Calcium acetate

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Calcium acetate
Calcium acetate.svg
Ca-acetate.png
Calcium acetate crystals
Names
Preferred IUPAC name
Calcium diacetate [1]
Other names
Acetate of lime
Calcium ethanoate
Identifiers
3D model (JSmol)
AbbreviationsCa(OAc)2
3692527
ChEBI
ChEMBL
ChemSpider
DrugBank
ECHA InfoCard 100.000.492 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 269-613-0
E number E263 (preservatives)
22320
KEGG
PubChem CID
RTECS number
  • AF7525000
UNII
  • InChI=1S/2C2H4O2.Ca/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2 Yes check.svgY
    Key: VSGNNIFQASZAOI-UHFFFAOYSA-L Yes check.svgY
  • InChI=1/2C2H4O2.Ca/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
    Key: VSGNNIFQASZAOI-NUQVWONBAW
  • CC(=O)O[Ca]OC(=O)C
  • [Ca+2].[O-]C(=O)C.[O-]C(=O)C
Properties
C4H6CaO4
Molar mass 158.166 g/mol (anhydrous)
176.181 g/mol (monohydrate)
AppearanceWhite solid
hygroscopic
Odor slight acetic acid odor
Density 1.509 g/cm3
Melting point 160 °C (320 °F; 433 K) [2] decomposition to CaCO3 + acetone
37.4 g/100 mL (0 °C)
34.7 g/100 mL (20 °C)
29.7 g/100 mL (100 °C)
Solubility slightly soluble in methanol, hydrazine
insoluble in acetone, ethanol and benzene
Acidity (pKa)ca. 0.7
-70.7·10−6 cm3/mol
1.55
Pharmacology
V03AE07 ( WHO )
Hazards
NFPA 704 (fire diamond)
NFPA 704.svgHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
1
0
680 to 730 °C (1,256 to 1,346 °F; 953 to 1,003 K)
Lethal dose or concentration (LD, LC):
4280 mg/kg (oral, rat)
Related compounds
Other cations
Magnesium acetate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
X mark.svgN  verify  (what is  Yes check.svgYX mark.svgN ?)

Calcium acetate is a chemical compound which is a calcium salt of acetic acid. It has the formula Ca(C2H3O2)2. Its standard name is calcium acetate, while calcium ethanoate is the systematic name. An older name is acetate of lime. The anhydrous form is very hygroscopic; therefore the monohydrate (Ca(CH3COO)2•H2O) is the common form.

Contents

Production

Calcium acetate can be prepared by soaking calcium carbonate (found in eggshells, or in common carbonate rocks such as limestone or marble) or hydrated lime in vinegar:

CaCO3(s) + 2CH3COOH(aq) → Ca(CH3COO)2(aq) + H2O(l) + CO2(g)
Ca(OH)2(s) + 2CH3COOH(aq) → Ca(CH3COO)2(aq) + 2H2O(l)

Since both reagents would have been available pre-historically, the chemical would have been observable as crystals then.

Uses

Ca(CH3COO)2 → CaCO3(s) + (CH3)2CO

Natural occurrence

Pure calcium acetate is yet unknown among minerals. Calclacitecalcium acetate chloride pentahydrate—is listed as a known mineral, [9] but its genesis is likely anthropogenic (human-generated, as opposed to naturally occurring). [10] [ failed verification ]

Related Research Articles

<span class="mw-page-title-main">Calcium</span> Chemical element with atomic number 20 (Ca)

Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to its heavier homologues strontium and barium. It is the fifth most abundant element in Earth's crust, and the third most abundant metal, after iron and aluminium. The most common calcium compound on Earth is calcium carbonate, found in limestone and the fossilised remnants of early sea life; gypsum, anhydrite, fluorite, and apatite are also sources of calcium. The name derives from Latin calx "lime", which was obtained from heating limestone.

<span class="mw-page-title-main">Carbonate</span> Salt or ester of carbonic acid

A carbonate is a salt of carbonic acid, H2CO3, characterized by the presence of the carbonate ion, a polyatomic ion with the formula CO2−3. The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate groupO=C(−O−)2.

<span class="mw-page-title-main">Stalactite</span> Elongated mineral formation hanging down from a cave ceiling

A stalactite is a mineral formation that hangs from the ceiling of caves, hot springs, or man-made structures such as bridges and mines. Any material that is soluble and that can be deposited as a colloid, or is in suspension, or is capable of being melted, may form a stalactite. Stalactites may be composed of lava, minerals, mud, peat, pitch, sand, sinter, and amberat. A stalactite is not necessarily a speleothem, though speleothems are the most common form of stalactite because of the abundance of limestone caves.

<span class="mw-page-title-main">Alkaline earth metal</span> Group of chemical elements

The alkaline earth metals are six chemical elements in group 2 of the periodic table. They are beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra). The elements have very similar properties: they are all shiny, silvery-white, somewhat reactive metals at standard temperature and pressure.

<span class="mw-page-title-main">Calcium carbonate</span> Chemical compound

Calcium carbonate is a chemical compound with the chemical formula CaCO3. It is a common substance found in rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skeletons and pearls. Materials containing much calcium carbonate or resembling it are described as calcareous. Calcium carbonate is the active ingredient in agricultural lime and is produced when calcium ions in hard water react with carbonate ions to form limescale. It has medical use as a calcium supplement or as an antacid, but excessive consumption can be hazardous and cause hypercalcemia and digestive issues.

<span class="mw-page-title-main">Base (chemistry)</span> Type of chemical substance

In chemistry, there are three definitions in common use of the word "base": Arrhenius bases, Brønsted bases, and Lewis bases. All definitions agree that bases are substances that react with acids, as originally proposed by G.-F. Rouelle in the mid-18th century.

<span class="mw-page-title-main">Calcium oxide</span> Chemical compound of calcium

Calcium oxide, commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term lime connotes calcium-containing inorganic compounds, in which carbonates, oxides, and hydroxides of calcium, silicon, magnesium, aluminium, and iron predominate. By contrast, quicklime specifically applies to the single compound calcium oxide. Calcium oxide that survives processing without reacting in building products, such as cement, is called free lime.

<span class="mw-page-title-main">Sodium carbonate</span> Chemical compound

Sodium carbonate is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood, sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the chloralkali process.

<span class="mw-page-title-main">Magnesium carbonate</span> Chemical compound

Magnesium carbonate, MgCO3, is an inorganic salt that is a colourless or white solid. Several hydrated and basic forms of magnesium carbonate also exist as minerals.

<span class="mw-page-title-main">Calcium hydroxide</span> Inorganic compound of formula Ca(OH)2

Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca(OH)2. It is a colorless crystal or white powder and is produced when quicklime (calcium oxide) is mixed with water. Annually, approximately 125 million tons of calcium hydroxide are produced worldwide.

<span class="mw-page-title-main">Calcium sulfate</span> Laboratory and industrial chemical

Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO4 and related hydrates. In the form of γ-anhydrite (the anhydrous form), it is used as a desiccant. One particular hydrate is better known as plaster of Paris, and another occurs naturally as the mineral gypsum. It has many uses in industry. All forms are white solids that are poorly soluble in water. Calcium sulfate causes permanent hardness in water.

Calcium bicarbonate, also called calcium hydrogencarbonate, has the chemical formula Ca(HCO3)2. The term does not refer to a known solid compound; it exists only in aqueous solution containing calcium (Ca2+), bicarbonate (HCO
3
), and carbonate (CO2−
3
) ions, together with dissolved carbon dioxide (CO2). The relative concentrations of these carbon-containing species depend on the pH; bicarbonate predominates within the range 6.36–10.25 in fresh water.

<span class="mw-page-title-main">Lime (material)</span> Calcium oxides and/or hydroxides

Lime is an inorganic material composed primarily of calcium oxides and hydroxides. It is also the name for calcium oxide which occurs as a product of coal-seam fires and in altered limestone xenoliths in volcanic ejecta. The International Mineralogical Association recognizes lime as a mineral with the chemical formula of CaO. The word lime originates with its earliest use as building mortar and has the sense of sticking or adhering.

<span class="mw-page-title-main">Lead carbonate</span> Chemical compound

Lead(II) carbonate is the chemical compound with the chemical formula PbCO3. It is a white, toxic solid. It occurs naturally as the mineral cerussite.

<span class="mw-page-title-main">Carbon dioxide scrubber</span> Device which absorbs carbon dioxide from circulated gas

A carbon dioxide scrubber is a piece of equipment that absorbs carbon dioxide (CO2). It is used to treat exhaust gases from industrial plants or from exhaled air in life support systems such as rebreathers or in spacecraft, submersible craft or airtight chambers. Carbon dioxide scrubbers are also used in controlled atmosphere (CA) storage and carbon capture and storage processes.

<span class="mw-page-title-main">Calcium sulfite</span> Chemical compound

Calcium sulfite, or calcium sulphite, is a chemical compound, the calcium salt of sulfite with the formula CaSO3·x(H2O). Two crystalline forms are known, the hemihydrate and the tetrahydrate, respectively CaSO3·½(H2O) and CaSO3·4(H2O). All forms are white solids. It is most notable as the product of flue-gas desulfurization.

<span class="mw-page-title-main">Magnesium acetate</span> Chemical compound

Anhydrous magnesium acetate has the chemical formula Mg(C2H3O2)2 and in its hydrated form, magnesium acetate tetrahydrate, it has the chemical formula Mg(CH3COO)2 • 4H2O. In this compound magnesium has an oxidation state of 2+. Magnesium acetate is the magnesium salt of acetic acid. It is deliquescent and upon heating, it decomposes to form magnesium oxide. Magnesium acetate is commonly used as a source of magnesium in biological reactions.

<span class="mw-page-title-main">Europium(III) acetate</span> Chemical compound

Europium(III) acetate is an inorganic salt of europium and acetic acid with the chemical formula of Eu(CH3COO)3. In this compound, europium exhibits the +3 oxidation state. It can exist in the anhydrous form, sesquihydrate and tetrahydrate. Its hydrate molecule is a dimer.

<span class="mw-page-title-main">Cerium(III) acetate</span> Chemical compound

Cerium acetate is an inorganic compound with the chemical formula of Ce(CH3COO)3. It is a white powder that is soluble in water. Its 1.5 hydrate loses water at 133°C to obtain an amorphous anhydrous form, and the amorphous phase changes to crystal at 212°C, and phase changes again at 286°C.

References

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  2. Dale L. Perry (May 19, 2011). Handbook of Inorganic Compounds (Second ed.). Taylor & Francis. p. 84. ISBN   978-1-4398-1461-1.
  3. "Calcium Acetate". Mayo Clinic. Retrieved 19 November 2019.
  4. Lu, J. Y.; Carter, Eloise; Chung, R. A. (1980). "Use of Calcium Salts for Soybean Curd Preparation". Journal of Food Science. 45: 32–34. doi:10.1111/j.1365-2621.1980.tb03864.x.
  5. Leo Frank Goodwin; Edward Tyghe Sterne (1920). "Losses Incurred in the Preparation of Acetone by the Distillation of Acetate of Lime". Industrial & Engineering Chemistry. 12 (3): 240–243. doi:10.1021/ie50123a012.
  6. E. G. R. Ardagh; A. D. Barbour; G. E. McClellan; E. W. McBride (1924). "Distillation of Acetate of Lime". Industrial & Engineering Chemistry. 16 (11): 1133–1139. doi:10.1021/ie50179a013.
  7. ""Canned Heat" at Journal of Chemical Education "Chemistry comes alive!"". Archived from the original on 2008-10-03. Retrieved 2008-03-26.
  8. Chemistry Teaching Resources
  9. "Calclacite".
  10. RRUFF (13 Jan 2024). "Database of Mineral Properties". International Mineralogical Association. Calclacite (dropdown option at left).