Aluminium carbonate

Last updated
Aluminium Carbonate
Names
IUPAC name
Dialuminium Tricarbonate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.930 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
UNII
  • InChI=1S/3CH2O3.2Al/c3*2-1(3)4;;/h3*(H2,2,3,4);;/q;;;2*+3/p-6
    Key: PPQREHKVAOVYBT-UHFFFAOYSA-H
  • C(=O)([O-])[O-].C(=O)([O-])[O-].C(=O)([O-])[O-].[Al+3].[Al+3]
Properties
Al2(CO3)3
Appearancewhite powder, unstable
Density 1.5 g/cm3
Melting point 58 °C
Boiling point decomposes
reacts
Structure [1]
orthorhombic
Fdd2
a = 21.989, b = 10.176, c = 4.4230
989.7
8
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Aluminium carbonate (Al2(CO3)3), is a carbonate of aluminium. It is not well characterized; one authority says that simple carbonates of aluminium are not known. [2] However related compounds are known, such as the basic sodium aluminium carbonate mineral dawsonite (NaAlCO3(OH)2) and hydrated basic aluminium carbonate minerals scarbroite (Al5(CO3)(OH)13•5(H2O)) and hydroscarbroite (Al14(CO3)3(OH)36•nH2O). [3] [4] [5]

Contents

Preparation

For many years there was no evidence for the existence of any carbonate-containing ternary Al-C-O phase, i.e., Al2(CO3)3, [6] however in 2023 Al2[CO3]3 and Al2[C2O5][CO3]2 (dialuminium carbonate pyrocarbonate) were produced with a carbon dioxide pressure of 24 and 38 GPa. This means that the Earth's mantle may contain aluminium carbonate minerals. [7]

Some minerals contain both aluminium and carbonate. Dawsonite has the formula NaAlCO3(OH)2. Hydrotalcites, both synthetic and natural, are layered metal hydroxides comprised in part of aluminium and carbonate. [8]

Surface carbonate species readily form upon exposure of aluminium oxide to CO2. [9]

Uses

Aluminium carbonate, along with aluminium hydroxide and aluminium oxide, is a phosphate-binding drug that is sometimes administered to dogs and cats to bind intestinal phosphate and prevent the absorption of dietary phosphate as well as to decrease absorption of phosphate excreted by the pancreas. It is seldom used in humans because of concerns with toxicity, but cats and dogs do not appear to have a toxic response to its presence. [10]

The reaction of aluminium sulfate and sodium bicarbonate forms carbon dioxide and aluminium hydroxide which stabilises the formation of a foam. [6] This reaction was the basis of an early fire extinguisher invented by Aleksandr Loran in 1904.


Related Research Articles

<span class="mw-page-title-main">Carbonate</span> Salt of carbonic acid

A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula CO2−3. The word carbonate may also refer to a carbonate ester, an organic compound containing the carbonate groupO=C(−O−)2.

<span class="mw-page-title-main">Hydroxide</span> Chemical compound

Hydroxide is a diatomic anion with chemical formula OH. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry.

<span class="mw-page-title-main">Oxide</span> Chemical compound where oxygen atoms are combined with atoms of other elements

An oxide is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– ion with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials considered pure elements often develop an oxide coating. For example, aluminium foil develops a thin skin of Al2O3 that protects the foil from further oxidation.

<span class="mw-page-title-main">Calcium carbonate</span> Chemical compound

Calcium carbonate is a chemical compound with the chemical formula CaCO3. It is a common substance found in rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skeletons and pearls. Materials containing much calcium carbonate or resembling it are described as calcareous. Calcium carbonate is the active ingredient in agricultural lime and is produced when calcium ions in hard water react with carbonate ions to form limescale. It has medical use as a calcium supplement or as an antacid, but excessive consumption can be hazardous and cause hypercalcemia and digestive issues.

<span class="mw-page-title-main">Potassium hydroxide</span> Inorganic compound (KOH)

Potassium hydroxide is an inorganic compound with the formula KOH, and is commonly called caustic potash.

<span class="mw-page-title-main">Basic copper carbonate</span> Chemical compound

Basic copper carbonate is a chemical compound, more properly called copper(II) carbonate hydroxide. It is an ionic compound consisting of the ions copper(II) Cu2+
, carbonate CO2−
3
, and hydroxide OH
.

<span class="mw-page-title-main">Magnesium carbonate</span> Chemical compound

Magnesium carbonate, MgCO3, is an inorganic salt that is a colourless or white solid. Several hydrated and basic forms of magnesium carbonate also exist as minerals.

<span class="mw-page-title-main">Lithium hydroxide</span> Chemical compound

Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While classified as a strong base, lithium hydroxide is the weakest known alkali metal hydroxide.

<span class="mw-page-title-main">Copper(II) oxide</span> Chemical compound – an oxide of copper with formula CuO

Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite. It is a product of copper mining and the precursor to many other copper-containing products and chemical compounds.

<span class="mw-page-title-main">Orthocarbonic acid</span> Hypothetical molecule with the formula C(OH)4

Orthocarbonic acid, carbon hydroxide or methanetetrol is the name given to a hypothetical compound with the chemical formula H4CO4 or C(OH)4. Its molecular structure consists of a single carbon atom bonded to four hydroxy groups. It would be therefore a fourfold alcohol. In theory it could lose four protons to give the hypothetical oxocarbon anion orthocarbonateCO4−4, and is therefore considered an oxoacid of carbon.

Potassium hypomanganate is the inorganic compound with the formula K3MnO4. Also known as potassium manganate(V), this bright blue solid is a rare example of a salt with the hypomanganate or manganate(V) anion, where the manganese atom is in the +5 oxidation state. It is an intermediate in the production of potassium permanganate and the industrially most important Mn(V) compound.

<span class="mw-page-title-main">Nickel(II) carbonate</span> Chemical compound

Nickel(II) carbonate describes one or a mixture of inorganic compounds containing nickel and carbonate. From the industrial perspective, the most important nickel carbonate is basic nickel carbonate with the formula Ni4CO3(OH)6(H2O)4. Simpler carbonates, ones more likely encountered in the laboratory, are NiCO3 and its hexahydrate. All are paramagnetic green solids containing Ni2+ cations. The basic carbonate is an intermediate in the hydrometallurgical purification of nickel from its ores and is used in electroplating of nickel.

<span class="mw-page-title-main">Layered double hydroxides</span> Class of ionic solids characterized by a layered structure

Layered double hydroxides (LDH) are a class of ionic solids characterized by a layered structure with the generic layer sequence [AcB Z AcB]n, where c represents layers of metal cations, A and B are layers of hydroxide anions, and Z are layers of other anions and neutral molecules. Lateral offsets between the layers may result in longer repeating periods.

<span class="mw-page-title-main">Cobalt(II) carbonate</span> Chemical compound

Cobalt(II) carbonate is the inorganic compound with the formula CoCO3. This reddish paramagnetic solid is an intermediate in the hydrometallurgical purification of cobalt from its ores. It is an inorganic pigment, and a precursor to catalysts. Cobalt(II) carbonate also occurs as the rare red/pink mineral spherocobaltite.

<span class="mw-page-title-main">Beryllium carbonate</span> Chemical compound

Beryllium carbonate is a chemical compound with the chemical formula BeCO3.

<span class="mw-page-title-main">Copper(II) phosphate</span> Chemical compound

Copper(II) phosphate are inorganic compounds with the formula Cu3(PO4)2. They can be regarded as the cupric salts of phosphoric acid. Anhydrous copper(II) phosphate and a trihydrate are blue solids.

<span class="mw-page-title-main">Dicarbonate</span> Chemical compound

A dicarbonate, also known as a pyrocarbonate, is a chemical containing the divalent −O−C(=O)−O−C(=O)−O− or −C2O5 functional group, which consists of two carbonate groups sharing an oxygen atom. These compounds can be viewed as derivatives of the hypothetical compound dicarbonic acid, HO−C(=O)−O−C(=O)−OH or H2C2O5. Two important organic compounds containing this group are dimethyl dicarbonate H3C−C2O5−CH3 and di-tert-butyl dicarbonate(H3C−)3C−C2O5−C(−CH3)3.

Cobalt(III) hydroxide or cobaltic hydroxide is a chemical compound with formula Co(OH)
3
or H
3
CoO
3
. It is an ionic compound, with trivalent cobalt cations Co3+
and hydroxyl anions OH
.

<span class="mw-page-title-main">Fluorocarbonate</span> Class of chemical compounds

A carbonate fluoride, fluoride carbonate, fluorocarbonate or fluocarbonate is a double salt containing both carbonate and fluoride. The salts are usually insoluble in water, and can have more than one kind of metal cation to make more complex compounds. Rare-earth fluorocarbonates are particularly important as ore minerals for the light rare-earth elements lanthanum, cerium and neodymium. Bastnäsite is the most important source of these elements. Other artificial compounds are under investigation as non-linear optical materials and for transparency in the ultraviolet, with effects over a dozen times greater than Potassium dideuterium phosphate.

References

  1. Bayarjargal, Lkhamsuren; Spahr, Dominik; Milman, Victor; Marquardt, Julien; Giordano, Nico; Winkler, Björn (2023). CCDC 2259169: Experimental Crystal Structure Determination (Report). Cambridge Crystallographic Data Centre. doi:10.5517/ccdc.csd.cc2ftvfk.
  2. Anthony John Downs, (1993), Chemistry of Aluminium, Gallium, Indium, and Thallium, Springer, ISBN   978-0-7514-0103-5
  3. "Scarbroite". www.mindat.org.
  4. "Hydroscarbroite". www.mindat.org.
  5. "Dawsonite". www.mindat.org. Retrieved 2020-12-14.
  6. 1 2 Moody, Bernard (2013). Comparative Inorganic Chemistry. Elsevier. p. 311. ISBN   9781483280080.
  7. Bayarjargal, Lkhamsuren; Spahr, Dominik; Milman, Victor; Marquardt, Julien; Giordano, Nico; Winkler, Björn (28 August 2023). "Anhydrous Aluminum Carbonates and Isostructural Compounds". Inorganic Chemistry. 62 (34): 13910–13918. doi:10.1021/acs.inorgchem.3c01832. PMID   37579301. S2CID   260898136.
  8. Costantino, Umberto; Marmottini, Fabio; Nocchetti, Morena; Vivani, Riccardo (1998). "New Synthetic Routes to Hydrotalcite-Like Compounds − Characterisation and Properties of the Obtained Materials". European Journal of Inorganic Chemistry. 1998 (10): 1439–1446. doi:10.1002/(SICI)1099-0682(199810)1998:10<1439::AID-EJIC1439>3.0.CO;2-1.
  9. Parkyns, N. D. (1969-01-01). "The surface properties of metal oxides. Part II. An infrared study of the adsorption of carbon dioxide on γ-alumina". Journal of the Chemical Society A: Inorganic, Physical, Theoretical: 410–417. doi:10.1039/J19690000410. ISSN   0022-4944.
  10. Deborah Silverstein; Kate Hopper (13 February 2008). Small Animal Critical Care Medicine - E-Book. Elsevier Health Sciences. p. 5. ISBN   978-1-4160-6926-3.