Dysprosium(III) acetate

Dysprosium(III) acetate

Names
Other names Dysprosium triacetate
Identifiers
CAS Number	18779-07-2 anhydrous Y 15280-55-4 tetrahydate Y
3D model (JSmol)	Interactive image
ChemSpider	146739
ECHA InfoCard	100.157.317
EC Number	242-565-8
PubChem CID	167746
CompTox Dashboard (EPA)	DTXSID40890780 DTXSID50934604, DTXSID40890780
InChI InChI=1S/3C2H4O2.Dy/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3 Key: HKCSKROOVZMKSO-UHFFFAOYSA-K
SMILES CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Dy+3]
Properties
Chemical formula	Dy(CH3COO)3
Molar mass	339.63 g/mol
Appearance	white powder [1]
Solubility in water	soluble in water [2]
Hazards
GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H315, H319, H335
Precautionary statements	P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, P501
Related compounds
Other cations	Terbium acetate Holmium acetate
Related compounds	Dysprosium oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Dysprosium acetate is an inorganic compound with the formula Dy(CH₃COO)₃. ^[3] It forms hydrates including a tetrahydrate. ^[4]

Preparation

Dysprosium acetate can be obtained by treating dysprosium oxide with acetic acid: ^[1]

Dy₂O₃ + 6 CH₃COOH → 2 Dy(CH₃COO)₃ + 3 H₂O

Its hydrate, when heated to 150 °C in vacuum, yields the anhydrous triacetate. ^[5]

Reactions

Dysprosium(III) acetate tetrahydrate catalyzes the cyclization of 2-{[2-(phenylsulfonyl)hydrazinylidene]methyl}benzoic acid (BSHOPA) to form 2-(phenylsulfonyl)phthalazin-1(2H)-one (PSP). ^[6]

Dysprosium(III) acetate forms a variety of coordination polymers, e.g. with cymantrenecarboxylic acid. ^[7]

References

1. 唐慧安, 陈灵娟, 李会学,等. 醋酸镝的合成方法, CN104151155A[P]. 2014.
2. 14595 Dysprosium(III) acetate tetrahydrate, MSDS. Alfa Aesar. [2017-11-5]
3. PubChem. "Acetic acid, dysprosium(3+) salt (3:1)". pubchem.ncbi.nlm.nih.gov. Retrieved 2025-06-20.
4. Perry, Dale L. (1995-05-17). Handbook of Inorganic Compounds. CRC Press. p. 152. ISBN   978-0-8493-8671-8.
5. J.R. Witt, E.I. Onstott (November 1962). "Preparation of anhydrous lanthanon acetates by desolvation" . Journal of Inorganic and Nuclear Chemistry. 24 (6): 637–639. doi:10.1016/0022-1902(62)80081-5. ISSN   0022-1902. Archived from the original on 2018-06-30. Retrieved 2018-05-09.
6. Asegbeloyin, Jonnie N.; Izuogu, David Chukwuma; Oyeka, Ebube Evaristus; Okpareke, Obinna C.; Ibezim, Akachukwu (2019-01-05). "Crystal structure, non-covalent interaction and molecular docking studies of 2-{[2-phenylsulfonyl)hydrazinylidene]methyl}benzoic acid and its dysprosium catalysed cyclized product: 2-(phenyl-sulfonyl)phthalazin-1(2H)-one" . Journal of Molecular Structure. 1175: 219–229. doi:10.1016/j.molstruc.2018.07.073. ISSN   0022-2860.
7. Koroteev, Pavel S.; Dobrokhotova, Zhanna V.; Ilyukhin, Andrey B.; Efimov, Nikolay N.; Kirdyankin, Denis I.; Tyurin, Aleksandr V.; Gavrikov, Andrey V.; Novotortsev, Vladimir M. (2015-01-08). "Polymeric lanthanide acetates with peripheral cymantrenecarboxylate groups – Synthesis, magnetism and thermolysis" . Polyhedron. 85: 941–952. doi:10.1016/j.poly.2014.09.040. ISSN   0277-5387.