Holmium acetate

Last updated
Holmium acetate
Holmium(III) acetate.jpg
Names
Other names
Holmium(III) acetate
Identifiers
3D model (JSmol)
ECHA InfoCard 100.042.773 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
  • InChI=1S/3C2H4O2.Ho/c3*1-2(3)4;/h3*1H3,(H,3,4);
    Key: NKWMPWXATGULJJ-UHFFFAOYSA-N
  • CC(=O)O.CC(=O)O.CC(=O)O.[Ho]
Properties
Ho(CH3COO)3
Appearancecrystals
soluble
Related compounds
Other anions
Holmium oxide
Holmium hydroxide
Other cations
Dysprosium acetate
Erbium acetate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Holmium in acetic acid Holmium acetic acid.jpg
Holmium in acetic acid

Holmium acetate is the acetate salt of holmium, with a chemical formula of Ho(CH3COO)3 [1] as well as at least one hydrate.

Contents

Preparation

Holmium acetate can be obtained by dissolving holmium oxide in hot acetic acid [2]

Ho2O3 + 6 CH3CO2H → 2 Ho(O2CH3)3 + 3 H2O

Dissolving holmium oxide in acetic acid at a pH of 4 will form the tetrahydrate of holmium acetate (Ho2(CH3COO)6·4H2O): [3] The anhydrous material can be obtained by heating the hydrated acetate in acetic acid. [1]

Physical properties and structure

Holmium acetate hemihepthydate decomposes at 105 °C, forming into a hemihydrate, further decomposing at 135 °C into an anhydride. Further adding heat will form Ho(OH)(CH3COO)2, HoO(CH3COO) then Ho2O2CO3, forming holmium oxide at 590 °C. [4]

According to X-ray crystallography, anhydrous holmium acetate is a coordination polymer. Each Ho(III) center is nine-coordinate, with two bidentate acetate ligands and the remaining sites occupied by oxygens provided by bridging acetate ligands. The lanthanum and praseodymium compounds are isostructural. [1] In a second polymorph, holmium acetate has 8-coordination. [2] A tetrahydrate has also been crystallized. [5]

Applications

Holmium acetate is used in the manufacture of ceramics, glass, phosphors, metal halide lamps, and as a dopant in garnet lasers. It is also used in nuclear reactors to keep the chain reaction in check. [6]

Related Research Articles

<span class="mw-page-title-main">Zinc acetate</span> Chemical compound

Zinc acetate is a salt with the formula Zn(CH3CO2)2, which commonly occurs as the dihydrate Zn(CH3CO2)2·2H2O. Both the hydrate and the anhydrous forms are colorless solids that are used as dietary supplements. When used as a food additive, it has the E number E650.

<span class="mw-page-title-main">Iron(II) acetate</span> Chemical compound

Iron(II) acetate describes compounds with formula Fe(CH3CO2)2·(H2O)x where x can be 0 (anhydrous) or 4 (tetrahydrate). The anhydrous compound is a white solid, although impure samples can be slightly colored. The tetrahydrate is light green solid that is highly soluble in water.

<span class="mw-page-title-main">Caesium acetate</span> Chemical compound

Caesium acetate or cesium acetate is an ionic caesium compound with the molecular formula CH3COOCs. It is a white solid that may be formed by the reaction of caesium hydroxide or caesium carbonate with acetic acid.

Trirhenium nonachloride is a compound with the formula ReCl3, sometimes also written Re3Cl9. It is a dark red hygroscopic solid that is insoluble in ordinary solvents. The compound is important in the history of inorganic chemistry as an early example of a cluster compound with metal-metal bonds. It is used as a starting material for synthesis of other rhenium complexes.

<span class="mw-page-title-main">Cobalt(II) acetate</span> Chemical compound

Cobalt(II) acetate is the cobalt salt of acetic acid. It is commonly found as the tetrahydrate Co(CH3CO2)2·4 H2O, abbreviated Co(OAc)2·4 H2O. It is used as a catalyst.

<span class="mw-page-title-main">Nickel(II) acetate</span> Chemical compound

Nickel(II) acetate is the name for the coordination compounds with the formula Ni(CH3CO2)2·x H2O where x can be 0, 2, and 4. The mint-green tetrahydrate Ni(CH3CO2)2·4 H2O is most common. It is used for electroplating.

<span class="mw-page-title-main">Neodymium(III) acetate</span> Compound of neodymium

Neodymium(III) acetate is an inorganic salt composed of a neodymium atom trication and three acetate groups as anions where neodymium exhibits the +3 oxidation state. It has a chemical formula of Nd(CH3COO)3 although it can be informally referred to as NdAc because Ac is an informal symbol for acetate. It commonly occurs as a light purple powder.

<span class="mw-page-title-main">Praseodymium(III) acetate</span> Compound of praseodymium

Praseodymium(III) acetate is an inorganic salt composed of a Praseodymium atom trication and three acetate groups as anions. This compound commonly forms the dihydrate, Pr(O2C2H3)3·2H2O.

<span class="mw-page-title-main">Neodymium compounds</span> Chemical compounds with at least one neodymium atom

Neodymium compounds are compounds formed by the lanthanide metal neodymium (Nd). In these compounds, neodymium generally exhibits the +3 oxidation state, such as NdCl3, Nd2(SO4)3 and Nd(CH3COO)3. Compounds with neodymium in the +2 oxidation state are also known, such as NdCl2 and NdI2. Some neodymium compounds have colors that vary based upon the type of lighting.

Carbide iodides are mixed anion compounds containing iodide and carbide anions. Many carbide iodides are cluster compounds, containing one, two or more carbon atoms in a core, surrounded by a layer of metal atoms, and encased in a shell of iodide ions. These ions may be shared between clusters to form chains, double chains or layers.

<span class="mw-page-title-main">Gallium acetate</span> Chemical compound

Gallium acetate is a salt composed of a gallium atom trication and three acetate groups as anions where gallium exhibits the +3 oxidation state. It has a chemical formula of Ga(CH3COO)3 although it can be informally referred to as GaAc because Ac is an informal symbol for acetate. Gallium is moderately water-soluble and decomposes to gallium oxide when heated to around 70 °C. Gallium acetate, like other acetate compounds, is a good precursor to ultra-pure compounds, catalysts and nanoscale materials. Gallium acetate is being considered as a substitute in de-icing compounds like calcium chloride and magnesium chloride.

<span class="mw-page-title-main">Europium(III) acetate</span> Chemical compound

Europium(III) acetate is an inorganic salt of europium and acetic acid with the chemical formula of Eu(CH3COO)3. In this compound, europium exhibits the +3 oxidation state. It can exist in the anhydrous form, sesquihydrate and tetrahydrate. Its hydrate molecule is a dimer.

<span class="mw-page-title-main">Dysprosium(III) acetate</span> Chemical compound

Dysprosium acetate is a hypothetical salt of dysprosium and acetate. Its proposed chemical formula is Dy(CH3COO)3.

<span class="mw-page-title-main">Erbium(III) acetate</span> Chemical compound

Erbium(III) acetate is the acetate salt of erbium, with the proposed chemical formula of Er(CH3COO)3. It can be used to synthesize some optical materials.

<span class="mw-page-title-main">Holmium(III) iodide</span> Chemical compound

Holmium(III) iodide is an iodide of holmium, with the chemical formula of HoI3. It is used as a component of metal halide lamps.

<span class="mw-page-title-main">Scandium acetate</span> Chemical compound

Scandium acetate is an compound, with the chemical formula of Sc(CH3COO)3. It exists in the anhydrous and the hydrate forms. It can be obtained by reacting scandium hydroxide or scandium oxide with acetic acid. It is a colorless, water-soluble solid. It decomposes into scandium oxide at high temperature. It can be used to prepare other scandium-containing materials.

<span class="mw-page-title-main">Terbium acetate</span> Chemical compound

Terbium(III) acetate is the acetate salt of terbium, with a chemical formula of Tb(CH3COO)3.

<span class="mw-page-title-main">Gadolinium acetate</span> Chemical compound

Gadolinium acetate is the acetate salt of the lanthanide element gadolinium, with the chemical formula Gd(CH3COO)3. It is a colorless crystal that is soluble in water and can form a hydrate. Its tetrahydrate has ground state ferromagnetism.

<span class="mw-page-title-main">Samarium(III) acetate</span> Chemical compound

Samarium(III) acetate is an acetate salt of samarium, with the chemical formula of Sm(CH3COO)3. It exists in the hydrate and tetrahydrate form. Its tetrahydrate can be obtained by dissolving samarium(III) oxide in 50% acetic acid solution, crystallizing and vacuum drying. The mixed anion acetate [Sm(CH3COO)(H2O)6]Cl2·H2O and [Sm(CH3COO)2(H2O)3]Cl can be crystallized from SmCl3·6H2O and SmOCl in acetic acid solution respectively.

<span class="mw-page-title-main">Lanthanum acetate</span> Chemical compound

Lanthanum acetate is an inorganic compound, a salt of lanthanum with acetic acid with the chemical formula La(CH3CO2)3. According to X-ray crystallography, anhydrous lanthanum acetate is a coordination polymer. Each La(III) center is nine-coordinate, with two bidentate acetate ligands and the remaining sites occupied by oxygens provided by bridging acetate ligands. The praseodymium and holmium compounds are isostructural.

References

  1. 1 2 3 Lossin, Adalbert; Meyer, Gerd (1994). "Pr(CH3COO)3, ein wasserfreies Selten-Erd-Acetat mit Netzwerkstruktur". Zeitschrift für Anorganische und Allgemeine Chemie. 620 (3). doi:10.1002/zaac.19946200306.
  2. 1 2 Lossin, Adalbert; Meyer, Gerd (1993). "Wasserfreie Selten-Erd-Acetate, M(CH3COO)3 (M = Sm-Lu, Y) mit Kettenstruktur. Kristallstrukturen von Lu(CH3COO)3 und Ho(CH3COO)3". Zeitschrift für Anorganische und Allgemeine Chemie. 619 (9). doi:10.1002/zaac.19936190917.
  3. Anna Mondry, Krystyna Bukietyńska (1991-08-01). "Spectral intensities of holmium acetate single crystals". Inorganica Chimica Acta. 186 (1): 135–138. doi:10.1016/S0020-1693(00)87943-8. ISSN   0020-1693.
  4. G. A. M. Hussein, B. A. A. Balboul, G. A. H. Mekhemer (2000-11-01). "Holmium oxide from holmium acetate, formation and characterization: thermoanalytical studies". Journal of Analytical and Applied Pyrolysis. 56 (2): 263–272. Bibcode:2000JAAP...56..263H. doi:10.1016/S0165-2370(00)00100-5. ISSN   0165-2370.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  5. . doi:10.1107/S0567740879005987.{{cite journal}}: Cite journal requires |journal= (help); Missing or empty |title= (help)
  6. "Holmium acetate" . Retrieved 2014-01-01.

External reading