Aluminium monoacetate

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Aluminium monoacetate
Aluminium monoacetate.png
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Names
IUPAC name
Aluminium monoacetate
Other names
Basic aluminium monoacetate Dihydroxyaluminium acetate
Identifiers
3D model (JSmol)
ChEMBL
ChemSpider
PubChem CID
UNII
  • InChI=1S/C2H4O2.Al.2H2O/c1-2(3)4;;;/h1H3,(H,3,4);;2*1H2/q;+3;;/p-3
    Key: KLMDYFUUSKOJAX-UHFFFAOYSA-K
  • CC(=O)[O-].[OH-].[OH-].[Al+3]
Properties
(HO)2AlCH3CO2 or C2H5AlO4
Molar mass 120.04 g/mol
AppearanceWhite powder
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Aluminium monoacetate, also known as dibasic aluminium acetate, and formally named dihydroxy aluminium acetate, is a salt of aluminium with acetic acid. It has the formula Al(OH)2(CH3COO), with aluminium in an oxidation state of +3, and appears under standard conditions as a white solid powder. [1]

Contents

Chemistry

Aluminium monoacetate is prepared from the reaction between Al(OH)3 and dilute aqueous acetic acid. [1] It is also formed from the successive hydrolysis of aluminium triacetate. [2] [3]

Al(CH3COO)3 + H2O → Al(OH)(CH3COO)2 + CH3COOH
Al(OH)(CH3COO)2 + H2O → Al(OH)2(CH3COO) + CH3COOH

Uses

Aluminium monoacetate is a dermatological agent used as an antiseptic and astringent. [4] It is used as an antiseptic to reduce the possibility of infection in minor wounds, cuts, and burns. Specifically, it treats itching, stinging of the infected skin, inflammation, and it promotes healing. It also can be used as a topical astringent to help shrink the body's tissues when applied to the skin as it acts as a protective layer on irritated and inflamed skin.

Related Research Articles

<span class="mw-page-title-main">Carboxylic acid</span> Organic compound containing a –C(=O)OH group

In organic chemistry, a carboxylic acid is an organic acid that contains a carboxyl group attached to an R-group. The general formula of a carboxylic acid is often written as R−COOH or R−CO2H, sometimes as R−C(O)OH with R referring to the alkyl, alkenyl, aryl, or other group. Carboxylic acids occur widely. Important examples include the amino acids and fatty acids. Deprotonation of a carboxylic acid gives a carboxylate anion.

<span class="mw-page-title-main">Acetate</span> Salt compound formed from acetic acid and a base

An acetate is a salt formed by the combination of acetic acid with a base. "Acetate" also describes the conjugate base or ion typically found in aqueous solution and written with the chemical formula C
2
H
3
O
2
. The neutral molecules formed by the combination of the acetate ion and a positive ion are also commonly called "acetates". The simplest of these is hydrogen acetate with corresponding salts, esters, and the polyatomic anion CH
3
CO
2
, or CH
3
COO
.

The Brønsted–Lowry theory (also called proton theory of acids and bases) is an acid–base reaction theory which was first developed by Johannes Nicolaus Brønsted and Thomas Martin Lowry independently in 1923. The basic concept of this theory is that when an acid and a base react with each other, the acid forms its conjugate base, and the base forms its conjugate acid by exchange of a proton (the hydrogen cation, or H+). This theory generalises the Arrhenius theory.

<span class="mw-page-title-main">Acetic anhydride</span> Organic compound with formula (CH₃CO)₂O

Acetic anhydride, or ethanoic anhydride, is the chemical compound with the formula (CH3CO)2O. Commonly abbreviated Ac2O, it is the simplest isolable anhydride of a carboxylic acid and is widely used as a reagent in organic synthesis. It is a colorless liquid that smells strongly of acetic acid, which is formed by its reaction with moisture in the air.

<span class="mw-page-title-main">Sodium acetate</span> Chemical compound

Sodium acetate, CH3COONa, also abbreviated NaOAc, is the sodium salt of acetic acid. This colorless deliquescent salt has a wide range of uses.

Aluminium acetate or aluminium ethanoate (also "aluminum ~"), sometimes abbreviated AlAc in geochemistry, can refer to a number of different salts of aluminium with acetic acid. In the solid state, three salts exist under this name: basic aluminium monoacetate, (HO)2AlCH3CO2, basic aluminium diacetate, HOAl(CH3CO2)2, and neutral aluminium triacetate, Al(CH3CO2)3. In aqueous solution, aluminium triacetate hydrolyses to form a mixture of the other two, and all solutions of all three can be referred to as "aluminium acetate" as the species formed co-exist and inter-convert in chemical equilibrium.

<span class="mw-page-title-main">Mercury(II) acetate</span> Chemical compound

Mercury(II) acetate, also known as mercuric acetate is a chemical compound, the mercury(II) salt of acetic acid, with the formula Hg(O2CCH3)2. Commonly abbreviated Hg(OAc)2, this compound is employed as a reagent to generate organomercury compounds from unsaturated organic precursors. It is a white, water-soluble solid, but some samples can appear yellowish with time owing to decomposition.

<span class="mw-page-title-main">Acetic acid</span> Colorless and faint organic acid found in vinegar

Acetic acid, systematically named ethanoic acid, is an acidic, colourless liquid and organic compound with the chemical formula CH3COOH. Vinegar is at least 4% acetic acid by volume, making acetic acid the main component of vinegar apart from water. It has been used, as a component of vinegar, throughout history from at least the third century BC.

<span class="mw-page-title-main">Magnesium acetate</span> Chemical compound

Anhydrous magnesium acetate has the chemical formula Mg(C2H3O2)2 and in its hydrated form, magnesium acetate tetrahydrate, it has the chemical formula Mg(CH3COO)2 • 4H2O. In this compound magnesium has an oxidation state of 2+. Magnesium acetate is the magnesium salt of acetic acid. It is deliquescent and upon heating, it decomposes to form magnesium oxide. Magnesium acetate is commonly used as a source of magnesium in biological reactions.

<span class="mw-page-title-main">Barium acetate</span> Chemical compound

Barium acetate (Ba(C2H3O2)2) is the salt of barium(II) and acetic acid. Barium acetate is toxic to humans, but it has use in chemistry and manufacturing.

<span class="mw-page-title-main">Allyl acetate</span> Chemical compound

Allyl acetate is an organic compound with formula C3H5OC(O)CH3. This colourless liquid is a precursor to especially allyl alcohol, which is a useful industrial intermediate. It is the acetate ester of allyl alcohol.

<span class="mw-page-title-main">Aluminium diacetate</span> Chemical compound

Aluminium diacetate, also known as basic aluminium acetate, is a white powder with the chemical formula C4H7AlO5. It is one of a number of aluminium acetates and can be prepared in a reaction of sodium aluminate (NaAlO2) with acetic acid.

Indium(III) hydroxide is the chemical compound with the formula In(OH)3. Its prime use is as a precursor to indium(III) oxide, In2O3. It is sometimes found as the rare mineral dzhalindite.

Aluminium triacetate, formally named aluminium acetate, is a chemical compound with composition Al(CH
3
CO
2
)
3
. Under standard conditions it appears as a white, water-soluble solid that decomposes on heating at around 200 °C. The triacetate hydrolyses to a mixture of basic hydroxide / acetate salts, and multiple species co-exist in chemical equilibrium, particularly in aqueous solutions of the acetate ion; the name aluminium acetate is commonly used for this mixed system.

<span class="mw-page-title-main">Cerium(IV) hydroxide</span> Chemical compound

Cerium(IV) hydroxide, also known as ceric hydroxide, is an inorganic compound with the chemical formula Ce(OH)4. It is a yellowish powder that is insoluble in water but soluble in concentrated acids.

<span class="mw-page-title-main">Europium(III) acetate</span> Chemical compound

Europium(III) acetate is an inorganic salt of europium and acetic acid with the chemical formula of Eu(CH3COO)3. In this compound, europium exhibits the +3 oxidation state. It can exist in the anhydrous form, sesquihydrate and tetrahydrate. Its hydrate molecule is a dimer.

<span class="mw-page-title-main">Lutetium(III) acetate</span> Compound of lutetium

Lutetium(III) acetate is the acetate salt of lutetium with the chemical formula of Lu(CH3COO)3.

<span class="mw-page-title-main">Dysprosium(III) acetate</span> Chemical compound

Dysprosium acetate is a hypothetical salt of dysprosium and acetate. Its proposed chemical formula is Dy(CH3COO)3.

<span class="mw-page-title-main">Holmium acetate</span> Compound of holmium

Holmium acetate is the acetate salt of holmium, with a chemical formula of Ho(CH3COO)3.

Tin(IV) acetate is the acetate salt of tin(IV), with the chemical formula of Sn(CH3COO)4.

References

  1. 1 2 Wade K, Banister AJ, Bailar JC, Emeléus HJ, Nyholm R, eds. (1973). The Chemistry of Aluminium, Gallium, Indium and Thallium : Comprehensive Inorganic Chemistry. Saint Louis: Elsevier Science. p. 1047. ISBN   978-1-4831-5322-3. OCLC   953379198.
  2. Daintith J, ed. (2008). "Aluminium ethanoate (aluminium acetate)". A Dictionary of Chemistry (6th ed.). Oxford University Press. ISBN   9780199204632.
  3. "CharChem. Dihydroxyaluminum Acetate". easychem.org. Retrieved 2020-07-19.
  4. Triggle DJ, Ganellin CR (1997). Dictionary of Pharmacological Agents. Cambridge: Chapman & Hall. pp. 595, 600. ISBN   0412466309.