Zinc carbonate

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Zinc carbonate
CaaCO3Code100679.png
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.020.435 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 222-477-6
  • basic:226-076-7
PubChem CID
UNII
UN number 9157
  • InChI=1S/CH2O3.Zn/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
    Key: FMRLDPWIRHBCCC-UHFFFAOYSA-L
  • C(=O)([O-])[O-].[Zn+2]
Properties
ZnCO3
Molar mass 125.4
Appearancewhite solid
Density 4.434 g/cm3 [1]
Melting point 140 °C (284 °F; 413 K) [1] (decomposes)
0.91 mg/L [1]
1.46×10−10 [2]
-34×10−6 cm3/mol [3]
n1=1.621, n2=1.848 [4]
Structure [5]
Calcite, hR30, No. 167
R3c
a = 4.6528 Å, c = 15.025 Å
6
Hazards
GHS labelling:
GHS-pictogram-pollu.svg
Warning
H319, H410, H411
P264, P273, P280, P302+P352, P305+P351+P338, P321, P332+P313, P337+P313, P362, P391, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Zinc carbonate is the inorganic compound with the formula ZnCO3. It is a white solid that is insoluble in water. It exists in nature as the mineral smithsonite. It is prepared by treating cold solutions of zinc sulfate with potassium bicarbonate. Upon warming, it converts to basic zinc carbonate (Zn5(CO3)2(OH)6). [6]

Zinc carbonate adopts the same structure as calcium carbonate (calcite). [7] Zinc is octahedral and each carbonate is bonded to six Zn centers such that oxygen atoms are three-coordinate.

Related Research Articles

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<span class="mw-page-title-main">Zinc chloride</span> Chemical compound

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<span class="mw-page-title-main">Zinc iodide</span> Chemical compound

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<span class="mw-page-title-main">Zinc bromide</span> Chemical compound

Zinc bromide (ZnBr2) is an inorganic compound with the chemical formula ZnBr2. It is a colourless salt that shares many properties with zinc chloride (ZnCl2), namely a high solubility in water forming acidic solutions, and good solubility in organic solvents. It is hygroscopic and forms a dihydrate ZnBr2·2H2O.

<span class="mw-page-title-main">Beryllium hydroxide</span> Chemical compound

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<span class="mw-page-title-main">Zinc cyanide</span> Chemical compound

Zinc cyanide is the inorganic compound with the formula Zn(CN)2. It is a white solid that is used mainly for electroplating zinc but also has more specialized applications for the synthesis of organic compounds.

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Zinc fluoride is an inorganic chemical compound with the chemical formula ZnF2. It is encountered as the anhydrous form and also as the tetrahydrate, ZnF2·4H2O (rhombohedral crystal structure). It has a high melting point and has the rutile structure containing 6 coordinate zinc, which suggests appreciable ionic character in its chemical bonding. Unlike the other zinc halides, ZnCl2, ZnBr2 and ZnI2, it is not very soluble in water.

<span class="mw-page-title-main">Zinc nitrate</span> Chemical compound

Zinc nitrate is an inorganic chemical compound with the formula Zn(NO3)2. This colorless, crystalline salt is highly deliquescent. It is typically encountered as a hexahydrate Zn(NO3)2·6H2O. It is soluble in both water and alcohol.

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Zinc phosphide (Zn3P2) is an inorganic chemical compound. It is a grey solid, although commercial samples are often dark or even black. It is used as a rodenticide. Zn3P2 is a II-V semiconductor with a direct band gap of 1.5 eV and may have applications in photovoltaic cells. A second compound exists in the zinc-phosphorus system, zinc diphosphide (ZnP2).

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Gallium(III) iodide is the inorganic compound with the formula GaI3. A yellow hygroscopic solid, it is the most common iodide of gallium. In the chemical vapor transport method of growing crystals of gallium arsenide uses iodine as the transport agent. In the solid state, it exists as the dimer Ga2I6. When vaporized, its forms GaI3 molecules of D3h symmetry where the Ga–I distance is 2.458 Angstroms.

<span class="mw-page-title-main">Zinc pyrophosphate</span> Chemical compound

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Zinc compounds are chemical compounds containing the element zinc which is a member of the group 12 of the periodic table. The oxidation state of zinc in most compounds is the group oxidation state of +2. Zinc may be classified as a post-transition main group element with zinc(II). Zinc compounds are noteworthy for their nondescript behavior, they are generally colorless, do not readily engage in redox reactions, and generally adopt symmetrical structures.

References

  1. 1 2 3 Haynes, p. 4.95
  2. Haynes, p. 5.178
  3. Haynes, p. 4.131
  4. Haynes, p. 4.137
  5. Haynes, p. 4.144
  6. Wagenknecht, F.; Juza, R. (1963). "Zinc carbonate". In G. Brauer (ed.). Handbook of Preparative Inorganic Chemistry, 2nd Ed. Vol. 2. NY, NY: Academic Press. p. 1086.
  7. Effenberger, H.; Mereiter, K.; Zemann, J. (1981). "Crystal structure refinements of magnesite, calcite, rhodochrosite, siderite, smithonite, and dolomite, with discussion of some aspects of the stereochemistry of calcite type carbonates". Zeitschrift für Kristallographie - Crystalline Materials. 156 (3–4): 233–243. Bibcode:1981ZK....156..233E. doi:10.1524/zkri.1981.156.3-4.233.

Cited sources