Dysprosium(III) selenide

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Dysprosium(III) selenide
2.svg Dy3+.svg 3.svg Se2-.svg
Identifiers
3D model (JSmol)
EC Number
  • 234-652-4
PubChem CID
  • InChI=1S/2Dy.3Se/q2*+3;3*-2
    Key: AXKRJHNJTNYZJO-UHFFFAOYSA-N
  • [Se-2].[Se-2].[Se-2].[Dy+3].[Dy+3]
Properties
Dy2Se3
Molar mass 561.913 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Dysprosium(III) selenide is one of the selenides of dysprosium, with the chemical formula of Dy2Se3.

Contents

Preparation

Dysprosium(III) selenide can be prepared by reacting dysprosium(III) oxide or dysprosium(III) chloride with hydrogen selenide: [1]

Dy2O3 + 3 H2Se → Dy2Se3 + 3 H2O
2 DyCl3 + 3 H2Se → Dy2Se3 + 6 HCl

It can also be obtained by reacting the elements at high temperatures: [2]

2 Dy + 3 Se → Dy2Se3

Properties

Dysprosium(III) selenide reacts with arsenic triselenide to obtain DyAsSe3. [3]

Dy2Se3 + As2Se3 → 2DyAsSe3

Related Research Articles

<span class="mw-page-title-main">Dysprosium</span> Chemical element, symbol Dy and atomic number 66

Dysprosium is a chemical element; it has symbol Dy and atomic number 66. It is a rare-earth element in the lanthanide series with a metallic silver luster. Dysprosium is never found in nature as a free element, though, like other lanthanides, it is found in various minerals, such as xenotime. Naturally occurring dysprosium is composed of seven isotopes, the most abundant of which is 164Dy.

<span class="mw-page-title-main">Dysprosium(III) chloride</span> Chemical compound

Dysprosium(III) chloride (DyCl3), also known as dysprosium trichloride, is a compound of dysprosium and chlorine. It is a white to yellow solid which rapidly absorbs water on exposure to moist air to form a hexahydrate, DyCl3·6H2O. Simple rapid heating of the hydrate causes partial hydrolysis to an oxychloride, DyOCl.

<span class="mw-page-title-main">Hydrogen selenide</span> Chemical compound

Hydrogen selenide is an inorganic compound with the formula H2Se. This hydrogen chalcogenide is the simplest and most commonly encountered hydride of selenium. H2Se is a colorless, flammable gas under standard conditions. It is the most toxic selenium compound with an exposure limit of 0.05 ppm over an 8-hour period. Even at extremely low concentrations, this compound has a very irritating smell resembling that of decayed horseradish or 'leaking gas', but smells of rotten eggs at higher concentrations.

<span class="mw-page-title-main">Selenium compounds</span> Chemical compounds containing selenium

Selenium compounds are compounds containing the element selenium (Se). Among these compounds, selenium has various oxidation states, the most common ones being −2, +4, and +6. Selenium compounds exist in nature in the form of various minerals, such as clausthalite, guanajuatite, tiemannite, crookesite etc., and can also coexist with sulfide minerals such as pyrite and chalcopyrite. For many mammals, selenium compounds are essential. For example, selenomethionine and selenocysteine are selenium-containing amino acids present in the human body. Selenomethionine participates in the synthesis of selenoproteins. The reduction potential and pKa (5.47) of selenocysteine are lower than those of cysteine, making some proteins have antioxidant activity. Selenium compounds have important applications in semiconductors, glass and ceramic industries, medicine, metallurgy and other fields.

<span class="mw-page-title-main">Dysprosium(III) oxide</span> Chemical compound

Dysprosium oxide (Dy2O3) is a sesquioxide compound of the rare earth metal dysprosium. It is a pastel yellowish-greenish, slightly hygroscopic powder having specialized uses in ceramics, glass, phosphors, lasers, as a Faraday rotator and dysprosium metal halide lamps.

<span class="mw-page-title-main">Sodium selenide</span> Chemical compound

Sodium selenide is an inorganic compound of sodium and selenium with the chemical formula Na2Se.

<span class="mw-page-title-main">Dysprosium acetylacetonate</span> Chemical compound

Dysprosium acetylacetonate is a chemical compound of dysprosium with formula Dy(C5H7O2)3(H2O)n.

Calcium selenide (CaSe) is a chemical compound consisting of the elements calcium and selenium in equal stoichiometric ratio.

<span class="mw-page-title-main">Dysprosium(III) hydroxide</span> Chemical compound

Dysprosium(III) hydroxide is an inorganic compound with the chemical formula Dy(OH)3.

<span class="mw-page-title-main">Dysprosium(III) nitrate</span> Chemical compound

Dysprosium(III) nitrate is an inorganic compound, a salt of dysprosium and nitric acid with the chemical formula Dy(NO3)3. The compound forms yellowish crystals, dissolves in water, forms a crystalline hydrate.

<span class="mw-page-title-main">Neodymium perrhenate</span> Chemical compound

Neodymium perrhenate is an inorganic compound with the chemical formula Nd(ReO4)3, which exists in anhydrous and tetrahydrate. It can be obtained by reacting excess neodymium oxide with 240 g/L perrhenic acid solution. In its solution, NdReO42+ and Nd(ReO4)2+ can be observed with stability constants of 16.5 and 23.6, respectively.

<span class="mw-page-title-main">Dysprosium(III) acetate</span> Chemical compound

Dysprosium acetate is a hypothetical salt of dysprosium and acetate. Its proposed chemical formula is Dy(CH3COO)3.

<span class="mw-page-title-main">Europium compounds</span> Compounds with at least one europium atom

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

<span class="mw-page-title-main">Dysprosium(III) bromide</span> Chemical compound

Dysprosium(III) bromide is an inorganic compound of bromine and dysprosium, with the chemical formula of DyBr3.

<span class="mw-page-title-main">Barium selenide</span> Chemical compound

Barium selenide is an inorganic compound, with the chemical formula of BaSe. It is a white solid although typically samples are colored owing to the effects of air oxidation.

Lutetium(III) selenide is an inorganic compound with the chemical formula Lu2Se3.

Thulium(III) selenide is an inorganic compound with the chemical formula Tm2Se3.

Erbium(III) selenide is an inorganic compound with a chemical formula of Er2Se3.

Holmium(III) selenide is an inorganic compound with the chemical formula Ho2Se3.

<span class="mw-page-title-main">Dysprosium(III) phosphate</span> Chemical compound

Dysprosium(III) phosphate is an inorganic compound with the chemical formula DyPO4.

References

  1. Klemm, Wilhelm; Koczy, Alfred. Selenides of the rare earths. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1937. 233: 84-96. ISSN   0044-2313.
  2. Guittard, Micheline; Flahaut, Jean; Domange, Louis. Yttrium, gadolinium, dysprosium, and erbium selenides. Compt. Rend., 1963. 256: 427-429.
  3. Azadaliev, R. A.; Aleiv, O. M.; Sadykhov, F. M.; Il'yasov, T. M.; Rustamov, P. G. Dysprosium sesquiselenide-arsenic sesquiselenide system. Zhurnal Neorganicheskoi Khimii, 1992. 37 (12): 2790-2791. ISSN   0044-457X.