Barium selenide

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Barium selenide
Barium selenide.vk.jpg
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.013.755 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 215-130-5
PubChem CID
UNII
  • InChI=1S/Ba.Se/q+2;-2
    Key: RJWLRCHYHHXJLX-UHFFFAOYSA-N
  • [Se-2].[Ba+2]
Properties
BaSe
Molar mass 216.298 g·mol−1
Appearancewhite solid
Structure [1]
NaCl type (cubic)
Fm3m (No. 225)
a = 662.9 pm
4
Hazards
GHS labelling: [2]
GHS-pictogram-skull.svg GHS-pictogram-silhouette.svg GHS-pictogram-pollu.svg
Danger
H301, H331, H373, H410
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Barium selenide is an inorganic compound, with the chemical formula of BaSe. It is a white solid although typically samples are colored owing to the effects of air oxidation. [3]

Contents

BaSe has the lowest energy band gap among alkaline earth chalcogenides. [4]

Preparation

Barium selenide can be obtained by the reduction of barium selenate in hydrogen flow:. [3] [5]

BaSeO4 + H2 → BaSe + 4 H2O

It can also be obtained by reacting selenium with barium carbonate or barium oxide at high temperature:[ citation needed ]

2 BaCO3 + 5 Se → 2 BaSe + 3 SeO2 + CO2

Barium can also forms a series of polyselenide compounds, such as Ba2Se3, BaSe2 and BaSe3. [1]

Related Research Articles

<span class="mw-page-title-main">Barium</span> Chemical element, symbol Ba and atomic number 56

Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element.

<span class="mw-page-title-main">Selenium</span> Chemical element, symbol Se and atomic number 34

Selenium is a chemical element with the symbol Se and atomic number 34. It is a metalloid with properties that are intermediate between the elements above and below in the periodic table, sulfur and tellurium, and also has similarities to arsenic. It seldom occurs in its elemental state or as pure ore compounds in Earth's crust. Selenium was discovered in 1817 by Jöns Jacob Berzelius, who noted the similarity of the new element to the previously discovered tellurium.

<span class="mw-page-title-main">Barium carbonate</span> Chemical compound

Barium carbonate is the inorganic compound with the formula BaCO3. Like most alkaline earth metal carbonates, it is a white salt that is poorly soluble in water. It occurs as the mineral known as witherite. In a commercial sense, it is one of the most important barium compounds.

Selenic acid is the inorganic compound with the formula H2SeO4. It is an oxoacid of selenium, and its structure is more accurately described as O2Se(OH)2. It is a colorless compound. Although it has few uses, one of its salts, sodium selenate is used in the production of glass and animal feeds.

<span class="mw-page-title-main">Sodium selenite</span> Chemical compound

Sodium selenite is the inorganic compound with the formula Na2SeO3. This salt is a colourless solid. The pentahydrate Na2SeO3(H2O)5 is the most common water-soluble selenium compound.

<span class="mw-page-title-main">Selenium compounds</span> Chemical compounds containing selenium

Selenium compounds commonly exist in the oxidation states −2, +2, +4, and +6.

Magnesium compounds are compounds formed by the element magnesium (Mg). These compounds are important to industry and biology, including magnesium carbonate, magnesium chloride, magnesium citrate, magnesium hydroxide, magnesium oxide, magnesium sulfate, and magnesium sulfate heptahydrate.

<span class="mw-page-title-main">Barium sulfide</span> Chemical compound

Barium sulfide is the inorganic compound with the formula BaS. BaS is the barium compound produced on the largest scale. It is an important precursor to other barium compounds including BaCO3 and the pigment lithopone, ZnS/BaSO4. Like other chalcogenides of the alkaline earth metals, BaS is a short wavelength emitter for electronic displays. It is colorless, although like many sulfides, it is commonly obtained in impure colored forms.

<span class="mw-page-title-main">Barium ferrate</span> Chemical compound

Barium ferrate is the chemical compound of formula BaFeO4. This is a rare compound containing iron in the +6 oxidation state. The ferrate(VI) ion has two unpaired electrons, making it paramagnetic. It is isostructural with BaSO4, and contains the tetrahedral [FeO4]2− anion.

<span class="mw-page-title-main">Sodium selenide</span> Chemical compound

Sodium selenide is an inorganic compound of sodium and selenium with the chemical formula Na2Se.

Managnese(II) selenide is an inorganic compound with the chemical formula MnSe.

Thullium(III) fluoride is an inorganic compound with the chemical formula TmF3.

<span class="mw-page-title-main">Lutetium(III) fluoride</span> Chemical compound

Lutetium(III) fluoride is an inorganic compound with a chemical formula LuF3.

<span class="mw-page-title-main">Europium compounds</span> Compounds with at least one europium atom

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

<span class="mw-page-title-main">Selenosulfide</span>

In chemistry, a selenosulfide refers to distinct classes of inorganic and organic compounds containing sulfur and selenium. The organic derivatives contain Se-S bonds, whereas the inorganic derivatives are more variable.

Lutetium compounds are compounds formed by the lanthanide metal lutetium (Lu). In these compounds, lutetium generally exhibits the +3 oxidation state, such as LuCl3, Lu2O3 and Lu2(SO4)3. Aqueous solutions of most lutetium salts are colorless and form white crystalline solids upon drying, with the common exception of the iodide. The soluble salts, such as nitrate, sulfate and acetate form hydrates upon crystallization. The oxide, hydroxide, fluoride, carbonate, phosphate and oxalate are insoluble in water.

Thulium selenide is an inorganic compound with the chemical formula Tm2Se3. It can be obtained by the reaction of thulium and selenium or thulium oxide and hydrogen selenide at high temperature, or generated in the thermal decomposition of (py)3Tm(SePh)3. In the binary system of it and antimony triselenide, TmSb3Se6, Tm6Sb8Se21, TmSbSe3 and Tm8Sb2Se15 can be formed.

Erbium selenide is an inorganic compound with a chemical formula of Er2Se3. It is an orthorhombic crystal with a Sc2S3 structure and a space group of Fddd. It can be obtained by the reaction of erbium and selenium or erbium oxide and hydrogen selenide at high temperature. It reacts with magnesium selenide at 1000 °C to obtain MgEr2Se4.

Holmium selenide is an inorganic compound with the chemical formula Ho2Se3. It can be obtained from the reaction of holmium and selenium (in the presence of iodine) or holmium oxide and hydrogen selenide at high temperature. It can form orthorhombic AgHoSe2 in the binary system of silver selenide.

<span class="mw-page-title-main">Strontium selenide</span> Chemical compound

Strontium selenide is an inorganic compound with the chemical formula SrSe.

References

  1. 1 2 Okamoto, H (August 1991). "The Ba-Se (Barium-Selenium) system". Journal of Phase Equilibria. 12 (4): 467–469. doi:10.1007/BF02645971. ISSN   1054-9714. S2CID   95845653.
  2. "C&L Inventory". echa.europa.eu.
  3. 1 2 P. Ehrlich (1963). "Alkaline Earth Metals". In G. Brauer (ed.). Handbook of Preparative Inorganic Chemistry, 2nd Ed. Vol. 2pages=939. NY,NY: Academic Press.
  4. V. V. Sobolev, D. А. Merzlyakov, V. Val. Sobolev (March 2017). "A Study of the Optical Properties of Barium Selenide Crystals. I. Fundamental Functions". Journal of Applied Spectroscopy. 84 (1): 59–65. Bibcode:2017JApSp..84...59S. doi:10.1007/s10812-017-0427-1. ISSN   0021-9037. S2CID   254609774 . Retrieved 2018-08-09.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  5. Handbuch der präparativen anorganischen Chemie Bd. 2. / Unter Mitarb. von M. Baudler ... Marianne Baudler (3., umgearb. Aufl ed.). Stuttgart. 1978. p. 949. ISBN   978-3-432-87813-3. OCLC   310719490.{{cite book}}: CS1 maint: location missing publisher (link) CS1 maint: others (link)