal	P3121	a = 7.2982 c = 19.002 and Z = 3			100 K	[19]
Rb4P2Se9			monoclinic	C2/c	a = 9.725 b = 10.468 c = 19.155 β = 93.627° Z = 4	1946.1	3.804		[12]
Rb4P6Se12			orthorhombic	Pca21	a =16.409 b =10.64 c =15.105			bicyclic with >PP< bridge and -SePSe2PSe2Se- ring	[43]
Rb10P4Se25									[44]
Rb4(P2Se6)(H2O)4			orthorhombic	Pnnm	a 9.834 b 12.456 c 7.585 Z=2	929.1	3.395		[7]
RbTiPSe5									[24]
Rb4Ti2(P2Se9)2(P2Se7)			orthorhombic	Fdd2	a=35.55 b=37.315 c=6.574 Z=4	8772	3.956	black	[24] [45]
Rb2MnP2Se6									[29]
Rb2ZnP2Se6			triclinic	P1	a = 7.494 b = 7.601 c = 12.729 α = 96.57° β = 105.52° γ = 110.54° Z = 2	636.6			[39]
Rb4GeP4Se12			orthorhombic	Pca21	a=14.1881 b=7.3566 c=24.2914				[40]
Rb6Ge2P2Se14			triclinic	P1	a = 7.2463 b = 9.707 c = 11.987 α = 79.516° β = 89.524° γ = 68.281°			band gap 2.2 eV	[41]
Sr2P2Se6			monoclinic	P21/n	a = 9.844 b = 7.788 c = 6.963 β = 91.50° Z=2				[22]
NaYP2Se6		647.6	triclinic	P1	a=6.9456 b=7.4085 c=9.5306 α=88.819° β=87.748° γ=89.580° Z=2			yellow	[46] [47] follow up refs
KYP2Se6			orthorhombic	P212121	a = 6.7366 b = 7.4286 c = 21.603 Z = 4				[46] [48]
[(Cp′′2Zr)2(μ,η1:1:1:1-P2Se4)]	Cp′′ = C5H3tBu2	1269.41	monoclinic	P21/n	a=15.2831 b=9.91947 c=18.6250 β=102.835° Z=2	2753	1.531	dark purple	[49]
KZrPSe6			orthorhombic	Pmc21	a=3.7079 b=15.074 c=18.491				[50]
RbZrPSe6									[50]
KNb2PSe10			monoclinic	Pc	a=7.2931 b=15.612 c=13.557 β=106.64°			resistivity 4.5 Ω·cm	[51]
RbNb2PSe10			monoclinic	Pc	a=7.381 b=7.8359 c=13.564 β=106.75°				[51]
K3RuP5Se10			monoclinic	P21/m	a 11.2099 b 7.2868 c 12.3474 β 93.958°				[52]
PdPSe								semiconductor	[53]
K2PdP2Se6									[24]
Rb2PdP2Se6									[24]
Ag4P2Se6		1013.69	orthorhombic	P212121	a=6.5760 b=11.5819 c=14.137 Z=4	1076.8	5.966	melt 642 °C; dark red	[54]
AgAl[P2Se6]			monoclinic	C2/m	a=6.348 b=10.989 c=7.028 β=107.2° Z=2			melt 588 °C; yellow	[3]
K2Ag2P2Se6			monoclinic	P21/c	a=8.528 b=11.251 c=20.975 β=93.24° Z=4	2009		orange	[29]
AgCrP2Se6			monoclinic	C2/m	a=6.305 b=10.917; c=6.991 β=107.7° Z=2			melt 720 °C; dark red	[3]
AgCrP2Se6				P3112	a=6.3257 c=20.0198			layered; antiferromagnetic <42K; band gap 1.240 eV	[55]
AgGa[P2Se6]			orthorhombic	Pbca	α=12.169 b=22.484 c=7.473 Z=4	2044.7		melt 450 °C; orange	[3]
AgGa[P2Se6]			trigonal	P31/c	a=6.375 c=13.320 Z=2	468.81	5.05	dark red	[3]
AgScP2Se6		688.54	trigonal	P31/c	a=6.463 c=13.249 Z=2	482.93	4.735	orange or brown	[56]
CdPSe3									[27]
K2CdP2Se6			monoclinic	P21/n				dark yellow	[38]
Rb2CdP2Se6		819.05	monoclinic	P21/n	a=6.640 b=12.729 c=7.778 β=98.24° Z=2	650.5	4.180	dark yellow; air stable	[38]
Rb8Cd4(Se2)(PSe4)4									[24]
InPSe3									[27]
In2(P3Se9)			monoclinic	P21/n					[35]
LiInP2Se6		657.46	trigonal	P31/c	a=6.397 c=13.350 Z=2	473.15	4.615	band gap 2.06 eV	[57]
(Ph4P)[In(P2Se6)]			monoclinic	C2/c	a = 23.127 b = 6.564 c = 19.083 β = 97.42° Z = 4	2873		@23 °C yellow	[58]
KInP2Se6			monoclinic	P21/n	a=7.511 b=6.4861 c=22.789 β=98.91° Z=4	1096.9			[59]
K5In3(μ3-Se)(P2Se6)3			triclinic	P1	a 7.6603 b 13.1854 c 18.378 α 87.04° β 88.659° γ 82.025°				[60]
K4In4(μ-Se)2(P2Se6)3			monoclinic	P21/c	a 19.707 b 7.712 c 13.229 α 90° β 106.42°				[60]
K4In2(PSe5)2(P2Se6)			monoclinic	Cc	a=11.1564 b=22.8771 c=12.6525 β=109.039° Z=4			brick-red; air stable	[61]
K4In4(μ-Se)(P2S2.36Se3.64)3			triclinic	P1	a 7.7709 b 13.0007 c 18.9382 α 105.382° β 92.632° γ 91.91°				[60]
CuInP2Se6			trigonal	P31/c	a=6.392 c=13.338 Z=2	472.0	5.0	melt 642 °C; dark red	[3]
AgInP2Se6			trigonal	P31/c	a=6.483 c=13.330 Z=2	485.2	5.2	semiconductor; melt 673 °C; dark red; band gap 1.79 eV	[62] [3]
SnP2Se6				R3	a = 6.3213 c = 19.962			band gap 1.36–1.41 eV	[63]
Sn2P2Se6									[64]
Na11.1Sn2.1P0.9Se12			tetragonal	I41/acd	a=14.2446 c=28.473 Z=8	5777.4	3.403	Na+ ion conductivity 3.0 mS/cm	[65]
Rb3Sn(PSe5)(P2Se6)			monoclinic	P21/a	a=14.013 b=7.3436 c=21.983 β=106.61° Z=4			black	[61]
K10Sn3(P2Se6)4			trigonal	R3	a = 24.1184 c = 7.6482			@100K; band gap 1.82 eV	[66]
Rb4Sn5P4Se20		2638.41	trigonal	P3m1	a=7.6163 c=18.6898 Z=1	938.91	4.64	black	[67]
Rb4Sn2Ag4(P2Se6)2			monoclinic	P21/n	a=11.189 b=7.688 c=21.850 β=94.31° Z=2	1874.2	4.639	black	[24] [68]
Rb5[Sn(PSe5)3]			triclinic	P1	a 11.745 b 19.23 c 7.278 α 99.97° β 107.03° γ 87.16°				[69]
Sb4(P2Se6)3			monoclinic	P21/n	a = 20.777 b = 7.4935 c = 9.4949 β = 91.25°				[70]
KSbP2Se6		696.55							[35]
β-KSbP2Se6		696.55	monoclinic	P21	a=6.8925 b=7.8523 c=10.166 β=91.487 Z=2	550.4	4.203	dark red	[71]
AgSbP2Se6								hygroscopic	[72]
α-CsPSe6			monoclinic	P21/n	a = 6.877 b = 12.713 c = 11.242 β = 92.735° Z = 4			orange	[14] [15]
β-CsPSe6		637.64	tetragonal	P421c	a = 12.526 c = 12.781 Z = 8	2005.3	4.224	red orange; metastable; SHG χ(2) ~30 pm/V	[14]
Cs2P2Se8			orthorhombic	Ccce	a = 14.982 b = 24.579 c = 13.065			band gap 2.44 ± 0.2 eV; P2Se4 ring; third harmonic generator coefficient 2.4 ± 0.1 × 105 pm2/V2	[73]
Cs3PSe4			orthorhombic	Pnma	a = 10.0146 b = 11.990 c = 9.9286 Z = 4	1192.2	4.154		[12]
Cs4P2Se9									[24]
Cs4P2Se10			triclinic	P1	a=7.359 b=7.455 c=10.142 α=85.938°, β=88.055° γ=85.609°			[P2Se10]4−	[74]
Cs4[P6Se12]		1664.98	monoclinic	P21/n	a =10.836 b =10.5437 c =12.273 β =98.661°	1386.3	3.989	orange; melt 697; NLO	[75]
Cs5[P5Se12]		1766.92	tetragonal	P4	a =13.968 c =7.546 Z=2	1472.2	3.986	orange; NLO; band gap 2.17 eV	[75] [76]
Cs10P8Se20			orthorhombic	Pnnm	a = 26.5456 b = 8.0254 c = 11.9031 Z = 2	2535.8	4.133	(PSe2)3Se rings and P2Se6	[77]
Cs4(P2Se6)(H2O)4			orthorhombic	Pnnm	a=10.0514 b=12.6867 c=7.8403 Z=2	999.8	3.775		[7]
K0.6Cs0.4PSe6			orthorhombic	Pca21	a=11.830 b=6.908 c=11.516 Z=4	941.1	4.085	orange; band gap 2.1 eV; SHG χ(2) ~150 pm/V	[14]
KCsP2Se8			orthorhombic	Ccce	a = 14.782 b = 23.954 c = 13.044			band gap 2.36 ± 0.2 eV	[73]
Cs2MnP2Se6			monoclinic	P21/n	6.4761 b=13.006 c=7.974 β=93.09° Z=2	670.6			[29]
Cs2FeP2Se6									[29]
Cs2Cu2P2Se6			monoclinic	P21/c	a=9.958 b=13.067 c=10.720 β=102.46° Z=4	1363		dark green	[29]
Cs2ZnP2Se6			triclinic	P1	a = 7.6543 b = 7.7006 c = 12.737 α = 97.007° β = 104.335° γ = 109.241° Z = 2	669.5		yellow; band gap 2.67 eV	[39] [76]
Cs4GeP4Se12			orthorhombic	Pca21	a=14.3268 b=7.6202 c=24.6301				[40]
Cs6As2(P2Se6)3			monoclinic	P21/c	a=19.5759 b=7.9206 c=13.0553 β=101.914°			orange band gap 2.1 eV	[42]
Cs5As(P2Se6)2			tetragonal	P42/m	a=13.826 c=7.5173			melt 416 °C; red; band gap 2.0 eV	[42]
RbCsP2Se8			orthorhombic	Ccce				band gap 2.41 ± 0.2 eV	[73]
CsZrPSe6								band gap 2.0 eV	[76] [50]
CsNb2PSe10			monoclinic	Pc	a=14.6257 b=7.8097 c=13.5533 β=98.557°				[51]
Cs4Pd(PSe4)2			monoclinic	P21/c	a = 7.491 b = 13.340 c = 10.030 β = 92.21° Z = 2			red	[78]
Cs10Pd(PSe4)4			tetragonal	P42c	a = 13.949 c = 11.527 Z = 4			red	[78]
Cs2PdP2Se6			tetragonal	P42/mnm	a = 8.5337 c = 10.5595 Z = 4			black	[78]
Cs2Ag2P2Se6			monoclinic	P21/n	a=6.807 b=12.517 c=8.462 β=95.75° Z=2	717.3		yellow	[29]
Cs2CdP2Se6			monoclinic	P21/n				yellow	[38]
Cs5In(P2Se6)2			tetragonal	P42/m	a = 13.886 c = 7.597 Z = 2	1464.9		@23 °C; dark orange	[58]
Cs4Sn(P2Se6)2		1721.73	trigonal	R3	a=7.808 c=37.905 Z=3	2001.4	4.285	black	[79]
α-Cs2SnP2Se6		920.2	monoclinic	P21/c	a=10.230 b =12.990 c=10.949 β=94.529°	1450.5	4.2126	orange	[79]
Cs2SnP2Se6			monoclinic	P21/c	a = 10.1160 b = 12.7867 c = 11.0828 β = 94.463°			@100K	[66]
Cs4(Sn3Se8)[Sn(P2Se6)]2		2828.17	tyrigonal	P3m1	a=7.695 c=18.797 Z=1	964.0	4.872	black; 2D	[79]
Cs6[Sn2Se4(PSe5)2]			triclinic	P1	a 9.899 b 12.416 c 7.497 α 91.62° β 110.19° γ 79.94°				[69]
CuSbP2Se6				C2/m					[80]
AgSbP2Se6				C2/m					[80]
Cs8Sb4(P2Se6)5									[35]
Ba2P2Se6			monoclinic	P21/n	a = 10.355 b = 7.862 c = 7.046 β = 90.83° Z=2				[22]
Ba3(PSe4)2			monoclinic	P21/a	a = 12.282 b = 6.906 c = 18.061 β = 90.23° Z = 4				[81] [82]
Ba3PO4PSe4			triclinic	P1	a=6.779 b=7.108 c=12.727 α=82.45 β=78.88 γ=81.34 Z=2			orange	[81]
KBaPSe4			orthorhombic	Pnma	a=11.972 b=6.973 c=10.388 Z=4			pale orange	[81]
KLaP2Se6		713.71	monoclinic	P21/c	a=12.425 b=7.8047 c=11.9279 β=109.612°	1089.6	4.351	yellow	[35]
K2La(P2Se6)1/2(PSe4)			monoclinic	P21/n	a = 9.4269 b = 7.2054 c = 21.0276 β = 97.484° Z = 4				[83]
K3La(PSe4)2			monoclinic	P21/c	a = 9.5782 b = 17.6623 c = 9.9869 β = 90.120° Z = 4				[83]
K3LaP2Se8									[84]
K4La0.67(PSe4)2			orthorhombic	Ibam	a = 19.0962 b = 9.1408 c = 10.2588 Z = 4				[83]
K6LaP4Se16
K8.5La1+1/3(PSe4)4			orthorhombic	Ccca	a = 18.2133 b = 38.0914 c = 10.2665 Z = 8				[83]
Ce4(P2Se6)3		722.06	monoclinic	P21/c	a = 6.8057 b = 22.969 c = 11.7226 β = 124.096° Z = 6		4.741	orange	[85]
NaCeP2Se6			monoclinic	P21/c	a = 12.1422 b = 7.6982 c = 11.7399 β = 111.545° Z=4			yellow	[85]
KCeP2Se6			monoclinic	P21/c					[46]
Cu0.4Ce1.2P2Se6			monoclinic	P21/c	a = 12.040 b = 7.6418 c = 11.700 β = 111.269° Z = 4			yellow	[85]
Rb2CeP2Se7			monoclinic	P21/n				red; air sensitive	[86]
Rb3CeP2Se8		1090.13	monoclinic	P21/c	a = 9.6013 b = 18.0604 c = 10.0931 β = 90.619° Z = 4	1750.07	4.137	orange; air sensitive	[86]
Rb9Ce(PSe4)4			monoclinic	C2/c	a=21.446 b=10.575 c=18.784 β =115.94° Z=4	3831	3.980	orange; air and water destroyed; soluble in 18-crown-6 + dmf; band gap 2.26 eV	[44]
AgCeP2Se6			monoclinic	P21/c	a = 9.971 b = 7.482 c = 11.757 β = 145.630° Z=2			orange	[85]
CsCe[P2Se6]			monoclinic	P21/c	a = 12.9786 b = 7.7624 c = 11.9843 β = 106.589° Z = 4				[87]
KPrP2Se6			monoclinic	P21/c					[46]
Cs2PrP2Se7			monoclinic	P21/n	a=10.2118 b=7.2423 c=20.3741 β =98.624° Z=4				[88]
Eu2P2Se6			monoclinic	P21/n	a = 9.779 b = 7.793 c = 6.957 β = 91.29° Z=2				[22]
LiEuPSe4			orthorhombic	Ama2	a = 10.5592 b = 10.415 c = 6.4924 Z = 4			red; air unstable	[89]
Na8Eu2(Si2Se6)2			monoclinic	C2/m	a=7.090 b=12.228 c=7.950 β=107.427° Z = 1	657.6			[90]
KEuPSe4			monoclinic	P21/m	a = 6.8469 b = 6.9521 c = 9.0436 β = 107.677° Z = 2			red; air unstable	[89]
KEuPSe4			orthorhombic	Pnma	a = 17.516 b = 7.0126 c = 6.9015 Z = 4				[83]
K4Eu(PSe4)2			orthorhombic	Ibam	a = 19.020 b = 9.131 c = 10.198 Z = 4				[35] [91]
Cs3GdP2Se8			monoclinic	P21/c					[86]
NaSmP2Se6		709.94	triclinic	P1	a 6.8368 b 7.5312 c 9.557 α 90.799° β 91.910° γ 90.351° Z=2			red	[46]
Na9Sm(Ge2Se6)2			monoclinic	C2/m	a = 7.916 b = 12.244 c = 7.105 β = 106.99° Z = 1	658.6			[90]
KSmP2Se6		725.15	monoclinic	P21	a=6.7888 b=7.6185 c=10.1962 β=91.508 Z=2	527.17	4.568	red	[92]
CsSmP2Se6			orthorhombic	P212121	a = 6.8867 b = 7.5448 c = 22.152 Z = 4				[46] [87]
NaGdP2Se6		715.94	triclinic	P1	a 6.8464 b 7.4916 c 9.5372 α 90.813° β 92.026° γ 90.241° Z=2			yellow	[46]
KGdP2Se6			monoclinic	P21	a=6.7802 b=7.5809 c=10.1967 β=91.638 Z=2	523.97	4.640	yellow	[46] [92]
Rb2GdP2Se7		1037.73	monoclinic	P21/n	a = 10.137 b = 7.212 c = 20.299 β = 98.23° Z = 4	1468.8	4.692	orange; air sensitive	[86]
NaTbP2Se6		717.61	triclinic	P1	a 6.8854 b 7.4580 c 9.5196 α 89.068° β 87.899° γ 89.974° Z=2			yellow	[46]
KTbP2Se6			monoclinic	P21	a=6.7609 b=7.5570 c=10.2158 β=91.732 Z=2	521.71	4.671	yellow	[46] [92]
KTbP2Se6			orthorhombic					red over 9.2 GPa	[93]
NaDyP2Se6		721.19	triclinic	P1	a 6.9114 b 7.4258 c 9.5256 α 88.914° β 87.829° γ 89.695° Z=2			yellow	[46]
CsEr[P2Se6]			monoclinic	P21/c	a = 7.5381 b = 12.8192 c = 12.7647 β = 106.898° Z = 4				[87]
AgErP2Se6		810.83	trigonal	P31/c	a=6.578 c=13.410 Z=2	502.6	5.358	dark brown	[56]
AgTmP2Se6		812.50	trigonal	P31/c	a=6.567 c=13.422 Z=2	501.27	5.383	dark brown	[56]
K3AuP2Se8			monoclinic	Cc	a = 7.122 b = 12.527 c = 18.666 β = 96.06° Z = 4				[94]
Rb3AuP2Se8			monoclinic	Cc					[94]
Cs3AuP2Se8			monoclinic	Cc					[94]
K2Au2P2Se6			monoclinic	C2/m	a = 12.289 b = 7.210 c = 8.107 β = 115.13° Z = 2			black	[94]
Rb2Au2P2Se6			monoclinic	C2/m					[94]
Rb2Au2P2Se6			monoclinic	P21/n	a=11.961 b=10.069 c=32.137 β=91.37° Z=12	3869	4.653	@-120 °C black	[95]
Hg2P2Se6									[35] [96]
K2HgP2Se6			monoclinic	P21/c	a=13.031 b=7.308 c=14.167 β=110.63° Z=4	1262.6	4.285	dark yellow	[38]
Rb2HgP2Se6			monoclinic	P21/c				drak yellow	[38]
Rb8Hg4(Se2)(PSe4)4				P42/n	a=17.654 c=7.226				[24] [97]
Tl4P2Se6			trigonal	R3	a=6.3808 c= 20.014			melt 963 K	[35] [98]
TlInP2Se6			triclinic	P1	a=6.4488 b=7.5420 c=12.166 α=100.72° β=93.63° γ=113.32°			melt 875K	[99] [98]
TlSbP2Se6			monoclinic	P21	a = 6.843 b = 7.841 c = 9.985 β = 90.77° Z = 2			melt 720K; band gap 1.75 eV	[100]
Pb2P2Se6			monoclinic	Pn	a = 9.742 b = 7.662 c = 6.898 β=91.44° Z=2	514.73	6.13	melt 812 °C;band gap 1.88 eV	[35] [101] [102]
Na1.5Pb0.75PSe4			cubic	I43d	a=14.3479 Z=16			band gap 2 eV	[103]
RbPbPSe4								red water stable	[91]
Rb4Pb(PSe4)2			orthorhombic	Ibam	a = 19.134 b = 9.369 c = 10.488 Z = 4			orange water unstable	[91]
CsPbPSe4			orthorhombic	Pnma	a = 18.607 b = 7.096 c = 6.612 Z = 4			red water stable	[91]
Cs4Pb(PSe4)2								orange water unstable	[91]
Bi4(P2Se6)3			monoclinic	P21/n	a = 20.869 b = 7.4745 c = 9.5923 β = 91.73°				[70]
β-Bi4(P2Se6)3			triclinic	P1	a = 12.2303 b = 6.7640 c = 17.866 α = 90.493° β = 94.133° γ = 91.163°			black	[104]
KBiP2Se6		783.78	monoclinic	P21	a 6.9183 b 7.663 c 10.239 β 91.508° Z=2	542.6	4.797		[35] [71]
CuBiP2Se6				R3	a = 6.553 c = 39.76			lamellar; p-type semiconductor; work function 5.26 eV	[105] [106]
AgBiP2Se6				R3	a = 6.652 c = 39.61			lamellar	[105]
Cs5BiP4Se12			orthorhombic	Pmc21	a = 7.5357 b = 13.7783 c = 28.0807 Z = 4			band gap 1.85 eV; melt 590 °C	[107]
α-TlBiP2Se6			monoclinic	P2l/c	a =12.539 b =7.499 c =12.248 β =113.731°			chains; band gap 1.23,1eV	[108]
β-TlBiP2Se6			monoclinic	P2l/c	a =12.25 b =7.5518 c =22.834 β =97.65°			melt 544 °C; layers; band gap 1.27 eV	[108]
K2ThP3Se9			triclinic	P1	a = 10.4582 b = 16.5384 c = 10.2245 α = 107.637 β = 91.652 γ = 90.343° Z = 2				[109]
β-K2ThP3Se9			monoclinic	P21/n	a = 10.2697 b = 7.7765 c = 20.472 β = 92.877° Z = 4			yellow	[110]
Rb2ThP3Se9			triclinic	P1	a = 10.5369 b = 16.6914, c = 10.2864 α = 107.614° β = 92.059° γ = 90.409° Z = 2				[109]
Rb7Th2P6Se21			triclinic	P1	a = 11.531 b = 12.359 c = 16.161 α = 87.289° β = 75.903° γ = 88.041° Z = 2			red; band gap 2.0 eV	[111]
Cs4Th4P4Se26			orthorhombic	Pbca	a = 12.0130 b = 14.5747 c = 27.134 Z = 8			orange; (P2Se9)6- anion	[112]
Cs4Th2P5Se17			monoclinic	P2l/c	a = 10.238 b = 32.182 c = 10.749 β = 95.832° Z = 4				[109]
K2UP3Se9			triclinic	P1	a = 10.407( b = 16.491 c = 10.143 α= 107.51° β = 91.74° γ = 90.28° Z = 4			black	[24] [113]
Rb4U2P5Se17			triclinic	P1	a =10.0824 b = 10.6905 c = 15.7845 α = 84.678 β = 76.125 γ = 85.874°			@100K	[114]
Rb4U4P4Se26		3470.84	orthorhombic	Pbca	a=11.9779 b=14.4874 c=27.1377 Z=4	4709.17	4.895	U5+	[115]
Cs2U2(P2Se9)(Se2)2			orthorhombic	Pbca	a 11.769 b 14.389 c 26.537			black	[116]

References

1. Devillanova, Francesco A.; Mont, Wolf-Walther Du (2013). "Chalcogen-Phosphorus (and Heavier Congener) Compounds". Handbook of Chalcogen Chemistry: New Perspectives in Sulfur, Selenium and Tellurium. Royal Society of Chemistry. p. 238. ISBN   978-1-84973-623-7.
2. Sanna, Michela; Ng, Siowwoon; Pumera, Martin (August 2021). "Layered transition metal selenophosphites for visible light photoelectrochemical production of hydrogen". Electrochemistry Communications. 129: 107077. doi: 10.1016/j.elecom.2021.107077 . hdl: 11012/203046 .
3. Pfeiff, Regine; Kniep, Rüdiger (July 1992). "Quaternary selenodiphosphates(IV): MIMIII[P2Se6], (MI =Cu, Ag; MIII = Cr, Al, Ga, In)". Journal of Alloys and Compounds. 186 (1): 111–133. doi:10.1016/0925-8388(92)90626-K.
4. Krauskopf, Thorben; Pompe, Constantin; Kraft, Marvin A.; Zeier, Wolfgang G. (24 October 2017). "Influence of Lattice Dynamics on Na + Transport in the Solid Electrolyte Na 3 PS 4– x Se x". Chemistry of Materials. 29 (20): 8859–8869. doi:10.1021/acs.chemmater.7b03474.
5. Tamura, Takashi; Yamamoto, Shinpei; Takahata, Muneaki; Sakaguchi, Hiromich; Tanaka, Hidehiko; Stadtman, Thressa C.; Inagaki, Kenji (16 November 2004). "Selenophosphate synthetase genes from lung adenocarcinoma cells: Sps1 for recycling l -selenocysteine and Sps2 for selenite assimilation". Proceedings of the National Academy of Sciences. 101 (46): 16162–16167. Bibcode:2004PNAS..10116162T. doi: 10.1073/pnas.0406313101 . PMC   528966 . PMID   15534230.
6. Rotter, Christiane; Schuster, Michael; Gebler, Sebastian; Klapötke, Thomas M.; Karaghiosoff, Konstantin (2010-04-19). "New Salts of the Waterstable P 2 Se 6 4− Anion". Inorganic Chemistry. 49 (8): 3937–3941. doi:10.1021/ic100200b. ISSN   0020-1669. PMID   20297773.
7. Rothenberger, Alexander; Malliakas, Christos D.; Kanatzidis, Mercouri G. (July 2009). "Hydrated Alkali Metal and Ammonium Salts of the [P 2 Se 6 ] 4– Anion". Zeitschrift für anorganische und allgemeine Chemie. 635 (9–10): 1374–1379. doi:10.1002/zaac.200900184. ISSN   0044-2313.
8. Rotter, Christiane; Schuster, Michael; Kidik, Mustafa; Schön, Oliver; Klapötke, Thomas M.; Karaghiosoff, Konstantin (2008-03-01). "Structural and NMR Spectroscopic Investigations of Chair and Twist Conformers of the P 2 Se 8 2− Anion". Inorganic Chemistry. 47 (5): 1663–1673. doi:10.1021/ic7015534. ISSN   0020-1669. PMID   18237117.
9. Karaghiosoff, Konstantin; Schuster, Michael (2001-01-01). "Monomeric, Dimeric, and Trimeric Triselenometaphosphate". Phosphorus, Sulfur, and Silicon and the Related Elements. 168 (1): 117–122. doi:10.1080/10426500108546540. ISSN   1042-6507. S2CID   98688633.
10. Rotter, Christiane; Schuster, Michael; Karaghiosoff, Konstantin (2009-08-17). "An Unusual Binary Phosphorus−Tellurium Anion and Its Seleno- and Thio- Analogues: P 4 Ch 2 2− (Ch = S, Se, Te)". Inorganic Chemistry. 48 (16): 7531–7533. doi:10.1021/ic901149m. ISSN   0020-1669. PMID   19621885.
11. Zhang, Long; Yang, Kun; Mi, Jianli; Lu, Lei; Zhao, Linran; Wang, Limin; Li, Yueming; Zeng, Hong (December 2015). "Solid Electrolytes: Na 3 PSe 4 : A Novel Chalcogenide Solid Electrolyte with High Ionic Conductivity (Adv. Energy Mater. 24/2015)". Advanced Energy Materials. 5 (24). doi:10.1002/aenm.201570133. ISSN   1614-6832.
12. Knaust, Jacqueline M.; Dorhout, Peter K. (March 2006). "Synthesis and structures of Na4P2Se6, Cs3PSe4, and Rb4P2Se9". Journal of Chemical Crystallography. 36 (3): 217–223. doi:10.1007/s10870-005-9050-8. ISSN   1074-1542. S2CID   96077297.
13. Jörgens, Stefan; Mewis, Albrecht (January 2004). "Die Kristallstrukturen von Hexachalcogeno-Hypodiphosphaten des Magnesiums und Zinks". Zeitschrift für anorganische und allgemeine Chemie. 630 (1): 51–57. doi:10.1002/zaac.200300244. ISSN   0044-2313.
14. Haynes, Alyssa S.; Saouma, Felix O.; Otieno, Calford O.; Clark, Daniel J.; Shoemaker, Daniel P.; Jang, Joon I.; Kanatzidis, Mercouri G. (2015-03-10). "Phase-Change Behavior and Nonlinear Optical Second and Third Harmonic Generation of the One-Dimensional K (1– x ) Cs x PSe 6 and Metastable β-CsPSe 6". Chemistry of Materials. 27 (5): 1837–1846. doi:10.1021/acs.chemmater.5b00065. ISSN   0897-4756.
15. Chung, In; Do, Junghwan; Canlas, Christian G.; Weliky, David P.; Kanatzidis, Mercouri G. (2004-05-01). "APSe 6 (A = K, Rb, and Cs): Polymeric Selenophosphates with Reversible Phase-Change Properties". Inorganic Chemistry. 43 (9): 2762–2764. doi:10.1021/ic035448q. ISSN   0020-1669. PMID   15106958.
16. Chung, In; Kim, Myung-Gil; Jang, Joon I.; He, Jiaqing; Ketterson, John B.; Kanatzidis, Mercouri G. (2011-11-11). "Strongly Nonlinear Optical Chalcogenide Thin Films of APSe 6 (A=K, Rb) from Spin-Coating". Angewandte Chemie International Edition. 50 (46): 10867–10870. doi:10.1002/anie.201103691. ISSN   1433-7851. PMID   21936037.
17. Jang, J. I.; Haynes, A. S.; Saouma, F. O.; Otieno, C. O.; Kanatzidis, M. G. (2013-09-01). "Broadband studies of the strong mid-infrared nonlinear optical responses of KPSe_6". Optical Materials Express. 3 (9): 1302. Bibcode:2013OMExp...3.1302J. doi: 10.1364/OME.3.001302 . ISSN   2159-3930.
18. Syrigos, Jonathan C.; Kanatzidis, Mercouri G. (2016-05-02). "Scandium Selenophosphates: Structure and Properties of K 4 Sc 2 (PSe 4 ) 2 (P 2 Se 6 )". Inorganic Chemistry. 55 (9): 4664–4668. doi:10.1021/acs.inorgchem.6b00535. ISSN   0020-1669. PMID   27078201.
19. Chung, In; Malliakas, Christos D.; Jang, Joon I.; Canlas, Christian G.; Weliky, David P.; Kanatzidis, Mercouri G. (2007-12-01). "Helical Polymer 1 / ∞ [P 2 Se 6 2 - ]: Strong Second Harmonic Generation Response and Phase-Change Properties of Its K and Rb Salts". Journal of the American Chemical Society. 129 (48): 14996–15006. doi:10.1021/ja075096c. ISSN   0002-7863. PMID   17988126.
20. Dickerson, Christine A.; Fisher, Mary J.; Sykora, Richard E.; Albrecht-Schmitt, Thomas E.; Cody, Jason A. (2002-02-01). "Solvothermal Synthesis and Structure of a New Selenium-Rich Selenophosphate K 3 PSe 4 ·2Se 6". Inorganic Chemistry. 41 (4): 640–642. doi:10.1021/ic015602d. ISSN   0020-1669. PMID   11849062.
21. Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1998-05-01). "[P 8 Se 18 ] 6 - : A New Oligomeric Selenophosphate Anion with P 4+ and P 3+ Centers and Pyramidal [PSe 3 ] Fragments". Inorganic Chemistry. 37 (10): 2582–2584. doi:10.1021/ic980024v. ISSN   0020-1669.
22. Jörgens, Stefan; Mewis, Albrecht; Hoffmann, Rolf-Dieter; Pöttgen, Rainer; Mosel, Bernd D. (March 2003). "Neue Hexachalcogeno-Hypodiphosphate der Erdalkalimetalle und des Europiums". Zeitschrift für anorganische und allgemeine Chemie. 629 (3): 429–433. doi:10.1002/zaac.200390071. ISSN   0044-2313.
23. Syrigos, Jonathan C.; Kanatzidis, Mercouri G. (2016-05-02). "Scandium Selenophosphates: Structure and Properties of K 4 Sc 2 (PSe 4 ) 2 (P 2 Se 6 )". Inorganic Chemistry. 55 (9): 4664–4668. doi:10.1021/acs.inorgchem.6b00535. ISSN   0020-1669. PMID   27078201.
24. Konstantinos, Chondroudis (1997). "Molten salt synthesis of multinary selenophosphates". ProQuest. Retrieved 2023-12-27.
25. Qian, Eric K.; Iyer, Abishek K.; Cheng, Matthew; Ryan, Kevin M.; Jirousek, Lillian; Chica, Daniel G.; Krantz, Patrick; Lee, Yea-Shine; Chandrasekhar, Venkat; Dravid, Vinayak P.; Kanatzidis, Mercouri G. (2023-05-09). "Synthesizing Mono- and Bimetallic 2D Selenophosphates Using a P 2 Se 5 Reactive Flux". Chemistry of Materials. 35 (9): 3671–3685. doi:10.1021/acs.chemmater.3c00342. ISSN   0897-4756. S2CID   258349455.
26. "Synthesis and Crystal Growth of 2D Layered Metal Chalophosphate Materials Using P2Q5 Reactive Fluxes - ProQuest". www.proquest.com. Retrieved 2024-11-06.
27. Chen, Xu; Wang, Junjie; Ying, Tianping; Huang, Dajian; Gou, Huiyang; Zhang, Qinghua; Li, Yanchun; Hosono, Hideo; Guo, Jian-gang; Chen, Xiaolong (2022-11-02). "Insulator-metal-superconductor transition in the medium-entropy van der Waals compound M P Se 3 ( M = Fe , Mn , Cd , and In ) under high pressure". Physical Review B. 106 (18): 184502. arXiv: 2207.08589 . doi:10.1103/PhysRevB.106.184502. ISSN   2469-9950. S2CID   250627324.
28. Du, Ke-zhao; Wang, Xing-zhi; Liu, Yang; Hu, Peng; Utama, M. Iqbal Bakti; Gan, Chee Kwan; Xiong, Qihua; Kloc, Christian (2016-02-23). "Weak Van der Waals Stacking, Wide-Range Band Gap, and Raman Study on Ultrathin Layers of Metal Phosphorus Trichalcogenides". ACS Nano. 10 (2): 1738–1743. doi:10.1021/acsnano.5b05927. ISSN   1936-0851. PMID   26607168.
29. McCarthy, Timothy J.; Kanatzidis, Mercouri G. (March 1995). "Synthesis in Molten Alkali Metal Polyselenophosphate Fluxes: A New Family of Transition Metal Selenophosphate Compounds, A2MP2Se6 (A = K, Rb, Cs; M = Mn, Fe) and A2M'2P2Se6 (A = K, Cs; M' = Cu, Ag)". Inorganic Chemistry. 34 (5): 1257–1267. doi:10.1021/ic00109a037. ISSN   0020-1669.
30. Li, Weiwei; Feng, Jiajia; Zhang, Xiaoliang; Li, Cong; Dong, Hongliang; Deng, Wen; Liu, Junxiu; Tian, Hua; Chen, Jian; Jiang, Sheng; Sheng, Hongwei; Chen, Bin; Zhang, Hengzhong (2021-12-08). "Metallization and Superconductivity in the van der Waals Compound CuP 2 Se through Pressure-Tuning of the Interlayer Coupling". Journal of the American Chemical Society. 143 (48): 20343–20355. doi:10.1021/jacs.1c09735. ISSN   0002-7863. PMID   34813695. S2CID   244529079.
31. Kuhn, Alexander; Schoop, Leslie M.; Eger, Roland; Moudrakovski, Igor; Schwarzmüller, Stefan; Duppel, Viola; Kremer, Reinhard K.; Oeckler, Oliver; Lotsch, Bettina V. (2016-08-15). "Copper Selenidophosphates Cu 4 P 2 Se 6 , Cu 4 P 3 Se 4 , Cu 4 P 4 Se 3 , and CuP 2 Se, Featuring Zero-, One-, and Two-Dimensional Anions". Inorganic Chemistry. 55 (16): 8031–8040. doi:10.1021/acs.inorgchem.6b01161. ISSN   0020-1669. PMID   27447868.
32. Neisius, Nathan A.; MacHale, Luke T.; Snyder, Erin R.; Finke, Richard G.; Prieto, Amy L. (2023-12-27). "Copper Selenophosphate, Cu 3 PSe 4 , Nanoparticle Synthesis: Octadecane Is the Key to a Simplified, Atom-Economical Reaction". Nano Letters. 23 (24): 11430–11437. Bibcode:2023NanoL..2311430N. doi:10.1021/acs.nanolett.3c02620. ISSN   1530-6984. PMID   38085913. S2CID   266217367.
33. Pfeiff, Regine; Kniep, Rüdiger (1993-09-01). "Darstellung von quaternären Selenodiphosphaten(IV) aus Halogenidschmelzen: Die Kristallstruktur des CuAl[P 2 Se 6 ] / Preparation of Quaternary Selenodiphosphates(IV) from Halide Melts: The Crystal Structure of CuAl[P 2 Se 6 ]". Zeitschrift für Naturforschung B. 48 (9): 1270–1274. doi: 10.1515/znb-1993-0916 . ISSN   1865-7117.
34. Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1998-05-01). "Flux Synthesis of K 2 Cu 2 P 4 Se 10 : A Layered Selenophosphate with a New Cyclohexane-like [P 4 Se 10 ] 4 - Group". Inorganic Chemistry. 37 (9): 2098–2099. doi:10.1021/ic971539+. ISSN   0020-1669. PMID   11670358.
35. Chen, John H.; Dorhout, Peter K. (November 1995). "Synthesis and Structural Characterization of a New Rare-Earth Selenodiphosphate: KLaP2Se6". Inorganic Chemistry. 34 (23): 5705–5706. doi:10.1021/ic00127a003. ISSN   0020-1669.
36. Dorhout, Peter K.; Malo, Todd M. (March 1996). "A three-dimensional network structure built from selenodiphosphate(IV) and copper selenide tetrahedral building blocks: K 3 Cu 3 P 3 Se 9". Zeitschrift für anorganische und allgemeine Chemie. 622 (3): 385–391. doi:10.1002/zaac.19966220302. ISSN   0044-2313.
37. Liu, C. W.; Chen, Hsiu-Chih; Wang, Ju-Chung; Keng, Tai-Chiun (2001-06-18). "[Cu12(P2Se6){Se2P(OR)2}8]: Discrete Copper Clusters Containing an Ethane-Like Hexaselenodiphosphate(IV)". Angewandte Chemie (in German). 113 (12): 2404–2406. doi:10.1002/1521-3757(20010618)113:12<2404::AID-ANGE2404>3.0.CO;2-7. ISSN   0044-8249.
38. Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (July 1998). "Group 10 and Group 12 One-Dimensional Selenodiphosphates:A2MP2Se6(A=K, Rb, Cs;M=Pd, Zn, Cd, Hg)". Journal of Solid State Chemistry. 138 (2): 321–328. doi:10.1006/jssc.1998.7791.
39. Haynes, Alyssa S.; Lee, Katherine; Kanatzidis, Mercouri G. (September 2016). "One-Dimensional Zinc Selenophosphates: A 2 ZnP 2 Se 6 ( A = K, Rb, Cs)". Zeitschrift für anorganische und allgemeine Chemie. 642 (19): 1120–1125. doi:10.1002/zaac.201600231. ISSN   0044-2313.
40. Morris, Collin D.; Chung, In; Park, Sungoh; Harrison, Connor M.; Clark, Daniel J.; Jang, Joon I.; Kanatzidis, Mercouri G. (2012-12-26). "Molecular Germanium Selenophosphate Salts: Phase-Change Properties and Strong Second Harmonic Generation". Journal of the American Chemical Society. 134 (51): 20733–20744. doi:10.1021/ja309386e. ISSN   0002-7863. PMID   23157167.
41. Morris, Collin D.; Malliakas, Christos D.; Kanatzidis, Mercouri G. (2011-10-17). "Germanium Selenophosphates: The Incommensurately Modulated 1 / ∞ [Ge 4-x P x Se 12 4– ] and the Molecular [Ge 2 P 2 Se 14 ] 6–". Inorganic Chemistry. 50 (20): 10241–10248. doi:10.1021/ic201249w. ISSN   0020-1669. PMID   21928764.
42. Morris, Collin D.; Kanatzidis, Mercouri G. (2010-10-04). "Arsenic-Containing Chalcophosphate Molecular Anions". Inorganic Chemistry. 49 (19): 9049–9054. doi:10.1021/ic101461w. ISSN   0020-1669. PMID   20825231.
43. Chung, In; Karst, Angela L.; Weliky, David P.; Kanatzidis, Mercouri G. (2006-04-01). "[P 6 Se 12 ] 4 - : A Phosphorus-Rich Selenophosphate with Low-Valent P Centers". Inorganic Chemistry. 45 (7): 2785–2787. doi:10.1021/ic0601135. ISSN   0020-1669. PMID   16562935.
44. Chondroudis, Konstantinos; Kanatzidis, Mercouri G (February 1998). "[Ce(PSe4)4]9−: a highly anionic Ce3+ selenophosphate coordination complex". Inorganic Chemistry Communications. 1 (2): 55–57. doi:10.1016/S1387-7003(98)00011-2.
45. Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (October 1995). "Complex Multinary Compounds from Molten Alkali Metal Polyselenophosphate Fluxes. Layers and Chains in A4Ti2(P2Se9)2(P2Se7) and ATiPSe5 (A = K, Rb). Isolation of [P2Se9]4-, a Flux Constituent Anion". Inorganic Chemistry. 34 (22): 5401–5402. doi:10.1021/ic00126a004. ISSN   0020-1669.
46. Zhao, Chen-Yi; Chen, Zi-Xia; Yao, Wen-Dong; Zhou, Wenfeng; Liu, Wenlong; Guo, Sheng-Ping (11 December 2023). "NaREP 2 Se 6 (RE = Y, Sm, Gd–Dy): Quaternary Rare-Earth Selenophosphates with Unique 3D {[REP 2 Se 6 ] − } ∞ Framework Built by RESe 8 and P 2 Se 6 Motifs and Multiple Properties". Inorganic Chemistry. 62 (49): 19843–19847. doi:10.1021/acs.inorgchem.3c03695. PMID   38032849. S2CID   265515288.
47. Zhao, Chen-Yi; Chen, Zi-Xia; Yao, Wen-Dong; Zhou, Wenfeng; Liu, Wenlong; Guo, Sheng-Ping (2023-12-11). "NaREP 2 Se 6 (RE = Y, Sm, Gd–Dy): Quaternary Rare-Earth Selenophosphates with Unique 3D {[REP 2 Se 6 ] − } ∞ Framework Built by RESe 8 and P 2 Se 6 Motifs and Multiple Properties". Inorganic Chemistry. 62 (49): 19843–19847. doi:10.1021/acs.inorgchem.3c03695. ISSN   0020-1669. PMID   38032849. S2CID   265515288.
48. Chen, John H.; Dorhout, Peter K.; Ostenson, J. E. (1996-01-01). "A Comparative Study of Two New Structure Types. Synthesis and Structural and Electronic Characterization of K(RE)P 2 Se 6 (RE = Y, La, Ce, Pr, Gd)". Inorganic Chemistry. 35 (19): 5627–5633. doi:10.1021/ic9516121. ISSN   0020-1669. PMID   11666755.
49. Seitz, A. E.; Heinl, V.; Timoshkin, A. Y.; Scheer, M. (2017). "Transformation of nortricyclane type cage compounds P 4 S 3 , P 4 Se 3 and As 4 S 3 by [Cp′′ 2 Zr(CO) 2 ]". Chemical Communications. 53 (6): 1172–1175. doi:10.1039/C6CC09427A. ISSN   1359-7345. PMID   28054088.
50. Banerjee, Santanu; Malliakas, Christos D.; Jang, Joon I.; Ketterson, John B.; Kanatzidis, Mercouri G. (2008-09-17). "1 / ∞ [ZrPSe 6 − ]: A Soluble Photoluminescent Inorganic Polymer and Strong Second Harmonic Generation Response of Its Alkali Salts". Journal of the American Chemical Society. 130 (37): 12270–12272. doi:10.1021/ja804166m. ISSN   0002-7863. PMID   18715000.
51. Syrigos, Jonathan C.; Clark, Daniel J.; Saouma, Felix O.; Clarke, Samantha M.; Fang, Lei; Jang, Joon I.; Kanatzidis, Mercouri G. (2015-01-13). "Semiconducting Properties and Phase-Matching Nonlinear Optical Response of the One-Dimensional Selenophosphates ANb 2 PSe 10 (A = K, Rb, and Cs)". Chemistry of Materials. 27 (1): 255–265. doi:10.1021/cm5038217. ISSN   0897-4756.
52. Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1997-07-04). "[P 3 Se]: A Novel Polyanion in K 3 RuP 5 Se 10 ; Formation of RuP Bonds in a Molten Polyselenophosphate Flux". Angewandte Chemie International Edition in English. 36 (12): 1324–1326. doi:10.1002/anie.199713241. ISSN   0570-0833.
53. Duan, Ruihuan; Zhu, Chao; Zeng, Qingsheng; Wang, Xiaowei; Gao, Yang; Deng, Ya; He, Yanchao; Yang, Jiefu; Zhou, Jiadong; Xu, Manzhang; Liu, Zheng (August 2021). "PdPSe: Component-Fusion-Based Topology Designer of Two-Dimensional Semiconductor". Advanced Functional Materials. 31 (35). doi:10.1002/adfm.202102943. ISSN   1616-301X. S2CID   237883693.
54. Xia, Houping; Ma, Qian (April 2019). "Experimental study on nonlinear−optical property of Ag4P2Se6". Journal of Alloys and Compounds. 780: 727–733. doi:10.1016/j.jallcom.2018.11.403. S2CID   139703145.
55. Susner, Michael A.; Conner, Benjamin S.; Rowe, Emmanuel; Siebenaller, Ryan; Giordano, Andrea; McLeod, Michael V.; Ebbing, Charles R.; Bullard, Thomas J.; Selhorst, Ryan; Haugan, Timothy J.; Jiang, Jie; Pachter, Ruth; Rao, Rahul (2024-03-02). "Structural, Magnetic, and Optical Properties of the van der Waals Antiferromagnet AgCrP 2 Se 6". The Journal of Physical Chemistry C. doi:10.1021/acs.jpcc.3c07433. ISSN   1932-7447.
56. Pfitzner, Arno; Seidlmayer, Stefan (April 2009). "Synthesis and Structure Determination of AgScP 2 Se 6 , AgErP 2 Se 6 and AgTmP 2 Se 6". Zeitschrift für anorganische und allgemeine Chemie. 635 (4–5): 704–707. doi:10.1002/zaac.200900004. ISSN   0044-2313. S2CID   94646944.
57. Chica, Daniel G.; He, Yihui; McCall, Kyle M.; Chung, Duck Young; Pak, Rahmi O.; Trimarchi, Giancarlo; Liu, Zhifu; De Lurgio, Patrick M.; Wessels, Bruce W.; Kanatzidis, Mercouri G. (2020-01-16). "Direct thermal neutron detection by the 2D semiconductor 6LiInP2Se6". Nature. 577 (7790): 346–349. doi:10.1038/s41586-019-1886-8. ISSN   0028-0836. PMID   31942050. S2CID   210221831.
58. Chondroudis, Konstantinos; Chakrabarty, Debojit; Axtell, Enos A.; Kanatzidis, Mercouri G. (June 1998). "Synthesis of the One-dimensional Compound (Ph4P)[In(P2Se6)] in a Ph4P+-Containing Selenophosphate Flux, and Structure of [In(P2Se6)2]5- - a Discrete Molecular Fragment of the [In(P2Se6)]nn- Chain". Zeitschrift für anorganische und allgemeine Chemie (in German). 624 (6): 975–979. doi:10.1002/(SICI)1521-3749(199806)624:6<975::AID-ZAAC975>3.0.CO;2-1. ISSN   0044-2313.
59. Coste, Servane; Kopnin, Evgeni; Evain, Michel; Jobic, Stéphane; Brec, Raymond; Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (April 2002). "Polychalcogenophosphate flux synthesis of 1D-KInP2Se6 and 1D and 3D-NaCrP2S6". Solid State Sciences. 4 (5): 709–716. doi:10.1016/S1293-2558(02)01317-1.
60. Rothenberger, Alexander; Wang, Hsien-Hau; Chung, DuckYoung; Kanatzidis, Mercouri G. (2010-02-01). "Structural Diversity by Mixing Chalcogen Atoms in the Chalcophosphate System K/In/P/Q (Q = S, Se)". Inorganic Chemistry. 49 (3): 1144–1151. doi:10.1021/ic902105j. ISSN   0020-1669. PMID   20030374.
61. Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (February 1998). "K4In2(PSe5)2(P2Se6) and Rb3Sn(PSe5)(P2Se6): One-Dimensional Compounds with Mixed Selenophosphate Anions". Journal of Solid State Chemistry. 136 (1): 79–86. doi:10.1006/jssc.1997.7659.
62. Zhang, Cheng-gong; Ji, Wei-xiao; Li, Ping; Zhang, Chang-wen; Wang, Pei-Ji (October 2021). "Tuning the electronic and optical properties of two-dimensional AgBiP2Se6 and AgInP2Se6 Janus monolayers". Chemical Physics Letters. 780: 138933. doi:10.1016/j.cplett.2021.138933.
63. Chica, Daniel; Sangwan, Vinod; Chu, Ting-Ching; Cheng, Matthew; Quintero, Michael; Hao, Shiqiang; Choi, Hyeonseon; Liu, Yukun; Qian, Eric (2022-10-17). SnP2Se6: A Chiral 2D Semiconductor for High-Performance Electronics and Optoelectronics (Report). In Review. doi:10.21203/rs.3.rs-2143024/v1.
64. Eijt, S; Maior, M.M (May 1999). "Raman and infrared hard mode spectroscopy of the internal vibrations in Sn2P2Se6". Journal of Physics and Chemistry of Solids. 60 (5): 631–643. Bibcode:1999JPCS...60..631E. doi:10.1016/S0022-3697(98)00319-9.
65. Duchardt, Marc; Neuberger, Sven; Ruschewitz, Uwe; Krauskopf, Thorben; Zeier, Wolfgang G.; Schmedt auf der Günne, Jörn; Adams, Stefan; Roling, Bernhard; Dehnen, Stefanie (2018-06-26). "Superion Conductor Na 11.1 Sn 2.1 P 0.9 Se 12 : Lowering the Activation Barrier of Na + Conduction in Quaternary 1–4–5–6 Electrolytes". Chemistry of Materials. 30 (12): 4134–4139. doi:10.1021/acs.chemmater.8b01656. ISSN   0897-4756.
66. Chung, In; Kanatzidis, Mercouri G. (2011-01-17). "Stabilization of Sn 2+ in K 10 Sn 3 (P 2 Se 6 ) 4 and Cs 2 SnP 2 Se 6 Derived from a Basic Flux". Inorganic Chemistry. 50 (2): 412–414. doi:10.1021/ic101140r. ISSN   0020-1669. PMID   21142146.
67. Chung, In; Biswas, Kanishka; Song, Jung-Hwan; Androulakis, John; Chondroudis, Konstantinos; Paraskevopoulos, Konstantinos M.; Freeman, Arthur J.; Kanatzidis, Mercouri G. (2011-09-12). "Rb 4 Sn 5 P 4 Se 20 : A Semimetallic Selenophosphate". Angewandte Chemie International Edition. 50 (38): 8834–8838. doi:10.1002/anie.201104050. ISSN   1433-7851. PMID   21812086.
68. Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1998-06-01). "Rb 4 Sn 2 Ag 4 (P 2 Se 6 ) 3 : First Example of a Quinary Selenophosphate and an Unusual Sn−Ag s 2 −d 10 Interaction". Inorganic Chemistry. 37 (12): 2848–2849. doi:10.1021/ic971468e. ISSN   0020-1669.
69. Chondroudis, Konstantinos; Kanatizidis, Mercouri G. (1996). "Isolation of [Sn(PSe 5 ) 3 ] 5– and [Sn 2 Se 4 (PSe 5 ) 2 ] 6– ; the first discrete complexes from molten alkali-metal polyselenophosphate fluxes". Chem. Commun. (11): 1371–1372. doi:10.1039/CC9960001371. ISSN   1359-7345.
70. Ruck, Michael (August 1995). "Darstellung und Kristallstruktur der Hexaselenodiphosphate(IV) von Antimon und Bismut". Zeitschrift für anorganische und allgemeine Chemie. 621 (8): 1344–1350. doi:10.1002/zaac.19956210812. ISSN   0044-2313.
71. Breshears, Jean D.; Kanatzidis, Mercouri G. (2000-08-01). "β-KMP 2 Se 6 (M = Sb, Bi): Kinetically Accessible Phases Obtained from Rapid Crystallization of Amorphous Precursors". Journal of the American Chemical Society. 122 (32): 7839–7840. doi:10.1021/ja001270k. ISSN   0002-7863.
72. Vu, Tuan V.; Lavrentyev, A.A.; Gabrelian, B.V.; Vo, Dat D.; Sabov, V.I.; Sabov, M.Yu.; Barchiy, I.E.; Piasecki, M.; Khyzhun, O.Y. (August 2020). "Highly anisotropic layered selenophosphate AgSbP2Se6: The electronic structure and optical properties by experimental measurements and first-principles calculations". Chemical Physics. 536: 110813. doi:10.1016/j.chemphys.2020.110813. S2CID   219077317.
73. Haynes, Alyssa S.; Banerjee, Abhishek; Saouma, Felix O.; Otieno, Calford O.; Jang, Joon I.; Kanatzidis, Mercouri G. (2016-04-12). "Phase Transition, Conformational Exchange, and Nonlinear Optical Third Harmonic Generation of A CsP 2 Se 8 ( A = K, Rb, Cs)". Chemistry of Materials. 28 (7): 2374–2383. doi:10.1021/acs.chemmater.6b00551. ISSN   0897-4756.
74. Gave, Matthew A.; Canlas, Christian G.; Chung, In; Iyer, Ratnasabapathy G.; Kanatzidis, Mercouri G.; Weliky, David P. (October 2007). "Cs4P2Se10: A new compound discovered with the application of solid-state and high temperature NMR". Journal of Solid State Chemistry. 180 (10): 2877–2884. doi:10.1016/j.jssc.2007.08.002.
75. Chung, In; Jang, Joon I.; Gave, Matthew A.; Weliky, David P.; Kanatzidis, Mercouri G. (2007). "Low valent phosphorus in the molecular anions [P5Se12]5– and β-[P6Se12]4–: phase change behavior and near infrared second harmonic generation". Chemical Communications (47): 4998–5000. doi:10.1039/b714301j. ISSN   1359-7345. PMID   18049732.
76. 李, 梦月; 谢, 秀媛; 吴, 新涛; 李, 晓芳; 林, 华 (2021). "Quaternary Selenophosphate Cs_2ZnP_2Se_6 Featuring Unique One-dimensional Chains and Exhibiting Remarkable Photo-electrochemical Response". Chinese Journal of Structural Chemistry. 40 (2): 246–255. doi:10.14102/j.cnki.0254-5861.2011-2822. ISSN   0254-5861.
77. Chung, In; Holmes, Daniel; Weliky, David P.; Kanatzidis, Mercouri G. (2010-04-05). "[P 3 Se 7 ] 3− : A Phosphorus-Rich Square-Ring Selenophosphate". Inorganic Chemistry. 49 (7): 3092–3094. doi:10.1021/ic902561h. ISSN   0020-1669. PMID   20180545.
78. Chondroudis, Konstantinos; Kanatzidis, Mercouri G.; Sayettat, Julien; Jobic, Stéphane; Brec, Raymond (1997-12-01). "Palladium Chemistry in Molten Alkali Metal Polychalcophosphate Fluxes. Synthesis and Characterization of K 4 Pd(PS 4 ) 2 , Cs 4 Pd(PSe 4 ) 2 , Cs 10 Pd(PSe 4 ) 4 , KPdPS 4 , K 2 PdP 2 S 6 , and Cs 2 PdP 2 Se 6". Inorganic Chemistry. 36 (25): 5859–5868. doi:10.1021/ic970593n. ISSN   0020-1669. PMID   11670209.
79. Haynes, Alyssa S.; Stoumpos, Constantinos C.; Chen, Haijie; Chica, Daniel; Kanatzidis, Mercouri G. (2017-08-09). "Panoramic Synthesis as an Effective Materials Discovery Tool: The System Cs/Sn/P/Se as a Test Case". Journal of the American Chemical Society. 139 (31): 10814–10821. doi:10.1021/jacs.7b05423. ISSN   0002-7863. PMID   28665593.
80. Galdámez, A; Manrı́quez, V; Kasaneva, J; Avila, R.E (May 2003). "Synthesis, characterization and electrical properties of quaternary selenodiphosphates: AMP2SE6 with A = Cu, Ag and M = Bi, Sb". Materials Research Bulletin. 38 (6): 1063–1072. doi:10.1016/S0025-5408(03)00068-0.
81. Jörgens, Stefan; Mewis, Albrecht (2005-04-01). "Neue Chalcogenophosphate: KBaPS 4 , KBaPSe 4 und Ba 3 PO 4 PSe 4 / New Chalcogenophosphates: KBaPS 4 , KBaPSe 4 , and Ba 3 PO 4 PSe 4". Zeitschrift für Naturforschung B. 60 (4): 431–436. doi: 10.1515/znb-2005-0414 . ISSN   1865-7117.
82. Jörgens, Stefan; Mewis, Albrecht (April 2007). "Synthese und Kristallstrukturen von α- und β -Ba 3 (PS 4 ) 2 sowie von Ba 3 (PSe 4 ) 2". Zeitschrift für anorganische und allgemeine Chemie. 633 (4): 570–574. doi:10.1002/zaac.200600360. ISSN   0044-2313.
83. Evenson; Dorhout, Peter K. (2001-06-01). "Selenophosphate Phase Diagrams Developed in Conjunction with the Synthesis of the New Compounds K 2 La(P 2 Se 6 ) 1/2 (PSe 4 ), K 3 La(PSe 4 ) 2 , K 4 La 0.67 (PSe 4 ) 2 , K 9- x La 1+ x /3 (PSe 4 ) 4 ( x = 0.5), and KEuPSe 4". Inorganic Chemistry. 40 (12): 2875–2883. doi:10.1021/ic000595z. ISSN   0020-1669. PMID   11375707.
84. Dorhout, Peter K.; Evenson, Carl R. (2001), Hochheimer, Hans D.; Kuchta, Bogdan; Dorhout, Peter K.; Yarger, Jeffery L. (eds.), "Synthesis of Low Dimensional F-Element Chalcogenide Compounds", Frontiers of High Pressure Research II: Application of High Pressure to Low-Dimensional Novel Electronic Materials, Dordrecht: Springer Netherlands, pp. 13–27, doi:10.1007/978-94-010-0520-3_2, ISBN   978-1-4020-0160-4 , retrieved 2023-12-27
85. Aitken, Jennifer A.; Evain, Michel; Iordanidis, Lykourgos; Kanatzidis, Mercouri G. (2002-01-01). "NaCeP 2 Se 6 , Cu 0.4 Ce 1.2 P 2 Se 6 , Ce 4 (P 2 Se 6 ) 3 , and the Incommensurately Modulated AgCeP 2 Se 6 : New Selenophosphates Featuring the Ethane-Like [P 2 Se 6 ] 4 - Anion". Inorganic Chemistry. 41 (2): 180–191. doi:10.1021/ic010618p. ISSN   0020-1669. PMID   11800606.
86. Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1998-07-01). "New Lanthanide Selenophosphates. Influence of Flux Composition on the Distribution of [PSe 4 ] 3 - /[P 2 Se 6 ] 4 - Units and the Stabilization of the Low-Dimensional Compounds A 3 REP 2 Se 8 , and A 2 (RE)P 2 Se 7 (A = Rb, Cs; RE = Ce, Gd)". Inorganic Chemistry. 37 (15): 3792–3797. doi:10.1021/ic980025n. ISSN   0020-1669. PMID   11670481.
87. Schulz, Beate M.; Lange, Pia L.; Schleid, Thomas (2020-11-26). "Three of a kind? The non-isotypic triple CsCe[P 2 Se 6 ], CsSm[P 2 Se 6 ] and CsEr[P 2 Se 6 ]". Zeitschrift für Naturforschung B. 75 (11): 959–967. doi:10.1515/znb-2020-0148. ISSN   1865-7117. S2CID   226968695.
88. 26th Annual Conference of the German Crystallographic Society, March 5–8, 2018, Essen, Germany. Walter de Gruyter GmbH & Co KG. 2018-03-05. p. 97. ISBN   978-3-11-059599-4.
89. Aitken, Jennifer A.; Chondroudis, Konstantinos; Young, Victor G.; Kanatzidis, Mercouri G. (2000-04-01). "LiEuPSe 4 and KEuPSe 4 : Novel Selenophosphates with the Tetrahedral [PSe 4 ] 3 - Building Block". Inorganic Chemistry. 39 (7): 1525–1533. doi:10.1021/ic991090f. ISSN   0020-1669. PMID   12526459.
90. Martin, Benjamin R.; Polyakova, Larisa A.; Dorhout, Peter K. (February 2006). "Synthesis and characterization of a family of two related quaternary selenides: Na8Eu2(Si2Se6)2 and Na9Sm(Ge2Se6)2". Journal of Alloys and Compounds. 408–412: 490–495. doi:10.1016/j.jallcom.2004.12.091.
91. Chondroudis, Konstantinos; McCarthy, Timothy J.; Kanatzidis, Mercouri G. (1996-01-01). "Chemistry in Molten Alkali Metal Polyselenophosphate Fluxes. Influence of Flux Composition on Dimensionality. Layers and Chains in APbPSe 4 , A 4 Pb(PSe 4 ) 2 (A = Rb, Cs), and K 4 Eu(PSe 4 ) 2". Inorganic Chemistry. 35 (4): 840–844. doi:10.1021/ic950479+. ISSN   0020-1669. PMID   11666254.
92. Chen, Zi-Xia; Zhao, Chen-Yi; Li, Xiao-Hui; Yao, Wen-Dong; Liu, Wenlong; Guo, Sheng-Ping (February 2023). "KREP 2 Se 6 (RE = Sm, Gd, Tb): The First Rare-Earth Selenophosphates with Remarkable Nonlinear Optical Activities Realized by Synergistic Effect of RE- and P-Based Motifs". Small. 19 (8): e2206910. doi:10.1002/smll.202206910. ISSN   1613-6810. PMID   36504482. S2CID   254617594.
93. Orgzall, I.; Lorenz, B.; Dorhout, P.K.; Van Calcar, P.M.; Brister, K.; Sander, T.; Hochheimer, H.D. (January 2000). "High pressure optical and X-ray diffraction studies of two polymorphs of K(RE)P2Se6 (RE=Pr and Tb)". Journal of Physics and Chemistry of Solids. 61 (1): 123–134. Bibcode:2000JPCS...61..123O. doi:10.1016/S0022-3697(99)00012-8.
94. Chondroudis, Konstantinos; Hanko, Jason A.; Kanatzidis, Mercouri G. (1997-06-01). "Chemistry of Gold in Molten Alkali Metal Polychalcophosphate Fluxes. Synthesis and Characterization of the Low-Dimensional Compounds A 3 AuP 2 Se 8 (A = K, Rb, Cs), A 2 Au 2 P 2 Se 6 (A = K, Rb), A 2 AuPS 4 (A = K, Rb, Cs), and AAuP 2 S 7 (A = K, Rb)". Inorganic Chemistry. 36 (12): 2623–2632. doi:10.1021/ic961376+. ISSN   0020-1669.
95. Chondroudis, Konstantinos; McCarthy, Timothy J.; Kanatzidis, Mercouri G. (1996-01-01). "A 2 AuP 2 Se 6 (A = K, Rb): Mixed-Valent Compounds with All Possible Coordination Geometries for Gold". Inorganic Chemistry. 35 (12): 3451–3452. doi:10.1021/ic9516020. ISSN   0020-1669.
96. Brockner, Wolfgang; Pätzmann, Ulrich (1987-05-01). "Schwingungsspektrum des Quecksilber-Hexaselenidohypodiphosphates Hg 2 P 2 Se 6". Zeitschrift für Naturforschung A. 42 (5): 517–518. doi: 10.1515/zna-1987-0518 . ISSN   1865-7109.
97. Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1997). "[M4(Se2)2(PSe4)4 ]8−: a novel, tetranuclear, cluster anion with a stellane-like core". Chemical Communications (4): 401–402. doi:10.1039/a607549e.
98. Nawaz, Zeeshan (2017-12-01). "Methyl-Tert-Butyl-Ether Synthesis Reactor Modelling and Optimization Using an Aspen Custom Modeler" (PDF). Hungarian Journal of Industry and Chemistry. 45 (2): 1–7. doi:10.1515/hjic-2017-0012. ISSN   2450-5102.
99. Barchii, I. E.; Tovt, V. A.; Piasecki, M.; Fedorchuk, A. A.; Solomon, A. M.; Pogodin, A. I. (April 2018). "Physicochemical Interaction in the TlInSe2–TlInP2Se6 System". Russian Journal of Inorganic Chemistry. 63 (4): 537–542. doi:10.1134/S0036023618040034. ISSN   0036-0236. S2CID   102636407.
100. Vu, Tuan V.; Lavrentyev, A.A.; Gabrelian, B.V.; Sabov, V.I.; Sabov, M.Y.; Pogodin, A.I.; Barchiy, I.E.; Fedorchuk, A.O.; Balinska, A.; Bak, Z.; Khyzhun, O.Y.; Piasecki, M. (December 2020). "TlSbP2Se6 - a new layered single crystal: growth, structure and electronic properties". Journal of Alloys and Compounds. 848: 156485. doi:10.1016/j.jallcom.2020.156485. S2CID   225134562.
101. Wang, Peng L.; Liu, Zhifu; Chen, Pice; Peters, John A.; Tan, Gangjian; Im, Jino; Lin, Wenwen; Freeman, Arthur J.; Wessels, Bruce W.; Kanatzidis, Mercouri G. (August 2015). "Hard Radiation Detection from the Selenophosphate Pb 2 P 2 Se 6". Advanced Functional Materials. 25 (30): 4874–4881. doi:10.1002/adfm.201501826. ISSN   1616-301X. S2CID   93827410.
102. Becker, Robert; Brockner, Wolfgang; Schäfer, Herbert (1984-04-01). "Kristallstruktur und Schwingungsspektren des Di-Blei-Hexaselenohypodiphosphates Pb 2 P 2 Se 6 / Crystal Structure and Vibrational Spectra of Pb 2 P 2 Se 6". Zeitschrift für Naturforschung A. 39 (4): 357–361. doi: 10.1515/zna-1984-0407 . ISSN   1865-7109.
103. Aitken, Jennifer A.; Marking, Gregory A.; Evain, Michel; Iordanidis, Lykourgos; Kanatzidis, Mercouri G. (August 2000). "Flux Synthesis and Isostructural Relationship of Cubic Na1.5Pb0.75PSe4, Na0.5Pb1.75GeS4, and Li0.5Pb1.75GeS4". Journal of Solid State Chemistry. 153 (1): 158–169. doi:10.1006/jssc.2000.8767.
104. Qian, Eric K.; Iyer, Abishek K.; Cheng, Matthew; Ryan, Kevin M.; Jirousek, Lillian; Chica, Daniel G.; Krantz, Patrick; Lee, Yea-Shine; Chandrasekhar, Venkat; Dravid, Vinayak P.; Kanatzidis, Mercouri G. (2023-05-09). "Synthesizing Mono- and Bimetallic 2D Selenophosphates Using a P 2 Se 5 Reactive Flux". Chemistry of Materials. 35 (9): 3671–3685. doi:10.1021/acs.chemmater.3c00342. ISSN   0897-4756. S2CID   258349455.
105. Gave, Matthew A.; Bilc, Daniel; Mahanti, S. D.; Breshears, Jean D.; Kanatzidis, Mercouri G. (2005-07-01). "On the Lamellar Compounds CuBiP 2 Se 6 , AgBiP 2 Se 6 and AgBiP 2 S 6 . Antiferroelectric Phase Transitions Due to Cooperative Cu + and Bi 3+ Ion Motion". Inorganic Chemistry. 44 (15): 5293–5303. doi:10.1021/ic050357+. ISSN   0020-1669. PMID   16022528.
106. He, Wei; Kong, Lingling; Yu, Peng; Yang, Guowei (April 2023). "Record-High Work-Function p-Type CuBiP 2 Se 6 Atomic Layers for High-Photoresponse van der Waals Vertical Heterostructure Phototransistor". Advanced Materials. 35 (14): e2209995. Bibcode:2023AdM....3509995H. doi:10.1002/adma.202209995. ISSN   0935-9648. PMID   36640444. S2CID   255825402.
107. Chung, In; Song, Jung-Hwan; Jang, Joon I.; Freeman, Arthur J.; Ketterson, John B.; Kanatzidis, Mercouri G. (2009-02-25). "Flexible Polar Nanowires of Cs 5 BiP 4 Se 12 from Weak Interactions between Coordination Complexes: Strong Nonlinear Optical Second Harmonic Generation". Journal of the American Chemical Society. 131 (7): 2647–2656. doi:10.1021/ja808242g. ISSN   0002-7863. PMID   19183006.
108. Gave, Matthew A.; Malliakas, Christos D.; Weliky, David P.; Kanatzidis, Mercouri G. (2007-04-30). "Wide Compositional and Structural Diversity in the System Tl/Bi/P/Q (Q = S, Se) and Observation of Vicinal P−Tl J Coupling in the Solid State". Inorganic Chemistry. 46 (9): 3632–3644. doi:10.1021/ic062465h. ISSN   0020-1669. PMID   17397145.
109. Briggs Piccoli, Paula M.; Abney, Kent D.; Schoonover, Jon R.; Dorhout, Peter K. (2000-07-01). "Synthesis and Structural Characterization of Quaternary Thorium Selenophosphates: A 2 ThP 3 Se 9 (A = K, Rb) and Cs 4 Th 2 P 5 Se 17". Inorganic Chemistry. 39 (14): 2970–2976. doi:10.1021/ic990767w. ISSN   0020-1669. PMID   11196891.
110. Briggs-Piccoli, Paula M.; Abney, Kent D.; Dorhout, Peter K. (November 2002). "The Synthesis and Structural Characterization of a New Beta Phase of K 2 ThP 3 Se 9". Journal of Nuclear Science and Technology. 39 (sup3): 611–615. Bibcode:2002JNST...39S.611B. doi:10.1080/00223131.2002.10875542. ISSN   0022-3131.
111. Chan, Benny C.; Hess, Ryan F.; Feng, Patrick L.; Abney, Kent D.; Dorhout, Peter K. (2005-03-21). "Synthesis and Characterization of Two Quaternary Thorium Chalcophosphates: Cs 4 Th 2 P 6 S 18 and Rb 7 Th 2 P 6 Se 21". Inorganic Chemistry. 44 (6): 2106–2113. doi:10.1021/ic049101e. ISSN   0020-1669. PMID   15762739.
112. Briggs Piccoli, Paula M.; Abney, Kent D.; Schoonover, Jon D.; Dorhout, Peter K. (2001-09-01). "Synthesis, Structure, and Properties of Cs 4 Th 4 P 4 Se 26 : A Quaternary Thorium Selenophosphate Containing the (P 2 Se 9 ) 6 - Anion". Inorganic Chemistry. 40 (19): 4871–4875. doi:10.1021/ic001103l. ISSN   0020-1669. PMID   11531433.
113. K., Chondroudis; M.G., Kanatzidis (1996). "Synthesis and characterization of K₂UP₃Se₉. The first actinide seleno-phosphate". Comptes Rendus de l'Académie des Sciences, Série 2. 322 (12). ISSN   1251-8069.
114. Bellott, Brian J.; Ibers, James A. (December 2012). "Synthesis and Structure of the Rubidium Uranium Selenophosphate Rb 4 U 2 P 5 Se 17". Zeitschrift für anorganische und allgemeine Chemie. 638 (15): 2473–2476. doi:10.1002/zaac.201200316. ISSN   0044-2313.
115. Chondroudis, Konstantinos; Kanatzidis, Mercouri G. (1997-03-01). "Stabilization of U 5+ in Rb 4 U 4 P 4 Se 26 . An Actinide Compound with a Mixed Selenophosphate/Polyselenide Framework and Ion-Exchange Properties". Journal of the American Chemical Society. 119 (10): 2574–2575. doi:10.1021/ja963673j. ISSN   0002-7863.
116. Mesbah, Adel; Prakash, Jai; Beard, Jessica C.; Lebègue, Sébastien; Ibers, James A. (2018-11-30). "Synthesis and Crystal Structure of Cs 2 U 2 (P 2 Se 9 )(Se 2 ) 2". Zeitschrift für anorganische und allgemeine Chemie. 644 (22): 1480–1484. doi:10.1002/zaac.201800263. ISSN   0044-2313. S2CID   105028651.

Extra reading

• Wang, Fengmei; Shifa, Tofik A.; Yu, Peng; He, Peng; Liu, Yang; Wang, Feng; Wang, Zhenxing; Zhan, Xueying; Lou, Xiaoding; Xia, Fan; He, Jun (September 2018). "New Frontiers on van der Waals Layered Metal Phosphorous Trichalcogenides". Advanced Functional Materials. 28 (37). doi:10.1002/adfm.201802151. hdl: 10278/3742841 . ISSN   1616-301X. S2CID   105564142.
• Samal, Rutuparna; Sanyal, Gopal; Chakraborty, Brahmananda; Rout, Chandra Sekhar (2021). "Two-dimensional transition metal phosphorous trichalcogenides (MPX 3 ): a review on emerging trends, current state and future perspectives". Journal of Materials Chemistry A. 9 (5): 2560–2591. doi:10.1039/D0TA09752G. ISSN   2050-7488. S2CID   233958469.
• Susner, Michael A.; Chyasnavichyus, Marius; McGuire, Michael A.; Ganesh, Panchapakesan; Maksymovych, Petro (October 2017). "Metal Thio- and Selenophosphates as Multifunctional van der Waals Layered Materials". Advanced Materials. 29 (38). Bibcode:2017AdM....2902852S. doi:10.1002/adma.201602852. ISSN   0935-9648. OSTI   1842642. PMID   28833546. S2CID   31497995.
• Chen, Zi-Xia; Liu, Wenlong; Guo, Sheng-Ping (January 2023). "A review of structures and physical properties of rare earth chalcophosphates". Coordination Chemistry Reviews. 474: 214870. doi:10.1016/j.ccr.2022.214870. S2CID   252869394.
• Li, Zhuang; Yao, Jiyong; Wu, Yicheng (4 November 2020). "Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials". Crystal Growth & Design. 20 (11): 7550–7564. doi:10.1021/acs.cgd.0c01234. S2CID   226340520.