Rubidium acetate

Last updated
Rubidium acetate
Rubidium acetate.svg
Names
IUPAC name
Rubidium acetate
Other names
  • Rubidium(I) acetate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.008.415 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 209-255-4
PubChem CID
UNII
  • InChI=1S/C2H4O2.Rb/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1
    Key: FOGKDYADEBOSPL-UHFFFAOYSA-M
  • CC(=O)[O-].[Rb+]
Properties
CH3COORb
Molar mass 144.51 g/mol
AppearanceWhite solid
Melting point 246 °C (475 °F; 519 K) [1] (decomposes)
86 g/100 ml (45 °C) [1]
89.3 g/100 ml (99.4 °C) [1]
log P −0.561[ citation needed ]
Hazards [2]
NFPA 704 (fire diamond)
NFPA 704.svgHealth 0: Exposure under fire conditions would offer no hazard beyond that of ordinary combustible material. E.g. sodium chlorideFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
0
1
1
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 10 mg/m3
Related compounds
Other anions
Rubidium formate
Other cations
Hydrogen acetate
Lithium acetate
Sodium acetate
Potassium acetate
Caesium acetate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Rubidium acetate (CH3COORb) is the rubidium salt of acetic acid. It is a white, hygroscopic solid. [1] It can be prepared by reacting rubidium metal, rubidium carbonate, or rubidium hydroxide [3] with acetic acid.

Uses

Rubidium acetate is used as a catalyst for the polymerization of silanol terminated siloxane oligomers. [4]

References

  1. 1 2 3 4 Perry, Dale L. (2016-04-19). Handbook of Inorganic Compounds. CRC Press. p. 348. ISBN   978-1-4398-1462-8.
  2. "Safety data sheet" (PDF). s3.amazonaws.com. 2015. Retrieved 2021-02-03.
  3. Kalle, Paulina; Bezzubov, Stanislav I.; Vener, Mikhail V.; Churakov, Andrei V. (2025-10-15). "Polymorphism and Crystallization of Sodium Acetate". Crystal Growth & Design. 25 (20): 8658–8664. doi:10.1021/acs.cgd.5c01101. ISSN   1528-7483.
  4. "Rubidium acetate". gelest.com.